Fibers and Yarns with Blocking Function

Abstract

A polymer composition comprising a polymer and at least one active substance selected from the group consisting of a substance generating an occlusion, in particular a substance generating an internal occlusion or a substance generating an external occlusion; a moisturizing substance; a substance reducing pain or itching; and mixtures of these.

Claims

1. A polymer composition comprising a polymer and at least one active substance selected from the group consisting of a substance generating an occlusion; a moisturizing substance; a substance reducing pain or itching; and mixtures of these.

2. The polymer composition according to claim 1, wherein the polymer is selected from the group consisting of cellulose, modified cellulose, polyamide, polyacrylic, polyester, polyurethane, polyethylene, polypropylene, modifications of these, derivatives of these and mixtures of these.

3. A polymer composition according to claim 1, wherein the at least one active substance is a nonpolar substance.

4. A polymer composition according to claim 3, wherein the at least one active substance generating an internal occlusion is a fatty acid derivative.

5. A polymer composition according to claim 1, wherein the at least one active substance generates an external occlusion and is selected from the group consisting of higher molecular weight alkanoic acids, higher molecular weight alkenoic acids, higher molecular weight carbonates, and mixtures of these, in particular cetearyl isononanoate, dicaprylyl carbonate and mixtures of these.

6. A polymer composition according to claim 1, wherein the at least one moisturizing active substance is selected from the group consisting of glycerol, polyols, in particular panthenol, and urea.

7. A polymer composition according to claim 6, wherein the at least one moisturizing active substance is glycerol.

8. A polymer composition according to claim 1, wherein the substance reducing pain or itching is a fatty acid amide compound, or a modification thereof or a derivative thereof, a flavonoid, or a modification thereof or a derivative thereof.

9. A polymer composition according to claim 1, wherein the at least one active substance reducing pain or itching is selected from the group consisting of palmitoylethanolamine (PEA), stearoylethanolamide (SEA), oxerutin, troxerutin, and mixtures of these.

10. The polymer composition according to claim 1, wherein the polymer composition is in the form of a formed body.

11. The polymer composition according to claim 10, wherein the formed body is a fiber.

12. The polymer composition according to claim 11, wherein the fiber is selected from the group consisting of a staple fiber, a monofilament, a multifilament or a continuous multifilament.

13. The polymer composition according to claim 10, wherein the formed body comprises threads or textile surfaces.

14. The polymer composition according to claim 13, wherein the thread comprises a formed body.

15. The polymer composition according to claim 13, wherein the polymer composition comprises a non-woven material including a formed body.

16. The polymer composition according to claim 13, comprising a clothing article or medical resource including a formed body.

17. A method of using a polymer composition according to claim 1, comprising adding the polymer composition in a sports resource or in a medical resource for skin care.

18. The polymer composition according to claim 14, wherein the thread comprises a non-woven material.

19. The polymer composition according to claim 14, wherein the threat comprises a clothing article or medical resource.

20. The polymer composition according to claim 4, wherein the fatty acid derivative is selected from the group consisting of isostearyl isostearate, isopropyl palmitate, and mixtures of these.

21. The polymer composition according to claim 5, wherein the at least one active substance is selected from the group consisting of cetearyl isononanoate, dicaprylyl carbonate and mixtures of these.

22. The polymer composition of claim 13, wherein the threads or textile surfaces comprise non-woven fabric.

Description

[0028] Examples of polycondensation and polymerization polymers are polyamides that are substituted with methyl, hydroxy or benzyl groups, for example. Examples of polyurethanes are those that are synthesized on the basis of polyether polyols.

[0029] According to the invention, the polymer composition thus includes at least one active substance, wherein the active substance may be a substance generating an occlusion, in particular a substance generating an internal occlusion or a substance generating an external occlusion; a substance contributing moisture; or a substance reducing pain or itching; or mixtures of these.

[0030] The at least one active substance is preferably incorporated into the polymer composition, and in particular is not applied onto the substrate matrix via impregnation or coating.

[0031] The polymer composition preferably includes at least one active substance generating an occlusion, in particular a substance generating an internal occlusion or a substance generating an external occlusion.

[0032] In connection with the present invention, what is understood by occlusion is the prevention or reduction of water loss through the skin to the environment, for example to a textile padding.

[0033] In addition to further important functions, the human skin protects against assaults from the environment. To maintain its protective function, it is essentially important to avoid the loss of water from the lower layers of skin.

[0034] The structure of human skin is divided in three components, namely the epidermis, the dermis and the subcutis. With their keratin filaments, the outer layers of the stratum corneum of the epidermis play a particular role in the water content of the skin. The keratin fibrous scaffold thus can hold considerable quantities of water. The target and point of application of the external occlusive effect of a corresponding substance is the epidermis. The major effect—namely the suppression of an escape of water (trans-epidermal water loss) from the stratum corneum—deploys via application of such a substance onto the skin surface. A film that prevents the escape of moisture is formed via these substances. Given the outer occlusion, water may thus move up from the lower layers and fill the keratin fibrous scaffold of the outer epidermis with moisture. The stratum corneum thereby protects against drying out. Elasticity and flexibility of the skin are maintained, and the skin achieves its physiological equilibrium for protection, for example against fungal infection. This occlusive mode of action of an active substance is also designated as external occlusion.

[0035] Internal occlusion designates a change to the skin lipid configuration in the stratum corneum. In the hexagonal configuration, the hydrocarbon chains of the lipid may rotate freely about their axis. This phase of “loose packing” achieves a more porous, thus permeable, structure and facilitates an unwanted release of water in the stratum corneum under stress, with corresponding disadvantageous consequences, such as dry skin. Given the inner occlusion, a denser ortho-rhombic packing of the lipids is generated via the action of specific active substances. This arrangement leads to a more rigid structure. Due to the “ortho-rhombic packing” of the lipids, such a molecular action produces significantly less permeability of the skin barrier, and thus significantly reduces the water loss from the stratum corneum.

[0036] In one embodiment, the at least one active substance generates an internal occlusion.

[0037] The at least one active substance generating an internal occlusion is preferably a fatty acid derivative. The fatty acid derivative is preferably selected from the group consisting of isostearyl isostearate, isopropyl palmitate, and mixtures of these. The fatty acid derivative is preferably isostearyl isostearate. Alternatively, the fatty acid derivative is preferably isopropyl palmitate.

[0038] In an alternative embodiment, the at least one active substance generates an external occlusion.

[0039] The at least one active substance generating an external occlusion is preferably selected from the group consisting of higher molecular alkanoic acids, higher molecular alkenoic acids, higher molecular carbonates, and mixtures of these. The at least one active substance generating an external occlusion is preferably selected from the group consisting of cetearyl isononanoate, dicaprylyl carbonate, and mixtures of these. The active substance is preferably cetearyl isononanoate. The active substance is preferably dicaprylyl carbonate.

[0040] In an alternative embodiment, the at least one active substance is a substance contributing moisture.

[0041] The at least one moisturizing active substance is preferably selected from the group consisting of glycerin, polyols, in particular panthenol, and other moisturizing substances such as urea. The at least one moisturizing active substance is preferably glycerol (propane-1,2,3-triol).

[0042] The at least one active substance reducing pain or itching is preferably a fatty acid amide compound, a modification thereof or a derivative thereof, or a flavonoid, a modification thereof or a derivative thereof.

[0043] The at least one active substance reducing pain or itching is preferably selected from the group consisting of palmitoylethanolamine (PEA), stearoylethanolamide (SEA), oxerutin, troxerutin, and mixtures of these.

[0044] The at least one active substance reducing pain or itching is preferably an N-acylethanolamine (NAE).

[0045] The at least one active substance reducing pain or itching is preferably a palmitoylethanolamine (PEA) or stearoylethanolamide (SEA).

[0046] The naturally occurring fatty amides PEA and its homologs, such as the closely related SEA, exhibit very good anti-inflammatory properties. They are thus used as lipid components in cosmetic formulations such as, for example, anti-dry scalp shampoo products. However, these substances are also used against influenza viruses, common cold illnesses, respiratory illnesses and rheumatic fever. The substances are also administered as an oral administration with pain-relieving property. These substances generally demonstrate an itch-reducing, pain-relieving and anti-inflammatory effect. The human epidermis may be irritated by both harmful environmental influences and continuous irritations; for example, it may be attacked by textile surfaces. The subjective sensation of itching and pain arises as a result of this. The active physiological mechanism may be explained as follows: pain and inflammation stimuli (triggered by a textile surface, for example) strike receptors for pain relaying, and the activation of the inflammation receptors of the mast cells leads to the discharge of strongly inflammatory histamines. The result is, first, the triggering of pain sensation due to relaying from the sensory nerve fibers of the skin to the relevant areas of the brain. Second, the release of the inflammatory substances in the epidermis leads to an itching, reddening and dryness of the skin. The assault by PEA and its homologs achieves palliation at the molecular level, due to two mechanisms: on the one hand, PEA and its homologs are mast cell modulators. The histamine release by the mast cells is blocked by increased PEA concentrations at the site of the inflammation. On the other hand, PEA and its homologs have a high affinity to the receptors responsible for pain and inflammation. This leads to a suppression of the corresponding irritation signaling. If acting on affected skin areas, PEA and its homologs thus show an anti-inflammatory, calming effect on dry, itchy and irritated skin.

[0047] The at least one active substance reducing pain or itching is preferably a flavonoid, a modification thereof or a derivative thereof. The at least one active substance reducing pain or itching is preferably a rutin, a modification thereof or a derivative thereof.

[0048] The at least one active substance reducing pain or itching is preferably rutin, oxerutin or troxerutin, a modification thereof or a derivative thereof. The at least one active substance reducing pain or itching is preferably troxerutin, a modification thereof or a derivative thereof. The at least one active substance reducing pain or itching is preferably troxerutin.

[0049] Troxerutin is a vegetable substance from the flavonoid group and is used for treating illnesses that are accompanied by an increased permeability of the blood vessels. Venous illnesses that are accompanied by water retention in tissue, i.e. edemas, are to be cited here. Belonging among these are, for example, surface venous inflammations or varicose veins, as well as venous weakness during pregnancy. Rutins, for example troxerutin, are also applied to open leg wounds, chronic venous insufficiency and given heavy, tired legs or leg cramps that are to be attributed to a blockage of the leg veins. In addition to a damage to the inner vessel walls, blood clots, blockages and inflammation arise given congestion in the veins. Inner vessel wall damage is caused by substances that release white blood cells during inflammation. Troxerutin prevents the release of these substances and thus stabilizes the permeable vessel walls of the blood capillaries. These are sealed such that fluid can no longer exit them. Moreover, troxerutin improves the flow properties of the blood in that it makes the red blood cells more elastic and has a slightly anti-coagulative effect. Given congestions in the veins, the sum of these effects contributes to less water escaping into the surrounding tissue and forming edemas. Symptoms of these venous illnesses, such as pain and a feeling of heaviness in the legs, are alleviated in this way via the application of troxerutin.

[0050] In an alternative embodiment, the polymer composition includes at least one active substance generating an occlusion, in particular a substance generating an internal occlusion or a substance generating an external occlusion, and at least one active substance reducing pain or itching.

[0051] In an alternative embodiment, the polymer composition includes at least one moisturizing active substance and at least one active substance reducing pain or itching.

[0052] In an alternative embodiment, the polymer composition includes at least one active substance generating an occlusion, in particular a substance generating an internal occlusion or a substance generating an external occlusion, and at least one moisturizing active substance.

[0053] In an alternative embodiment, the polymer composition includes at least one active substance generating an occlusion, in particular a substance generating an internal occlusion or a substance generating an external occlusion; at least one active substance reducing pain or itching; and at least one moisturizing active substance.

[0054] The present invention also concerns a formed body or a plurality of formed bodies comprising a polymer composition according to the invention.

[0055] One advantage of the formed body according to the invention in which the additives according to the invention are comprised is the uniform incorporation of the active substances into the formed body, in particular into the fiber matrix, given different fiber cross sections that can be produced. Processing as a monofilament thread or continuous filament thread is in this respect also possible, facilitating its use for technical articles.

[0056] The formed body according to the invention may be used for the most varied purposes.

[0057] The formed body is preferably a fiber. The fiber is preferably a staple fiber, a monofilament, a multifilament or a continuous multifilament.

[0058] In particular if the fiber is a cellulose fiber, for example, it can be constructed as shown in FIGS. 1 and 2 of DE 10 2007 054 702 A1. The at least one active substance may be present in the form of dispersed inclusions in a matrix, in particular a cellulose matrix.

[0059] The at least one active substance is preferably stabilized with at least one hydrophobic thickening agent.

[0060] In particular, if a textile surface is produced from the fibers according to the invention, this may not only be comprised of the fibers according to the invention but may also include additional components, for example wool, lyocell, rayon, carbacell, polyester, polyamide, cellulose acetate, acrylate, polypropylene, or mixtures of these.

[0061] The present invention also concerns the use of a formed body according to the invention for the production of threads.

[0062] The present invention also concerns a thread including a formed body according to the invention. The present invention also concerns a thread including the formed bodies according to the invention as a basic component. The present invention also concerns a thread comprised of formed bodies according to the invention.

[0063] The present invention also concerns a non-woven material including a formed body according to the invention. The present invention also concerns a non-woven material including a thread according to the invention.

[0064] The present invention also concerns a clothing article or a medical resource including a formed body according to the invention or a thread according to the invention. These are preferably clothing articles or medical resources that, at least in part, rest directly on the skin when worn.

[0065] The present invention also concerns a clothing article including a formed body according to the invention or a thread according to the invention. The clothing article is preferably underclothes, in particular underpants, an undershirt or a stocking. Alternatively, the clothing article may also be a glove.

[0066] The present invention also concerns a medical resource including a formed body according to the invention or a thread according to the invention. The medical resource is preferably a compression stocking or a bandage.

[0067] The present invention also concerns a sport bandage and other sport resources including a formed body according to the invention or a thread according to the invention.

[0068] The present invention also concerns the use of a polymer composition according to the invention or a formed body according to the invention in a clothing article, in a sport resource or in a medical resource for skin care.

[0069] The present invention also concerns the use of a polymer composition according to the invention or a formed body according to the invention in a clothing article, in a sport resource or in a medical resource to prevent skin from drying out.

[0070] The present invention also concerns the use of a polymer composition according to the invention or a formed body according to the invention in a clothing article, in a sport resource or in a medical resource, to reduce pain and/or itching, in particular given damaged skin and skin diseases such as atopic dermatitis. At the same time, a drying out of the skin is thereby preferably reduced or prevented.