SURFACE-MODIFIABLE INJECTION-MOLDED BODY AND METHOD FOR ITS PRODUCTION

Abstract

The present disclosure relates to a surface-modifiable injection-molded body comprising a thermoplastic polymer matrix and second polymer material at least in parts, in which the polymer matrix and the second polymer material have different weight average molecular weights and polarities, and the second polymer material is an adhesive. The present disclosure also relates to a method for its production.

Claims

1-11. (canceled)

12. A surface-modifiable injection-molded body, comprising: a surface having a first surface tension; a thermoplastic polymer matrix having a first weight average molecular weight and a first polarity; and a second polymer material at least in regions of the injection-molded body, the second polymer material having a second weight average molecular weight that is lower than the first weight average molecular weight and a second polarity that is higher than the first polarity, wherein the second polymer material is configured to function as an adhesive; wherein the thermoplastic polymer matrix and the second polymer material are configured to at least partly enter into a phase separation when exposed to heat, the second polymer material accumulating on the surface of the injection-molded body, the surface having a second surface tension greater than the first surface tension.

13. The surface-modifiable injection-molded body according to claim 1, wherein the thermoplastic polymer matrix is selected from the group consisting of acrylonitrile-butadiene styrene (ABS), styrene acrylonitrile (SAN), polystyrene (PS), polycarbonate (PC), polyethylene (PE), polypropylene (PP), polyamide (PA), or mixtures thereof.

14. The surface-modifiable injection-molded body according to claim 1, wherein the thermoplastic polymer matrix is one of fiber-reinforced or unreinforced.

15. The surface-modifiable injection-molded body according to claim 1, wherein the second polymer material is a functionalized thermoplastic polyolefin elastomer (POE), an olefin block copolymer (OBC), or a mixture thereof.

16. The surface-modifiable injection-molded body according to claim 1, wherein the second polymer material is capable of being melted and re-solidified.

17. The surface-modifiable injection-molded body according to one of claim 1, wherein the injection-molded body contains a 5-40% proportion by mass of the second polymer material.

18. The surface-modifiable injection-molded body according to claim 1, wherein the injection-molded body contains a 10-30% or 10-25% proportion by mass of the second polymer material.

19. The surface-modifiable injection-molded body according to claim 1, wherein the second polymer material has an average molecular weight of 11,000 to 37,000 g/mol.

20. The surface-modifiable injection-molded body according to claim 1, wherein at least one of the thermoplastic polymer matrix or the second polymer material comprises additives configured to being coupled by microwave treatment.

21. The surface-modifiable injection-molded body according to claim 20, wherein the additives comprise at least one of carbon fibers, carbon nanotubes, or graphene.

22. A method for the production of a surface-modified molded body, the method comprising: providing a mixture comprising a thermoplastic polymer matrix and a second polymer material, the thermoplastic polymer matrix having a first weight average molecular weight and a first polarity and the second polymer material having a second weight average molecular weight that is lower than the first weight average molecular weight and a second polarity that is higher than the first polarity, wherein the second polymer material is configured to function as an adhesive; injection molding the mixture into an injection-molding tool to form an injection-molded body, the thermoplastic polymer matrix and the second polymer material being statistically distributed in the mixture; removing the molded body from the injection-molding tool; melting and re-solidifying the injection-molded body, the thermoplastic polymer matrix and the second polymer material at least partly entering into a phase separation such that the second polymer material accumulates on a surface of the injection-molded body; and adhering the injection-molded body to a first component, the second polymer material bonding the injection-molded body to the first component.

23. The method according to claim 22, further comprising: heating and cooling the injection-molded body at least in parts under gradient control to selectively accumulate the second polymer material on at least part of a predetermined surface of the injection-molded body.

24. The method according to claim 22, further comprising: heating and cooling the injection-molded body at least in parts under gradient control to selectively accumulate the second polymer material on a visible surface of the injection-molded body; and adhering the visible surface of the injection-molded body to a flat decor part.

25. The method according to claim 22, wherein the thermoplastic polymer matrix is selected from the group consisting of acrylonitrile-butadiene styrene (ABS), styrene acrylonitrile (SAN), polystyrene (PS), polycarbonate (PC), polyethylene (PE), polypropylene (PP), polyamide (PA), or mixtures thereof.

26. The method according to claim 22, wherein the thermoplastic polymer matrix is one of fiber-reinforced or unreinforced.

27. The method according to claim 22, wherein the second polymer material is a functionalized thermoplastic polyolefin elastomer (POE), an olefin block copolymer (OBC) or a mixture thereof.

28. The method according to claim 22, wherein the injection-molded body contains a 5-40% proportion by mass of the second polymer material.

29. The method according to claim 22, wherein the injection-molded body contains a 10-30% or 10-25% proportion by mass of the second polymer material.

30. The method according to claim 22, wherein the second polymer material has an average molecular weight of 11,000 to 37,000 g/mol.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0061] Individual embodiments of the injection-molded body and/or its production and use are explained in greater detail below with reference to the drawings.

[0062] FIG. 1 shows a schematic representation of a surface-modifiable injection-molded body according to the present disclosure, with a thermoplastic polymer matrix and a second polymer material at least in parts;

[0063] FIG. 2 shows a schematic representation of the structural change and/or phase separation of a surface-modifiable injection-molded body when subjected to heat; and

[0064] FIG. 3 shows a schematic representation of the adhesion of a heated surface-modified injection-molded body to a decor part.

[0065] FIG. 1 shows the general structure of the injection-molded body 1 during the injection molding includes a thermoplastic polymer matrix 2, shown as large tangled knots. The matrix may consist of acrylonitrile-butadiene styrene (ABS), styrene acrylonitrile (SAN), polystyrene (PS), polycarbonate (PC), polyethylene (PE), polypropylene (PP), polyamide (PA), in each case reinforced with fibers or unreinforced, or mixtures thereof.

[0066] Integrated into this matrix are the products “Infuse™” (Dow Chemical Company) olefin block copolymers (OBC) and/or “Affinity™” GA (Dow Chemical Company) polyolefin elastomers (POE), which form the tackifying component of the molded body and are depicted as small tangled knots. These may differ from the matrix material particularly by a lower average molecular weight and a comparatively high polarity.

[0067] Before and during the injection-molding process the thermoplastic polymer matrix 2 and the tackifying olefin block copolymers (OBC) and/or polyolefin elastomers (POE) are initially present in the injection-molding granulate as a largely homogenous mixture, and subsequently as a homogenous statistical mixture in the injection-molding material.

[0068] FIG. 2 illustrates the structural change in the surface-modifiable injection-molded body 1 when subjected to thermal influence, for example by heat or radiation, and subsequent cooling. Due to the low average molecular masses and densities of the olefin block copolymers (OBC) and the polyolefin elastomers, as well as their increased polarity relative to the matrix material, the olefin block copolymers (OBC) and the polyolefin elastomers move relatively freely within the polymer matrix 2 upon being heated. A thermodynamically controlled phase separation takes place during the cooling. The olefin block copolymers (OBC) and/or the polyolefin elastomers ideally accumulate on the colder tool parts and/or on the surface or surfaces of the injection-molded body 1.

[0069] FIG. 3 shows a schematic representation of how the hotmelt adhesive functionality of the olefin block copolymers (OBC) and/or thermoplastic polyolefin elastomers (POE) is utilized. They have now accumulated on the molded body surface, and the surface-modified injection-molded body 1 is heated and then adhered to a suitable decor part. The heating may take place by microwave treatment alone, preferably supported by integrated additives capable of being coupled by microwave treatment. In this manner, a separate application of adhesive is not necessary. The decor part is particularly an elastic, flat covering element, for instance of leather or artificial leather.