GEL/GEL COMPOSITION COMPRISING A UV-SCREENING AGENT

Abstract

A composition, in particular a cosmetic composition, for making up and/or caring for keratin materials, including at least one aqueous phase gelled with at least one non-starchy hydrophilic gelling agent; at least one oily phase gelled with at least one non-cellulose-based lipophilic gelling agent other than apolar hydrocarbon-based waxes with a melting point of greater than 75.0° C. and silicone polyamides; the phases forming therein a macroscopically homogeneous mixture; the composition also including at least one UV-screening agent.

Claims

1. Composition for making up and/or caring for keratin materials, comprising: at least one aqueous phase gelled with at least one non-starchy hydrophilic gelling agent, at least one oily phase gelled with at least one non-cellulose-based lipophilic gelling agent other than apolar hydrocarbon-based waxes with a melting point of greater than 75.0° C. and silicone polyamides; said phases forming therein a macroscopically homogeneous mixture; said composition also comprising at least one UV-screening agent.

2. Composition according to claim 1, in which said non-starchy hydrophilic gelling agent is chosen from synthetic polymeric gelling agents, mixed silicates and fumed silicas, non-starchy polymeric gelling agents that are natural or of natural origin, and mixtures thereof.

3. Composition according to claim 2, in which the hydrophilic gelling agent is a synthetic polymeric gelling agent.

4. Composition according to claim 3, in which the synthetic polymeric hydrophilic gelling agent is chosen from crosslinked ammonium acrylamido-2-methylpropanesulfonate polymers, copolymers of AMPS° and of hydroxyethyl acrylate, and crosslinked (meth)acrylic acid homopolymers.

5. Composition according to claim 1, in which the lipophilic gelling agent is chosen from organopolysiloxane elastomers, semicrystalline polymers, dextrin esters, hydrocarbon-based polyamides, block hydrocarbon-based copolymers, particulate gelling agents chosen from polar waxes, hydrocarbon-based apolar waxes with a melting point of less than or equal to 75.0° C., silicone waxes, modified clays, silicas, and also mixtures thereof.

6. Composition according to claim 5, in which the lipophilic gelling agent is chosen from semicrystalline homopolymers or copolymers bearing at least one crystallizable side chain and semicrystalline homopolymers or copolymers bearing at least one crystallizable block in the backbone, hydrocarbon-based polyamides, hydrophobic silica aerogels, hectorites modified with a C.sub.10 to C.sub.22 ammonium salt.

7. Composition according to claim 6, in which the lipophilic gelling agent is chosen from hectorites modified with a C.sub.10 to C.sub.22 ammonium salt.

8. Composition according to claim 5, in which the lipophilic gelling agent is chosen from the following organopolysiloxane elastomers: dimethicone crosspolymer, vinyl dimethicone crosspolymer, dimethicone/vinyl dimethicone crosspolymer, dimethicone crosspolymer-3, vinyl dimethicone/methicone silsesquioxane crosspolymer, phenyl vinyl dimethicone crosspolymer.

9. Composition according to claim 1, comprising at least one non-starchy hydrophilic gelling agent chosen from crosslinked and/or neutralized 2-acrylamido-2-methylpropanesulfonic acid (AMPS®) copolymers, and at least one non-cellulose-based lipophilic gelling agent chosen from hectorites modified with a salt, at least one UV-screening agent.

10. Composition according to claim 1, in which the UV-screening agent(s) are chosen from water-soluble organic UV-screening agents, liposoluble organic UV-screening agents, and mixtures thereof.

11. Composition according to claim 1, in which the UV-screening agent(s) are totally or partly present in the gelled aqueous phase or are totally or partly present in the gelled oily phase.

12. Composition according to claim 1, containing the gelled aqueous and oily phases in an aqueous phase/oily phase weight ratio of from 95/5 to 5/95.

13. Composition according to claim 1, also comprising at least solid particles.

14. Composition according to claim 1, also comprising volatile and/or non-volatile silicone oils.

15. Composition according to claim 1, also comprising at least one moisturizer.

16. Process for preparing a composition for making up and/or caring for keratin materials, comprising at least one step of mixing: an aqueous phase gelled with at least one non-starchy hydrophilic gelling agent; and at least one oily phase gelled with at least one non-cellulose-based lipophilic gelling agent other than apolar hydrocarbon-based waxes with a melting point of greater than 75.0° C. and silicone polyamides; said phases forming therein a macroscopically homogeneous mixture; said composition also comprising at least one UV-screening agent.

17. Process according to claim 16, comprising a step of mixing at least two gelled phases.

18. Process according to claim 16, in which the mixing is performed at room temperature.

19. Cosmetic process for making up and/or caring for keratin materials and/or keratin fibers, comprising at least one step which consists in applying to said keratin material a composition as defined according to claim 1.

20. Cosmetic process for making up and/or caring for keratin materials and/or keratin fibers, comprising at least the application to said keratin materials of a macroscopically homogeneous composition obtained by extemporaneous mixing, before application or at the time of application to said keratin material, of an aqueous phase gelled with at least one non-starchy hydrophilic gelling agent; and at least one oily phase gelled with at least one non-cellulose-based lipophilic gelling agent other than apolar hydrocarbon-based waxes with a melting point of greater than 75.0° C. and silicone polyamides; and said composition also comprising at least one UV-screening agent.

21. Cosmetic process for limiting the darkening of the skin and/or improving the color and/or uniformity of the complexion, comprising the application, to the surface of the keratin material, of a composition as defined according to claim 1.

22. Cosmetic process for preventing and/or treating the signs of aging of a keratin material, comprising the application, to the surface of the keratin material, of a composition as defined according to claim 1.

Description

EXAMPLES

[1211] In the tables that follow, the amount of each compound is given as a weight percentage of raw material relative to the total weight of the composition.

[1212] The following formulations are prepared such that the following remain constant: [1213] the mass percentage of the oily phase, [1214] the mass percentage of the aqueous phase, [1215] the mass percentage of oily gelling agent, [1216] the mass percentage of aqueous gelling agent, [1217] the mass percentage of UV-screening agents.

[1218] All the other constituents of the formulations are present in the same mass percentage.

[1219] A/ First Series of Examples

[1220] Preparation of the Compositions

[1221] Preparation of the Lipophilic Phases L

[1222] The fatty phase is gelled with at least one oily gelling agent with or without organic or particulate screening agents.

[1223] In the compositions according to the invention, the fatty phase is gelled with Disteardimonium hectorite (Bentone 38 V) alone (Examples 1-2 and 9).

[1224] The comparative examples are, themselves, gelled either with ethylcellulose (Examples 3, 4, 10, 11 and 12) or with a high-melting apolar hydrocarbon-based wax, microcrystalline wax (Examples 5 and 6) or a silicone polyamide (Examples 7 and 8).

[1225] Procedure: In a first stage, all of the liposoluble screening agents and of the hot-soluble starting materials are weighed out in a beaker and dissolved with mechanical stirring at 80° C.

[1226] As soon as the solution of screening agents is macroscopically clear, the oily gelling agents are added with mechanical stirring using a “deflocculator”. As soon as the homogeneous gelled phase is obtained, the solvents are added with the same mechanical stirring. The gel obtained constitutes a homogeneous gel.

[1227] Preparation of the Hydrophilic Gels H

[1228] The components of the aqueous phase are weighed out in a beaker and stirred.

[1229] The aqueous phase is gelled with at least one aqueous gelling agent with or without organic or particulate screening agents.

[1230] In the compositions according to the invention, the aqueous phase is gelled with hydroxyethyl acrylate/sodium acryloydimethyl taurate copolymer—Sepinov EMT 10 (Examples 1 and 2) or with a Carbomer (Example 9).

[1231] The comparative examples are gelled either with hydroxyethyl acrylate/sodium acryloydimethyl taurate copolymer—Sepinov EMT 10 (comparative Examples 3 to 8) or with a Carbomer (Example 10 outside the invention) or with a poloxamer (Example 11 outside the invention) or sodium CMC (Example 12 outside the invention).

[1232] Procedure: The aqueous gelling agent is introduced into the aqueous solvents with stirring using a “deflocculator” at room temperature. The gel obtained constitutes a homogeneous gel.

[1233] Gel/Gel Procedure

[1234] Since the lipophilic and hydrophilic phases are homogeneous, the gel/gel is prepared by mixing the two phases in a “kneader”-type mixer equipped with a tank and an axial paddle with moderate stirring for 4 minutes.

[1235] The final gel is characterized by a macroscopically homogeneous bicontinuous dispersion.

[1236] Properties Tested

[1237] Observation of the macroscopic appearance of the oily gel, of the aqueous gel and of the gel/gel is observed at:

[1238] t0, i.e. at the end of formulation, on exiting the tank;

[1239] t1, i.e. after two hours of leaving to stand at room temperature.

[1240] Compositions:

TABLE-US-00001 Example 2 Compounds Example 1 In Example 3 Example 4 INCI name In accordance accordance Comparative Comparative LIPOPHILIC Ethylhexyl salicylate 5 5 5 5 PHASE B sold under the name Neo Heliopan OS by Symrise Octocrylene sold under the 7 7 7 7 name Uvinul N539 T by BASF Butyl 3 3 3 3 methoxydibenzoylmethane sold under the name Avobenzone by MFCI Disteardimonium hectorite 5 5 — — sold under the name Bentone 38 VCG by Elementis Ethylcellulose sold under — — 5 5 the name Ethocel by Dow Chemicals Propylene carbonate sold 1.5 1.5 1.5 1.5 under the name Arconate propylene carbonate by Lyondell Octyldodecanol sold under 27.7 27.7 27.7 27.7 the name Eutanol G by Cognis Caprylyl glycol sold under 0.1 0.1 0.1 0.1 the name Dermasoft Octiol by Dr Straetmans Phenoxyethanol sold under 0.5 0.5 0.5 0.5 the name Sepicide LD by SEPPIC Disodium EDTA sold 0.2 0.2 0.2 0.2 under the name EDETA BD by BASF HYDROPHILIC Terephthalylidenedi- — 18 — 18 PHASE A camphorsulfonic acid (at 33% AM) sold under the name Mexoryl SX by Chimex Phenylbenzimidazole — 6 — 6 sulfonic acid sold under the name Eusolex 232 by Merck Triethanolamine sold — 6.75 — 6.75 under the name Triethanolamine by BASF Deionized water 39.9 9.15 39.9 9.15 Caprylyl glycol sold under 0.1 0.1 0.1 0.1 the name Dermasoft Octiol by Dr Straetmans Phenoxyethanol sold under 0.5 0.5 0.5 0.5 the name Sepicide LD by SEPPIC Glycerol sold under the 7 7 7 7 name Glycerine USP by VVF Hydroxyethyl 2.5 2.5 2.5 2.5 acrylate/sodium acryloydimethyl taurate copolymer sold under the name Sepinov EMT 10 by SEPPIC

[1241] Results:

[1242] For compositions 1 and 2 in accordance, the oily gel, the aqueous gel and the final gel/gel are always homogeneous at t0 and at t1.

[1243] However, [1244] as regards the comparative composition 3, the macroscopic appearance of the composition at t1 appears phase-separated and [1245] as regards the comparative composition 4, release of the oily gel at t1 and phase separation of the composition at t0 are observed.

TABLE-US-00002 Compounds Example 5 Example 6 Example 7 Example 8 INCI name Comparative Comparative Comparative Comparative LIPOPHILIC Ethylhexyl salicylate 5 5 5 5 PHASE B sold under the name Neo Heliopan OS by Symrise Octocrylene sold under the 7 7 7 7 name Uvinul N539 T by BASF Butyl 3 3 3 3 methoxydibenzoylmethane sold under the name Avobenzone by MFCI Microcrystalline Wax sold 5 5 — — under the name Microwax HW by Paramelt Nylon-611/dimethicone — — 5 5 copolymer sold under the name Dow Corning 2-8179 Gellant by Dow Corning Propylene carbonate sold 1.5 1.5 1.5 1.5 under the name Arconate propylene carbonate by Lyondell Octyldodecanol sold under 27.7 27.7 27.7 27.7 the name Eutanol G by Cognis Caprylyl glycol sold under 0.1 0.1 0.1 0.1 the name Dermasoft Octiol by Dr Straetmans Phenoxyethanol sold under 0.5 0.5 0.5 0.5 the name Sepicide LD by SEPPIC Disodium EDTA sold 0.2 0.2 0.2 0.2 under the name EDETA BD by BASF HYDROPHILIC Terephthalylidenedi- — 18 — 18 PHASE A camphorsulfonic acid (at 33% AM) sold under the name Mexoryl SX by Chimex Phenylbenzimidazole — 6 — 6 sulfonic acid sold under the name Eusolex 232 by Merck Triethanolamine sold — 6.75 — 6.75 under the name Triethanolamine by BASF Deionized water 39.9 9.15 39.9 9.15 Caprylyl glycol sold under 0.1 0.1 0.1 0.1 the name Dermasoft Octiol by Dr Straetmans Phenoxyethanol sold under 0.5 0.5 0.5 0.5 the name Sepicide LD by SEPPIC Glycerol sold under the 7 7 7 7 name Glycerine USP by VVF Hydroxyethyl 2.5 2.5 2.5 2.5 acrylate/sodium acryloydimethyl taurate copolymer sold under the name Sepinov EMT 10 by SEPPIC

[1246] Results:

[1247] For all the comparative compositions 5, 6, 7 and 8 during the study of the macroscopic appearance of the oily gel, a lump of said oily gel is observed from t0, accompanied for compositions 7 and 8 by the presence of surface oil.

[1248] In addition, phase separation of all of these comparative compositions is observed from t0.

TABLE-US-00003 Compounds Example 9 Example 10 Example 11 Example 12 INCI name In accordance Comparative Comparative Comparative LIPOPHILIC Ethylhexyl 7 7 7 7 PHASE B methoxycinnamate sold under the name Parsol MCX by BASF Disteardimonium hectorite 5 — — — sold under the name Bentone 38 VCG by Elementis Ethylcellulose sold under — 5 5 5 the name Ethocel by Dow Chemicals Propylene carbonate sold 1.5 — — — under the name Arconate propylene carbonate by Lyondell Caprylic/Capric 35.9 37.4 37.4 37.4 Triglyceride sold under the name Triglyceride C8/C10 by Stéarineries Dubois Caprylyl glycol sold under 0.1 0.1 0.1 0.1 the name Dermasoft Octiol by Dr Straetmans Phenoxyethanol sold under 0.5 0.5 0.5 0.5 the name Sepicide LD by SEPPIC HYDROPHILIC Deionized water 46.9 46.9 46.9 46.9 PHASE A Caprylyl glycol sold under 0.1 0.1 0.1 0.1 the name Dermasoft Octiol by Dr Straetmans Phenoxyethanol sold under 0.5 0.5 0.5 0.5 the name Sepicide LD by SEPPIC Carbomer sold under the 1.25 1.25 — — name Carbopol 980 Polymer by Ashland Triethanolamine sold 1.25 1.25 — — under the name Triethanolamine by BASF Synperonic PE/L 64-LQ- — — 2.5 — (CQ) sold under the name Ploxamer by Croda Sodium — — — 2.5 carboxymethylcellulose sold under the name Blanose by Ashland

[1249] Results

[1250] For composition 9 in accordance, the oily gel, the aqueous gel and the final gel/gel are always homogeneous at t1.

[1251] However, for the comparative compositions 10, 11 and 12, the macroscopic appearance of the composition at t1 appears phase-separated.

[1252] Only Examples 1, 2 and 9 in accordance with the invention lead to stable, homogeneous gel/gel compositions which also have a pleasant sensory aspect.

[1253] B Second Series of Examples (Comprising a Silicone Elastomer and a Silica Aerogel)

[1254] Compositions

TABLE-US-00004 Example 1 Example 2 In accordance Comparative Compounds (Gel/gel composition) (direct emulsion) LIPOPHILIC Homosalate 4 4 PHASE B sold under the name Neo Heliopan HMS PBF by Symrise Ethylhexyl salicylate 2 2 sold under the name Neo Heliopan OS by Symrise Octocrylene sold under the 5 5 name Uvinul N539 T by BASF Butyl 4 4 methoxydibenzoylmethane sold under the name Avobenzone by MFCI Bis-ethylhexyloxyphenol 2 2 methoxyphenyl triazine sold under the name Tinosorb S by BASF Ethylhexyl triazone sold 1 1 under the name Uvinul T150 by BASF Disteardimonium hectorite 2.69 2.69 sold under the name Bentone 38 VCG by Elementis Silyl silica sold under the 1 1 name DC V %-2270 Aerogel Fine Particles by Dow Corning Dimethicone sold under 7.1 7.1 the name DC Toray SH200 C Fluid 5cs by Dow Corning Dimethicone and 15.4 15.4 dimethicone crosspolymer (i.e. 2.4% Dimethicone (i.e. 2.4% Dimethicone sold under the name Dow Crosspolymer) Crosspolymer) Corning 9041 Silicone Elastomer Blend by Dow Corning Stearic acid sold under the — 1.5 name Radiacid 0461 by Oleon Glyceryl Stearate and — 1.5 PEG-100 stearate sold under the name Simulsol 165 by SEPPIC Denatured alcohol sold 5.31 5.31 under the name Ethanol SDA 40B 200 Proof by Sasol HYDROPHILIC Deionized water 38.35 38.35 PHASE A Disodium EDTA sold 0.2 0.2 under the name EDETA BD by BASF Caprylyl glycol sold under 0.7 0.7 the name Dermasoft Octiol by Dr Straetmans Phenoxyethanol sold under 0.2 0.2 the name Sepicide LD by SEPPIC Glycerol sold under the 6.6 6.6 name Glycerine USP by VVF Triethanolamine sold — 0.45 under the name Triethanolamine 99% by Dow Chemical Potassium cetyl phosphate — 1 sold under the name Amphisol K by DSM Nutritional Products Hydroxyethyl 4.45 — acrylate/sodium acryloydimethyl taurate copolymer sold under the name Sepinov EMT 10 by SEPPIC

[1255] Preparation of the Compositions

[1256] Preparation of the Lipophilic Phases L

[1257] The fatty phase is gelled with at least the aerogel, the oily gelling agent with or without organic or particulate screening agents.

[1258] In Example 1, the fatty phase is gelled with aerogel combined with Bentone 38 VCG. Example 2 outside the invention is also gelled with the same gelling agents, but it contains in addition surfactants to form the emulsion.

[1259] In a first stage, all of the lipophilic screening agents and of the hot-soluble raw materials are weighed out in a beaker and dissolved with mechanical stirring at 80° C.

[1260] As soon as the solution of screening agents is macroscopically clear, the oily gelling agents are added with mechanical stirring using a “deflocculator”. Once a homogeneous gelled phase is obtained, the solvents are added with the same mechanical stirring. The gel obtained is homogeneous.

[1261] Preparation of the Hydrophilic Phases H

[1262] The components of the aqueous phase are weighed out in a beaker and stirred.

[1263] The aqueous phase is gelled with at least one aqueous gelling agent with or without organic or particulate screening agents.

[1264] In Example 1, the aqueous phase is gelled with Sepinov EMT 10.

[1265] The aqueous gelling agent is introduced into the aqueous solvents with stirring using a “deflocculator” at room temperature. The gel obtained is homogeneous.

[1266] The aqueous phase of Example 2 outside the invention is not gelled with Sepinov EMT 10, but contains an equivalent mass percentage of surfactants and combined neutralizer.

[1267] Gel/Gel Procedure Example 1 in Accordance

[1268] The gel/gel is prepared by mixing the two phases in a “kneader”-type mixer equipped with a tank and an axial paddle with moderate stirring for 4 minutes.

[1269] The final gel is characterized by a macroscopically homogeneous bicontinuous dispersion.

[1270] Emulsion Preparation Method—Comparative Example 2

[1271] The emulsion is prepared by introduction of phase L into phase H with stirring using a rotor-stator homogenizer at a stirring speed of 4500 rpm for 20 minutes. The emulsion is cooled to room temperature.

[1272] The final emulsion is characterized by drops between 1 μm and 20 μm in size.

[1273] Measurements

[1274] The SPF, the PPD and the sensory analysis of these compositions 1 and 2 were measured.

[1275] Protocol for Evaluating In Vitro the Screening Efficiency (SPF)

[1276] The sun protection factor (SPF) is determined according to the “in vitro” method described by B. L. Diffey in J. Soc. Cosmet. Chem. 40, 127-133, (1989). The measurements were made using a UV-1000S spectrophotometer from the company Labsphere. Each composition is applied to a rough plate of PMMA, in the form of a homogeneous and even deposit in a proportion of 1 mg/cm.sup.2.

[1277] Protocol for Measuring the PPD In Vitro

[1278] The in vitro PPD index measurements were taken under the same conditions using a UV-1000S spectrophotometer from the company Labsphere. Each composition is applied to a rough plate of PMMA, in the form of a homogeneous and even deposit in a proportion of 1 mg/cm.sup.2.

[1279] The UV-A ppd index: “Persistent Pigment Darkening” action spectrum value is extracted.

[1280] The UVA PPD sun protection factor (UVAppd PF) is expressed mathematically by the ratio of the dose of UVA radiation necessary to reach the pigmentation threshold with the UV-screening agent (MPPDp) to the dose of UVA radiation necessary to reach the pigmentation threshold without UV-screening agent (MPPDnp).

[00001]${\mathrm{PFUVA}}_{\mathrm{PPD}}=\frac{\mathrm{MPPDp}}{\mathrm{MPPDnp}}$

[1281] Protocol for Evaluating the Sensory Properties of the Formulations on the Skin

[1282] The sensory properties of the formulations on the skin are evaluated by applying the formulation to a forearm in a proportion of 2 mg/cm.sup.2 and allowing a drying time equal to 2 minutes. The freshness is evaluated during the application, whereas the greasy and soft aspects are assessed after application, between the fingers and the surface of the forearm.

[1283] Results

[1284] Results

TABLE-US-00005 Example 1 Example 2 Property tested In accordance Comparative in vitro SPF 43.9 ± 4.8 21.3 ± 3.9 in vitro PPD 21.8 ± 2.1 10.4 ± 1.1 Sensory analysis Fresh on application, soft Greasier feel

[1285] These results show that composition 1 of the invention makes it possible to obtain a higher level of screening efficiency than composition 2 (direct emulsion), while at the same time showing an improved sensory aspect.

[1286] C Third Series of Examples (Comprising a Silicone Elastomer)

[1287] Non-Dyed Compositions

[1288] Preparation of the Compositions

[1289] Preparation of the Lipophilic Phases L

[1290] The fatty phase is gelled with the oily gelling agent.

[1291] Procedure

[1292] In a first stage, all of the lipophilic screening agents and of the hot-soluble raw materials are weighed out in a beaker and dissolved with mechanical stirring at 80° C.

[1293] As soon as the solution of screening agents is macroscopically clear, the oily gelling agents and the solvents are added with mechanical stirring using a “deflocculator”. The gel obtained is homogeneous.

[1294] Preparation of the Hydrophilic Phases H

[1295] The components of the aqueous phase are weighed out in a beaker and stirred.

[1296] The aqueous phase is gelled with at least one hydrophilic gelling agent.

[1297] Procedure

[1298] The hydrophilic gelling agent is introduced into the aqueous solvents with stirring using a “deflocculator” at room temperature. The gel obtained is homogeneous.

[1299] Gel/Gel Procedure

[1300] The gel/gel is prepared by mixing the two phases in a “kneader”-type mixer equipped with a tank and an axial paddle with moderate stirring for 4 minutes.

[1301] The final gel is characterized by a macroscopically homogeneous bicontinuous dispersion.

[1302] Measurements

[1303] The protocol for in vitro evaluation of the screening efficiency (SPF), the protocol for measuring the PPD in vitro and the protocol for evaluating the sensory properties of the formulations on the skin correspond to those described for series B above.

[1304] Evaluation of the Haze Effect of the Formulations in a Thin Film

[1305] Compositions 1 and 2 were spread to a thickness of 50 microns on a transparent film and the soft-focus effect of each composition was evaluated via a “Haze” measurement.

[1306] The “Haze” corresponds to the percentage of light scattered relative to the total transmittance according to standard ASTM D 1003 (Standard Test Method for Haze and Luminous Transmittance of Transparent Plastics).

[1307] Protocol for Evaluating the Homogeneity of the Film

[1308] The formulation is spread in the form of a 30 μm film onto a glass plate using a manual film spreader. The homogeneity of the formulation film is then evaluated by observation of the deposits by eye.

[1309] The notes applied are as follows:

[1310] “−” a nonuniform deposit, which is characterized by the presence of substantial holes visible to the naked eye;

[1311] “+” a homogeneous deposit;

[1312] “++” a very homogeneous deposit, which is characterized by a very small number of visible holes.

TABLE-US-00006 Example 1 Example 2 Compounds In accordance In accordance LIPO- Homosalate 4 4 PHILIC sold under the name Neo PHASE B Heliopan HMS PBF by Symrise Ethylhexyl salicylate 2 2 sold under the name Neo Heliopan OS by Symrise Octocrylene sold under the 7 7 name Uvinul N539 T by BASF Butyl 3 3 methoxydibenzoylmethane sold under the name Avobenzone by MFCI Silyl silica sold under the 1 1.13 name DC V %-2270 Aerogel Fine Particles by Dow Corning Disteardimonium hectorite 2.69 — sold under the name Bentone 38 VCG by Elementis Propylene carbonate sold 0.81 — under the name Arconate propylene carbonate by Lyondell Dimethicone sold under 8.8 1 the name DC Toray SH200 C Fluid 5cs by Dow Corning Dimethicone and 15.4 — dimethicone crosspolymer (i.e. 2.4% sold under the name Dow Dimethicone Corning 9041 Silicone Cross- Elastomer Blend by Dow polymer) Corning Dimethicone and — 15.4 Dimethicone crosspolymer (i.e. 2.0% sold under the name EL- Dimethicone 9240 Silicone Elastomer Cross- Blend by Dow Corning polymer) Denatured alcohol sold 4.5 — under the name Ethanol SDA 40B 200 Proof by Sasol HYDRO- Deionized water qs 100 qs 100 PHILIC Preserving agent 0.98 0.9 PHASE A Glycerol sold under the 6.6 6.6 name Glycerine USP by VVF Hydroxyethyl 2.25 2.25 acrylate/sodium acryloydimethyl taurate copolymer sold under the name Sepinov EMT 10 by SEPPIC

[1313] Results

TABLE-US-00007 Example 1 Property tested In accordance in vitro SPF 46 ± 8 in vitro PPD 20 ± 3 Haze on 50 μm films 87.7

[1314] Composition 1 has good photoprotective properties (level of screening efficiency) and also substantial haze.

[1315] In addition, composition 1 has freshness and velvety properties and also very satisfactory sensory and matt-effect properties.

[1316] For composition 2, only the homogeneity property of the film was tested.

TABLE-US-00008 Property tested Example 2 Homogeneity of the film (30 ++ μm), covering power

[1317] Composition 2 has very good homogeneity, which is reflected by a smooth appearance of the composition deposited, which is visible to the naked eye.

[1318] Tinted Compositions (Examples 3 to 9)

[1319] Foundation compositions are prepared according to the protocol below in accordance with the protocol for evaluating the homogeneity of the film, described above.

[1320] Preparation of the Compositions

[1321] Preparation of the Hydrophilic Phase H

[1322] The components of the aqueous phase are weighed out in a beaker and stirred with a Rayneri blender, at room temperature.

[1323] The aqueous gelling agent is added with stirring at room temperature. The stirring is adjusted so as not to incorporate air into the mixture. The mixture is stirred moderately for about 10 minutes at room temperature.

[1324] A homogeneous aqueous gel is obtained.

[1325] Preparation of the Lipophilic Phase L

[1326] The pigments are ground with the solvents of the lipophilic phase B using a three-roll mill. The ground material is then introduced into a beaker and stirred using a Rayneri blender at room temperature. The gelling agent is added with vigorous stirring at room temperature. The gel slowly thickens. The mixture is stirred vigorously for 10 minutes and the fatty phase is gelled with the oily gelling agent.

[1327] A homogeneous oily gel is obtained.

[1328] Preparation of the Foundation Formulation

[1329] The formulation is obtained by mixing the phases intended to form the foundation in accordance with the invention.

[1330] The aqueous and oily gels are weighed out and then mixed using a Rayneri blender with moderate stirring. The formulation is prepared from the weight proportions described in the formulations.

[1331] For the tinted compositions, only the homogeneity property of the film was tested.

TABLE-US-00009 Example 3 Example 4 Example 5 Compounds In accordance In accordance In accordance LIPOPHILIC Homosalate 4 4 4 PHASE B sold under the name Neo Heliopan HMS PBF by Symrise Ethylhexyl salicylate 2 2 2 sold under the name Neo Heliopan OS by Symrise Octocrylene sold under 7 7 7 the name Uvinul N539 T by BASF Iron oxides coated with 2.54 2.54 2.54 aluminum stearoyl glutamate (NAI-C33- 9001-10 sold by the company Miyoshi Kasei) Titanium dioxide 8.46 8.46 8.46 coated with aluminum stearoyl glutamate (NAI-TAO-77891 sold by the company Miyoshi Kasei) Disteardimonium — 3 — hectorite sold under the name Bentone 38 VCG by Elementis Silyl silica sold under — — 0.96 the name DC V %- 2270 Aerogel Fine Particles by Dow Corning Dimethicone and 7 7 7 Dimethicone (i.e. 0.9% (i.e. 0.9% (i.e. 0.9% crosspolymer sold Dimethicone Dimethicone Dimethicone under the name EL- Crosspolymer) Crosspolymer) Crosspolymer) 9240 Silicone Elastomer Blend by Dow Corning HYDROPHILIC Deionized water qs 100 qs 100 qs 100 PHASE A Preserving agent 0.7 0.7 0.7 Glycerol sold under the 6 6 6 name Glycerine USP by VVF Hydroxyethyl 2.4 2.4 2.4 acrylate/sodium acryloydimethyl taurate copolymer sold under the name Sepinov EMT 10 by SEPPIC

[1332] Results

TABLE-US-00010 Example 3 Example 4 Example 5 In accordance In accordance In accordance Homogeneity of + ++ ++ the film (30 μm), covering power

TABLE-US-00011 Example 6 Example 7 Example 8 Example 9 In In In In Compounds accordance accordance accordance accordance LIPOPHILIC Homosalate 4 4 4 4 PHASE B sold under the name Neo Heliopan HMS PBF by Symrise Ethylhexyl salicylate 2 2 2 2 sold under the name Neo Heliopan OS by Symrise Octocrylene sold under the 7 7 7 7 name Uvinul N539 T by BASF Iron oxides coated with 2.54 2.54 2.54 2.54 aluminum stearoyl glutamate (NAI-C33-9001- 10 sold by the company Miyoshi Kasei) Titanium dioxide coated 8.46 8.46 8.46 8.46 with aluminum stearoyl glutamate (NAI-TAO-77891 sold by the company Miyoshi Kasei) Dimethicone and 7 — — — dimethicone crosspolymer (i.e. 1.1% sold under the name Dow Dimethicone Corning 9041 Silicone Crosspolymer) Elastomer Blend by Dow Corning Diphenylsiloxy phenyl — 7 — — trimethicone 84% dimethicone/phenyl vinyl dimethicone crosspolymer 16% (KSG 18A sold by the company Shin-Etsu) Vinyl — — 7 — dimethicone/methicone silsesquioxane crosspolymer (KSP 100 sold by the company Shin-Etsu) Diphenyl dimethicone/vinyl — — — 7 diphenyl dimethicone/silsesquioxane crosspolymer (KSP 300 sold by the company Shin-Etsu) HYDROPHILIC Deionized water qs 100 qs 100 qs 100 qs 100 PHASE A Preserving agent 0.7 0.7 0.7 0.7 Glycerol sold under the 6 6 6 6 name Glycerine USP by VVF Hydroxyethyl 2.4 2.4 2.4 2.4 acrylate/sodium acryloydimethyl taurate copolymer sold under the name Sepinov EMT 10 by SEPPIC

[1333] Results

TABLE-US-00012 Example 6 Example 7 Example 8 Example 9 In accor- In accor- In accor- In accor- dance dance dance dance Homogeneity ++ ++ ++ ++ of the film (30 μm), covering power

[1334] Compositions 3 to 9 have very good homogeneity, which is reflected by a smooth appearance of the composition deposited, this property being visible to the naked eye.