ULTRAVIOLET LIGHT EMITTING DIODE AND METHOD OF MANUFACTURING THE SAME
20170309788 ยท 2017-10-26
Inventors
- Dong-Seon LEE (Gwangju, KR)
- Duk-Jo KONG (Gwangju, KR)
- Jun-Yeob LEE (Gwangju, KR)
- Mun-Do PARK (Gwangju, KR)
Cpc classification
H01L33/62
ELECTRICITY
H01L33/44
ELECTRICITY
H01L33/24
ELECTRICITY
H01L2933/0066
ELECTRICITY
International classification
H01L33/00
ELECTRICITY
H01L33/62
ELECTRICITY
Abstract
A sidewall light emitting ultraviolet light emitting diode and a method of manufacturing thereof are disclosed. A light emitting structure is formed in an active region recessed from a substrate surface, and the light emitting structure is formed by growth in a direction parallel to the surface of the substrate. Also, a reflective metal layer is formed above or below the light emitting structure such that ultraviolet light can be released in a second direction perpendicular to a first direction which is the growth direction of the light emitting structure.
Claims
1. An ultraviolet light emitting diode comprising: a substrate; an active region recessed from a surface of the substrate and exposing a lower surface and side surfaces of the substrate; an insulating material layer formed above the active region and on side surfaces of the active region and exposing a side surface of the active region; a light emitting structure having an n-type semiconductor layer, an active layer, and a p-type semiconductor layer grown in a first direction from the exposed portion of the side surface of the active region; a negative electrode formed on the n-type semiconductor layer; and a positive electrode formed on the p-type semiconductor layer.
2. The ultraviolet light emitting diode of claim 1, wherein the substrate comprises Al.sub.2O.sub.3, GaN, or AN.
3. The ultraviolet light emitting diode of claim 1, wherein the lower surface of the substrate and the side surfaces of the substrate are different materials.
4. The ultraviolet light emitting diode of claim 1, wherein the light emitting structure is formed in the active region.
5. The ultraviolet light emitting diode of claim 4, wherein the n-type semiconductor layer, the active layer, and the p-type semiconductor layer mainly have crystal growth in the c-axis direction.
6. The ultraviolet light emitting diode of claim 1, wherein the negative and the positive electrodes are formed in the same plane.
7. The ultraviolet light emitting diode of claim 1, further comprising a reflective metal layer between the lower surface of the substrate and the insulating material layer.
8. The ultraviolet light emitting diode of claim 7, wherein the reflective metal layer guides the direction of light formed in the active layer in a second direction perpendicular to the first direction.
9. The ultraviolet light emitting diode of claim 1, further comprising: an inter-layer insulating film formed on the light emitting structure, the negative electrode, and the positive electrode; and a reflective metal layer formed on the inter-layer insulating film and at a position corresponding to the active layer.
10. The ultraviolet light emitting diode of claim 9, further comprising: a first via contact through the inter-layer insulating film electrically connected to the negative electrode; and a second via contact through the inter-layer insulating film electrically connected to the positive electrode.
11. An ultraviolet light emitting diode comprising: an active region defined by a region recessed from a surface of a substrate; a light emitting structure formed in a first direction in the active region, having an n-type semiconductor layer and a p-type semiconductor layer, and forming ultraviolet light; a negative electrode electrically connected to the n-type semiconductor layer of the light emitting structure; and a positive electrode electrically connected to the p-type semiconductor layer, wherein the ultraviolet light is released in a second direction perpendicular to the first direction which is the direction in which the light emitting structure is formed.
12. The ultraviolet light emitting diode of claim 11, wherein electrons of the n-type semiconductor layer and holes of the p-type semiconductor layer are supplied to an active layer by moving parallel to the surface of the substrate.
13. A method of manufacturing an ultraviolet light emitting diode comprising: forming an active region recessed from a surface of a substrate through selective etching of the substrate; forming an insulating material layer exposing a sidewall of the active region and shielding the top of a protrusion of the substrate, a lower surface of the substrate, and the remaining sidewalls of the active region; forming a light emitting structure having an n-type semiconductor layer, an active layer, and a p-type semiconductor layer in a first direction parallel to the surface of the substrate with the insulating material layer at the terminal end of the growth from the exposed sidewall of active region; and forming a negative electrode on the n-type semiconductor layer and a positive electrode on the p-type semiconductor.
14. The method of manufacturing an ultraviolet light emitting diode of claim 13, further comprising forming a reflective metal layer on the lower surface of the active region after the forming of the active region.
15. The method of manufacturing an ultraviolet light emitting diode of claim 14, wherein the insulating material layer shields the reflective metal layer.
16. The method of manufacturing an ultraviolet light emitting diode of claim 13, further comprising removing the insulating material layer formed on top of the protrusion of the substrate by performing a planarizing process on the substrate after the forming of the light emitting structure.
17. The method of manufacturing an ultraviolet light emitting diode of claim 13, after the forming of the negative electrode and the positive electrode, further comprising: forming an inter-layer insulating material film on the negative electrode, the positive electrode and the light emitting structure exposed in a second direction perpendicular to the first direction; and forming a reflective metal layer on the inter-layer insulating material film.
18. The method of manufacturing an ultraviolet light emitting diode of claim 17, wherein the reflective metal layer is disposed at a position corresponding to the active layer in the second direction.
19. The method of manufacturing an ultraviolet light emitting diode of claim 17, further comprising forming a via contact through the inter-layer insulating film after the forming of the inter-layer insulating film.
20. The method of manufacturing an ultraviolet light emitting diode of claim 13, wherein the forming of the active region comprises: forming a compound semiconductor layer as the substrate on a growth substrate; and forming the active region recessed from the compound semiconductor surface through selective etching of the compound semiconductor layer.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0018]
[0019]
[0020]
[0021]
[0022]
MODE OF INVENTION
[0023] While the present invention may be modified in various ways and implemented in many forms, specific embodiments are described in the drawings and explained in detail. However, there is no intent to limit the present invention to the specific disclosure, and it should be understood that the present invention includes all modifications, equivalents, and alternatives included in the idea and technical scope thereof. In describing each of the drawings, like reference numerals are used to denote like elements.
[0024] Unless otherwise defined, all terms including technical and scientific terms used herein each have the same meaning generally understood by those of ordinary knowledge in the art to which the present invention belongs. Generally used terms, such as terms defined in dictionaries, should each be interpreted by a meaning consistent within the context of related technologies and should not be interpreted by an ideal or excessively formal meaning unless clearly defined so in the present invention.
[0025] Hereinafter, exemplary embodiments of the present invention are described in further detail with references to accompanying drawings.
First Embodiment
[0026]
[0027] Referring to
[0028] Also, the substrate 100 may be a particular membrane formed on an arbitrary substrate. For example, the substrate 100 may be a GaN layer formed on a sapphire substrate.
[0029] Also, the substrate 100 is not provided as a smooth substrate and is provided with an active region 105 defined therein. The active region 105 refers to a region recessed from a surface of the substrate 100, and the light emitting structure 130 is formed in the active region 105. That is, compound semiconductor crystal growth occurs in the active region 105 recessed from the surface of the substrate 100. Also, it is preferable that the crystal growth direction is the first direction parallel to the substrate.
[0030] The active region 105 defined by the recession from the surface of the substrate 100 exposes a surface of the substrate 100 as a lower surface and exposes a side surface of a protrusion of the substrate 100 as a side surface. Also, the lower surface and the side surface may be different materials. In the case of using a compound semiconductor layer formed on a growth substrate as the substrate 100, the side surface of the substrate 100 may include the compound semiconductor layer as long as the surface of the growth substrate is exposed by selective etching of the compound semiconductor layer.
[0031] The reflective metal layer 110 is provided on the substrate 100. In particular, the reflective metal layer 110 is formed on the lower surface of the active region 105 and is formed in the recessed portion of the substrate 100. Ultraviolet light formed in the light emitting structure 130 is released in a second direction due to the reflective metal layer 110.
[0032] The reflective metal layer 110 may be Cr, Ag, or an alloy thereof and may be any material that can function as a light reflector.
[0033] The insulating material layer 120 is provided on the reflective metal layer 110. The insulating material layer is formed on the lower surface of the active region 105, and a portion of the insulating material layer 120 is formed on the sidewall of the active region 105. The insulating material layer 120 may include SiO.sub.2 or SiN and may be any material that can retain form and material properties without fusing into other materials during a formation process of the light emitting structure 130.
[0034] Also, the insulating material layer 120 is formed such that a portion of the sidewall of the substrate 100 that defines the active region 105 is exposed.
[0035] The light emitting structure 130 is formed on the insulating material layer 120. The light emitting structure 130 is grown such that growth is in the first direction which is parallel to the substrate 100. The light emitting structure 130 grown in the first direction contacts a sidewall of the substrate 100 in one direction along the first direction and contacts the insulating material layer 120 in the other direction along the first direction.
[0036] The light emitting structure 130 has an n-type semiconductor layer 131, an active layer 132, a p-type junction layer 133, and a p-type semiconductor layer 134.
[0037] The n-type semiconductor layer 131 may be AlGaN, and Si may be used as a dopant. The n-type semiconductor layer 131 is formed using a conventional MOCVD process, TMAl is used as a precursor of Al, TMGa is used as a precursor of Ga, NH.sub.3 is used as a precursor of N, and SIH.sub.4 is used as a precursor of Si. In particular, the n-type semiconductor layer 131 may be formed from the inside sidewall of the substrate that define the active region 105, and a buffer layer or another functional membrane may be inserted between the sidewall of the substrate 100 and the n-type semiconductor layer 131 according to embodiments.
[0038] The active layer 132 is provided on the side surface extending in the first direction of the n-type semiconductor layer 131. The active layer 132 preferably has a multiple quantum well structure. Accordingly, the active layer 132 may include AlInGaN or AlGaN. The active layer 132 may be formed using a conventional MOCVD process, TMAl is used as a precursor of Al, TMIn is used as a precursor of In, TMGa is used as a precursor of Ga, and NH3 is used as a precursor of N. For forming the well layers, Al or In fraction is adjusted. That is, because the bandgap between the conduction band and the valance band varies depending on Al or In fraction, Al or In fraction is adjusted according to the wavelength of the intended ultraviolet light. Also, the barrier layers have a smaller Al or In fraction compared to the well layers.
[0039] The p-type junction layer 133 is provided on the side surface extending in the first direction of the active layer 132. The p-type junction layer 133 preferably is AlGaN. In particular, it is preferable that the active layer 132 is grown in the c-axis direction during crystal growth and that the side surface of the grown active layer 132 is exposed. Accordingly, the n-type semiconductor layer 131, the active layer 132, and the p-type junction layer 133 also may be grown in the c-axis direction. Accordingly, the p-type junction layer 133 growth is accomplished from the exposed terminal end of the growth in the first direction of the active layer 132. For forming the p-type junction layer 133, Mg is used as a dopant during crystal growth of AlGaN. Cp2Mg(Bis(cyclopentadienyl) magnesium) may be used as a precursor of the Mg dopant. However, even with Mg doping achieved, hole density is small in the p-type junction layer 133, and thus the holes contribute little to light emitting action.
[0040] The p-type semiconductor layer 134 is formed at the terminal end of the extension in the first direction of the p-type junction layer 133. The p-type semiconductor layer 134 is preferably GaN and with Mg used as a dopant. The p-type semiconductor layer 134 is extended in the first direction and is formed between the p-type junction layer 133 and the insulating material layer 120. Also, the p-type junction layer 133 has a form in which growth is in the first direction which is the c-axis direction and is formed to contact the insulating material layer 120 formed on the sidewall of the active region 105.
[0041] Also, an electron blocker layer may be provided between the active layer 132 and p-type junction layer 133 according to embodiments. The electron blocker layer prevents electrons introduced in the first direction towards the active layer 132 from overflowing to the p-type junction layer 133. For this, the electron blocker layer may include AlN or AlGaN.
[0042] Also, the negative electrode 140 is formed in the second direction from the n-type semiconductor layer 131 of the substrate 100. That is, the negative electrode 140 is formed on the n-type semiconductor layer 131, the negative electrode 140 is electrically connected to the n-type semiconductor layer 131, and a portion of the negative electrode 140 may be formed extending over the substrate 100 according to embodiments.
[0043] The positive electrode 150 is formed in the opposite direction from the negative electrode 140 with the active region 105 in the center. The positive electrode 150 is electrically connected to the p-type semiconductor layer 134. For this, the positive electrode 150 is formed on the p-type semiconductor layer 134. Also, a portion of the positive electrode 150 may be formed extending over the substrate 100 according to embodiments.
[0044] In
[0045] Also, in
[0046]
[0047] Referring to
[0048] First, an etch mask is formed on a smoothly flat substrate surface. The etch mask may be formed by resist pattern formation in a process of applying a photoresist and subsequently exposing to light. The etch mask may be a hard mask including SiN, etc. When wet or dry etching is performed with the formed etch mask, substrate regions below the etch mask remain while other regions are etched. Through this, active region 105 recessed from the surface is formed. Also, the substrate 100 may refer to a particular membrane other than membranes that a person in the art considers as substrates for growing light emitting diodes. This is explained in
[0049] Referring to
[0050] Then, an etch mask is formed on the formed substrate 100 through a conventional photolithography process, and the active region 105 may be formed using the etch process described above.
[0051] Also, although it is indicated in
[0052] Referring to
[0053] In case of using a fine metal mask, the fine mask corresponding to the lower surface of the active region 105 is open, and the reflective metal layer 110 may be deposited through the open region.
[0054] Subsequently, the insulating material layer 120 is formed on the entire front surface of the substrate 100 on which the reflective metal layer 110 is formed. The insulating material layer 120 is preferably SiO.sub.2 or SiN. In particular, when the active layer 132 is formed using an MOCVD or an MOVPE process, any non-conductive and transparent material that does not result in the growth of the active layer 132 may be used as the insulating material layer 120. Through this, an insulating material layer 120 that shields the sidewall of the active region 105, the reflective metal layer 110, and the protrusion of substrate 100 is formed.
[0055] Referring to
[0056] Selective etching of the insulating material layer 120 may be accomplished by faceted etching. For example, when dry etching is performed with a facet angle less than 45 degrees from the surface of the substrate 100, the surface facing the direction of the etchant progression has increased level of etching, and, through this, a side surface of the active region 105 is exposed. Also, selective etching of the insulating material layer 120 may be accomplished through wet or dry etching using a photoresist pattern used as an etch mask. The photoresist pattern is formed in a pattern to open a portion of the sidewall of the active region 105, and, by etching the open region, a sidewall of the active region 105 may be exposed.
[0057] Referring to
[0058] Subsequently, the growth of the active layer 132 begins from the terminal end of the n-type semiconductor layer 131 grown in the first direction. The active layer 132 preferably has a multiple quantum well structure. The barrier and well layers of the active layer 132 preferably include AlInGaN or AlGaN.
[0059] Subsequently, the p-type junction layer 133 is formed through growth in the first direction on the terminal end of the growth of the active layer 132 grown in the first direction. The p-type junction layer 133 is AlGaN and has p-type conductivity due to using Mg as a dopant. The p-type junction layer 133 may accomplish relieving a lattice mismatch between the p-type semiconductor layer 134 and the active layer 132 grown later and may accomplish delivering holes supplied by the p-type semiconductor layer 134 to the active layer 132.
[0060] Also, the p-type semiconductor layer 134 is formed on the terminal end of the p-type junction layer 133 grown in the first direction. The p-type semiconductor layer 134 includes GaN, and Mg is used as a dopant. In particular, the p-type semiconductor layer 134 is grown in the first direction, and the growth ends at a sidewall of the protrusion of the substrate 100 protruding from the active region 105 or the insulating material layer 120 formed on a sidewall of the active region 105. Because the compound semiconductor growth is stopped by the insulating material layer 120, a light emitting structure 130 that fills the recessed space of the active region 105 is formed.
[0061] Subsequently, the insulating material layer 120 formed on the protrusion of the substrate 100 that defines the active region 105 is removed. While the removal of the insulating material layer 120 formed on the protrusion of the substrate 100 may be accomplished using a conventional etching process, it is preferred that Chemical Mechanical Polishing be used. This may be defined as a planarizing process.
[0062] For example, even in the case the light emitting structure 130 is mainly grown in the first direction, there may still be partial growth in the second direction.
[0063] The partial growth in the second direction causes a portion of the light emitting structure 130 to protrude higher than the protrusion of the substrate 100. There is an advantage in that this may be removed by Chemical Mechanical Polishing.
[0064] Through this, the active layer 132, the n-type semiconductor layer 131, and the p-type semiconductor layer 134 may be all exposed in the same plane.
[0065] Referring to
[0066] However, the negative electrode 140 and the positive electrode 150 are formed in the same plane. Also, according to embodiments, the negative electrode 140 may be formed extending over the n-type semiconductor layer 131 and the protrusion of the substrate 100, and the positive electrode 150 may be formed extending over the p-type semiconductor layer 134 and the protrusion of the substrate 100.
[0067] In the present invention, the light emitting structure 130 is grown in the first direction parallel to the surface formed by the substrate 100. Also, the growth in the first direction is limited within the active region 105 recessed from the surface of the substrate 100. Ultraviolet light generated in the light emitting structure 130 is reflected by the reflective metal layer 110 provided on the lower surface of active region 105 and released in the second direction. Also, the positive electrode 150 and the negative electrode 140 are provided in the second direction from the lower surface of the substrate 100. That is, the negative electrode 140 and the positive electrode 150 are provided in the side surface of the growth progression direction.
[0068]
[0069] Referring to
[0070] Also, the insulating material layer 120 is formed to surround the top of the reflective metal layer and the sidewall of the active region 105. However, the insulating material layer 120 exposes a portion of the sidewall of the protrusion of the substrate 100 or the active region 105. Crystal growth of the light emitting structure 130 is accomplished on the exposed sidewall of the substrate 100. Based on this, the n-type semiconductor layer 131, the active layer 132, the p-type junction layer 133, and the p-type semiconductor layer 134 that fill the active region 105 are formed.
[0071] The active region 105 may be formed in plurality, and the light emitting structure 130 that fill the active region 105 may also be formed in plurality. Also, the exposed surface of the light emitting structure 130 and the exposed surface of the substrate 100 are formed in the same plane. Accordingly, the negative electrode 140 and the positive electrode 150 electrically connecting each light emitting structure 130 may be formed in the same plane.
[0072] For example, as shown in
[0073] Also, the negative wiring is electrically connected to the negative contact pad 161, and the positive wiring is electrically connected to the positive contact pad 162.
[0074] Through the formed wiring structure, a plurality of light emitting structures 130 may simultaneously accomplish light emitting action, and convenience during packaging processing is increased.
Second Embodiment
[0075]
[0076] Referring to
[0077] In particular, the active region 205 defined by a recession from a surface of the substrate 200 exposes a surface of the substrate 200 as a lower surface and exposes a sidewall of a protrusion of the substrate 200 as a side surface. Also, the side surface and the front surface of the substrate 200 that define the active region 205 may be different materials. In the case of using a compound semiconductor layer formed on a growth substrate as the substrate 200, the side surface of the substrate 200 may include the compound semiconductor layer as long as the surface of the growth substrate is exposed by selective etching of the compound semiconductor layer.
[0078] A sidewall of the active region 205 contacts a light emitting structure 230, and an insulating material layer 220 is provided on other sidewalls and the lower surface of the active region 205. The insulating material layer 220 is preferably SiO.sub.2 or SiN.
[0079] Also, the recessed portion of the active region 205 is filled by the light emitting structure 230. The light emitting structure 230 may includes an n-type semiconductor layer 231 grown from the exposed sidewall of the substrate 200, an active layer 232, a p-type junction layer 233, and a p-type semiconductor layer 234, and the materials and formation method are identical to those explained in
[0080] Also, a negative electrode 240 is formed on the n-type semiconductor layer 231, and a positive electrode 250 is formed on the p-type semiconductor layer 234. The negative electrode 240 and the positive electrode 250 may be formed in the same plane.
[0081] Also, an inter-layer insulating film 260 is formed on the surface of the substrate 200 on which the negative contact 240 and the positive contact 250 are formed, and via contacts 271, 272 are formed through the inter-layer insulating film 260. That is, a first via contact 271 is electrically connected to the negative contact 240 and a second via contact 272 is electrically connected to the positive contact 250. In particular, the inter-layer insulating film 260 preferably is made of a transparent material and may include SiO.sub.2 or SiN.
[0082] A reflective metal layer 210 is formed on the inter-layer insulating film 260. The reflective metal layer 210 in
[0083]
[0084] Referring to
[0085] The insulating material layer 220 is formed using a conventional deposition process on the substrate 200 for which the active region 205 recessed from the surface of the substrate 200 is defined, and a sidewall of the protrusion of the active region 205 is exposed through a process including faceted etching, etc. on the substrate 200 on which the insulating material layer 220 is formed. Accordingly, the insulating material layer 220 shields the top surface of the protrusion of the substrate 200, the lower surface and a portion of the side surface of the active region 205 and exposes other side surfaces of the active region 205.
[0086] Referring to
[0087] Subsequently, a process of planarizing the insulating material layer 220 formed on the protrusion of the substrate 200 is performed. Through this, the protrusion of the substrate 200, a portion of the insulating material layer 220, and a side surface of the grown light emitting structure 230 are exposed in the second direction as shown in
[0088] Referring to
[0089] Referring to
[0090] Also, the reflective metal layer 210 may be formed extending over the inter-layer insulating film 260 and active layer 232. According to embodiments, the reflective metal layer 210 may be formed first, and then the via contacts 271, 272 are subsequently formed.
[0091] Electrons moving in the first direction and holes moving in the opposite direction become quantum confined in the active layer 232, and light emitting action is accomplished due to recombination thereof. Ultraviolet light generated in the active layer 232 is released in the opposite direction from the second direction towards the substrate 200 due to the reflective metal layer 210 formed on the substrate 200 along the second direction.
[0092] According to the present invention, generated ultraviolet light propagates in a direction toward the substrate due to the reflective metal layer formed on the surface facing the substrate with the light emitting structure in the center. Also, the negative electrode and the positive electrode may be formed in the same plane, thus increasing the level of convenience for contact formation.
[0093] Also, in the present invention, the positive contact and the negative contact are formed in the second direction perpendicular to the first direction which is the crystal growth direction for forming the light emitting structure. That is, contacts are formed on the side surface of the crystal growth direction. Also, the crystal growth proceeds in a direction parallel to the surface of the substrate and is limited within the active region recessed from the substrate surface.
[0094] In particular, while a portion of ultraviolet light generated in the active layer may be absorbed by the p-type semiconductor layer positioned in the crystal growth direction, the ultraviolet light may easily be released to outside by the reflective metal layer disposed above or below the active layer. Accordingly, light extraction efficiency may be increased. Also, there is an advantage in which a desired ultraviolet light intensity may be obtained by selecting a size of the active region, enabling flexible layouts and forming electrodes in the same plane on the wiring.
DESCRIPTION OF REFERENCE NUMERALS
[0095] 100, 200: substrate
[0096] 110, 210: reflective metal layer
[0097] 120, 220: insulating metal layer
[0098] 130, 230: light emitting structure
[0099] 140, 240: negative contact
[0100] 150, 250: positive contact