Systems and methods for converting biomass to biocrude via hydrothermal liquefaction
09797597 · 2017-10-24
Assignee
Inventors
- Halil Berberoglu (Austin, TX, US)
- Rhykka L. Connelly (Austin, TX, US)
- Joey Anthony (Austin, TX, US)
- Cody Bond (Austin, TX, US)
Cpc classification
Y02P20/133
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C12M43/00
CHEMISTRY; METALLURGY
C10G1/00
CHEMISTRY; METALLURGY
Y02E50/10
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02W10/37
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
F23G2900/50803
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E20/12
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02P30/20
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C12M43/08
CHEMISTRY; METALLURGY
F23G5/027
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Y02E50/30
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02P20/129
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
C12M1/107
CHEMISTRY; METALLURGY
F23G5/027
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
Abstract
Systems and processes of providing novel thermal energy sources for hydrothermal liquefaction (HTL) reactors are described herein. According to various implementations, the systems and processes use concentrated solar thermal energy from a focused high-energy beam to provide sufficient energy for driving the HTL biomass-to-biocrude process. In addition, other implementations convert biowaste, such as municipal biosolids and grease and food waste, to biocrude using anaerobic digesters, and a portion of the biogas generated by the digesters is used to produce the thermal and/or electrical energy used in the HTL reactor for the biomass-to-biocrude process. Furthermore, alternative implementations may include a hybrid system that uses biogas and solar radiation to provide sufficient thermal energy for the HTL reactor.
Claims
1. A system for converting biomass to biocrude comprising: a hydrothermal liquefaction reactor configured for converting biomass feedstock to biocrude; and a solar thermal energy collection system configured for providing concentrated solar thermal energy to the hydrothermal liquefaction reactor for heating the biomass feedstock, the solar thermal energy collection system comprises: a solar thermal energy concentrating mechanism, and a receiver that is operatively positioned adjacent the solar thermal energy concentrating mechanism, the receiver configured for receiving concentrated solar thermal energy from the solar thermal energy concentrating mechanism, wherein the hydrothermal liquefaction reactor is disposed adjacent the receiver.
2. The system of claim 1 wherein the solar thermal energy concentrating mechanism is selected from the group consisting of a concave dish, a parabolic mirror, a photovoltaic panel, and a Fresnel lens.
3. The system of claim 1 wherein the hydrothermal liquefaction reactor comprises a coiled conduit disposed within a housing of the receiver.
4. The system of claim 1, further comprising a pump configured for continuously pumping the biomass feedstock through the hydrothermal liquefaction reactor.
5. The system of claim 4, wherein the pump is configured for pumping the biomass feedstock at a pressure around 20 MPa.
6. The system of claim 1, further comprising a quencher disposed adjacent an exit of the hydrothermal liquefaction reactor, the quencher configured for quickly cooling the biocrude.
7. The system of claim 1, further comprising a heat exchanger downstream of the hydrothermal liquefaction reactor, the heat exchanger configured for harvesting the thermal energy from the biomass feedstock.
8. The system of claim 7, further comprising a generator configured for generating electrical energy for at least one of one or more pumps and one or more electrical components, wherein the thermal energy from the heat exchanger is used for driving the generator.
9. The system of claim 7, wherein the hydrothermal liquefaction reactor comprises a first hydrothermal liquefaction reactor, the system further comprising a second hydrothermal liquefaction reactor, the second hydrothermal liquefaction reactor being disposed downstream of the first hydrothermal liquefaction reactor, and the thermal energy from the heat exchanger is transferred to the second hydrothermal liquefaction reactor.
10. The system of claim 1, further comprising a filtration mechanism disposed downstream of the hydrothermal liquefaction reactor, the filtration mechanism configured for substantially removing polar components from the biocrude.
11. The system of claim 1, wherein the biomass feedstock comprises biowaste.
12. The system of claim 11, wherein the biowaste comprises municipal biosolid waste, grease waste, and/or food waste.
13. The system of claim 1, wherein the biomass feedstock comprises algae and/or marine biomass.
14. The system of claim 1, wherein the biomass feedstock comprises animal waste.
15. The system of claim 1, wherein the biomass feedstock comprises wood waste.
16. The system of claim 1, wherein the biomass feedstock comprises cellulosic waste.
17. The system of claim 1, wherein a first portion of the thermal energy from the solar thermal energy collection system is provided to the hydrothermal liquefaction reactor for heating the biomass feedstock and a second portion of the thermal energy from the solar thermal energy collection system is provided to a generator to generate electrical energy, at least a portion of the generated electrical energy being provided to the hydrothermal liquefaction reactor for heating the biomass feedstock.
18. The system of claim 1, wherein thermal energy is collected from combusted biogas, a first portion of the thermal energy collected from the combusted biogas being provided to a generator to generate electrical energy, and a second portion of the thermal energy collected from the combusted biogas being provided to the hydrothermal liquefaction reactor for heating the biomass feedstock.
19. A system for converting biomass to biocrude comprising: a hydrothermal liquefaction reactor configured for converting biomass feedstock to biocrude; and a solar thermal energy collection system configured for providing concentrated solar thermal energy to the hydrothermal liquefaction reactor for heating the biomass feedstock, wherein the solar thermal energy collection system comprises a receiver and a solar thermal energy concentrating mechanism, the receiver being operatively positioned adjacent the solar thermal energy concentrating mechanism and configured for receiving concentrated solar thermal energy from the solar thermal energy concentrating mechanism, and a heat transfer fluid is configured for transferring at least a portion of the concentrated thermal energy from the receiver to the hydrothermal liquefaction reactor, the hydrothermal liquefaction reactor being disposed remotely from the receiver.
20. The system of claim 19, wherein a first portion of the thermal energy from the solar thermal energy collection system is provided to the hydrothermal liquefaction reactor for heating the biomass feedstock and a second portion of the thermal energy from the solar thermal energy collection system is provided to a generator to generate electrical energy, at least a portion of the generated electrical energy being provided to the hydrothermal liquefaction reactor for heating the biomass feedstock.
21. The system of claim 19, wherein thermal energy is collected from combusted biogas, a first portion of the thermal energy collected from the combusted biogas being provided to a generator to generate electrical energy, and a second portion of the thermal energy collected from the combusted biogas being provided to the hydrothermal liquefaction reactor for heating the biomass feedstock.
22. The system of claim 19, wherein the solar thermal energy concentrating mechanism is selected from the group consisting of a concave dish, a parabolic mirror, a photovoltaic panel, and a Fresnel lens.
23. The system of claim 19, further comprising a pump configured for continuously pumping the biomass feedstock through the hydrothermal liquefaction reactor.
24. The system of claim 23, wherein the pump is configured for pumping the biomass feedstock at a pressure around 20 MPa.
25. The system of claim 19, further comprising a quencher disposed adjacent an exit of the hydrothermal liquefaction reactor, the quencher configured for quickly cooling the biocrude.
26. The system of claim 19, further comprising a heat exchanger downstream of the hydrothermal liquefaction reactor, the heat exchanger configured for harvesting the thermal energy from the biomass feedstock.
27. The system of claim 26, further comprising a generator configured for generating electrical energy for at least one of one or more pumps and one or more electrical components, wherein the thermal energy from the heat exchanger is used for driving the generator.
28. The system of claim 26, wherein the hydrothermal liquefaction reactor comprises a first hydrothermal liquefaction reactor, the system further comprising a second hydrothermal liquefaction reactor, the second hydrothermal liquefaction reactor being disposed downstream of the first hydrothermal liquefaction reactor, and the thermal energy from the heat exchanger is transferred to the second hydrothermal liquefaction reactor.
29. The system of claim 19, further comprising a filtration mechanism disposed downstream of the hydrothermal liquefaction reactor, the filtration mechanism configured for substantially removing polar components from the biocrude.
30. The system of claim 19, wherein the biomass feedstock comprises biowaste.
31. The system of claim 30, wherein the biowaste comprises municipal biosolid waste, grease waste, and/or food waste.
32. The system of claim 19, wherein the biomass feedstock comprises algae and/or marine biomass.
33. The system of claim 19, wherein the biomass feedstock comprises animal waste.
34. The system of claim 19, wherein the biomass feedstock comprises wood waste.
35. The system of claim 19, wherein the biomass feedstock comprises cellulosic waste.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
(14) Described herein are systems and processes of providing novel thermal energy sources for hydrothermal liquefaction (HTL) reactors. For example, various implementations include a novel hydrothermal liquefaction (HTL) reactor that uses solar thermal concentration technology in a novel way such that the energy barrier for the HTL process is removed. According to various implementations, the systems and processes use concentrated solar thermal energy from a focused high-energy beam to provide sufficient energy for driving the HTL biomass-to-biocrude process. The concentrated solar thermal energy may be collected via various solar thermal energy concentrating mechanisms, including, for example, a concave dish, parabolic mirrors, and Fresnel lenses, and the solar thermal energy may be used directly or indirectly, such as via heat exchange fluids, by the HTL reactor.
(15) In addition, other implementations convert biowaste, such as municipal biosolids and grease and food waste, to biocrude using anaerobic digesters, and a portion of the biogas generated by the digesters is used to produce the thermal and/or electrical energy used in the HTL reactor for the biomass-to-biocrude process. Furthermore, alternative implementations may include a hybrid system that uses biogas and solar radiation to provide sufficient thermal energy for the HTL reactor. These implementations are described in detail below.
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(17) In particular, the system 10 includes a hydrothermal liquefaction (HTL) system 12 and a solar thermal energy concentrating mechanism 14 configured for providing thermal energy to the hydrothermal liquefaction (HTL) system 12 for heating the biomass slurry. The system 10 also includes a generator 16 for generating electricity. The solar thermal energy concentrating mechanism 14 may be a concave dish, such as shown in
(18) The exemplary solar radiation concentration mechanism 14 shown in
(19) The system 10 also includes a pump (not shown) that is configured for continuously pumping the biomass slurry through the HTL system 12. The pump may be configured for pumping the biomass slurry at a pressure around 20 MPa.
(20) According to various implementations, wet biomass slurry is continuously pumped under high pressure through the HTL system 12. The biomass slurry is heated (directly or indirectly) by using the high energy beam focused by the solar thermal energy concentrating mechanism 14. In one implementation, the beam can reach about 1000° C. The subcritical water heated by the beam acts as a reaction solvent converting organic matter into biocrude. As shown in
(21) Thus, the system 10 uses the thermal energy from the solar concentration mechanism 14 as the primary source of thermal energy for driving the HTL process, but secondary or backup sources of thermal energy may include combustion of biogas and/or natural gas. For example, the biogas may be captured from the HTL process or produced elsewhere and stored for use by the system 10. Combustion of the biogas and/or natural gas may be used to produce thermal energy on suboptimal solar days, for example. In addition, at least a portion of the thermal energy from the solar radiation concentration mechanism 12 and/or from the combustion of biogas and/or natural gas may be used by the generator to generate electricity. Furthermore, electricity may also be generated by using solar photovoltaic devices.
(22) The thermal energy from the combustion of biogas and/or natural gas or from stored solar energy may be delivered to the HTL system 12 directly or indirectly via a heat transfer fluid and heat exchanger.
(23) The system 10 may also includes a quencher (not shown) that is disposed adjacent an exit of the HTL system 12. The quencher quickly cools the biocrude to prevent degradation.
(24) In addition, the system 10 may include a heat exchanger (not shown) downstream of the HTL system 12 that is configured for harvesting the heat energy from the biomass slurry. For example, the generator 16 may be configured for using this harvested heat energy for generating power for at least one of one or more biomass slurry pumps and one or more electrical components. In addition, the system 10 may further include a second HTL system (not shown) disposed downstream of the HTL system 12. The heat energy from the heat exchanger may be transferred to the second HTL system. In addition, the system 10 may include thermal and pressure-rated parts that are capable of withstanding the temperatures and pressures of the HTL process.
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(27) Solar energy driven systems, such as system 10 described above in relation to
(28) According to other various implementations, municipal biosolids, grease waste, and food waste may be converted to renewable biocrude using biogas from anaerobic digesters as fuel for supplying the electrical and thermal energy required to produce the biocrude. Municipal biosolids, grease waste, and food waste pose a serious problem for water utilities for their proper treatment, discharge, and elimination. Currently, treatment facilities anaerobically digest part of the biosolid, grease, and food waste, but the facilities cannot eliminate it. The remaining portion is sent to landfills or sprayed onto large fields. In addition, facilities combust more than half of the biogas generated from their anaerobic digesters, which goes to waste. Thus, these implementations address at least two globally important problems of a growing population, namely: (i) biowaste reduction/utilization and (ii) renewable advanced biofuels generation. In addition, the process is energy self-sufficient and uses a reliable feedstock for consistently producing a reliable source of biocrude, which are major barriers for biocrude production with other technologies.
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(31) In some implementations, the anaerobic digester 36 may be configured to generate more hydrogen, which can be separated from the biogas. In addition, the biocrude may be fed upstream of the HTL system 32 to an upgrading unit (not shown) to remove nitrogen and sulfur from the biocrude.
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(33) According to certain implementations, high pressure and high temperature-rated parts are used in the system due to the high temperature and high pressure environment. In addition, the aqueous phase may be further processed to form a third stream of product, for example, fertilizer supplement, according to some implementations. Furthermore, other sources of biowaste, such as brown or yellow grease and food waste, may be used in the process 700 according to some implementations.
(34) Other sources of thermal and/or electrical energy may be used for the HTL system, such as energy from photovoltaic panels, biogas from landfills, inexpensive natural gas, concentrating solar thermal systems, such as the solar thermal system described above in relation to
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(36) Municipal biosolids have high organic content for biocrude production, are pre-collected and concentrated at treatment plants, do not require extra energy or effort for collection, and are likely to be consistently and increasingly available over time as populations grow. The biogas produced in anaerobic digesters from biosolids is an excellent source of fuel that may be generated on-site for supplying the electrical and thermal energy required to produce biocrude. In addition, the above described process and production system readily integrate into an existing biosolids treatment facility, providing a pathway for cost-effective biocrude production.
(37) As noted above, one of the main barriers to the widespread application of the HTL process is that the energy necessary to create a subcritical water environment (high temperature, high pressure) to drive the biomass-to-biocrude conversion process exceeds the energy available in the biocrude product, creating a negative EROI. The thermal energy collected by the solar energy concentration mechanism and/or the combustion of biogas and/or natural gas of the systems and processes described above provides heat energy in excess of that necessary to create a subcritical water state. In addition, the systems and processes described herein provide an engineered continuous flow that facilitates the high heat, high pressure conditions necessary to drive the HTL reaction forward (converting biomass to biocrude). This coupled process, unlike other HTL processes, produces a positive EROI and thus a pathway to cost-effective biomass-to-biocrude production on any scale.
(38) The system allows for use of a variety of biomass and/or biowaste feedstocks in the process, including municipal biosolids, food waste, animal waste, grease waste, cellulosic waste, as well as microalgae. This facilitates recycling of waste materials that may have otherwise been subject to disposal in a land-fill.
(39) Advantages of one or more implementations of the systems and methods described herein include: (1) continuous flow, (2) comparatively high biomass-to-biocrude yields, (3) nearly free energy input capable of generating a positive EROI for the process, (4) recycling of organic waste materials to renewable biocrude, (4) energy self-sufficiency, (5) use of a reliable biowaste feedstock that is low cost and is likely to increase in amount over time with growing populations, (6) the ability to implement the system in developed and under-developed countries, (7) applicability to a wide variety of biomass feedstocks, and (8) easily scalable.