METHOD AND APPARATUS FOR DESALINATING WATER
20220362683 · 2022-11-17
Assignee
Inventors
- Bahman Abbasi (Bend, OR, US)
- Xiang Zhang (Bend, OR, US)
- Mohammed Abbas Elhashimi Khalifa (Corvallis, OR, US)
- Deepak Sharma (Corvallis, OR, US)
Cpc classification
B01D45/16
PERFORMING OPERATIONS; TRANSPORTING
B01D1/14
PERFORMING OPERATIONS; TRANSPORTING
F04F5/18
MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
B01D5/006
PERFORMING OPERATIONS; TRANSPORTING
B01D1/30
PERFORMING OPERATIONS; TRANSPORTING
C02F1/10
CHEMISTRY; METALLURGY
Y02A20/131
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
Y02W10/30
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
International classification
B01D1/30
PERFORMING OPERATIONS; TRANSPORTING
B01D1/14
PERFORMING OPERATIONS; TRANSPORTING
B01D45/16
PERFORMING OPERATIONS; TRANSPORTING
B01D5/00
PERFORMING OPERATIONS; TRANSPORTING
C02F1/10
CHEMISTRY; METALLURGY
Abstract
This disclosure concerns a system and a method for removing dissolved solids from liquids. Specific implementations concern desalinating water. The system may comprise a blower, such as a thermal fan/compressor, configured to atomize a solid-bearing liquid to produce a hot, humid gas containing dissolved solids; a gas-solid separator configured to receive hot, humid gas containing entrained dissolved solids from the blower to separate the solids from the humid gas and to transmit the humid gas with solids removed through an exit port; a heater configured to heat the hot, humid gas received from the exit port of the gas-solid separator; and a condenser configured to receive heated humid gas from the heater and to condense solids-free liquid therefrom. The thermal fan/compressor may comprise a plurality of nozzles with outlets positioned adjacent atomization apertures across which a solid-bearing liquid flows and through which gas exiting the nozzles passes.
Claims
1. A thermal fan/compressor, comprising: an inlet face having a plurality of inlet ports; a plurality of nozzles configured to receive a gas from the inlet ports, each nozzle comprising a heat exchange wall, an inlet orifice having a first size, and an outlet orifice having a second size smaller than the first size of the inlet orifice; an outlet face having at least one atomization aperture across which a fluid can flow and be contacted by gas exiting the nozzles; and a wall separating the inlet face from the outlet face and forming a condensation and heat exchange chamber in which the plurality of nozzles is disposed.
2. The thermal fan/compressor according to claim 1 wherein the nozzles are conical or otherwise tapered such that a diameter of the inlet orifice is greater than a diameter of the outlet orifice to establish a fluid velocity at the outlet orifice, v.sub.1, that is greater than fluid velocity at the inlet orifice, v.sub.0.
3. The thermal fan/compressor according to claim 1 wherein the nozzles are made from a polymeric material selected from polyetheretherketone (PEEK™), polysulfone (PSU), or polyvinylidene fluoride (PVDF).
4. The thermal fan/compressor according to claim 3 wherein the nozzles comprise a thermally-conductive metal powder selected to improve the strength and/or thermal conductivity of the nozzles.
5. The thermal fan/compressor according to claim 1 wherein the outflow face includes at least one atomization aperture configured to allow gas exiting the outlet orifices of the nozzles to flow through the at least one atomization aperture.
6. The thermal fan/compressor according to claim 1 wherein the outflow face includes plural atomization apertures configured to allow gas exiting the outlet orifices of the nozzles to flow through the plural atomization apertures to accommodate required mass flow rates for selected applications.
7. The thermal fan/compressor according to claim 6 wherein gas exiting the outlet orifices of the nozzles and passing through the at least one atomization aperture atomizes a fluid flowing along a surface of the outlet face.
8. The thermal fan/compressor according to claim 7 wherein gas exiting the outlet orifices of the nozzles is air, and the fluid flowing along the surface of the outlet face is contaminated water.
9. The thermal fan/compressor according to claim 1 wherein the wall defines a cylindrical housing and includes a plurality of ports configured to introduce humid air and contaminated water having entrained solids into thermal fan/compressor.
10. The thermal fan/compressor according to claim 5, further comprising: a primary manifold configured to provide uniform fluid distribution to the at least one atomization aperture; a secondary manifold to maintain a continuous thin liquid film around the atomization aperture or apertures to facilitate continuously atomizing the thin liquid film; or both the primary and the secondary manifolds.
11. The thermal fan/compressor according to claim 1 further comprising a heater to heat a fluid receive by the thermal fan/compressor.
12. The thermal fan/compressor according to claim 11 wherein the heater is a solar heater.
13. The thermal fan/compressor according to claim 1, wherein: dry or low humidity air enters the plurality of nozzles through inlet orifices with a velocity v.sub.0 near 0 m/s, and an initial temperature of T.sub.0; thermal energy is transferred to the heat exchange chamber and is conducted to fluid inside the thermal fan/compressor nozzles, thereby accelerating the fluid to a velocity v.sub.1 greater than v.sub.0, and heating the fluid to a temperature T.sub.1 greater than T.sub.0; and jets of dry fluid moving at velocity v.sub.1 contact a dissolved solids-bearing feed fluid at the outlet face, whereby the solids-bearing feed fluid is atomized by high-velocity jets of dry fluid, and solid particles of the solids-bearing feed fluid are entrained in the resulting hot fluid.
14. A thermal fan/compressor, comprising: an inlet face having a plurality of inlet ports; a plurality of nozzles associated with and configured to receive a gas from the inlet ports, each nozzle comprising a heat exchange wall, an inlet orifice having a first size, and an outlet orifice having a second size smaller than the first size of the inlet orifice, the nozzles being tapered such that a diameter of the inlet orifice is greater than a diameter of the outlet orifice to establish a fluid velocity at the outlet orifice, v.sub.1, that is greater than fluid velocity at the inlet orifice, v.sub.0; an outlet face having plural atomization apertures across which a fluid can flow and be contacted by gas exiting the nozzles, thereby atomizing the fluid flowing across the apertures; and a wall separating the inlet face from the outlet face and forming a housing to house a condensation and heat exchange chamber in which the plurality of nozzles are disposed, the wall comprising a plurality of ports configured to allow fluids to flow into the heat exchange and condensation chamber.
15. The thermal fan/compressor according to claim 14, further comprising: a primary manifold configured to provide uniform fluid distribution to the at least one atomization aperture; maintain a secondary manifold configured to provide a thin liquid film to flow over the atomization aperture or apertures to facilitate continuously atomizing the thin liquid film; or both a primary and a secondary manifold.
16. The thermal fan/compressor according to claim 14, wherein: dry or low humid air enters the plurality of nozzles through inlet orifices with a velocity v.sub.0 near 0 m/s, and an initial temperature of T.sub.0; thermal energy is transferred to the heat exchange chamber and is conducted to fluid inside the thermal fan/compressor nozzles, thereby accelerating the fluid to a velocity v.sub.1 greater than v.sub.0, and heating the fluid to a temperature T.sub.1 greater than T.sub.0; and jets of dry air moving at velocity v.sub.1 contact water comprising dissolved solids, whereby the water is atomized by high-velocity jets of dry fluid, and solid particles are entrained in the resulting hot fluid.
17. A thermal fan/compressor for use in a system for purifying contaminated water comprising entrained solids, comprising: an inlet face having a plurality of inlet ports; a plurality of nozzles associated with and configured to receive dry air from the inlet ports, each nozzle comprising a heat exchange wall, an inlet orifice having a first size, and an outlet orifice having a second size smaller than the first size of the inlet orifice, the nozzles being tapered such that a diameter of the inlet orifice is greater than a diameter of the outlet orifice to establish an air velocity at the outlet orifice, v.sub.1, that is greater than an air velocity at the inlet orifice, v.sub.0; an outlet face having plural atomization apertures across which contaminated water can flow and be contacted by air exiting the nozzles, thereby atomizing the contaminated water flowing across the apertures; and a wall separating the inlet face from the outlet face and forming a housing to house a condensation and heat exchange chamber in which the plurality of nozzles are disposed, the wall comprising a plurality of ports configured to allow air and contaminated water to flow into the system.
18. The thermal fan/compressor according to claim 17, further comprising: a primary manifold configured to provide uniform fluid distribution to the at least one atomization aperture; maintain a secondary manifold configured to provide a thin liquid film to flow over the atomization aperture or apertures to facilitate continuously atomizing the thin liquid film; or both a primary and a secondary manifold.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
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DETAILED DESCRIPTION
[0040] The following detailed description is provided with reference to the drawings and embodiments described herein. The drawings are illustrative and are not intended to limit the scope of the disclosure. It should further be understood that the term “desalination” as used herein refers to the removal of salt and other total dissolved solids (TDS) from any fluid source, particularly a water source contaminated with such solids. TDS refers to any material that may be dissolved in a fluid, particularly water, and includes by way of example dissolved salts, ionic compounds, minerals, metals or other materials dissolved in water.
I. DEFINITIONS
[0041] The following explanations of terms and abbreviations are provided to better describe the present disclosure and to guide those of ordinary skill in the art in the practice of the present disclosure. As used herein, “comprising” means “including” and the singular forms “a” or “an” or “the” include plural references unless the context clearly dictates otherwise. The term “or” refers to a single element of stated alternative elements or a combination of two or more elements, unless the context clearly indicates otherwise.
[0042] Unless explained otherwise, all technical and scientific terms used herein have the same meaning as commonly understood to one of ordinary skill in the art to which this disclosure belongs. Although methods and materials similar or equivalent to those described herein can be used in the practice or testing of the present disclosure, suitable methods and materials are described below. The materials, methods, and examples are illustrative only and not intended to be limiting. Other features of the disclosure are apparent from the following detailed description and the claims.
[0043] The disclosure of numerical ranges refers to each discrete point within the range, inclusive of endpoints, unless otherwise noted. Unless otherwise indicated, all numbers expressing quantities of components, molecular weights, percentages, temperatures, times, and so forth, as used in the specification or claims are to be understood as being modified by the term “about.” Accordingly, unless otherwise implicitly or explicitly indicated, or unless the context is properly understood by a person of ordinary skill in the art to have a more definitive construction, the numerical parameters set forth are approximations that may depend on the desired properties sought and/or limits of detection under standard test conditions/methods as known to those of ordinary skill in the art. When directly and explicitly distinguishing embodiments from discussed prior art, the embodiment numbers are not approximates unless the word “about” is recited.
[0044] Certain disclosed embodiments concern processing fluids, particularly water, to produce a “substantially solid free” fluid. “Substantially solid free” will be understood by a person of ordinary skill in the art to depend upon the fluid, the solids content, and the purpose for which the fluid is used. “Substantially solid free” refers to a fluid having a reduced solids content after processing according to disclosed embodiments relative to the same fluid prior to processing, and such processing to produce a reduced solids content provides a processed fluid having an improved property or benefit relative to the fluid prior to processing. For disclosed embodiments directed to desalinating water to produce potable water, “substantially solid free” means water having a salt concentration after processing according to disclosed embodiments approaching 0 ppm, more typically greater than 0 ppm to 1,000 ppm, and preferably equal to or less than 500 ppm, such as 100 to 500 ppm or less.
II. INTRODUCTION
[0045]
[0046]
III. FLUID PURIFICATION SYSTEM
[0047] Described herein are embodiments of a system for the energy-efficient purification of fluids, with particular embodiments concerning desalination of water. Also disclosed herein are embodiments of a method for using the disclosed system.
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[0051] Each of the exemplary systems discussed above include a thermal fan/compressor, such as thermal fan/compressors 300, 400 and 500. However, a thermal fan/compressor is not a required component, and instead can be replaced with a component that provides substantially the same function, such as desalination chamber 1100 that includes an air blower and a humidifier-dehumidifier as illustrated by
[0052]
[0053] Each of the exemplary systems discussed above includes a cyclone, such as cyclones 310, 412, 512 and 1112. However, in each such disclosed exemplary system, the cyclone could be replaced with a packed bed component. The packed bed would include a sorbent or combinations of sorbents suitable for separating solids from fluids to produce a fluid with a reduced solids content, such as a substantially solids-free fluid.
IV. EMBODIMENTS OF THERMAL NOZZLES AND FANS
[0054] Described herein are examples of thermal fan/compressors suitable for use in the fluid purification system and method embodiments disclosed herein, such as a water desalination system and process. The present disclosure also provides thermal fan/compressor nozzles for use in the thermal fan/compressors. Additional features of exemplary thermal fan/compressor embodiments are disclosed by assignee's U.S. provisional patent application No. 62/968,747, filed on Jan. 31, 2020, and entitled Thermal Fan Apparatus and Method of Use. U.S. provisional patent application No. 62/968,747 is incorporated herein by reference in its entirety.
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[0056] Thermal fan/compressor nozzles may be made of any material that is chemically and thermally compatible with fluid purification processes, such as desalination. Certain embodiments are suitable for use with 450,000 ppm TDS water, more typically 100,000 ppm TDS or less water, under the temperature and pressure conditions under which the invention is used. Exemplary materials that can be used include polymers, such as polyetheretherketone (PEEK™), polysulfone (PSU), and polyvinylidene fluoride (PVDF). In some embodiments, the strength and thermal conductivity of nozzles 602 may be improved by including thermally-conductive metal powder in the thermal fan/compressor nozzle body.
[0057] Thermal fan/compressor 600 incorporates a plurality of thermal fan/compressor nozzles 602. The exemplary thermal fan/compressor 600 of
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[0059] As illustrated in
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[0061] In a generalized operational example, dry or low humidity air enters the thermal fan/compressor nozzles 602, 702 through inlet orifices, such as orifices 614, in a near-stagnant state with a velocity of v.sub.0, near 0 m/s, and a temperature of T.sub.0. Thermal energy is transferred to the heat exchange chamber 612, 712 and is conducted to the air inside the thermal fan/compressor nozzles 602, 702, accelerating the air to velocity v.sub.1 greater than v.sub.0 and heating it to a temperature of T.sub.1 greater than T.sub.0. Jets of dry air moving at velocity v.sub.1 contacts incoming dissolved solids-bearing feed water at the outlet face 608, 708. The feed water is atomized by the high-velocity hot air, and the solid particles are entrained in the resulting hot, humid air.
V. EMBODIMENTS OF OTHER COMPONENTS
[0062] Described herein are examples of various other components suitable for desalination.
[0063] In one disclosed embodiment, the gas-solid separator (e.g. the cyclone) is substantially conical in shape and has an inlet at an upper end. The inlet communicates with the passageway and is located adjacent to the upper end of the cyclone. The inlet is arranged tangentially to the side wall of the cyclone such that warm, humid air entering the cyclone is directed in a helical path around the interior of the cyclone. The cyclone further includes an outlet. The outlet provides a passageway for cleaned air leaving the cyclonic separating apparatus and passing to other parts of the desalination apparatus downstream of the cyclone, such as the condensation chamber of the thermal fan/compressor or the air-water separator. A solids collector is located at the lower end of the cyclone. The solids collector collects salt and other solids rejected from the warm and humid air in the cyclone and subsequently caused to fall towards the lower end of the cyclone.
[0064] In operation, hot, humid air from a thermal fan/compressor enters the cyclone through an inlet. The airflow may follow a helical path around the interior of the cyclone. Entrained solids, such as salts, are separated from the hot, humid air by this cyclonic motion, accumulate at the lower end of the cyclone, and are collected in the solids collector. Cleaned hot, humid air that no longer contains entrained solids exits the cyclone through outlet and proceeds to downstream elements of the desalination apparatus.
VI. EXAMPLES
[0065] The following examples are provided to illustrate certain features of exemplary embodiments of the present invention. A person of ordinary skill in the art will understand that the scope of the disclosed invention is not limited to, nor defined by, these exemplary features.
Example 1
[0066] In one example of a method for the desalination of water, dry, near-stagnant (v.sub.0=near 0 m/s) air enters a thermal fan/compressor such as illustrated in
Example 2
[0067] In another embodiment of a method for desalinating water, dry, near-stagnant (v=near 0 m/s) air enters a thermal fan/compressor at a temperature of approximately 30° C. and a pressure of 1 atmosphere. An array of thermal fan/compressor nozzles containing the near-stagnant air is externally heated by contact with hot, humid air, raising the temperature of the dry air inside the nozzles to 100° C. and accelerating it to a second velocity greater than the first velocity, such as about 2.6 m/s. The dry air exits the nozzles and contacts incoming feed water having a temperature of 90° C. The high-velocity jets of hot air atomize the feed water, entraining solids, such as salt(s) in the humidified air stream. The resulting humidified air stream with entrained solid particles exits the thermal fan/compressor at a velocity of 2 m/s, a temperature of 93° C., and a pressure of approximately 2 atmospheres. The humid air stream then enters a cyclone in which solids larger than approximately 3 μm are separated from the humid air and collected in a combined salt collector and heat recuperator, where intake feed water is heated to 90° C. before being introduced to the thermal fan/compressor for atomization. The substantially solids-free humid air leaves the cyclone and is heated by a heater, such as a solar heater, before flowing to the thermal fan/compressor nozzles. This causes substantially solid-free liquid, such as salt-free water, to condense as heat transfers to the air within the thermal fan/compressor nozzles.
Example 3
[0068] In another embodiment of a method for desalinating water, dry, near-stagnant (v=near 0 m/s) air enters the thermal fan/compressor at a temperature of approximately 98° C. An array of thermal fan/compressor nozzles containing the near-stagnant air is externally heated, such as by using a solar heater, to raise the temperature of the dry air inside the nozzles to 120° C. The thermal fan/compressor nozzles accelerate the heated air to a second velocity greater than the first velocity, such as velocity greater than about 19 m/s. The dry air exits the nozzles and contacts incoming hot saline feed water having a temperature of 95° C. The high-velocity hot air jets atomize the feed water, entraining solids in the humidified air stream. The humidified air is further heated by heat of condensation that is supplied by contacting the interior surface of a condenser. The resulting humidified air stream with entrained solid particles, such as salt particles, exits the thermal fan/compressor at a velocity of about 12 m/s and a temperature of about 108° C. The humid air stream then enters a cyclone in which solids larger than approximately 3 μm are separated from the humid air. Substantially particle-free humid air exits the cyclone at about 107° C. and is reintroduced to the outside surface of the condenser, where water condenses, and excess heat is transferred to the flow of atomized feed water. The hot, condensed fresh water then flows to an air-water separator. Remaining air is removed and reintroduced to the thermal fan/compressor nozzles. Fresh water then enters a heat recuperator, where heat is transferred to intake fluid, such as saline water, to heat it to a target temperature of 95° C. prior to atomization.
[0069] In view of the many possible embodiments to which the principles of the disclosed invention may be applied, it should be recognized that the illustrated embodiments are only preferred examples of the invention and should not be taken as limiting the scope of the invention. Rather, the scope of the invention is defined by the following claims. We therefore claim as our invention all that comes within the scope and spirit of these claims.