PHOSPHOR COMPOSITION AND LIGHT EMITTING DEVICE USING THE SAME

Abstract

The present invention provides a phosphor composition and light emitting device using the same. The phosphor composition includes a first phosphor and a second phosphor, the second phosphor includes Phellodendron extract, Phellodendron extract emits lights with wavelength from 450 nm to 750 nm as it is excited by lights with wavelength from 300 nm to 480 nm. The LED device using the phosphor composition could emit warm white lights with wavelength from 400 nm to 800 nm.

Claims

1. A phosphor composition, comprising: a first phosphor; and a second phosphor including a Phellodendron extract.

2. The phosphor composition according to claim 1, wherein a weight ratio of the first phosphor and the second phosphor is between 4:1 and 32:1.

3. The phosphor composition according to claim 2, wherein the weight ratio of the first phosphor and the second phosphor is 10:1.

4. The phosphor composition according to claim 1, wherein the phosphor composition extracts lights with wavelength from 400 nm to 800 nm.

5. The phosphor composition according to claim 1, wherein the Phellodendron extract is excited by lights with wavelength from 300 nm to 480 nm.

6. The phosphor composition according to claim 1, wherein the Phellodendron extract extracts lights with wavelength from 450 nm to 750 nm.

7. The phosphor composition according to claim 1, wherein the first phosphor is selected from the group consisting of a yellow phosphor, a red phosphor, and a green phosphor.

8. The phosphor composition according to claim 7, wherein the yellow phosphor is selected from the group consisting of Y.sub.3Al.sub.5O.sub.12:Ce.sup.3+(YAG), Tb.sub.3Al.sub.5O.sub.12:Ce.sup.3+(TAG), (Mg, Ca, Sr, Ba).sub.2SiO.sub.4:Eu.sup.2+, and (Ca, Mg, Y)Si.sub.wAl.sub.xO.sub.yN.sub.z:Eu.sup.2+.

9. The phosphor composition according to claim 7, wherein the red phosphor is selected from the group consisting of (Sr, Ca)S:Eu.sup.2+, (Y, La, Gd, Lu).sub.2O.sub.3:Eu.sup.3+, Bi.sup.3+, (Y, La, Gd, Lu).sub.2O.sub.2S:Eu.sup.3+(, Bi.sup.3+), (Ca, Sr, Ba).sub.2Si.sub.5N.sub.8:Eu.sup.2+, (Ca, Sr)AlSiN.sub.3:Eu.sup.2+, Sr.sub.3SiO.sub.5:Eu.sup.2+, Ba.sub.3MgSi.sub.2O.sub.8:Eu.sup.2+, Mn.sup.2+ and ZnCdS:Ag.sup.1+, Cl.sup.1−.

10. The phosphor composition according to claim 7, wherein the green phosphor is selected from the group consisting of BaMgAl.sub.10O.sub.17:Eu.sup.2+, Mn.sup.2+(BAM-Mn), SrGa.sub.2S.sub.4:Eu.sup.2+, Lu.sub.3Al.sub.5O.sub.12:Ce.sup.3+(LuAG), (Ca, Sr, Ba)Al.sub.2O.sub.4:Eu.sup.2+, SrSi.sub.2N.sub.2O.sub.2:Eu.sup.2+, CaSc.sub.2O.sub.4:Ce.sup.3+, Ca.sub.3Sc.sub.2Si.sub.3O.sub.12:Ce.sup.3+, (Ca, Sr, Ba).sub.4Al.sub.14O.sub.25:Eu.sup.2+, Ca.sub.8Mg(SiO.sub.4).sub.4Cl.sub.2:Eu.sup.2+, Mn.sup.2+, and (Ba, Sr).sub.2SiO.sub.4:Eu.sup.2+.

11. A light emitting device including the phosphor composition of claim 1.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0024] FIG. 1 is a schematically flowing diagram illustrating manufacture of Phellodendron extract according to the present invention.

[0025] FIG. 2 is an NMR diagram illustrating Phellodendron extract according to the present invention.

[0026] FIG. 3 is a spectrogram illustrating Phellodendron extract being excited and extracting according to the present invention.

[0027] FIG. 4 is a schematic crossing-sectional diagram illustrating a LED device using the phosphor composition with Phellodendron extract according to the present invention.

[0028] FIG. 5 is a chromaticity diagram illustrating a package LED including the phosphor composition with various ratios of Phellodendron extracts according to the present invention.

[0029] FIG. 6 is a chromaticity diagram illustrating a package LED including the phosphor composition with various ratios of Phellodendron extract according to the present invention.

[0030] FIG. 7 is a chromaticity diagram illustrating a package LED including the phosphor composition with various ratios of Phellodendron extract according to the present invention.

[0031] FIG. 8 is a chromaticity diagram illustrating a package LED including the phosphor composition with commercial yellow phosphor and red phosphor according to the present invention.

[0032] FIG. 9 is a diagram illustrating relative strength of wavelength of the phosphor composition including commercial yellow phosphor and Phellodendron extract according to the present invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

[0033] The present invention provides Phellodendron extract for the replacement material of red phosphor and a LED package including the Phellodendron extract that performs chroma similar to the ones including commercial red phosphor.

[0034] Please refer to FIG. 1, No. 10 is a flow chart illustrating a method of manufacturing Phellodendron extract of the present invention. The Cortex Phellodendri used in the present invention may be acquired from rutaceau, such as Phellodendron of Phellodendron chinense Schneid or Amur Cork-tree Bark of Phellodendron amurense Rupr, and so on, but not limited to Cortex Phellodendri. Cortex Phellodendri is ground first to become Cortex Phellodendri powder (step S11). Next, ether is added into Cortex Phellodendri powder and they are uniformly mixed (step S12) to get Cortex Phellodendri solution.

[0035] Next, the got Cortex Phellodendri solution is extracted at room temperature (step S13) and filtered with a filter paper (step S14). After filtering (step S14), reduced-pressure concentration performs on a filtrate at temperature of 10° C. (step S15). As a result, Phellodendron extract that can be preserved for a long time is got after step S15.

[0036] Next, the Phellodendron extract aforementioned is further concentrated to become wet powder (step S16) and then the wet powder is dried by nitrogen gas (step S17) to get dried Phellodendron extract powder that may be used for LED package.

[0037] FIG. 2 is an NMR diagram illustrating Phellodendron extract according to the present invention.

[0038] FIG. 3 is a photoluminescence (PLE) and photoluminescence (PL) of spectrogram for the Phellodendron extract according to the present invention. Shown in FIG. 3, the Phellodendron extract mentioned in the present invention is excited by lights with wavelength from 300 nm to 480 nm. Accordingly, lights of wavebands from ultra violet (UV) to blue light may be used as an exciting light source. The excited Phellodendron extract emits lights with wavelength from 450 nm to 750 nm and may be used as replacement material of red phosphor.

[0039] FIG. 4 is a crossing-sectional diagram illustrating a LED device 40 packaged by the phosphor composition of Phellodendron extract according to the present invention. Shown in FIG. 4, the LED device 40 is packaged as follows: a blue light emitting diode (LED) chip 400 is arranged on a substrate 401 and mounted onto the substrate 401 by wire bonding. Next, fluorescent glue 402 that covers the blue LED chip 400 and conductive wires 403 is formed on the substrate 401 by dispensing. Next, a lens 404 is arranged onto the fluorescent glue 402 that includes the Phellodendron extract of the present invention and yellow phosphor. Accordingly, the phosphor composition of the Phellodendron extract and the yellow phosphor in the fluorescent glue 402 is excited by the blue lights with wavelength from 455 nm to 457.5 nm emitted from the blue LED chip 400 to emit warm white light with wavelength from 400 nm to 800 nm for the LED device 40.

[0040] Besides, for embodiments of the present invention, red phosphor or green phosphor may be added into the fluorescent glue 402 for chroma control. Material of the yellow phosphor may be selected from the group consisted of Y.sub.3Al.sub.5O.sub.12:Ce.sup.3+(YAG), Tb.sub.3Al.sub.5O.sub.12:Ce.sup.3+(TAG), (Mg, Ca, Sr, Ba).sub.2SiO.sub.4:Eu.sup.2+ and (Ca, Mg, Y)Si.sub.wAl.sub.xO.sub.yN.sub.z:Eu.sup.2+. Material of the red phosphor may be selected from the group consisted of (Sr, Ca)S :Eu.sup.2+, (Y, La, Gd, Lu).sub.2O.sub.3:Eu.sup.3+, Bi.sup.3+, (Y, La, Gd, Lu).sub.2O.sub.2S:Eu.sup.3+(, Bi.sup.3+), (Ca, Sr, Ba).sub.2Si.sub.5N.sub.8: Eu.sup.2+, (Ca, Sr)AlSiN.sub.3: Eu.sup.2+, Sr.sub.3SiO.sub.5: Eu.sup.2+, Ba.sub.3MgSi.sub.2O.sub.8: Eu.sup.2+, Mn.sup.2+ and ZnCdS:Ag.sup.1+, Cl.sup.3−. Material of green phosphor may be selected from the group consisted of BaMgAl.sub.10O.sub.17:Eu.sup.2+, Mn.sup.2+(BAM-Mn), SrGa.sub.2S.sub.4: Eu.sup.2+, Lu.sub.3Al.sub.5O.sub.12:Ce.sup.3+(LuAG), (Ca, Sr,Ba)Al.sub.2O.sub.4: Eu.sup.2+, SrSi.sub.2N.sub.2O.sub.2 :Eu.sup.2+, CaSc.sub.2O.sub.4 :Ce.sup.3+, Ca.sub.3 Sc.sub.2Si.sub.3O.sub.12 : Ce.sup.3+, (Ca, Sr,Ba).sub.4Al.sub.14O.sub.25:Eu.sup.2+, Ca.sub.8Mg(SiO.sub.4).sub.4Cl.sub.2:Eu.sup.2+, Mn.sup.2+ and (Ba, Sr).sub.2SiO.sub.4:Eu.sup.2+.

[0041] Though only a known LED device with a known package is illustrated in the present invention, however, the phosphor composition of the Phellodendron extract of the present invention may apply to various LED packages, not limited to the one aforementioned.

[0042] FIG. 5, FIG. 6 and FIG. 7 are Commission International de l'Eclairage (CIE) diagrams of LED packages with the phosphor composition of the Phellodendron extract in various ratios, and FIG. 8 is the one of control group having LED package of yellow phosphor and red phosphor.

[0043] Shown in FIG. 5, the phosphor composition with such a CIE diagram includes: the yellow phosphor of 0.06 grams and the Phellodendron extract of 0.015 grams (weight ratio is 4:1). Package test data of FIG. 5 is shown in Table 1.1: (Num is number of testing package; x and y are chromaticity coordinates; Lv is brightness; Vf is forward voltage; CCT is color temperature; CRI is color rendering index; IR is reverse current; Max is maximum value; Avg is average value; and Min is minimum value.)

TABLE-US-00001 TABLE 1.1 Num x y Lv Vf CCT CRI Ir 1 0.3836 0.3472 14.3624 3.085 3686.8891 72.8629 0.1088 2 0.3836 0.3452 15.6251 3.0453 3668.2375 73.2911 0.102 3 0.3958 0.3382 13.6458 3.0859 3256.336 74.2915 0.1086 4 0.3827 0.3482 14.7417 3.0454 3722.0864 72.9483 0.1192 5 0.3829 0.3292 12.8831 3.0527 3526.4769 74.2811 0.1176 6 0.381 0.3502 14.7321 3.0494 3789.3236 73.2644 0.1026 7 0.391 0.3403 12.2726 3.0992 3409.1959 74.3822 0.1183 8 0.3726 0.3392 14.8946 3.1002 3953.2003 72.1099 0.1158 9 0.3722 0.3523 13.6346 3.0746 4071.4795 74.9281 0.1084 10 0.3707 0.3395 12.3711 3.0444 4018.3477 72.8372 0.1014 11 0.3967 0.3546 15.7363 3.0625 3403.1497 74.0922 0.1178 12 0.3937 0.3492 14.2030 3.0689 3427.5195 76.2832 0.119 13 0.3788 0.3476 15.7261 3.1025 3831.8569 74.9190 0.1175 14 0.3976 0.3477 14.182 3.0726 3311.2913 72.1987 0.1196 15 0.3937 0.3503 12.3111 3.0615 3438.3929 72.0102 0.1097 Max 0.3976 0.3546 15.7363 3.1025 4071.4795 76.2832 0.1196 Avg 0.3851 0.3453 14.0881 3.0700 3634.2522 73.6467 0.1124 Min 0.3707 0.3292 12.2726 3.0444 3256.336 72.0102 0.1014

[0044] Shown in FIG. 6, the phosphor composition with such a CIE diagram includes: the yellow phosphor of 0.08 grams and the Phellodendron extract of 0.01 grams (weight ratio is 8:1). Package test data of FIG.6 is shown in Table 1.2:

TABLE-US-00002 TABLE 1.2 Num x y Lv Vf CCT CRI Ir 1 0.4388 0.4267 4.904 2.8692 3158.253 70.0242 0.1098 2 0.4122 0.4177 5.721 2.8702 3567.195 71.3984 0.1283 3 0.4211 0.42 5.482 2.8722 3415.324 72.1948 0.1034 4 0.3922 0.4102 6.211 2.8711 3935.165 70.2112 0.1298 5 0.3966 0.4185 5.764 2.8719 3888.813 72.8311 0.3011 6 0.4373 0.4187 5.632 2.8674 3124.25 71.9282 0.1092 7 0.4275 0.4241 6.372 2.8723 3329.652 70.2839 0.1088 8 0.419 0.4244 5.836 2.8796 3483.811 72.1184 0.1029 9 0.3919 0.4108 6.338 2.8719 3945.409 70.1983 0.0915 10 0.4008 0.4119 5.962 2.8765 3759.507 71.2711 0.1387 11 0.3966 0.4116 6.298 2.8722 3847.2 70.3682 0.1197 12 0.4167 0.4122 5.387 2.8371 3442.535 70.1873 0.1223 13 0.4413 0.4281 5.444 2.8356 3128.218 70.1825 0.1192 14 0.3977 0.4133 5.873 2.8411 3834.067 72.3817 0.1182 15 0.4356 0.4215 6.392 2.8319 3173.083 72.9855 0.0918 Max 0.4413 0.4281 6.372 2.8796 3945.4 72.8311 0.3011 Avg 0.4136 0.4177 5.8017 2.8649 3561.4 71.1128 0.1288 Min 0.3919 0.4102 4.904 2.8356 3124.2 70.0242 0.0915

[0045] Shown in FIG. 7, the phosphor composition with such a CIE diagram includes: the yellow phosphor of 0.1 grams and the Phellodendron extract of 0.01 grams (weight ratio is 10:1). Package test data of FIG. 7 is shown in Table 1.3:

TABLE-US-00003 TABLE 1.3 Num x y Lv Vf CCT CRI Ir 1 0.4119 0.3902 16.1649 3.092 3370.9 75.1883 0.1107 2 0.4036 0.4014 14.4833 3.0866 3629.6 73.8024 0.1124 3 0.3989 0.3904 14.9441 3.1058 3653.1 76.4275 0.0879 4 0.4083 0.3847 13.5631 3.0976 3401.8 75.5625 0.0959 5 0.3948 0.3821 15.1003 3.1229 3685.9 73.465 0.1175 6 0.3921 0.3856 13.9142 3.1016 3776.2 73.9228 0.0883 7 0.4138 0.3867 16.5929 3.0794 3303.1 74.3124 0.1016 8 0.4078 0.4173 16.7609 3.1386 3651.1 75.1052 0.1094 9 0.3935 0.3841 15.6146 3.1107 3731.8 73.2344 0.1161 10 0.3921 0.3952 13.1694 3.0859 3842.7 75.8994 0.1014 11 0.4167 0.4106 16.2008 3.0812 3431.1 75.9073 0.0888 12 0.3913 0.4056 13.5012 3.1025 3927.6 76.8594 0.1033 13 0.4027 0.3876 15.509 3.1099 3547.0 73.2164 0.1115 14 0.4117 0.4138 16.5689 3.1213 3550.5 75.5408 0.0986 15 0.4037 0.4173 16.3155 3.0648 3733.8 75.2346 0.089 Max 0.4167 0.4173 16.7609 3.1386 3927.6 76.8594 0.1175 Avg 0.4029 0.3968 15.2269 3.1001 3615.7 74.9119 0.1022 Min 0.3913 0.3821 13.1694 3.0648 3303.1 73.2164 0.0879

[0046] Shown in FIG. 8, a commercial phosphor composition of yellow phosphor and red phosphor with such a CIE diagram includes: the yellow phosphor of 0.1 grams and the red phosphor of 0.00475 grams. Package test data of FIG. 8 is shown in Table 1.4:

TABLE-US-00004 TABLE 1.4 Num x y Lv Vf CCT CRI Ir 1 0.4207 0.4134 17.1853 3.1026 3375.9 75.2355 0.1317 2 0.4189 0.419 16.6273 3.0903 3448.9 73.345 0.0954 3 0.4119 0.4084 19.455 3.1185 3508.8 78.6778 0.0688 4 0.4182 0.3821 20.3318 3.1147 3174.7 75.5782 0.1235 5 0.3933 0.3935 17.4936 3.0868 3803.4 78.4704 0.1135 6 0.4211 0.4127 15.219 3.1106 3363.4 75.9279 0.1164 7 0.4249 0.4075 20.7841 3.0816 3254.7 73.9641 0.1049 8 0.4069 0.4029 20.5891 3.0724 3571.0 73.7909 0.0752 9 0.4226 0.391 18.2292 3.1001 3165.3 78.2689 0.0717 10 0.417 0.3912 16.1234 3.1154 3275.9 73.4401 0.0794 11 0.4045 0.413 16.4876 3.0617 3689.7 78.2971 0.1284 12 0.3988 0.3815 15.7927 3.1194 3587.5 74.6027 0.0803 13 0.3946 0.4144 17.7012 3.0859 3907.5 73.9042 0.1174 14 0.4202 0.3827 17.4893 3.0965 3140.4 78.7245 0.127 15 0.3933 0.408 17.7934 3.1135 3897.4 74.5846 0.1153 Max 0.4249 0.419 20.7841 3.1194 3907.5 78.7245 0.1317 Avg 0.4111 0.4014 17.8201 3.0980 3477.6 75.7875 0.1033 Min 0.3933 0.3815 15.219 3.0617 3140.4 73.345 0.0688

[0047] Accordingly, square marks shown on FIG. 5, FIG. 6 and FIG. 7, the phosphor compositions of the Phellodendron extract in various ratios of the present invention may emit warm white lights similar to the commercial one of yellow phosphor and red phosphor shown in FIG. 8.

[0048] FIG. 9 is a diagram illustrating relative strengths of wavelengths of the phosphor compositions including commercial yellow phosphor and Phellodendron extract, respectively, according to the present invention. Shown in FIG. 9, the packages respectively including commercial yellow phosphor of 0.08 grams and the phosphor composition of the Phellodendron extract (including 0.08 grams yellow phosphor and 0.01 grams Phellodendron extract) are tested. It is shown that the relative strength(%) of the phosphor composition including 0.01 grams Phellodendron extract is higher than the ones of the commercial yellow phosphor without Phellodendron extract. Accordingly, compared with the commercial yellow phosphor without Phellodendron extract, the phosphor composition including Phellodendron extract performs better color rendering index.

[0049] Compared with prior technologies, the present invention provides the phosphor composition that is easy to be prepared and may emit warm white light similar to the ones from LED device in markets. The phosphor composition of the present invention reduces much manufacturing cost of LED device because of its easy preparation and low consumption. Consequently, it is a worthy composition in fields.

[0050] While the invention has been described in terms of what is presently considered to be the most practical and preferred embodiments, it is to be understood that the invention needs not be limited to the disclosed embodiments. On the contrary, it is intended to cover various modifications and similar arrangements included within the spirit and scope of the appended claims which are to be accorded with the broadest interpretation so as to encompass all such modifications and similar structures.