Method of making LED light bulb with Graphene filament

Abstract

A method of making a LED light bulb with the Graphene filament contains steps of: A. providing a flexible substrate, wherein the flexible substrate is flexible printed circuit board (PCB); B. coating graphene-based heat dissipation ink on a back side of the flexible substrate; C. cutting the printed circuit board (PCB) on which a graphene-based heat dissipation film is coated to form plural Graphene filaments; D. fixing the plural Graphene filaments into a light bulb. The flexible substrate has copper lines formed on both sides thereof for electronic circuits and heat conduction, and LED chips are mounted on a front side of the flexible substrate. The graphene-based heat dissipation ink is coated on the back side of the flexible substrate before or after LED chips/phosphor molding and then is dried. In addition, the Graphene filaments are fixed in a bended or arched position.

Claims

1. A method of making a LED light bulb with the Graphene filament according to a preferred embodiment comprises steps of: A. providing a flexible substrate, wherein the flexible substrate is flexible printed circuit board (PCB); B. coating graphene-based heat dissipation ink on a back side of the flexible substrate; C. cutting the printed circuit board (PCB) on which a graphene-based heat dissipation film is coated to form plural Graphene filaments; and D. fixing the plural Graphene filaments into a light bulb.

2. The method of making the LED light bulb as claimed in claim 1, wherein the flexible substrate has copper lines formed on both sides thereof for electronic circuits and heat conduction, and LED chips are mounted on a front side of the flexible substrate.

3. The method of making the LED light bulb as claimed in claim 1, wherein the graphene-based heat dissipation ink is coated on the back side of the flexible substrate before or after LED chips/phosphor molding and then is dried.

4. The method of making the LED light bulb as claimed in claim 1, wherein the graphene-based heat dissipation ink consists of graphene, heat dissipation fillers, dispersants and binders, such that the graphene-based heat dissipation ink takes both lateral heat spreading ability and heat radiation ability to dissipate heat.

5. The method of making the LED light bulb as claimed in claim 1, wherein the graphene-based heat dissipation film is coated by any one of spray coating, brushing, screen printing, or nozzle printing via the graphene-based heat dissipation ink.

6. The method of making the LED light bulb as claimed in claim 1, wherein the Graphene filaments are fixed in a bended or arched position.

7. The method of making the LED light bulb as claimed in claim 1, wherein the heat dissipation fillers are at least one of carbon materials, metal particles and far infrared-ray radiation powders.

8. The method of making the LED light bulb as claimed in claim 7, wherein the carbon materials include at least one of graphene, carbon black, graphite, carbon nanotubes, activated carbon.

9. The method of making the LED light bulb as claimed in claim 7, wherein the metal particles include at least one of Cu, Ni, Zn, Fe, Co, Ag, Au, Pt and their alloys.

10. The method of making the LED light bulb as claimed in claim 7, wherein the far infrared-ray radiation powders include at least one of SiO.sub.2, A1.sub.2O.sub.3, TiO.sub.2, ZrO.sub.2, ZrC, SiC, TaC, TiB.sub.2, ZrB.sub.2, TiSi.sub.2, Si.sub.3N.sub.4, TiN, BN.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0022] These and other features, aspects, and advantages of the present invention will become better understood with regard to the following description, appended claims, and accompanying drawings where:

[0023] FIGS. 1 and 2 show graphene laminate film is deposited on a polyethylene terephthalate (PET) substrate, and a thermal conductivity of the graphene laminate film is in a range from 40 to 90 W/mk at room temperature.

[0024] FIGS. 3 to 9 show a LED light bulb with the Graphene filament according to a preferred embodiment of the present invention is made.

[0025] FIGS. 10A to 10C show the graphene film coated on different substrates demonstrating superior ability for heat dissipation according to the preferred embodiment of the present invention.

[0026] FIG. 11 shows a huge dissipation path in which graphene coating illustrated obvious heat spreading effect. The terminal temperature with and without graphene coating has a 6° C. difference from thermal image measurement, indicating a great heat dissipation effect according to the preferred embodiment of the present invention.

[0027] FIG. 12 shows, the LED light bulb with the Graphene filament is tested according to the preferred embodiment of the present invention.

DETAILED DESCRIPTION OF THE INVENTION

[0028] The present invention will be described with reference to illustrative embodiments. For this reason, numerous modifications can be made to these embodiments and the results will still come within the scope of the invention. No limitations with respect to the specific embodiments described herein are intended or should be inferred.

[0029] With reference to FIGS. 1 to 2, a graphene laminate film is deposited on a polyethylene terephthalate (PET) substrate, and the thermal conductivity of the graphene laminate film is found to be in a range from 40 to 90 W/mk at room temperature, which provides up to 600× higher thermal conductivity than plastics. Thus, a LED light bulb with Graphene filament made of graphene laminate film removes heat away from heat source very rapidly.

[0030] Referring to FIGS. 3 to 9, a method of making LED light bulb with the Graphene filament according to a preferred embodiment comprises steps of:

[0031] A. providing a flexible substrate such as flexible printed circuit board (PCB); both sides of the substrate have metal lines formed not only for electronic circuits but also for heat conduction. LED chips are mounted on the front side. Processes are shown in FIG. 3 to FIG. 5. FIG. 3 shows the front side (left) and the back side (right) of the flexible substrates with circuits on both sides. LEDs are then bonded on the front side (Fig.4). Afterwards, phosphor molding is applied (FIG. 5.)

[0032] B. coating graphene-based heat dissipation ink on a back side of the flexible substrate such as flexible printed circuit board (PCB) as shown in FIG. 6; the coating process is employed before or after LED chips/phosphor molding, and is dried by traditional drying process. The post-processing not only prevents expensive and complicated procedures such as CVD, but also eliminates the bulky heat sinks or heavy bulb metal shell. Graphene-based heat dissipation ink in this invention is consisted of graphene, heat dissipation fillers, dispersants and binders, can take advantage of heat radiation effect, besides high lateral heat conduction and high surface area. Heat dissipation fillers can be carbon materials (e.g., graphene, carbon black, graphite, carbon nanotubes, activated carbon), metal particles (e.g., Cu, Ni, Zn, Fe, Co, Ag, Au, Pt and their alloys) and far infrared-ray radiation powders (e.eg, SiO.sub.2, Al.sub.2O.sub.3, TiO.sub.2, ZrO.sub.2, ZrC, SiC, TaC, TiB.sub.2, ZrB.sub.2, TiSi.sub.2, Si.sub.3N.sub.4, TiN, BN). The coating could be applied by spray coating, brushing, screen printing, or nozzle printing.

[0033] C. Cutting the printed circuit board (PCB) on which the graphene-based radiation film is coated to form plural Graphene filaments; Due to coating on large area beforehand, cut Graphene filaments can have homogeneous graphene coating on the backside without defects, as shown in FIG. 7 and FIG. 8.

[0034] D. fixing the plural Graphene filaments into a light bulb as shown in FIG. 9. Because the substrate of Graphene filaments is flexible, filaments fixed into a light bulb may not necessary to be orthogonal vertical. Filaments can be designed in bended or arched fixing position that gives variety of filament arrays design.

[0035] The Graphene filament structure integrates high heat-conduction of metal and high lateral heat-spreading ability of graphene. Heat generated by LED on the filament is localized under each LED chip. By this design, heat can be conducted fast outward by metal, and spread over the surface by graphene to increase dissipation area. Moreover, graphene-based heat dissipation coating in this invention has heat radiation effects that dissipate heat more efficiently.

[0036] As shown in FIGS. 10A to 10C, the graphene-based heat dissipation film coated on different substrates demonstrating superior ability for heat dissipation. In comparison with pure substrate without graphene film coating, IR images clearly show outstanding heat spreading ability of graphene film on all three substrate, copper, aluminum, and PET. According to the preferred embodiment of the present invention, severe hot spot from LED arrays on filaments can be effectively alleviated by coating graphene-based heat dissipation coating.

[0037] People typically use white and reflecting materials in LED because they think white can reflect and black only absorb light. On the contrary, in our light bulb and in our present invention, we found the heat radiation effect by our graphene-based heat dissipation film. As shown in FIG. 11, thermal image test is illustrated with lower side of substrate coated with graphene-based heat dissipation film in the middle of heat dissipation path, while upper side of substrate as control. Heat radiation meter detects obvious heat radiation on the area of graphene-based heat dissipation films, while no heat dissipation on the control. The temperature difference on two ends is 6° C., which indicates efficient heat radiation ability of graphene-based heat dissipation film. So the Graphene filament which inside the LED light bulb can dissipate heat away from a never invented path: radiation through space/air.

[0038] With reference to FIG. 12, the LED light bulb with the Graphene filament is tested based on LED 1,000 hours burn in data and found LED life by exponential regression. The data shows improved lifetime of LED light bulb in the preferred embodiment of the present invention.

[0039] From the above description, one skilled in the art can easily ascertain the essential characteristics of the present invention, and without departing from the spirit and scope thereof, can make various changes and modifications of the invention to adapt it to various usages and conditions. Thus, other embodiments are also within the scope of the following claims.