METHOD OF CLEANING MICROFILTRATION AND ULTRAFILTRATION MEMBRANES

Abstract

A system for and method of cleaning polymeric and ceramic microfiltration and ultrafiltration membranes in hollow fiber, flat sheet, and tubular membrane units is provided. The method includes using a reducing agent, specifically ascorbic acid, based formulation. The method also includes certain protocols useful in conducting such cleanings. The system includes features for facilitating the method of the present invention.

Claims

1. A method of cleaning a membrane contaminated with a contaminant, the method comprising: bringing a solution into direct contact with the contaminant, wherein the solution comprises a solvent that is compatible with the membrane, and wherein the solution comprises a reducing agent that is soluble in the solvent.

2. The method of claim 1, wherein the reducing agent is ascorbic acid.

3. The method of claim 2, wherein ascorbic acid is present in the solution in an amount of approximately 2.0 percentage weight to volume.

4. The method of claim 2, wherein ascorbic acid is present in the solution in an amount of between 0.5 and 5.0 percentage weight to volume.

5. The method of claim 4, wherein the solution pH is between 1.5 and 3.5.

6. The method of claim 4, wherein the solution further comprises an inorganic acid.

7. The method of claim 4, wherein the solution further comprises 0.5 to 2.0 percentage weight to volume of one of sodium bisulfite, sodium metabisulfite, and sodium hydrosulfite.

8. The method of claim 1, wherein the solution is at ambient temperature.

9. The method of claim 8, wherein the ambient temperature is between one degree Celsius and forty degrees Celsius.

10. The method of claim 1, further comprising heating the solution to an elevated temperature prior to bringing the solution into direct contact with the contaminant.

11. The method of claim 10, wherein the elevated temperature is between fifteen degrees Celsius and ninety-five degrees Celsius.

12. The method of claim 10, wherein the elevated temperature is approximately forty-five degrees Celsius.

13. The method of claim 10, further comprising maintaining the solution at the elevated temperature for an extended period of time while the solution is in direct contact with the contaminant.

14. The method of claim 13, wherein the extended period of time is between ten and twelve hours.

15. The method of claim 1, wherein the contaminant comprises ferric floc.

16. The method of claim 1, further comprising maintaining the fluid in contact with the contaminant for an extended period of time, wherein the extended period of time is between approximately ten and twelve hours.

17. A system for cleaning a membrane contaminated with a contaminant, the system comprising: a tank for holding a volume of fluid; and a pump that is configured to selectively couple to the membrane so as to be in fluid communication with fluid within said membrane; wherein said tank is configured to receive at least a portion of the membrane so as to at least partially submerge the membrane in the volume of fluid, thereby allowing fluid from the volume of fluid to come into contact with the contaminant; wherein said pump is configured to draw fluid from the membrane when said pump is coupled to the membrane and the membrane is received by said tank, and wherein drawing fluid from the membrane by said pump causes fluid from the volume of fluid to flow past the contaminant and into the membrane.

18. The system of claim 17, wherein the volume of fluid is a solution comprising ascorbic acid in an amount of between 0.5 and 5.0 percentage weight to volume.

19. The system of claim 17, wherein said tank is configured to receive the membrane so as to fully submerge the membrane in the volume of fluid.

20. A system for cleaning a membrane contaminated with a contaminant, the system comprising: a tank for holding a volume of fluid; and a pump in fluid communication with the volume of fluid, said pump being configured to selectively couple to a feed of the membrane, wherein said pump is configured to draw fluid from the tank and direct the fluid towards the feed of the membrane when said pump is coupled to the membrane, thereby creating a positive feed-to-filtrate differential pressure across the membrane, and wherein creating a positive feed-to-filtrate differential pressure across the membrane causes fluid from the volume of fluid to flow past the contaminant and into the membrane.

21. The system of claim 19, wherein the volume of fluid is a solution comprising ascorbic acid in an amount of between 0.5 and 5.0 percentage weight to volume.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0032] A preferred embodiment of the invention, illustrative of the best mode in which the applicant has contemplated applying the principles, is set forth in the following description and is shown in the drawings and is particularly and distinctly pointed out and set forth in the appended claims.

[0033] FIG. 1 illustrates a schematic of the submerged MF/UF module cleaning system configuration.

[0034] FIG. 2 illustrates a schematic of the pressurized MF/UF module cleaning system configuration.

[0035] FIG. 3 is a chart showing a 90-day Trend of Before Backpulse Trans-membrane Pressure (“TMP”) of an Avista 127 train (Train 4), a control train (Train 8), and an ascorbic acid train (Train 12).

[0036] FIG. 4 is a chart showing a 90-day Trend of Before Backpulse Temperature Corrected Permeability (“TCP”) of an Avista 127 train (Train 4), a control train (Train 8), and an ascorbic acid train (Train 12).

[0037] FIG. 5 is a chart showing a 90-day Trend of Before Backpulse Transmembrane Pressure.

DETAILED DESCRIPTION OF A PREFERRED EMBODIMENT

[0038] As required, a detailed embodiment of the present invention is disclosed herein; however, it is to be understood that the disclosed embodiment is merely exemplary of the principles of the invention, which may be embodied in various forms. Therefore, specific structural and functional details disclosed herein are not to be interpreted as limiting, but merely as a basis for the claims and as a representative basis for teaching one skilled in the art to variously employ the present invention in virtually any appropriately detailed structure.

[0039] The system 10 of the present invention includes a tank 100 that is configured to hold a volume of fluid 50. In some embodiments, the system 10 is configured to clean polymeric and/or ceramic microfiltration (MF) and/or ultrafiltration (UF) membranes, such as hollow fiber, flat-sheet, and/or tubular membranes, and/or membrane units/modules 200. Referring to FIG. 1, some embodiments of the system 10 are Clean-In-Place (“CIP”) systems and/or are configured to operate while the module 200 is submerged. Referring to FIG. 2, other embodiments of the system 10 are CIP systems and/or are configured to operate while the module is pressurized.

[0040] In some embodiments, the system 10 includes one or more heater 110 for introducing heat energy into the volume of fluid 50 for the purpose of raising the fluid temperature. In other embodiments, the system 10 further includes one or more pump 310, flow control valve 320, and/or flowmeter 330 in fluid communication with the volume of fluid 50.

[0041] Referring to FIG. 1, some methods of the present invention comprise positioning a module 200 fully within the tank 100 so as to submerge the module 200 in the volume of fluid 50. In this way, fluid from the volume of fluid 50 is allowed to flow against and/or into the membranes contained in the module, thereby allowing the fluid to come into contact with contaminants (not shown) so as to dissolve and/or otherwise break-up the contaminants. In some such embodiments, a low-pressure end of the pump 310 is in fluid communication with the module 200 so as to enable the pump 310 to draw fluid from the module 200. In this way, fluid from the volume of fluid 50 is allowed to continually flow past the contaminants, into the module, and back out of the module, carrying the dissolved and/or otherwise broken-up portions of the contaminants away from the module 200.

[0042] Referring to FIG. 1, an alternative method of the present invention comprise positioning a module 200 fully within the tank 100 so as to submerge the module 200 in the volume of fluid 50. In this way, fluid from the volume of fluid 50 is allowed to flow against and/or into the membranes contained in the module, thereby allowing the fluid to come into contact with contaminants (not shown) so as to dissolve and/or otherwise break-up the contaminants. In this embodiment, a low-pressure end of the pump 310 is in fluid communication with the tank 100 so as to enable the pump 310 to draw fluid from the tank 100. In this way, fluid from the volume of fluid 50 is allowed to continually flow past the contaminants, across the surface of the membranes within the module, and back into the tank 100, carrying the dissolved and/or otherwise broken-up portions of the contaminants away from the module 200.

[0043] Referring to FIG. 2, other methods of the present invention comprise connecting the tank 100 to the module 200 such that a high pressure end of the pump 310 is in fluid communication with the module 200 so as to allow the pump 310 to force fluid from the volume of fluid 50 through the module 200. In this way, fluid from the volume of fluid 50 is allowed to continually flow through the module 200 so as to dissolve and/or otherwise break-up contaminants without requiring the module to be removed from its normal place of operation. In this embodiment, fluid from volume of fluid 50 can flow through the membranes contained in the module, across the surface of the membranes contained in the module, or both.

[0044] In some embodiments, the volume of fluid consists of a solution that includes a solvent and one or more additives, such as a reducing agent and/or an enhancing agent. In some embodiments, the solution composition includes 0.5 to 5.0 wt. % ascorbic acid. In other embodiments, the solution composition includes 0.5 to about 5.0 wt. % sodium ascorbate or other ascorbate salt. In still other embodiments, the solution composition includes 0.5 to 5.0 wt. % ascorbic acid and an inorganic acid to adjust the solution pH to between 1.5 and 3.5. In yet other embodiments, the solution composition includes 0.5 to 5.0 wt. % sodium ascorbate or other ascorbate salt and an inorganic acid to adjust the solution pH to between 1.5 and 3.5. In still yet other embodiments, the solution composition includes 0.5 to 5 wt. % ascorbic acid and 0.5 to 2.0 wt. % sodium bisulfite, sodium metabisufite, or sodium hydrosulfite. In yet other embodiments, the solution composition includes 0.5 to 5.0 wt. % sodium ascorbate or other ascorbate salt, and 0.5 and 2.0 wt. % sodium bisulfite, sodium metabisulfite, or sodium hydrosulfite.

[0045] Some embodiments of the present invention are particularly well-suited for PVDF membranes. In some such embodiments, ascorbic acid is used as a cleaning agent on PVDF membranes, alone or in conjunction with one or more enhancing agent, to remove contaminants such as metal oxides and/or metal hydroxides.

[0046] Ascorbic acid generally is available as a solid material (powder or granules), and must first be dissolved in a solvent prior to use as a membrane cleaning agent. In some embodiments, the ascorbic acid is diluted to as low as 0.5 wt. %. In other embodiments, the ascorbic acid is diluted to around 1 to 2 wt. %.

[0047] In some embodiments, the present invention obtains commercial importance by allowing membranes that are subject to ferric floc fouling and that have suffered significant declines in water permeability and water production to be cleaned, and thereby have their capacity restored and life extended. In some such embodiments, operation at higher flux and water production and lower transmembrane pressure is achieved. This is particularly advantageous with submerged membrane applications where, for practical purposes, transmembrane pressure is limited to 11 pounds per square inch (psi).

[0048] In some embodiments of the present invention, a cleaning methods facilitate running ferric floc applications at a higher flux because such embodiments facilitate quick and efficient cleaning of fouled membranes. In other embodiments, more efficient removal of the ferric floc facilitates membrane permeability at higher levels, resulting in longer membrane life. Both higher flux and longer life translate into a significant commercial advantage.

[0049] Some methods of preferred embodiments can be used in conjunction with CEB, MC, and CIP.

[0050] The methodology for conducting a CEB, MC, or CIP depends on the configuration of the membrane system. Where a pump is used to pressurize the feed and create a positive feed-to-filtrate differential pressure across the membrane, and where the membranes are encased in a pressure vessel, the membrane system is referred to as a pressurized system. Where a pump is used to create a vacuum on the filtrate side of the membrane and create a negative feed-to-filtrate differential pressure via vacuum, the membrane system is referred to as a submerged or immersed system.

[0051] In some embodiments, pressurized membrane system CEB is conducted by injecting cleaning chemical into the filtrate during backwash, followed by a soak period. In other embodiments, pressurized system MC and CIP are conducted by mixing cleaning chemicals in a tank and then recirculating the solution across the feed side of the membrane and back to the tank for a given period of time, followed by a soak period, and in some instances ending with a second recirculation period. In some embodiments, feed-side recirculation is conducted by recirculating from feed port to concentrate port, from concentrate port to feed port, or in an alternating or sequential arrangement. In some embodiments, during recirculation, a portion of the cleaning solution is allowed to permeate the membrane and be directed back to the tank in order to enhance reduction and solubilization of the ferric floc or oxidized metals.

[0052] In some embodiments, the membranes are contacted with the solution at ambient temperature. In some such embodiments, depending upon the temperature of the filtrate and temperature of the atmosphere in which the filtrate is stored, the solution temperature ranges from 1 to 40 degrees Celsius (° C.). In other embodiments, the membranes are contacted with the solution at elevated temperature. In some such embodiments, depending upon the allowable temperature at which the membranes can be contacted with the solution, the solution temperature ranges from 15 to 95° C.

[0053] In some embodiments, CEB and MC typically are conducted using ambient temperature solution. In other embodiments, CIP is conducted using heated solution, depending on the ambient temperature of the filtrate. In some embodiments, higher cleaning solution temperatures are used to increase dissolution and displacement of solids compared to cleaning at ambient temperature. In other embodiments, longer soak and/or recirculation times are used to compensate, in part or in whole, for cleanings conducted at ambient temperature.

[0054] In some embodiments, vacuum system membrane CEB is conducted by injecting a cleaning chemical into the filtrate during backwash, but with the tank in which the membranes are housed drained of feed. Following backwash and a pre-determined soak period, the tank is re-filled with feed and the membranes contacted with diluted cleaning chemical for a given soak period. In some such embodiments, coarse bubble aeration is applied intermittently during the soak period to agitate the membrane fibers and to mix the cleaning solution. CEB and MC are, in most cases, synonymous with vacuum systems. In other embodiments, the CEB is conducted by injecting a cleaning chemical into the filtrate during backwash, but with the tank in which the membranes are housed filled with feed.

[0055] In some embodiments, vacuum membrane system CIP is conducted in a manner similar to CEB but with stronger chemical solutions and with longer soak periods. In other arrangements, a pump is used to recirculate cleaning solution between the membrane tank and a tank used to prepare cleaning solution (feed recirculation mode). In alternative configurations, the permeate pump is used to draw cleaning solution through the membrane and recirculate back to the membrane tank (permeate recirculation mode). In most instances, filtrate used during the backwash sequence of CIP is not heated, as the benefits of heating are limited once the tank is filled with unheated feed.

[0056] In some embodiments, conducting CIP with a vacuum membrane system includes removing a membrane array (rack or cassette) from the membrane tank and inserting it into a ‘dip’ tank. In some such embodiments, the dip tank is equipped with a heater, permeate pump, coarse air supply system, and/or a means to add cleaning chemical to the tank, either in pre-solution or neat form. In some embodiments, use of the dip tank provides a means to conduct CIP using heated solutions, and with both feed and permeate recirculation.

[0057] Once the cleaning is completed, the cleaning solution is flushed from the membranes, membrane modules, and membrane system before returning the membranes to service by reconnecting to the normal fluid flow.

[0058] In some embodiments, CIP is carried out manually or by means of fully automated systems that activate in response to pressure differentials, rate of trans-membrane pressure (TMP) increase, and/or after predetermined module operating times.

[0059] In some embodiments, cleaning solution containing ascorbic acid or ascorbate salt, alone or in conjunction with one more enhancing agents, is used with both pressurized and vacuum membrane systems using any or all of the CEB, MC, and CIP configurations described herein.

[0060] In some embodiments of the present invention, the membranes are cleaned with a 2% ascorbic acid solution at 40 degrees Celsius. In some such embodiments, the membrane is allowed to soak in the solution for ten to twelve hours.

TEST RESULTS

[0061] Bench scale membrane cleaning study results comparing the effectiveness of various methods are summarized in Table 1, below, with reducing agent percentages representing percentage weight to volume. Tests were conducted by soaking single fiber test specimens in static solutions (“static soak”) having either ascorbic acid, sodium metabisulfite (“SBS”), a proprietary cleaning solution (“Avista 127”), or citric acid. Each test specimen had an average (plus or minus approximately 25%) initial “pre-clean” permeability of approximately 17.2 gallons per square foot per day (“GFD”) per pound per square inch (“psi”). Permeability was measured (with a certainty of approximately plus or minus 15%) after approximately 6 hours and/or 24 hours.

TABLE-US-00001 TABLE 1 Post Clean Permeability Resists (Avg. Pre-clean Permeability = 17.2 GFD/psi) Perme- Perme- ability ability (GFD/psi) (GFD/psi) No. Sample ID Temperature 6 Hours 24 Hours 1 0.5% Ascorbic Acid Ambient 26.6 26.9 2 1% Ascorbic Acid Ambient 24.6 36.5 3 0.5% Ascorbic Acid Heated to 35° C. 29.3 33.9 4 1% SBS Ambient 17.7 19.8 5 2% SBS Ambient 20.1 20.8 6 1% Avista 127 Ambient 20.2 26.6 7 1.5% Avista 127 Ambient 28.2 8 2% Avista 127 Ambient 41 9 2% Avista 127 Ambient 40.8 (w/vacuum) 10 0.5% Avista 127 Heated to 35° C. 55.1 (w/vacuum) 11 0.2% Avista 127 Heated to 35° C. 51.6 (w/vacuum) 12 1% Citric Acid* Ambient 26.1 26.4 13 1% Citric Acid* Heated to 35° C. 26.2 26.7

[0062] Based on the bench scale cleaning study results, an enhanced recovery clean (RC) protocol was developed to test the effectiveness of ascorbic acid and Avista 127 cleaning agents on full-scale UF cassettes using the two existing dip tanks. Two trains (identified as UF Trains 4 and 12) were selected for the enhanced RC. In preparation, both trains were first cleaned using a standard hypochlorite recovery clean protocol (600 mg/L chlorine followed by 2% citric acid). The trains were placed in supervisory mode before and after RC to allow operation at fixed permeate flow. Table 2, below, lists the operating parameters (with a certainty of approximately plus or minus 15%) that were recorded prior to and following the standard hypo RC.

TABLE-US-00002 TABLE 2 Operating Parameters Before and After Standard Hypochlorite RC UF Train #4 - UF Train #12 - Avista 127 Ascorbic Acid Before After Before After hypochlorite hypochlorite hypochlorite hypochlorite Operating Parameters Clean Clean Clean Clean Feed Water Temperature (in ° C.) 26.2 24.4 26.2 24.4 Permeate Flow (in gpm) 1,625 1,630 1,625 1,629 Membrane Flux (in gfd) 20.00 20.06 20.00 20.05 Transmembrane Pressure, TMP (psi) 4.65 3.13 3.4 2.51 Temperature Corrected Permeability 3.71 5.77 5.07 7.19 (@ 20° C. in gfd/psi)

[0063] When in supervisory mode, train permeate flow was maintained near 1,625 gpm flow in order to match the membrane flux that could be achieved when individual cassettes were operated in the dip tanks based on the rated flow capacity of the dip tank permeate pumps (125 gpm @40 ft TDH). However, the dip tank permeate pumps were able to deliver only 70 gpm and consequently, the transmembrane pressure (TMP) recorded during the Enhanced RCs could not be compared with those exhibited during supervisory mode operation. Table 3, below, summarizes the chemical concentrations & cleaning conditions used when the Enhanced RCs were conducted with thirteen cassettes from each of the two trains (Trains 4 & 12). Hydrochloric acid (“HCl”/“muriatic acid”) was used to adjust pH of Avista 127, as necessary.

TABLE-US-00003 TABLE 3 Enhanced Recovery Cleaning Summary for UF Trains 4 and 12 UF Chemical and Weight Solution Dip Cleaning Train # Cassette #s Weight (dry) (dry-lbs) pH.sup.1 Tank Duration (hrs) Temp. 4 1 0.2 wt % Avista 127 70 3.0-3.5 A 24 >35° C. 4 2 & 3 0.2 wt % Avista 127 70 3.0-3.5 A 11 >35° C. 4 4 & 5 0.2 wt % Avista 127 70 3.0-3.5 A 11 >35° C. 4 6 & 7 0.2 wt % Avista 127 70 3.0-3.5 A 11 >35° C. 4 8 & 9 0.2 wt % Avista 127 70 3.0-3.5 A 11 >35° C. 4 10 & 11 1 wt % Avista 127 350 3.0-3.5 A 11 >35° C. 4 12 & 13 1 wt % Avista 127 350 3.0-3.5 A 11 >35° C. 12 1 2 wt % Ascorbic Acid 700 3.0-3.5 B 24 >35° C. 12 2 & 3 2 wt % Ascorbic Acid 700 3.0-3.5 B 11 >35° C. 12 4 & 5 2 wt % Ascorbic Acid 700 3.0-3.5 B 10 >35° C. 12 6 & 7 2 wt % Ascorbic Acid 700 3.0-3.5 B 10 >35° C. 12 8 & 9 2 wt % Ascorbic Acid 700 3.0-3.5 B 10 >35° C. 12 10 & 11 2 wt % Ascorbic Acid 700 3.0-3.5 B 10 >35° C. 12 12 & 13 1 wt % Ascorbic Acid 350 3.0-3.5 B 10 >35° C.

[0064] Permeability tests were conducted on fiber samples collected from various cassettes in UF Trains 4 (Avista 127) and 12 (Ascorbic Acid). The samples were coded to ensure no bias was introduced when the permeability of the cleaned fibers was measured. Table 4, below, summarizes the permeability results (with a certainty of approximately plus or minus 15%).

TABLE-US-00004 TABLE 4 Post Enhanced Recovery Clean Permeability Test Results Cassette Cleaning % in Batch Time Fiber Permeability Chemical wt. Cassette # Module # Solution (hrs) Location (GFD/psi)* Ascorbic 2.0% 1 1 1.sup.st 24 Edge 45.8 Acid 19 Middle 45.1 2.0% 5 1 2.sup.nd 10 Edge 55.0 19 Middle 41.1 2.0% 6 1 1.sup.st 10 Edge 51.0 19 Middle 54.0 1.0% 13 1 2.sup.nd 10 Edge 47.8 19 Middle 54.0 Avista 127 0.2% 1 1 1.sup.st 24 Edge 21.4 19 Middle 41.1 0.2% 5 1 2.sup.nd 11 Edge 33.6 19 Middle 43.6 0.2% 6 1 1.sup.st 11 Edge 21.5 19 Middle 67.3 1.0% 11 1 2.sup.nd 11 Edge 35.8 19 Middle 52.8 *Permeability result for a single fiber harvested from the designated UF cassette.

[0065] As shown in Table 1, the permeability results associated with ambient temperatures with static soak using 1% wt ascorbic acid and Avista 127 were measured at 36.5 GFD/psi and 26.6 GFD/psi, respectively. The dip tank cleans with heating and permeate recirculation resulted in average permeabilities of 50.9 GFD/psi (Cassette #13 in Train 12) and 44.3 GFD/psi (Cassette #11 in Train 14).

[0066] As shown in the above tables:

[0067] 1. Cassettes cleaned with 1 or 2% ascorbic acid had more uniform permeabilities (<20% difference between fibers from edge and middle modules). Cassettes cleaned with 0.2 and 1% Avista 127 showed significantly greater permeability variability (approx. 2 fold difference)/

[0068] 2. Longer cleaning time did not result in significant improvement in permeability (see permeability of fibers from Cassette #1, cleaned for 24 hours vs. Cassette #6, cleaned for less than 12 hours). However, the 24-hr ascorbic acid clean did result in more uniform clean across the cassette (approx. 45 gfd/psi across the cassette)

[0069] 3. Reducing ascorbic acid concentration to 1% had no discernable impact on cleaning effectiveness. (Compare Cassette #13 permeability to that from Cassettes #1, #5 and #6.)

[0070] 4. Increasing Avista 127 concentration to 1% resulted in more uniform permeability (Cassette #11). However, uniformity was less than with ascorbic acid (compare Cassettes #11 and #13.)

[0071] 5. Ascorbic acid cleaning effectiveness is not diminished when the solution is used to clean a second cassette (Cassettes #5, #6, & #13)

[0072] Full scale performance testing of two trains (Trains 4 and 12) was conducted to quantify the effectiveness of the enhanced RCs in both restoring and maintaining train permeability. Avista 127 was used with the first train (Train #4) and ascorbic acid was used with the second train (Train #12). A third train (Train #8) was selected as a control train (only cleaned with standard hypo and citric acid RC solutions). Each train is represented in the charts of FIGS. 3 and 4.

[0073] Based on the trends shown on FIGS. 3 and 4, the Trans-membrane Pressure (“TMP”) is significantly lower and the temperature-corrected permeability (“TCP”) significantly higher for Train 12 cleaned with 2%/1% ascorbic acid compared with TMP and TCP for Train 4 cleaned with 0.2%/1% Avista 127. Surprisingly and unexpectedly, Train 4 TCP is lower than the control train (Train 8) that has not undergone an enhanced RC. The following conclusions can be drawn from the trends for these three trains:

[0074] 1. Cleaning with ascorbic acid increased Train 12 TCP by nearly 100% (compared to control Train 8).

[0075] 2. TMP of Train 12 following the ascorbic acid clean is much more stable than that of the control train.

[0076] 3. Operation at fixed flux results in more stable permeability and TMP for all trains

[0077] An additional single fiber cleaning trial was conducted to evaluate the ability of 2% citric acid to restore cassette permeability. Results from the single fiber cleaning trials showed poor permeability improvements for citric acid (see Table 1). Consequently, the use of citric acid for future Enhanced RCs was dismissed. Also, the results for Citric Acid cleaned single fibers (see Table 1) from the bench scale cleaning study did not support the data trends observed for Train 8 during the performance testing.

[0078] Performance testing for Train 12 was extended beyond 14-days in order to see when the TMP rise rate would match the control train and what TMP would result at the end of the 30-day filtration cycle (before a standard RC is conducted). Given the low observed TMP rise rate and sustained permeability, the Train 12 permeate flow was increased to 2,500 gpm (while in supervisory, fixed flow mode) to evaluate the impact of higher flux operation on TCP and TMP rise rate. Based on the low TMP readings shown in FIG. 5, it is clear that cleaning the Train 12 cassettes using the Enhanced RC protocol (10 hours of permeate recirculation with heated 2% ascorbic acid solution at pH˜3) provides excellent and sustained permeability restoration.

[0079] In the foregoing description, certain terms have been used for brevity, clearness and understanding; but no unnecessary limitations are to be implied therefrom beyond the requirements of the prior art, because such terms are used for descriptive purposes and are intended to be broadly construed. Moreover, the description and illustration of the inventions is by way of example, and the scope of the inventions is not limited to the exact details shown or described.

[0080] Although the foregoing detailed description of the present invention has been described by reference to an exemplary embodiment, and the best mode contemplated for carrying out the present invention has been shown and described, it will be understood that certain changes, modification or variations may be made in embodying the above invention, and in the construction thereof, other than those specifically set forth herein, may be achieved by those skilled in the art without departing from the spirit and scope of the invention, and that such changes, modification or variations are to be considered as being within the overall scope of the present invention. Therefore, it is contemplated to cover the present invention and any and all changes, modifications, variations, or equivalents that fall with in the true spirit and scope of the underlying principles disclosed and claimed herein. Consequently, the scope of the present invention is intended to be limited only by the attached claims, all matter contained in the above description and shown in the accompanying drawings shall be interpreted as illustrative and not in a limiting sense.

[0081] Having now described the features, discoveries and principles of the invention, the manner in which the invention is constructed and used, the characteristics of the construction, and advantageous, new and useful results obtained; the new and useful structures, devices, elements, arrangements, parts and combinations, are set forth in the appended claims.

[0082] It is also to be understood that the following claims are intended to cover all of the generic and specific features of the invention herein described, and all statements of the scope of the invention which, as a matter of language, might be said to fall there between.