WATER TREATMENT SYSTEM AND METHOD
20170297929 · 2017-10-19
Inventors
- Michael James Whitaker (Noble Park, AU)
- Alastair Lockey (Canterbury, AU)
- Abhyuday Bhartia (Mulgrave, AU)
- Peter John Meikle (Mont Albert, AU)
- Sharmen Rajendran (Oakleigh East, AU)
Cpc classification
C02F2209/10
CHEMISTRY; METALLURGY
C02F1/008
CHEMISTRY; METALLURGY
C02F2209/003
CHEMISTRY; METALLURGY
C02F2209/008
CHEMISTRY; METALLURGY
C02F2209/001
CHEMISTRY; METALLURGY
C02F1/5209
CHEMISTRY; METALLURGY
C02F2103/34
CHEMISTRY; METALLURGY
International classification
Abstract
Disclosed herein is a water treatment system for connection to a water treatment plant (e.g. a dissolved air flotation device). The plant may have an inlet for the receipt of feed water (e.g. waste water) and an outlet for the discharge of treated water. The treatment system may comprise a first sensor disposed such that it is in fluidity communication with the feed water, and a second sensor disposed such that it is in fluidity communication with the treated water. The first and second sensors may be configured to sense parameters of the feed and treated water. The system may further comprise a first applicator (e.g. a pump) that is configured to discharge a treatment source (e.g. a chemical source) to the plant to treat the feed water. The disclosed system may be used to treat waste water (e.g. the treatment of effluent from oil refineries, petrochemical and chemical plants, natural gas processing plants, paper mills and general water treatment). The system has analogous applications in other processing methods that also use DAF, or very similar, systems, such as the processing of mineral ores and other such solid extraction processing methods.
Claims
1. A water treatment system for use with an apparatus which receives feed water and releases treated water, the system comprising: one or more feed water sensors to measure in substantially real-time a water quality metric of the feed water; one or more treatment sources to apply one or more treatments to the feed water; one or more treated water sensors to measure in substantially real-time a water quality metric of the treated water; and a processor and memory, the memory storing instructions that, when executed by the processor, cause the system to: receive data associated with the water quality metric of the feed water from the one or more feed water sensors and data associated with the water quality metric of the treated water from the one or more treated water sensors; and control the application of treatments from the one or more treatment sources; the memory storing further instructions that, when executed by the processor, cause the system to operate in a first mode or a second mode, wherein in the first mode: (a) the system implements the application of the one or more treatments from the treatment sources in accordance with an initial set of values and then monitors in substantially real-time the water quality metric of the treated water; (b) conducts a series of tests in which the application of each of the treatments is systematically varied from the initial value and monitors in substantially real-time the water quality metric of the treated water; (c) generates a model of the relationship between the application of the treatments and the water quality metric of the treated water; (d) selects a set of commissioning values from the model for the application of the one or more treatments that correspond to a best value for the water quality metric of the treated water; (e) repeats steps (a) to (d) using the set of commissioning values from step (d) as the initial set of values until either (i) the water quality metric of the treated water falls within a pre-determined water quality value, or (ii) there is no measurable improvement in the water quality metric as the application of the treatments is varied; (f) after either (i) the water quality metric of the treated water falls below a pre-determined value, or (ii) the controller determines that there is no measurable improvement in the water quality metric as the application of the treatments is varied, then the system selects a set of commissioned values for the application of the treatments which provides a desired water quality result; and wherein in the second mode; (g) the system outputs instructions to the one or more treatment sources to apply the treatments using the commissioned set of values from step (f) and continues to monitor in substantially real-time the water quality metric of either or both the feed water and the treated water; (h) if the controller detects that the water quality metric is outside (i) the desired water quality result, and/or (ii) a pre-determined range from the values measured during the first mode, for a pre-determined period of time, then the controller will implement the first mode again.
2. The water treatment system according to claim 1 wherein the tests involve varying the application of the treatments within a specified range from the initial value and the models are generated using response surface methodology.
3. The water treatment system of claim 1, wherein the apparatus includes a dissolved air flotation device (DAF).
4. The water treatment system of claim 1, wherein the water quality metric is total suspended solids (TSS).
5. A computer implemented method for treating feed water in a water treatment system, comprising: a first mode and a second mode, wherein the first mode comprises (a) applying one or more treatments from one or more treatment sources in accordance with an initial set of values and monitoring in substantially real-time a water quality metric of the treated water; (b) conducting a series of tests in which the application of each of the treatments is systematically varied from the initial value and monitoring in substantially real-time a water quality metric of the treated water; (c) generating a model of the relationship between the application of the treatments and the water quality metric of the treated water; (d) selecting a set of commissioning values from the model for the application of the one or more treatments that correspond to a best value for the water quality metric of the treated water; (e) repeating steps (a) to (d) using the set of commissioning values from step (d) as the initial set of values until either (i) the water quality metric of the treated water falls below a pre-determined water quality value, or (ii) there is no measurable improvement in the water quality metric as the application of the treatments is varied; and (f) after either (i) the water quality metric of the treated water falls within a pre-determined value, or (ii) there is no measurable improvement in the water quality metric as the application of the treatments is varied, selecting a set of commissioned values for the application of the treatments which provides a desired water quality result; wherein the second mode comprises; (g) applying the treatments using the commissioned set of values from step (f) and continuing to monitor in substantially real-time the water quality metric of either or both of the feed water and the treated water; and (h) if the water quality metric is (i) outside the desired water quality result, and/or (ii) a pre-determined range from the values measured during the calibration mode, for a pre-determined period of time, implementing the first mode again, system includes a communication apparatus to transmit and/or receive data to/from a remote device, including the sensor data and/or the values for the application of the treatments and/or messages, including alarms.
6. A treatment system for connection to a treatment plant, the plant having an inlet for the receipt of feed fluid and an outlet for the discharge of treated fluid, the treatment system comprising; a first sensor disposed such that it is in fluidity communication with the feed fluid, the first sensor being configured to sense a first parameter of the feed fluid; a second sensor disposed such that it is in fluidity communication with the treated fluid, the second sensor being configured to sense a second parameter of the treated fluid; a first applicator connected to a first treatment source and to the plant, the first applicator configured to discharge the first treatment source to the plant; and a processor and memory connected via a data network, the memory storing instructions that, when executed by the processor, cause the system to: receive first data values from the first sensor and second data values from the second sensor, the first data values being associated with the sensed first parameter of the feed fluid and the second data values being associated with the sensed second parameter of the treated fluid; conduct a plurality of treatment tests, each test comprising generating test instructions, outputting the test instructions to the first applicator to discharge the first treatment source to the plant, receiving the second data values from the second sensor, and storing the received second data values; generate modeling data in dependence on the plurality of tests, the modeling data being representative of a relationship between the first treatment source discharged to the plant and the second data values, and generate dosing instructions in dependence on the generated modeling data, and output the generated dosing instructions to the first applicator.
7. A treatment system in accordance with claim 6, wherein the first applicator comprises a first pump, the first pump being fluidically connected to the plant and the first treatment source.
8. A treatment system in accordance with claim 7, wherein the first pump is configured to discharge a variable flow rate of the first treatment source to the plant.
9. A treatment system in accordance with claim 6, further comprising; a second applicator connected to a second treatment source and to the plant, the second applicator configured to discharge the second treatment source to the plant; and wherein each test further comprises outputting the test instructions to the second applicator to discharge the second treatment source to the plant.
10. A treatment system in accordance with claim 9, wherein the second applicator comprises a second pump, the second pump being fluidically connected to the plant and the second treatment source and configured to discharge a variable flow rate of the second treatment source to the plant.
11. A treatment system in accordance with claim 10, wherein the modeling data is representative of a relationship between the first treatment source discharged to the plant, the second treatment source discharged to the plant, and the second data values.
12. A treatment system in accordance with claim 11, the memory stores instructions that, when executed by the processor, cause the system to output the generated dosing instructions to first and second pumps.
13. A treatment system in accordance with claim 9, further comprising: a third sensor disposed such that it is in fluidity communication with the feed fluid, the third sensor being configured to sense a third parameter of the feed fluid; and a fourth sensor disposed such that it is in fluidity communication with the treated fluid, the fourth sensor being configured to sense a fourth parameter of the treated fluid. the memory storing further instructions that, when executed by the processor, cause the system to receive and store the third data values from the third sensor and fourth data values from the fourth sensor, the third data values being associated with the sensed third parameter of the feed fluid and the fourth data values being associated with the sensed fourth parameter of the treated fluid.
14. A treatment system in accordance with claim 13, wherein the modeling data is representative of a relationship between the first treatment source discharged to the plant, the second treatment source discharged to the plant, and the first, third and fourth data values.
15. A treatment system in accordance with claim 14, wherein the plurality of tests comprises a first test, the memory storing further instructions that, when executed by the processor, cause the system to select first test instructions for the first test and output the first instructions to the first and second applicators, and store the sensed first, third and fourth data values.
16. A treatment system in accordance with claim 15, wherein the memory stores further instructions that, when executed by the processor, for a subsequent test, cause the system to select varied test instructions in dependence on the sensed first, third and fourth data values stored during the first test, output the varied test instructions to the first and second applicators, and store the sensed first, third and fourth data values.
17. A treatment system in accordance with claim 16, wherein the memory stores further instructions that, when executed by the processor, for each subsequent test, cause the system to select varied test instructions in dependence on the sensed second and fourth data values stored during the previous test, output the varied test instructions to the first and second applicators, and store the sensed second and fourth data values.
18. A treatment system in accordance with claim 17, wherein the memory stores further instructions that, when executed by the processor, cause the system to conduct a predetermined number of tests.
19. A treatment system in accordance with claim 13, wherein the memory stores further instructions that, when executed by the processor, cause the system to monitor one or more of the first, second, third and fourth data values associated with the first, second, third and fourth parameters respectively following the generation and output of the dosing instructions to first and second applicators, and generate varied dosing instructions in dependence on the monitored values.
20. A treatment system in accordance with claim 19, wherein the memory stores further instructions that, when executed by the processor, cause the system to monitor one or more of the first, second, third and fourth data values associated with the first, second, third and fourth parameters respectively following the generation and output of the varied dosing instructions, and when the monitored values are outside a predetermined range of values, re-conduct the plurality of tests and generate revised modeling data in dependence on the plurality of tests.
Description
BRIEF DESCRIPTION OF DRAWINGS
[0115] Various embodiments/aspects of the disclosure will now be described with reference to the following drawings in which:
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DETAILED DESCRIPTION
[0126] A detailed description of one or more embodiments of the invention is provided below, along with accompanying figures that illustrate by way of example the principles of the invention. While the invention is described in connection with such embodiments, it should be understood that the invention is not limited to any one embodiment. On the contrary, the invention encompasses numerous alternatives, modifications and equivalents.
[0127] For the purpose of example, numerous specific details are set forth in the following description in order to provide a thorough understanding of the present invention. The present invention may be practiced according to the claims with some or all of these specific details depending on the embodiment chosen for the purpose. For the purpose of clarity, technical material that is known in the technical fields related to the invention has not been described in detail so that the present invention is not unnecessarily obscured.
[0128] The following terminology will be referred with reference to the chemicals used to treat waste water in the disclosed DAF system: [0129] An acid and/or a base, for pH adjustment of the waste water stream to aid in the demobilization of the colloids in the effluent, will generally be referred to as “suspended solids”, causing these particles to come out of suspension. [0130] Chemicals that aid in the demobilization of the colloids will generally be referred to as “coagulants”. The purpose of a coagulant is to reduce the surface potential of the colloidal particles. Coagulants are typically positively charged molecules which provide an avenue for the colloids to aggregate. [0131] Chemicals that cause particles in a dispersion to form larger aggregates/flocs and come out of solution, easing the separation from the liquid phase and aiding the clarification process, will generally be referred to as “Flocculants”.
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[0133] The DAF system 200 receives feed water at one end, into inlet chamber 210, where treatment begins. The partially treated water proceeds to the main DAF chamber 220, where further treatment enables sludge to be generated and transferred into sludge hopper 230, while the treated (i.e., clarified) water enters the outlet chamber 240. The sludge and treated water are then separately discharged.
[0134] The control cabinet 300 of the water treatment apparatus, shown in more detail in
[0135] In the embodiment shown in
[0136] To determine whether an adjustment is required, the controller receives data from a plurality of sensors or instruments that sense a metric (e.g. a parameter) of the water that is indicative of water quality and conducts real-time tests to determine the optimum chemical dosages. In another form, a metric (e.g. a parameter) may be measured that is a proxy for determining another water quality metric (e.g. measuring turbidity as a proxy for TSS levels). In one form, the data sensed by the sensor is outputted to a transmitter, that then transmits the data to the IPC for analysis. In the particular embodiment shown in
[0137] Other sensors, not shown in the embodiment of
[0138] Similarly, in other embodiments, the controller 310 may be configured to control settings other than the outputs of the chemical dosing pumps, such as scraper speeds, solenoids, motors, valves, decanters, pumps (other than chemical dosing) and other ancillaries used with a DAF system alongside post treatment processes to further treat the water or sludge.
[0139] The controller 310 may include a display 315 to display the sensor data and other information (such as historical information or alarm notifications) to a user. The display 315 may comprise a HMI touch-screen system allowing user input to be received by controller 310, although other user input means may also be used.
[0140] The controller 310 may further include, or interface to, communication apparatus to transmit the data to a database or data storage system offside. The communication apparatus may be cabled, but is preferably wireless—for example, a WiFi, Bluetooth or 3G/4G cellular transmitter and/or receiver.
[0141] A video/surveillance camera 500 (e.g. an industrial camera) is also provided, and images and/or videos may be transmitted from the video camera 500 to a remote monitoring device to trouble-shoot or identify abnormalities in the operation of the water treatment system.
[0142] The present invention enables automatic management and optimization of the treatments used in the water treatment system—in particular, with respect to
[0143] The user may nominate a desired water quality result for the treated water from a range of options. In one option, the system may be set manually to provide the “Best Water Quality” i.e., the best possible water quality through the best separation of solids (obtained by optimal and precise dosing of coagulants, flocculants, pH modifiers or combinations thereof). Alternatively, the system may be set manually to provide the “Minimum Chemical Usage” to maintain a nominally acceptable water quality, while using the lowest possible amount of chemicals.
[0144] However, in a preferred embodiment of the present invention, a user may set the system to “minimum overall cost” (e.g. balanced or automatic) mode (i.e. Ha mode that corresponds to the minimum aggregate of trade waste and chemical costs) after the commissioning stage, wherein it determines the dosing levels to be applied during operation that result in a reduced overall operating cost of the system. Specifically, the inventors recognize that although highly clarified water may require greater chemical dosing (increasing the overall chemical cost involved in treating the water), the discharge cost of less turbid water is likely to be lower. Accordingly, in the “Automatic” mode, the present invention balances these two costs to lower the overall cost of the treatment process.
[0145] The desired water quality result can be selected by an operator, and set by providing an input to the controller 310 (e.g. via a touch screen 315, via a remote connection, etc.). The setting could, for example, be in the form of a simple on-screen slider, indicating the desired discharge water quality, as shown for example in
[0146] In “Automatic” mode, the controller 310 will determine after the commissioning mode the appropriate dosing levels used in the water treatment system 100. Specifically, in this embodiment, the controller 310 is provided with an “Automatic Commissioning” capability that allows an installer to set the nominal initial control parameters, that will be subsequently modified in a controlled fashion by an algorithm or a combination of algorithms by means of controller 310 in order to develop a model describing control parameters to achieve the selected objective in an operation mode (e.g. maximum water quality or minimum chemical consumption) in response to the DAF inflows. This may be performed over an initial commissioning period of approximately 10 days. The generation of the model will be described in detail below with respect to an illustrative example.
[0147] The nominal initial control parameters may also be retrieved from a remote server, by either suitable cabled or wireless apparatus (e.g. the nominal initial control parameters may be retrieved witlessly from memory located within the cloud).
[0148] For illustrative purposes, an example commissioning process is described below. First, upon initialization of the system, the user may select from a choice of default settings, such as “Abattoir”, “Dairy”, “Oil Dense” or “General” setting. Other default or user-configurable settings may be provided. These may provide default initialization information such as maximum pump speeds, volume of the DAF system, etc.
[0149] Of particular note, initialization information may include a typical chemical cost (e.g. $ per liter), to enable the system to compute and monitor the impact of increasing chemical dosing levels. The cost of chemicals as well as trade waste discharge costs can be provided to the controller 310, by a user via touch-screen 315 or from a remote database, in order to allow the controller 310 to calculate the output water quality metric value which results in the minimum total operating cost.
[0150] Once the initial parameters are entered into the system, the system can begin a first mode (e.g. “Automatic Commissioning” mode). In this mode, a sequence of initial tests to perform is generated or retrieved from a database (e.g. a remotely connected database) which incorporates a few combinations of values for each of the controlled variables. The number of initial tests performed is limited to a predetermined number based on available commissioning time, and tests are performed in succession until the resulting water quality metric, in this case outlet TSS, falls within an acceptable dead band to begin the RSM and steepest descent tests (e.g. TSS levels of 500 mg/L to 200 mg/L). If all tests are conducted with no results in this band, the lowest result above this dead band is taken as the starting value. This ensures that the algorithm will function correctly without being affected by excessive noise, while starting in close proximity to the minimum value, reducing the number of tests required.
[0151] As the tests are conducted by the system in this embodiment, the controller 310 receives the sensor data, intermittently or continuously, and averages it over a time period. An algorithm (e.g. an RSM algorithm) is then used to allow the system to learn how to reduce the overall cost of treating the water. As will be evident to the skilled addressee, an RSM is an example of an algorithm that enables the disclosed system to be automated and other techniques could be implemented (e.g. alternative optimization algorithms and processes such as convex optimization) to automate the system.
[0152] The algorithm involves performing Central Composite Design (CCD) tests around the starting point. Once the CCD has been completed, a number of tests are then performed sequentially along the direction found by the CCD to be of steepest descent. When the error margin exceeds a threshold, a new starting point is taken and the process repeats. The tests take place sequentially as long as flow is present and the pH remains consistent and within limits. It will be evident to the skilled addressee that the utilization of ‘steepest descent’ in the detailed embodiment could take another form (e.g. a single-layer or multi-layer perception neural network). , or other methods may be utilized to automated the optimization process such as convex optimization.
[0153] For each test, once a certain volume, relative to the volume of the DAF, has passed through the DAF, the weighted average TSS result is stored as the output TSS value of the test.
[0154] This continues until a minimum output TSS value is achieved, at which point the value and operating parameters are stored, and a set of full factorial RSM tests are generated, which exclude values where any of the variables a-d increase, as this refers to an unnecessary increase in chemical consumption.
[0155] The full factorial sets are then conducted sequentially until complete. The generated full factorial surface is used to find a solution based on the position of the output TSS slider as configured by the user. The data obtained from these tests are used to calculate the outlet TSS for the ‘balanced’ mode as well as the operating parameters for various points on the slider.
[0156] The controlled variables that may be used in the RSM are the following: [0157] (a) pH; [0158] (b) a; [0159] (c) b; [0160] (d) c; and [0161] (e) d
[0162] In this example embodiment, the variables a-d are used in the coagulant and flocculant dosing equations, which are as follows:
coagulant dosing L/Hr=(a*Inlet TSS(mg/L)/1000+b)*Inlet flow (kL/Hr) (a)
flocculant dosing L/Hr =(c*Inlet TSS(mg/L)/1000+d)*Inlet flow (kL/Hr) (b)
[0163] Although the above equations relate to the dosing of flocculant and coagulant, a person skilled in the art would recognize that other embodiments of the invention may use different types of chemicals for dosing. Examples of other chemical types that may be dosed include, but are not limited to, precipitation reagents for removing dissolved metals, or water softening agents.
[0164] These five variables, plus the outlet TSS, are used to generate a model, in the fours of data associated with a multi-dimensional graph, where combinations of variables are tested and recorded. The initial priority for the “Automatic Commissioning” period is to minimize the outlet TSS concentration. Then, with the relevant chemical and trade waste cost infoimation (i.e., discharge costs of treated water, and/or sludge), the algorithm can be weighted to minimize the overall cost of the treatment process.
[0165] In the scenario that the pH reference value and linear operating regimes for coagulant and flocculant are to be used as RSM variables, the following variables can be used: [0166] pH, a, b, c and d.
[0167] Here, ‘a’ and ‘b’ are coefficients for a first order polynomial dictating the flow value through a coagulant pump that uses the inlet effluent quality metric as the independent variable ‘x’:
coagulant flow=a*x+b
[0168] Similarly, ‘c’ and ‘d’ are coefficients for a first order polynomial dictating the flow value through a flocculant pump that uses the inlet effluent quality metric as the independent variable ‘x’:
flocculant flow=c*x+d
[0169] The independent variable ‘x’ in this context refers to the water quality metric or a proxy.
[0170] Given a broader time constraint for the calibration period, a higher order polynomial can instead be used, introducing more coefficients to populate the CCD matrix. Here, x.sub.nis a given coefficient:
[0171] The model for the response surface is required to find the desired operating point. A computer is required for this due to the arithmetic complexity that is involved. For example, a QR-decomposition of a large square matrix is required when conducting Ordinary Least Squares estimation, which is beyond the capability of a human being.
TABLE-US-00001 A polynomial model for the outlet TSS is generated as a function of the variables used in the RSM tests, using the method of linear least squares regression. The surface is then used to evaluate the operating point with the lowest TSS value and shift the variables closer to this optimal value by a pre-determined step size, or by evaluating the gradient of the surface and choosing the operating point leading to the steepest descent. This step size is a function of the duration of the calibration period for each application, and can also be industry specific. A Central Composite Design (CCD) is applied to aid in the population of the operating point matrix, forming the basis of every experiment that is conducted. An example is shown below for a 5-variable experiment: −1 −1 −1 −1 1 −1 −1 −1 1 −1 −1 −1 1 −1 −1 −1 −1 1 1 1 −1 1 −1 −1 −1 −1 1 −1 1 1 −1 1 1 −1 1 −1 1 1 1 −1 1 −1 −1 −1 −1 1 −1 −1 1 1 1 −1 1 −1 1 1 −1 1 1 −1 1 1 −1 −1 1 1 1 −1 1 −1 1 1 1 −1 −1 1 1 1 1 1 −2 0 0 0 0 2 0 0 0 0 0 −2 0 0 0 0 2 0 0 0 0 0 −2 0 0 0 0 2 0 0 0 0 0 −2 0 0 0 0 2 0 0 0 0 0 −2 0 0 0 0 2 0 0 0 0 0
[0172] The values of the matrix above are in a normalized form and can be used to directly derive a set of testing operating points. The operating point corresponding to the center location (e.g. value) is defined by the context in which the CCD experiment is required. A value of ‘1’ in a cell corresponds to the center value plus the increment value corresponding to the column of the cell where the value is found. The increment value is dependent on the application of the technology and on the identity of the variable.
[0173] In a case where a simple option is required to be used, such as when no coagulant is to be used in operation, the variables ‘a’ and ‘b’ can be omitted. Doing so reduces the size of the experiment to 15 tests instead of the 27 tests required when 5 variables are used.
TABLE-US-00002 −1.0000 −1.0000 −1.0000 −1.0000 −1.0000 1.0000 −1.0000 1.0000 −1.0000 −1.0000 1.0000 1.0000 1.0000 −1.0000 −1.0000 1.0000 −1.0000 1.0000 1.0000 1.0000 −1.0000 1.0000 1.0000 1.0000 −1.6818 0 0 1.6818 0 0 0 −1.6818 0 0 1.6818 0 0 0 −1.6818 0 0 1.6818 0 0 0
[0174] For example, when creating a 5-variable CCD experiment, where the variables might be pH, a, b, c and d, the center operating point is [5.9616 0.0067 0.0652 0.4895 0.4416], and the increment vector is [0.1600 0.0004 0.0055 0.0209 0.0445]:
[0175] The design matrix X is dependent on whether a full quadratic model for the response surface or a pure quadratic mode is required. A pure quadratic model assumes finite coefficients for all terms in the multi variable polynomial describing the value of the outlet TSS as a function of the operating parameters, except the interaction terms. A full polynomial model includes the interaction terms. For example, when both the coagulant and flocculant are being dosed and the pH set point is within the prescribed tolerances, the polynomial below is used to define the response surface with a pure quadratic mode:
[0176] The following polynomial is used to define the response surface with a full quadratic model:
[0177] To generate the coefficients x.sub.n, an Ordinary Least Squares estimator is used:
x.sub.n=(X.sup.T*X).sup.−1*X.sup.T*y
[0178] Here, ‘X’ is defined as the design matrix, and is dependent on the type of model that is preferred to define the response surface. For a pure quadratic model, the following design matrix is applicable:
[0179] When a full quadratic model is used, the following design matrix is applicable:
[0180] The choice of model implemented by the system is a trade-off between accuracy and available computing power. Increasing the number of coefficients, significantly increases the computational time but increases the accuracy of the model. Other models may also be used, such as the quadratic model with interaction terms only, or higher order or non-polynomial models.
[0181] Once a polynomial model for the response surface has been generated, as estimate for the operating point with the lowest TSS value cn be made by finding a stationary point in the quadratric surface:
operating parameters=−1/2*B.sup.−1*b
[0182] ‘B’ is defined as:
[0183] ‘b’ is defined as:
[0184] If an optimal operating point is found within the scope of the RSM experiment, this point is evaluated as the final result of the steepest descent algorithm. An additional CCD experiment may be conducted centered at the operating point to confirm that this is the minimum point.
[0185] Values for the application of treatments determined at any stage during the commissioning process or normal operation, such as the control parameters described above, may be uploaded to a remote server, by either suitable cabled or wireless apparatus. The collection of these parameters may be used, either individually or in aggregate, to develop or improve the accuracy of the initial default settings, such as an “Abattoir” or “Dairy” setting.
[0186] During the “Automatic Commissioning” period, the progress of the automatic commissioning may be represented on the controller display, on a status/overview page, with a progress bar. This progress will be calculated based on the completed and remaining expected RSM tests to complete.
[0187] After completion of the ‘Automatic Commissioning’ phase, the controller 310 begins to run chemical dosing based on the input TSS as dictated by the RSM response surface. As will be evident to the skilled addressee, alternative outputs such as turbidity, colour and chemical oxygen demand may be used in lieu of TSS, to name a few. The precise mix of chemicals used may vary depending on the particular water treatment application, but for a DAF water treatment system, the chemical mix will typically include a flocculant, a coagulant, an acid and/or a base. The controller 310 may dose a pH modifier at the outlet of the DAF system using a PID loop based on a configurable pH set point. In some embodiments, the controller 310 may also dose an oxidant to the DAF system outlet based on a configurable pump speed set point or using a PID loop based on sensory data such as that obtained using an oxygen reduction potential sensor, as one possible option.
[0188] During normal system operation, the controller 310 continues to generate a more precise response surface directly around the current set point by performing full factorial tests with minute changes to the controlled variables. This will result in small deviations from the set point, within a tolerance. This serves to provide an accurate and updated response surface for the output TSS upon completion of the commissioning phase.
[0189] The operation of controller 310 can be toggled with a button on the main menu, depicted on the controller display or performed remotely. This button toggles between “Run” and “Shutdown” based on the current operating state of the controller 310. The operation of controller 310 can also be terminated using a signal from the client's program/system to a dedicated digital input on controller 310, allowing any external alarms raised by the customer's systems to shut down the controller 310 automatically.
[0190] In one embodiment, the controller 310 can be put into a “Manual” mode at any time, including during automatic commissioning. When in Manual mode, the controller 310 ceases to operate automatically. When the user accesses the DAF overview screen in Manual mode, any input can be varied either by changing the set points under the settings menu or by tapping on the desired graphic on the overview screen and changing its set point via a popup keypad. If the controller 310 is in automatic commissioning before entering Manual Mode, any test that is currently being performed will be terminated and restarted once Manual Mode is switched off.
[0191] During normal operation, the flocculant and/or coagulant (again, note that chemicals performing a similar function to those described could be applied) dosing is based on the RSM results. In some forms, a ramping function may be applied to increase the dosage of the flocculant and/or coagulant if the system determines that a water metric (e.g. TSS) increases beyond a predetermined threshold to ensure that the system is not under dosing the flocculant and/or coagulant during operation mode. In the event that the DAF inlet process composition changes from the typical process that was tested in the RSM auto commissioning phase, the flocculant and/or coagulant dosing factor increases slowly as the outlet TSS deviates from the expected result. If the flocculant and/or coagulant dosing factor is greater than 1, then the dosing factor automatically decreases after set time intervals. This will allow the dosing factor to return to 1.0 once the variance in the process ceases.
[0192] The controller may display real-time measurements of the system on a touch-screen 315 as ongoing status information, as shown in
[0201] Remote monitoring may be available by means of either suitable cabled apparatus (e.g. Ether net), or by wireless apparatus (in this embodiment, a 4G cellular service). The remote monitoring information may be provided to a mobile communication device, and may be viewable by a user on an app.
[0202] The Controller 310 may keep a log of all important sensor data and internal variables, alaiiiis, set points, calculated totaled flow, dosing curve data, and optionally backup this data remotely (i.e., to a server located remotely from the system). The controller 310 display may also be configured to display a log of important values over the past 24 hours in graphical format under the trend graph pages, as shown for example in
[0209] Periodic reporting may also be provided, for example setting out minimum, maximum, and average values collected for that period.
[0210] Relevant information stored on the Controller 310 may be transmitted to a remote server, by either suitable cabled or wireless apparatus, where it may be stored in a database. The controller may also retrieve from a remote server data, including (but not limited to): [0211] (a) Relevant inlet sensor data (e.g. TSS, temperature, pH, flow rate etc.); [0212] (b) Values for the application of treatments from the treatment sources (e.g. chemical dosing rates); [0213] (c) Alaiiiis and events in a chronological list; and/or [0214] (d) Chemical cost data. [0215] (e) Operating parameters.
[0216] As previously described, a live video feed of the operation of the DAF system may be provided by an internet protocol (IP) enabled camera mounted at a vantage point housed either on the control cabinet 300 or elsewhere where a good vantage of the water treatment apparatus may be obtained. The video footage may be stored on the hard drive or solid state drive of controller 310, using appropriately sized local storage. If the memory allocated to video storage on controller 310 becomes full, the oldest footage may be overwritten by new footage. The footage may be accessible to the end user from the controller display and may also be retrieved remotely from a remote connection to the controller 310.
[0217] Alarm functionality may be provided if functional anomalies are detected—for instance, exceedance of threshold values, excessive rates of change in sensor data—as well as issues in output performance. An alarm indicator may be visible at all times on the controller display, with a page to show all active alarms as depicted in
[0228] Alarms may be distributed by email or text message (or by other communication means) to relevant persons, and the surveillance footage recorded over the time of the alarm may also be transmitted along with the alarm notification.
[0229] An example logic sequence of the controller will now be described with reference to
[0230] An example flow diagram of the RSM process will now be described with reference to
EXAMPLE 1
[0231] The present invention was tested on waste water generated at an abattoir. The waste water from the abattoir contained high levels of fats and proteins which contributed to a high level of TSS in the effluent. At the abattoir, this value, measured in parts per million (ppm), fluctuated constantly between 6,000 and 30,000 ppm, with the average value being approximately 10,000 ppm.
[0232] Discharging an effluent stream with a high TSS count can be very costly for a client as part of the discharge cost, as prescribed by the relevant water authorities, is directly proportional to the TSS concentration of the discharged effluent. As a result, the managers of the abattoir opted to treat their waste water to reduce the TSS levels prior to discharging it. Prior to testing the present invention, the managers of the abattoir used a manually operated DAF system to treat the effluent stream, with the chemistry determined by an operator through jar testing.
[0233] Prior to testing the present invention at the abattoir, an operator would perform a number of jar tests using chemicals supplied by a specialist chemical provider. These jar tests needed to be carried out regularly, in response to dynamic inlet composition and flow rate variations signaled by a visible decline in the clarity of the waste water, in particular, following significant changes in upstream conditions, e.g. The abattoir moving to a different stage of the process. The outlet TSS levels achieved pursuant to regular jar tests by an operator fluctuated between approximately 200 ppm and 1200 ppm.
[0234] Before the present invention was tested at the abattoir, jar tests were conducted using the waste water. The mixture of dosing chemicals that resulted in the highest separation of solids in these jar tests was chosen as the starting point for the present invention. From this starting point, the present invention automatically began iteratively adjusting the relative flow rates of the dosing chemicals to try to achieve the lowest TSS levels for the treated water. No further human input or supervision was required.
[0235] At the time of this specification, the present invention had been tested at the abattoir for more than 6 months. The present invention reached the optimum chemical dosing mixture in about 48 hours, after approximately 60 iterations, which yielded outlet TSS levels of 91 ppm. In comparison, most operators would only be able to achieve outlet TSS levels between 200 and 300 ppm at best and would not be able to maintain this consistently. Additionally, this may change significantly when the composition of the inlet water changed as operators are not able to monitor this as precisely and regularly as an automated process with in-situ sensors.
[0236] Table 1 below summaries the change in outlet TSS levels at each iteration from immediately after the present invention was connected, until the auto commissioning stage was completed.
TABLE-US-00003 TABLE 1 Performance of the present invention from commissioning until reaching the optimum chemical dosing mixture Inlet TSS Outlet TSS Outlet TSS reduction Waste water flow rate (ppm) (ppm) (%) (m3/h) 5299 446 — 80 6056 141 98 80 5543 164 97 80 19219 201 99 80 1758 613 65 80 562 156 72 80 7302 596 92 80 7106 399 94 80 6887 223 97 80 6764 162 98 80 5934 135 98 80 5763 134 98 80 6642 124 98 80 8547 125 99 80 5739 111 98 80 5763 115 98 80 6081 118 98 80 6398 162 97 80 5543 129 98 80 4860 161 97 80 3858 182 95 80 2711 200 93 80 1807 202 89 80 2149 171 92 80 5299 237 96 80 82784 444 99 80 11990 6417 46 80 2247 246 89 90 1197 160 87 90 2100 137 93 86 3565 117 97 90 4249 99 98 90 4322 100 98 88 5397 97 98 90 6325 113 98 90 16606 98 99 88 6691 111 98 85 5788 101 98 90 5861 105 98 90 7180 124 98 90 7106 5080 29 88 806 486 40 54 4249 121 97 90 5128 1887 63 90 4444 106 98 87 4054 116 97 86 4029 116 97 85 4176 132 97 82 3907 139 96 83 4567 142 97 83 4884 148 97 81 5079 153 97 82 5495 157 97 90 5910 161 97 90 5372 177 97 90 3981 183 95 90 3468 399 88 90 4103 136 97 90 4005 115 97 87 4347 100 98 80 25250 203 99 68 10598 91 99 80
[0237] Table 2 below contains a summary of the projected annual savings at the abattoir, based on the results of testing the present invention on-site.
TABLE-US-00004 TABLE 2 Estimated annual savings generated by the present invention Estimated Annual cost annual cost Category Details (Before) (After) Chemicals Sulphuric Acid (98%) $70,200 $25,500 Caustic Soda (46%) $213,000 $28,800 Poly Aluminium Chloride $46,800 $0 (10%) Flocculant $213,300 $94,800 Labour Operator $156,000 $5,200 Waste water Council charges $1,230,000 $330,000 discharge costs Total costs $1,929,300 $484,300 Overall estimated annual savings $1,530,500
[0238] After approximately 6 months of testing the present invention at the abattoir, the quantity of chemicals required to treat the waste water was reduced significantly leading to substantial cost savings. In addition, the present invention determined that the optimum chemistry for the waste water at this abattoir did not require a coagulant, removing the need to utilize the coagulant—which would equate to an estimated saving of about AU$47,000 per annum. Besides reducing the quantity of the required dosing chemicals at the abattoir, the present invention would also generate considerable savings in other areas, including labor and trade waste discharge costs.
[0239] Parts of the software and system components may be housed in the “cloud”. This embodiment of the system is implemented by appropriate software providing instructions for operation of the computing system hardware to implement the system and methods of the detailed embodiment. Part of the system or the entire system may be portable, and may be implemented, for example, by a laptop or tablet computing device, smartphone or other portable computing device.
[0240] In some forms, the system may conclude that particular dosing chemicals are not required to meet the objectives of the user. In this instance, the operating cost of the system is significantly reduced as dosing chemicals that may previously have been considered as important to the treatment of feed water, are no longer required. Further, the system can provide substantial water quantity savings for users. For example, the treated water can be used as non-potable water supply for irrigation, washing of truck bays, etc. If the treated water undergoes further treatment downstream, such as disinfection and reverse osmosis, the water can be used in more applications such as makeup water for a cooling tower.
[0241] In at least one embodiment, the disclosed system performs a full factorial during modeling to determine the lowest chemical cost as well as to generate a slider.
[0242] The system has been described with reference to waste water treatment (e.g. the treatment of effluent from oil refineries, petrochemical and chemical plants, natural gas processing plants, paper mills and general water treatment). The system has analogous applications in other processing methods that also use DAF, or very similar, systems, such as the processing of mineral ores and other such solid extraction processing methods. For example, the system can be utilized to increase the yield of an input fluid, such as a mineral solids stream, to capture high value components in the input fluid, such as extracting mineral ores from a mineral solids stream. In this instance, the DAF system would be set-up to reduce the TSS to extract the high value solids in the sludge. This analogous use of the system is similar to the use of the disclosed system for waste water treatment, whereby the feed water is highly treated/clarified to either obtain highly clarified output water. When treating an input fluid for mineral ore extraction, the minerals of interest would be separated from the fluid in a sludge that is extracted from the DAF. Thus, the disclosed system, depending on the configuration, could be used to selectively extract components in a fluid stream, to obtain a sludge with a high concentration of required minerals.
[0243] The word ‘comprising’, and forms of the word ‘comprising’, when used in this specification is taken to specify the presence of stated features, integers, steps or components but does not preclude the presence or addition of one or more other features, integers, steps, components or groups thereof.
[0244] In this specification, where a document, act or item of knowledge is referred to or discussed, this reference or discussion is not an admission that the document, act or item of knowledge or any combination thereof was at the priority date, publicly available, known to the public, part of the common general knowledge; or known to be relevant to an attempt to solve any problem with which this specification is concerned.