System for joining resin and metal
09789672 · 2017-10-17
Assignee
Inventors
Cpc classification
B29C66/02245
PERFORMING OPERATIONS; TRANSPORTING
B29C65/72
PERFORMING OPERATIONS; TRANSPORTING
B29C65/1635
PERFORMING OPERATIONS; TRANSPORTING
B29C2793/0054
PERFORMING OPERATIONS; TRANSPORTING
B29C66/91423
PERFORMING OPERATIONS; TRANSPORTING
B29C66/41
PERFORMING OPERATIONS; TRANSPORTING
B29C65/06
PERFORMING OPERATIONS; TRANSPORTING
B29C66/3492
PERFORMING OPERATIONS; TRANSPORTING
B29C66/91443
PERFORMING OPERATIONS; TRANSPORTING
B29C66/7392
PERFORMING OPERATIONS; TRANSPORTING
B29C66/21
PERFORMING OPERATIONS; TRANSPORTING
Y10T156/1028
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
B29C66/91413
PERFORMING OPERATIONS; TRANSPORTING
B29C65/3656
PERFORMING OPERATIONS; TRANSPORTING
B29K2077/00
PERFORMING OPERATIONS; TRANSPORTING
B29C66/7212
PERFORMING OPERATIONS; TRANSPORTING
B32B37/04
PERFORMING OPERATIONS; TRANSPORTING
B29C66/71
PERFORMING OPERATIONS; TRANSPORTING
B32B37/08
PERFORMING OPERATIONS; TRANSPORTING
B29C66/45
PERFORMING OPERATIONS; TRANSPORTING
B29C66/30325
PERFORMING OPERATIONS; TRANSPORTING
B29C65/10
PERFORMING OPERATIONS; TRANSPORTING
B29C66/91933
PERFORMING OPERATIONS; TRANSPORTING
B29C66/028
PERFORMING OPERATIONS; TRANSPORTING
B29K2067/00
PERFORMING OPERATIONS; TRANSPORTING
B29K2055/02
PERFORMING OPERATIONS; TRANSPORTING
B29C65/44
PERFORMING OPERATIONS; TRANSPORTING
B29K2077/00
PERFORMING OPERATIONS; TRANSPORTING
B32B37/06
PERFORMING OPERATIONS; TRANSPORTING
B29C66/3474
PERFORMING OPERATIONS; TRANSPORTING
B29C65/3644
PERFORMING OPERATIONS; TRANSPORTING
B29C66/1122
PERFORMING OPERATIONS; TRANSPORTING
B29C66/91921
PERFORMING OPERATIONS; TRANSPORTING
B29C66/43
PERFORMING OPERATIONS; TRANSPORTING
B29C66/71
PERFORMING OPERATIONS; TRANSPORTING
B29K2067/00
PERFORMING OPERATIONS; TRANSPORTING
B29C66/7212
PERFORMING OPERATIONS; TRANSPORTING
B29C66/83413
PERFORMING OPERATIONS; TRANSPORTING
B32B37/0046
PERFORMING OPERATIONS; TRANSPORTING
B29C66/348
PERFORMING OPERATIONS; TRANSPORTING
B29C66/91935
PERFORMING OPERATIONS; TRANSPORTING
B29K2305/00
PERFORMING OPERATIONS; TRANSPORTING
B29C66/91951
PERFORMING OPERATIONS; TRANSPORTING
B29L2031/737
PERFORMING OPERATIONS; TRANSPORTING
B29K2055/02
PERFORMING OPERATIONS; TRANSPORTING
International classification
B32B37/08
PERFORMING OPERATIONS; TRANSPORTING
B32B37/04
PERFORMING OPERATIONS; TRANSPORTING
B32B37/00
PERFORMING OPERATIONS; TRANSPORTING
B32B37/06
PERFORMING OPERATIONS; TRANSPORTING
Abstract
A joining method for joining a resin member and a metal member by heating is provided. Joining of the resin member and metal member is performed by heating a joining interface of the resin member and metal member to a temperature in a range of equal to or higher than a decomposition temperature of the resin member and lower than a temperature at which gas bubbles are generated in the resin member and by cooling a surface of the resin member on the opposite side from a joining surface thereof with the metal member to a temperature that is lower than the melting point of the resin member.
Claims
1. A joining system, comprising: a resin; a metal that includes at least one concavity that is formed in a zone of the metal around a joining region of the resin and the metal; a heating tool configured to heat a joining interface of the resin and the metal from a top surface of the metal on an opposite side of the metal from a bottom joining surface of the metal in contact with the resin; and a cooling tool configured to cool a surface of the resin on an opposite side of the resin from a joining surface thereof with the metal to a temperature that is lower than a melting point of the resin.
2. The joining system according to claim 1, wherein the heating tool is configured to heat the joining interface of the resin and the metal to a temperature in a range of equal to or higher than a decomposition temperature of the resin and lower than a temperature at which gas bubbles are generated in the resin.
3. The joining system according to claim 1, wherein each of the at least one concavity is a slit that penetrates through the metal and that is formed in a zone of the metal around a joining region of the resin and the metal.
4. The joining system according to claim 3, wherein each of the at least one slit penetrates through the metal from the top surface of the metal to the bottom surface of the metal.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1) The foregoing and further features and advantages of the invention will become apparent from the following description of example embodiments with reference to the accompanying drawings, wherein like numerals are used to represent like elements and wherein:
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
DETAILED DESCRIPTION OF EMBODIMENTS
(17) An embodiment of the invention will be described below with reference to the appended drawings.
(18) As shown in
(19) More specifically, for example, the joining interface of the resin member 4 and metal member 3 is heated by bringing the heating body 1 into contact with the surface of the metal member 3 on the opposite side from the joining surface thereof with the resin member 4. Further, the heating with the heating body 1 is conducted so that the joining surface 5 of the resin member 4 with the metal member 3 assumes a temperature in a range of equal to or higher than the decomposition temperature of the resin member 4 and lower than a temperature at which gas bubbles are generated in the resin member 4.
(20) In this case, as shown in
(21) At the same time as the heating is performed with the heating body 1 in the above-described manner, a cooling body 2, which is a cooling tool, is brought into contact with the surface of the resin member 4 on the opposite side from the joining surface 5, and the surface of the resin member 4 on the opposite side from the joining surface 5 is cooled to a temperature less than the melting point of the resin member 4.
(22) In other words, in a state in which the resin member 4 and metal member 3 are stacked, the joining of the resin member 4 and metal member 3 is performed by heating the joining surface 5 of the resin member 4 that is in contact with the joining interface with the metal member 3 to a temperature in a range of equal to or higher than the decomposition temperature of the resin member 4 and lower than the temperature at which gas bubbles are generated in the resin member 4 and cooling the surface of the resin member 4 on the opposite side from the joining surface 5 to a temperature that is lower than the melting point of the resin member 4.
(23) In a case where the joining of the resin member 4 and metal member 3 is performed by heating the resin member 4 to the melting point ta, the two are joined only because the joining surface 5 of the resin member 4 that has reached the melting temperature and softened is deformed along the peaks and valleys of the joining surface of the metal member 3 and the anchor effect is demonstrated. By contrast, where the joining surface 5 of the resin member 4 is heated, as described hereinabove, to a temperature equal to or higher than the decomposition temperature of the resin member 4, the resin member 4 at the joining surface 5 is decomposed and fusion active groups are created at the joining surface 5. The fusion active groups that are created at the joining surface 5 of the resin member 4 are bonded by intermolecular forces to the joining surface of the metal member 3 with the resin member 4, and joining by the intermolecular forces of the fusion active groups is conducted in addition to the joining by the anchor effect on the joining interface of the resin member 4 and metal member 3, whereby a high joining strength can be obtained.
(24) The joining is thus conducted with a joining apparatus including a heating body 1 that heats the joining interface of the resin member 4 and metal member 3 from a surface of the metal member 3 on the opposite side from the joining surface thereof with the resin member 4, and a cooling body 2 that cools the surface of the resin member 4 on the opposite side from the joining surface 5 thereof with the metal member 3 to a temperature that is lower than a melting point of the resin member 4.
(25) In other words, because the resin member 4 and metal member 3 are joined by heating the joining surface 5 of the resin member 4 to a temperature in a range of equal to or higher than a decomposition temperature of the resin member 4 and lower than a temperature at which gas bubbles are generated in the resin member 4, neither an adhesive nor a surface treatment agent such as an acid, an alkali, and a primer treatment agent is used, a necessary and sufficient joining strength can be obtained within a short time, and environmental load in the process of joining the resin member 4 and metal member 3 can be reduced. Further, because the heating temperature of the joining surface 5 of the resin member 4 is less than a temperature at which gas bubbles are generated in the resin member 4, no gas bubbles are generated at the joining surface 5 of the resin member 4 by heating, the occurrence of cracks that originate from gas bubbles at the joining interface of the resin member 4 and metal member 3 can be prevented, and the joining strength of the resin member 4 and metal member 3 can be ensured after the resin member 4 and metal member 3 have been joined.
(26) In addition, when the resin member 4 and metal member 3 are joined, the surface of the resin member 4 on the opposite side from the joining surface 5 is cooled to a temperature that is lower than the melting point of the resin member 4. Therefore, this surface is not deformed by heating. Because the resin member 4 can be prevented from thermal deformation during joining of the resin member 4 and metal member 3, the design property of the external surface of the joint body of the resin member 4 and metal member 3 on the side of the resin member 4 is not reduced and the product value of the joint body can be increased.
(27) For example, various ferrous metals, stainless steel, aluminum materials (including aluminum alloys), magnesium materials (including magnesium alloys), and copper materials (including copper alloys) can be used as the material constituting the metal member 3, but this list is not limiting and other metal materials may be also used.
(28) For example, nylon resins, polyester resins, acrylonitrile butadiene styrene (ABS) resins, and other thermoplastic resins of general use, engineering plastics of general use, super-engineering plastics, and thermoplastic elastomers can be used as the material constituting the resin member 4. A filler such as carbon fibers, glass fibers, talc, mica, kaolin, and calcium carbonate that increases the mechanical strength and the like may be admixed to the resin member 4.
(29) In a case where the resin member 4 is constituted by a nonpolar resin that has absolutely no functional groups, the joining of the resin member 4 and metal member 3 may be conducted after subjecting the joining surface 5 of the resin member 4 to a typical dry surface treatment such as plasma treatment or corona treatment, without using a surface treatment agent such as an acid, an alkali, or a primer treatment agent. By so joining the resin member 4 and metal member 3 after performing the dry surface treatment, it is possible to introduce fusion active groups to the joining surface 5 by the surface treatment method with a low environmental load and increase the joining strength.
(30) Further, in a case where the resin member 4 is constituted by a nonpolar resin that has absolutely no functional groups, the joining of the resin member 4 and metal member 3 is preferably conducted after roughening the joining surface of the metal member 3 with the resin member 4 by using a polishing tool such as sandpaper or forming peaks and valleys on the joining surface of the metal member 3 with the resin member 4 by electron beam processing or laser processing. Where the joining surface of the metal member 3 with the resin member 4 is thus provided with roughness or peaks and valleys, the heated resin member 4 can penetrate into the joining surface of the metal member 3 and demonstrate the anchor effect.
(31) Further, the heating body 1 can be constituted by a high-temperature substance (solid, liquid, or gaseous) that can heat the joining surface 5 of the resin member 4 to a temperature in a range of equal to or higher than a decomposition temperature of the resin member 4 and lower than a temperature at which gas bubbles are generated in the resin member 4 and can be configured so that the heating of the joining surface 5 be performed by bringing the high-temperature substance into contact with the surface of the metal member 3 on the opposite side from the joining surface thereof with the resin member 4. Further, the heating body 1 can be constituted to heat the joining surface 5, for example, by electric resistance heating, high frequency, infrared radiation, or laser radiation, or to heat the joining surface 5 by using friction heat created by vibrations or ultrasound. These examples are not limiting and other heating means may be also used.
(32) The cooling body 2 can be constituted by a low-temperature substance (solid, liquid, or gaseous) that can cool the surface of the resin member 4 on the opposite side from the joining surface 5 thereof to a temperature that is less than the melting point of the resin member 4, but such a configuration is not limiting and other cooling bodies may be also used.
(33) An embodiment will be explained below in which, as shown in
(34) The heating body 1 and cooling body 2 of the present embodiment are formed to a shape similar to that of a gun of a spot welding machine. More specifically, the heating body 1 and cooling body 2 are substantially cylindrical columnar members in which the end portions thereof on the side that will come into contact with the metal member 3 and resin member 4, respectively, are tapered, and these cylindrical columnar members are disposed on both sides of the metal member 3 and resin member 4 in a state in which the metal member 3 and resin member 4 are stacked. The heating body 1 is pressed against the metal member 3, the cooling body 2 is pressed against the resin member 4, and the metal member 3 and resin member 4 are pressed together in a state in which the metal member 3 and resin member 4 are stacked. As a result, the joining surface 5 of the resin member 4 is melted by heat from the heating body 1 and also decomposed, thereby joining the resin member 4 to the metal member 3. In this case, the surface of the resin member 4 that has come into contact with the cooling body 2 is cooled by the cooling body 2 and, therefore, prevented from thermal deformation. Because the heating body 1 and cooling body 2 are formed to a shape similar to that of a gun of a spot welding machine, a line and system of the spot welding machine can be used in the process of joining the metal member 3 and resin member 4.
(35) Further, as shown in
(36) By feeding the metal member 3 and resin member 4 in a stacked state thereof between the heating body 1 and cooling body 2 disposed opposite each other and squeezing the metal member 3 and resin member 4 in a stacked state thereof by the heating body 1 and cooling body 2, the joining surface 5 of the resin member 4 is melted by the heat of the heating body 1 and decomposed, whereby the metal member 3 and resin member 4 are joined together. In this case, the surface of the resin member 4 that comes into contact with the cooling body 2 is cooled by the cooling body 2 and, therefore, prevented from thermal deformation. When the joining of the metal member 3 and resin member 4 is performed, the metal member 3 and resin member 4 that have been fed between the roll-shaped heating body 1 and cooling body 2 are successively conveyed by rotation of the heating body 1 and cooling body 2, thereby making it possible to join the metal member 3 and resin member 4 continuously, as in seam welding.
(37) The metal member 3 may have the following configuration. Thus, as shown in
(38) As shown in
(39) At the joining surface 5 of the resin member 4, because the resin member 4 melts within a region somewhat wider than the joining region 6, the molten and softened resin member 4 penetrates into the slits 3a, as shown in
(40) Thus, by forming the slits 3a on the circumference of the joining region 6 in the metal member 3, it is possible to inhibit heat transfer between the portions of the metal member 3 on both sides of the slits 3a, and the heat that is supplied to the joining interface of the metal member 3 and resin member 4 from the heating body 1 via the metal member 3 is prevented from diffusing to the outside in the plane direction of the joining region 6 (see
(41) As shown in
(42) Instead of forming the above-described slits 3a in the metal member 3, it is also possible to form grooves 3b, as shown in
(43) Similarly to the slits 3a, the grooves 3b are formed in a plurality of places on the circumference of the joining region 6, and heat supplied from the heating body 1 to the joining interface of the metal member 3 and resin member 4 through the metal member 3 can be prevented from diffusing to the outside in the plane direction of the joining region 6. In a case where the grooves 3b are formed as a configuration that inhibits the diffusion of heat transferred to the joining region 6 to the outside in the plane direction, a bottom portion is formed in the grooves 3b at the joining interface side of the metal member 3 and resin member 4 and the grooves 3b do not pass as the aforementioned slits 3a through the metal member 3. Therefore, the rigidity of the metal member 3 can be increased by comparison with that in the case in which the slits 3a are formed in the metal member 3.
(44) Grooves 3c and grooves 3d can be also formed respectively on the joining interface side of the metal member 3 with the resin member 4 and on the surface side on the opposite side from the joining interface side, as shown in
(45) Further, similarly to the slits 3a, the grooves 3c and 3d are formed in a plurality of places on the circumference of the joining region 6, and heat supplied from the heating body 1 to the joining interface of the metal member 3 and resin member 4 through the metal member 3 can be prevented from diffusing to the outside in the plane direction of the joining region 6. Thus, in a case where the grooves 3c and 3d are formed as a configuration that inhibits the diffusion of heat transferred to the joining region 6 to the outside in the plane direction, a bottom portion of each pair of grooves 3c and 3d is formed between the grooves 3c and grooves 3d of the metal member 3, and the grooves 3c and 3d do not pass as the aforementioned slits 3a through the metal member 3. Therefore, the rigidity of the metal member 3 can be increased by comparison with that in the case in which the slits 3a are formed in the metal member 3. Further, the melted and softened resin member 4 penetrates into the grooves 3c, thereby generating the anchor effect in the portions where the resin member 4 has penetrated into the grooves 3c of the metal member 3.
(46) Grooves 3e such as shown in
(47) Similarly to the slits 3a, the grooves 3e are formed in a plurality of places on the circumference of the joining region 6, and heat supplied to the joining interface of the metal member 3 and resin member 4 can be prevented from diffusing to the outside in the plane direction of the joining region 6. In a case where the grooves 3e are formed as a configuration that inhibits the diffusion of heat transferred to the joining region 6 to the outside in the plane direction, a bottom portion of the groove 3e is formed at the surface of the metal member 3 on the opposite side from the joining surface thereof with the resin member 4 and the grooves 3e do not pass, as the aforementioned slits 3a, through the metal member 3. Therefore, the rigidity of the metal member 3 can be increased by comparison with that in the case in which the slits 3a are formed in the metal member 3.
(48) In the configuration in which the grooves 3b shown in
(49) Further, as shown in
(50) The heating method in which the thin film 8 is inserted between the metal member 3 and resin member 4 and the joining interface of the metal member 3 and resin member 4 is heated using the high-frequency heating apparatus 11 can be applied when the metal member 3 is a non-magnetic material having a low thermal conductivity and a low electric resistance, such as aluminum (Al) and copper (Cu).
(51) In this case, a magnetic material with an electric resistance higher than that of the metal member 3, for example, a metal material such as iron (Fe), nickel (Ni), and cobalt (Co) may be used as the thin film 8. The thin film 8 may be provided by subjecting the joining surface of the metal member 3 with the resin member 4 to various processing methods, for example, electroplating, spraying, or cold spraying with the aforementioned metal materials. The metal member 3 and resin member 4 are joined together by stacking the metal member 3 provided with the thin film 8 with the resin member 4 and then high-frequency heating the thin film 8 interposed in the joining interface of the metal member 3 with the resin member 4 using the high-frequency heating apparatus 11.
(52) Generally, in a case where the metal member 3 is constituted by a material with a high thermal conductivity and a low electric resistance, such as aluminum (Al) and copper (Cu), when the metal member 3 is heated from the surface on the side opposite from the joining surface thereof with the resin member 4 and the joining interface is heated by the heat transferred to the metal member 3, the heat transferred to the metal member 3 from the surface on the opposite side from the joining surface diffuses over a large range, the efficiency of heat input to the joining region 6 of the metal member 3 and resin member 4 is low, and the heat input range is difficult to control.
(53) By contrast, when the thin film 8 is interposed in the joining interface of the metal member 3 and resin member 4 and the thin film 8 is directly heated by the high-frequency heating apparatus 11 disposed on the side of the resin member 4, the joining surface 5 of the resin member 4 is heated to a temperature in a range of equal to or higher than a decomposition temperature of the resin member 4 and lower than a temperature at which gas bubbles are generated in the resin member 4.
(54) Where the thin film 8 disposed at the joining interface of the metal member 3 and resin member 4 is thus directly heated, the efficiency of heat input in the joining region 6 can be increased even when the metal member 3 is constituted by a material with a high thermal conductivity and a low electric resistance. Further, by constituting the heating body 1 by the high-frequency heating apparatus 11 and forming the heating coil of the high-frequency heating apparatus 11 to a size corresponding to the size of the joining region 6, it is possible to control the range of heat input to the joining interface of the metal member 3 and resin member 4. As a result, joining can be performed by adequately heating the joining interface of the metal member 3 and resin member 4 within a short period by a simple process and a sufficient joining strength can be obtained. In the above-described configuration, only the high-frequency heating apparatus 11 is used as the heating tool that heats the joining interface of the metal member 3 and resin member 4, but the high-frequency heating apparatus 11 may be used together with the heating body 1 and/or cooling body 2.
(55) Further, as shown in
(56) The heating method in which the thin film 9 is inserted between the metal member 3 and resin member 4 and the joining interface of the metal member 3 and resin member 4 is heated using laser radiation from the laser irradiation apparatus 12 can be applied when the metal member 3 is a material having a low thermal conductivity and a high reflectance of laser radiation in the infrared region, such as aluminum (Al) and copper (Cu).
(57) In this case, the resin member 4 may be constituted by a material that can transmit the laser radiation, and a metal material with reflectance of laser radiation in the infrared region lower than that of the metal member 3, for example, iron (Fe), nickel (Ni), cobalt (Co), and zinc (Zn) may be used as the thin film 9. The thin film 9 may be provided by subjecting the joining surface of the metal member 3 with the resin member 4 to various processing methods, for example, electroplating, spraying, or cold spraying with the aforementioned metal materials.
(58) The metal member 3 and resin member 4 are joined together by stacking the metal member 3 provided with the thin film 9 with the resin member 4 and then heating the joining interface by irradiating the thin film 9 interposed in the joining interface of the metal member 3 with the resin member 4 with laser radiation from the laser irradiation apparatus 12. The laser irradiation apparatus 12 may be constituted by an apparatus that emits infrared laser radiation, such as a yttrium aluminum garnet (YAG) laser, a semiconductor laser, or a CO.sub.2 laser.
(59) Generally, in a case where the metal member 3 is constituted by a material with a high reflectance of infrared laser radiation, such as aluminum (Al) and copper (Cu), even when the joining surface of the metal member 3 with the resin member 4 is irradiated with laser radiation, most of the radiation is reflected at the joining surface. As a result, the heating efficiency is poor and the metal member 3 and resin member 4 are difficult to join together by heating by irradiation with laser radiation.
(60) By contrast, where the thin film 9 is interposed in the joining interface of the metal member 3 and resin member 4 and laser radiation is emitted toward the thin film 9 from the laser irradiation apparatus 12 disposed on the side of the resin member 4, the joining surface 5 of the resin member 4 is heated to a temperature in a range of equal to or higher than a decomposition temperature of the resin member 4 and lower than a temperature at which gas bubbles are generated in the resin member 4.
(61) Where the thin film 9 disposed at the joining interface of the metal member 3 and resin member 4 is thus heated by laser radiation, the efficiency of heat input in the joining region 6 can be increased even when the metal member 3 is constituted by a material with a high reflectance of laser radiation and joining of the metal member 3 and resin member 4 can be easily realized by heating by irradiation with laser radiation. Further, by constituting the heating body 1 by the laser irradiation apparatus 12 and forming the irradiation range of laser radiation from the laser irradiation apparatus 12 to a size corresponding to the size of the joining region 6, it is possible to control the range of heat input to the joining interface of the metal member 3 and resin member 4. As a result, joining can be performed by adequately heating the joining interface of the metal member 3 and resin member 4 within a short period by a simple process and a sufficient joining strength can be obtained. In the above-described present example, only the laser irradiation apparatus 12 is used as the heating tool that heats the joining interface of the metal member 3 and resin member 4, but the laser irradiation apparatus 12 may be used together with the heating body 1 and/or cooling body 2.