Adhesive and flexible display using the same
11258037 · 2022-02-22
Assignee
Inventors
Cpc classification
C08G18/7671
CHEMISTRY; METALLURGY
C08F222/1006
CHEMISTRY; METALLURGY
B32B2457/20
PERFORMING OPERATIONS; TRANSPORTING
G09F9/301
PHYSICS
C08F222/1006
CHEMISTRY; METALLURGY
Y02E10/549
GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
C09J2203/318
CHEMISTRY; METALLURGY
C09J2301/18
CHEMISTRY; METALLURGY
C08F220/286
CHEMISTRY; METALLURGY
C09J2301/1242
CHEMISTRY; METALLURGY
C09J133/08
CHEMISTRY; METALLURGY
B32B7/14
PERFORMING OPERATIONS; TRANSPORTING
H10K50/8426
ELECTRICITY
C09J133/08
CHEMISTRY; METALLURGY
C08F220/286
CHEMISTRY; METALLURGY
B32B3/30
PERFORMING OPERATIONS; TRANSPORTING
International classification
C08G18/66
CHEMISTRY; METALLURGY
C09J133/08
CHEMISTRY; METALLURGY
C08G18/32
CHEMISTRY; METALLURGY
G09F9/30
PHYSICS
Abstract
Provided is an adhesive provided by patterning a metal plate with a predetermined elastic modulus, wherein the adhesive is compressively deformed in response to an operation of an adherend to be folded, so that the adhesive can easily return to an original state thereof through formation of a plurality of inner neutral planes upon deformation.
Claims
1. An adhesive, comprising: a metal plate including a metal body having a top surface and a bottom surface opposite to the top surface with a first thickness between the top and the bottom surfaces, and a plurality of hollows regularly spaced apart from each other among the metal body; a first adhesive layer covering the top surface; and a second adhesive layer covering the bottom surface, wherein the metal body has an elastic modulus of between 10 GPa and 100 GPa, wherein each of the plurality of hollows is extended in a thickness direction of the metal plate and has the first thickness, wherein the first adhesive layer is singly structured on the top surface of the metal plate, and the second adhesive layer is one sheet corresponding to the bottom surface and the plurality of hollows of the metal plate.
2. An adhesive, comprising: a metal plate including a metal body having a top surface and a bottom surface opposite to the top surface with a first thickness between the top and the bottom surfaces, and a plurality of hollows regularly spaced apart from each other among the metal body; a first adhesive layer covering the top surface; and a second adhesive layer covering the bottom surface, wherein the metal body has an elastic modulus of between 10 GPa and 100 GPa, wherein each of the plurality of hollows is extended in a thickness direction of the metal plate and has the first thickness, wherein the first adhesive layer is singly structured and is provided on the top surface of the metal plate and fills the plurality of hollows, and wherein the second adhesive layer is singly structured on the bottom surface of the metal plate.
3. The adhesive according to claim 2, wherein material of the metal body is fully removed to penetrate the top surface and the bottom surface at each of the plurality of hollows.
4. The adhesive according to claim 2, wherein the metal plate is a liquid metal plate.
5. The adhesive according to claim 2, wherein the metal plate comprises an alloy including at least one material chosen from zirconium, titanium, nickel, and copper.
6. The adhesive according to claim 2, wherein the first adhesive layer fills the plurality of hollows and contacts the second adhesive layer.
7. The adhesive according to claim 2, wherein the plurality of hollows are provided in a folding part of the metal plate.
8. The adhesive according to claim 7, wherein a region of the metal plate other than the folding part is not provided with hollows.
9. The adhesive according to claim 2, wherein the first and second adhesive layers include a urethane acrylate resin or an epoxy resin as a base binder resin.
10. The adhesive according to claim 2, wherein the metal plate has higher rigidity than the first and second adhesive layers.
11. The adhesive according to claim 2, wherein the hollows are disposed as a plurality of columns, and the hollows in odd columns and the hollows in even columns stagger and partly overlap with each other.
12. The adhesive according to claim 2, wherein the metal plate is amorphous without any grain within the metal plate.
Description
BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS
(1) The accompanying drawings, which are included to provide a further understanding of the disclosure and are incorporated in and constitute a part of this application, illustrate embodiment(s) of the disclosure and together with the description serve to explain the principle of the disclosure. In the drawings:
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DETAILED DESCRIPTION
(15) Reference will now be made in detail to the preferred embodiments of the present disclosure, examples of which are illustrated in the accompanying drawings. In the following description of the present disclosure, substantially the same elements are denoted by the same reference numerals. In the following description, when detailed description of well-known technologies or configurations relating to the present disclosure is deemed to unnecessarily make the subject matter of the present disclosure unclear, detailed explanation thereof will be omitted. In addition, names of constituent components used in the following description may be different from part names of actual products because they are selected in consideration of convenience in drafting of the specification.
(16) In addition, in the description of embodiments, it will be understood that, when one element or layer is referred to as being “on” or “above” another element, one element may directly contact the other element or layer, or one or more intervening elements or layers may also be present between the two elements or layers. In addition, when one element or layer is referred to as “contacting” another element, one or more intervening elements are not present between the two elements or layers.
(17) The sizes and thicknesses of respective elements are illustrated in the drawings for convenience of description and the present disclosure is necessarily not limited to the sizes and thicknesses thereof.
(18) Hereinafter, preferred embodiments of the present disclosure will be described with reference to the annexed drawings.
(19) The display illustrated in the following embodiments represents a foldable display, but a folding region may be located in any part of the display. In the flexible display according to the present disclosure, the location of deformation of a back plate in the folding region can be changed depending on change of the folding region of the flexible display. In addition, the flexible display according to the present disclosure may also be called “foldable”, “bendable”, “rollable” or the like so long as it is flexible regardless of a bent or folded region.
(20)
(21) As shown in
(22) The patterned adhesive 1000 includes a plurality of hollows 505 in a substrate of a metal plate and will be described in more detail later.
(23) Here, when the display panel 100 and the back plate 200 are folded along a folding region (FR) in the direction of line I-I′, in the folding region FR, the display panel 100 is compressed and the back plate 200 is expanded. In this case, the patterned adhesive 1000 is dispersed by the hollows 505, and plastic deformation does not occur due to small difference in length variation between a first surface facing the display panel 100 and a second surface facing the back plate 200. In particular, the metal plate 1000 is made of a liquid metal plate having an elastic modulus of 10 GPa to 100 GPa, which has high strength comparable to a general metal and excellent elasticity without plastic deformation.
(24) Accordingly, regarding the display panel 100 and the back plate 200 which contact each other, upon folding, as the display panel 100 is compressed and the back plate 200 is expanded, compressive deformation may occur due to stress in an opposite direction to the first and second surfaces. When folding stress is removed, the display panel 100 and the back plate 200 can easily return to the original state thereof due to elastic restoration strength without plastic deformation.
(25) Meanwhile, the display panel 100 of the flexible display according to the present disclosure includes an active area AA which includes a plurality of pixels in the center of the display panel 100 and a non-display area NA which surrounds the periphery of the active area AA.
(26) In addition, the display panel 100 includes a substrate 101, an array 110 including a thin film transistor and an organic light emitting diode in each subpixel provided in the active area AA, a encapsulation layer 120 which seals the thin film transistor and the organic light emitting diode, a touch electrode array 130 provided on the encapsulation layer 120, and a cover layer 140 which protects the touch electrode array 130.
(27) The substrate 101 and the cover layer 140 may be a thin glass or plastic film which has a thickness of 0.2 mm or less and can be flexibly changed in shape without cracking even upon folding. In addition, the substrate 101 and the cover layer 140 may be made of different materials in consideration of light-emission direction and heat-resistance in the process of forming the array 110. When light is emitted upward, the cover layer 140 may be made of a transparent polymer and the substrate 101 may be made of colorful polyimide.
(28) In addition, the array 110 includes a plurality of layers, i.e., an insulation layer, a metal layer and a semiconductor layer, formed on the substrate 101, and each layer has a small thickness of 5,000 Å or less and thus is neither deformed nor cracked even upon folding.
(29) In addition, the encapsulation layer 120 has a thin film laminate which is formed by alternately staking an organic film and an inorganic film and sufficiently covers the top as well as the side surfaces of the active area AA-provided array 110 to prevent exterior humidity or air from permeating into the array 110. That is, the encapsulation layer 120 is formed on the substrate 100 with a size larger than the active area AA, over the edge of the substrate 101, excluding a side at which the pad electrode 145 is provided. In addition, the thicknesses of the organic film and the inorganic film provided in the encapsulation layer 120 are 3 μm or less and 1 μm or less, respectively, the total thickness of the encapsulation layer 120 does not exceed about 20 μm, and the uppermost part of the encapsulation layer 120 may be subjected to planarization due to the relatively thick organic film.
(30) In addition, a touch electrode array 130 is directly formed on the surface of the flat uppermost part of the encapsulation layer 120 or an additional inorganic protective film is further provided thereon, so that the touch electrode array 130 can be provided. In some cases, after the touch electrode array 130 is formed on the inner surface of the cover layer 140, it may be attached to the surface of the encapsulation layer 120.
(31) In addition, the substrate 101 may include a pad part having one side exposed from the encapsulation layer 120, a plurality of pad electrodes 145 are disposed in the pad part and the pad electrodes 145 are connected to a flexible printed circuit board 300. In addition, the flexible printed circuit board 300 is folded toward the bottom of the substrate 101 and is finally accommodated in the structure of a cover bottom (not shown).
(32) The flexible printed circuit board 300 is folded toward the bottom of the substrate 101 and the back plate 200 in the finished flexible display.
(33) Meanwhile, although the back plate 200 having a similar thickness to the substrate 101 is shown in
(34) In addition, a skin layer is provided in upper and lower parts of a core layer which includes the openings of the back plate 200, so that a step can be compensated for and the inner core layer can be protected from exterior shock. As shown in the drawing, the back plate 200 has a configuration in which the core layer and the skin layer provided in upper and lower parts thereof are integrated, excluding the openings. However, the core layer is made of rigid stainless steel, whereas the skin layer is a resin film or inorganic insulation film, which means that the core layer and the skin layer are made of different materials.
(35) The patterned adhesive 1000 shown in
(36)
(37) As shown in
(38) The metal plate used for the adhesive of the present disclosure is not a general conductive metal, but is a liquid metal plate which is a kind of commonly used material. The liquid metal plate is produced by mixing zirconium with titanium, nickel, copper or the like, molding the mixture and forming a plate with a predetermined thickness. The name of the liquid metal plate is determined because it has a soft surface like a liquid. That is, the liquid metal plate is produced by mixing, not liquid ingredients meant by the name thereof, zirconium with titanium, nickel, copper or the like and quenching the mixture to prevent formation of crystalline grains therein, so that it has excellent elastic force, compared to the thickness thereof, and high strength comparable to titanium which is known to have high rigidity. The metal plate may comprise an alloy including at least one among zirconium, titanium, nickel and copper in order to control its elastic modulus and strength. As such, both excellent elastic force and high strength are not shown in a general metal and are obtained due to use of a certain material like a liquid metal plate. In addition, such a property is greatly different from the aspect that predetermined permanent deformation remains in a general polymer adhesive which contains butyl rubber, styrene butadiene rubber, chloroprene rubber, fluoro-rubber or silicone rubber which is known to have high elasticity. The term “liquid metal” or “liquid metal plate” as used herein therefore does not mean a metal that is in a fluid or liquid phase at room temperature.
(39) The metal plate 500 used for the adhesive 1000 of the present disclosure is patterned by regularly forming hollows 505 by etching a liquid metal plate with a predetermined thickness. Since the hollows 505 are spaced from one another, the metal plate 500 constituting the adhesive 1000 even after formation of the hollows 505 may be an integrated form.
(40) In addition, the first adhesive layer 510 and the second adhesive layer 520 are provided for bonding on both surfaces of the metal plate 500 in the adhesive 1000 corresponding to both adherends. As shown in the drawing, the first and second adhesive layers 510 and 520 may be provided in the form of a sheet, or the first and second adhesive layers 510 and 520 may be formed only in areas of the first and second surfaces, where the metal plate 500 remains, excluding the hollows 505. In some cases, only one of the first and second adhesive layers 510 and 520 may take the form of a sheet, and the other may be patterned in a shape excluding the hollows 505 of the metal plate 500.
(41) In addition, the first and second adhesive layers 510 and 520 may include a urethane acrylate resin or an epoxy resin as a base binder resin including a substantial adhesive ingredient. For example, to synthesize a urethane acrylate resin, as acrylate-based compounds, 9 parts by weight of N-acryloyl morpholine, 8 parts by weight of isobornyl acrylate, 20 parts by weight of 2-phenoxy ethyl acrylate, 20 parts by weight of tetraethylene glycol diacrylate, and 10 parts by weight of tetraethylene glycol are added. In addition, in order to synthesize a urethane prepolymer, 19 parts by weight of polyether polyol and 14 parts by weight of diphenylmethane diisocyanate (MDI) are added. Phenylbis(2,4,6-trimethyl benzoyl-phosphine oxide), which is a long-wavelength (405 nm) initiator, is added as a photoinitiator to cure the acrylate compound.
(42) Here, the first and second adhesive layers 510 and 520 are mentioned as examples and can be changed to other materials that have an adhesive property and have low rigidity not to apply stress to the curve of the adherend.
(43) In the adhesive 1000 according to the first embodiment of the present disclosure, the first and second adhesive layers 510 and 520 have the same low rigidity, and the metal plate 500 has higher rigidity than the first and second adhesive layers 510 and 520.
(44)
(45) As shown in
(46) On the other hand, materials such as a metal such as titanium or highly rigid stainless steel linearly vary to stress of compressive strength and expansion strength up to the predetermined strain, but have an increase in strain, above the predetermined strain, even if stress is slightly increased. In particular, when titanium has a strain of 0.5%, variation of stress/strain is serious, which means that, when stress of 400 MPa or more is applied to titanium, unrecoverable variation occurs.
(47) Meanwhile, stainless steel maintains linear stress/strain relationship of compressive strength or expansion strength linear at a strain of 1% or less, but exhibits great variation in strain. That is, stainless steel undergoes an unrecoverable variation when stress of 1,600 MPa or more is applied. In addition, stainless steel has a stress/strain ratio of expansion strength of about 160 GPa and a region where the elastic modulus is considerably high at strain of 1% or less. When converting this into rigidity, stainless steel has excessively high rigidity which is very high compared to the stress generated upon folding or bending of a flexible display. Accordingly, stainless steel cannot follow variation in length according to compression and expansion of the display panel or back plate and causes the problem of slip from the upper or lower display panel or back plate due to high strength itself even though patterned.
(48) Meanwhile, the metal plate of the present disclosure includes, as a base material for the adhesive 1000, a metal plate having a high elastic modulus (62.5 GPa in
(49) That is, the formation of a plurality of neutral planes in the adhesive 1000 according to the first embodiment of the present disclosure means that a plurality of shape-retaining parts are present when attractive force upon folding or the like is applied to the patterned adhesive 1000 between the adherends (see 100 and 200 of
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(51) As shown in
(52) In some cases, as shown in
(53) Here, when the first adhesive layer 610 of the adhesive 2000 faces a first adherend (not shown), the second adhesive layer 620 filling the hollows 505 may be bonded to the second adherend (not shown) such that the second adhesive layer 620 faces the second adherend (not shown) in an island form.
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(55) As shown in
(56) In addition, by switching the location of the shape shown in
(57) Meanwhile, regarding the adhesive shown in the plane view relating to embodiments of the present disclosure, the plane surfaces of the hollows 505 of the metal plate 500 take the shape of a dumbbell which is long along a folding axis and is short in a direction crossing the folding axis. This is provided as an example and any shape which has a long length along a folding axis and a short width in a direction crossing the folding axis may be used. Here, folding is carried out based on the folding axis, and a direction in which compression and extension occur upon substantially folding is the direction crossing the folding axis, so that hollows 505 are repeatedly formed with a short width in the direction crossing the folding axis to make formation of a plurality of neutral planes advantageous in a compression/shrinkage length direction.
(58) In addition, when the hollows 505 are disposed as a plurality of columns, they are not parallel to odd columns and even columns and are arranged diagonally in order to facilitate formation of a plurality of neutral planes. The hollows 505 in odd columns and the hollows 505 in even columns stagger and partly overlap with each other.
(59) Meanwhile, in the aforementioned embodiment of the adhesive, the metal plate 500, which is a base material (substrate) for the adhesive, has a thickness of about 10 μm to 20 μm, and the adhesive layers taking a flat shape have a thickness of about 3 μm to 7 μm, so that the metal plate 500 controls the overall elasticity and rigidity of the adhesive 1000, based on relatively high thickness compared to the adhesive layers 510 and 520.
(60) In the above embodiments (
(61)
(62) As shown in
(63) In the aforementioned embodiment of patterned adhesives, hollows 505 are provided over the entire region facing the display panel 100 and the back plate 200. However, the present disclosure is not limited to this configuration and the hollows of the adhesive may be selectively provided only in a specific region where folding occurs.
(64)
(65) As shown in
(66) As described in the first embodiment and the second embodiment or a modification example thereof, the adhesive 3000 according to the third embodiment of the present disclosure may be provided with a second adhesive layer, while filling hollows 705, or the adhesive layer may be provided as a plane shape of the adherends of the display panel 100 and the back plate 200 which each face both surfaces of the metal plate 700, or a patterned adhesive layer excluding the hollows 705 may be provided.
(67) As described above, the adhesive of the present disclosure and the flexible display including the same have the following effects.
(68) First, the adhesive of the present disclosure includes, as a base material, a metal plate which has no plastic deformation and has a high elastic modulus of 10 GPa to 100 GPa, and is provided in the metal plate with hollows spaced from one another to create a predetermined pattern, so that a plurality of neutral planes, on which neutrality of compression and extension during folding is created, can be provided and, as a result, deformation of adhesives by repeated folding can be prevented.
(69) Second, when the adhesive is formed using a highly rigid material like stainless steel or a general metal, restoration is high, but in response to this, stress is created in a display panel, disadvantageously causing cracks, and, when the adhesive is formed using a weak rigid material like a polymer, the display panel does not crack due to flexibility, but the polymer requires a relaxation time of one day or longer to return to the original shape after receiving stress, thus being inapplicable to flexible displays. The adhesive of the present disclosure is provided in, as a base material, a metal plate which is moldable, has no internal crystallinity and has an elastic modulus not less than a predetermined level, like a liquid metal. Accordingly, the adhesive of the present disclosure operates without any slip in response to other forces applied to other facing surfaces between the display panel and the back plate upon folding due to high restoration force of the material and formation of a plurality of neutral planes for dispersing stress applied upon folding, and is advantageous for application to a flexible display due to high elastic modulus and thus high restoration force of returning to the original state upon removal of folding stress.
(70) In addition, although the preferred embodiments of the present disclosure have been disclosed for illustrative purposes with reference to the annexed drawings, it will be apparent to those skilled in the art that the present disclosure is not limited to the same configurations, actions and effects as the specific embodiments, and various modifications and variations can be made in the present disclosure without departing from the spirit or scope of the disclosure. Accordingly, it is intended that such modifications and alterations fall within the scope of the present disclosure and the true technical protection scope of the disclosure is defined by the technical spirit of the appended claims.
(71) The various embodiments described above can be combined to provide further embodiments. All of the U.S. patents, U.S. patent application publications, U.S. patent applications, foreign patents, foreign patent applications and non-patent publications referred to in this specification and/or listed in the Application Data Sheet are incorporated herein by reference, in their entirety. Aspects of the embodiments can be modified, if necessary to employ concepts of the various patents, applications and publications to provide yet further embodiments.
(72) These and other changes can be made to the embodiments in light of the above-detailed description. In general, in the following claims, the terms used should not be construed to limit the claims to the specific embodiments disclosed in the specification and the claims, but should be construed to include all possible embodiments along with the full scope of equivalents to which such claims are entitled. Accordingly, the claims are not limited by the disclosure.