BRAZE MATERIAL FOR HYBRID STRUCTURES

Abstract

A nickel braze alloy may include less than about 2.0 wt. % aluminum, about 18.0-23.0 wt. % cobalt, about 12.0-15.0 wt. % chromium, about 3.8-4.5 wt. % molybdenum, about 0.8-1.5 wt. % niobium, about 1.8-3.0 wt. % tantalum, less than about 2.0 wt. % titanium, about 2.0-3.5 wt. % tungsten, about 0.8-1.2 wt. % boron, about 0.02-0.10 wt. % carbon, about 0.03-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

Claims

1. A nickel braze alloy comprising in combination less than about 2.0 wt. % aluminum, about 18.0-23.0 wt. % cobalt, about 12.0-15.0 wt. % chromium, about 3.8-4.5 wt. % molybdenum, about 0.8-1.5 wt. % niobium, about 1.8-3.0 wt. % tantalum, less than about 2.0 wt. % titanium, about 2.0-3.5 wt. % tungsten, about 0.8-1.2 wt. % boron, about 0.02-0.10 wt. % carbon, about 0.03-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

2. The nickel braze alloy of claim 1, wherein the composition includes less than about 1.8 wt. % aluminum, about 20.0-22.0 wt. % cobalt, about 13.0-14.5 wt. % chromium, about 3.9-4.3 wt. % molybdenum, about 0.9-1.0 wt. % niobium, about 2.0-2.5 wt. % tantalum, less than about 1.95 wt. % titanium, about 2.1-3.0 wt. % tungsten, about 0.9-1.1 wt. % boron, about 0.04-0.06 wt. % carbon, about 0.04-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

3. The nickel braze alloy of claim 1, wherein the composition includes about 21.90 wt. % cobalt, about 14.00 wt. % chromium, about 4.10 wt. % molybdenum, about 0.97 wt. % niobium, about 2.58 wt. % tantalum, about 2.26 wt. % tungsten, about 1.00 wt. % boron, about 0.05 wt. % carbon, about 0.05 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

4. The nickel braze alloy of claim 1, wherein the composition includes about 1.73 wt. % aluminum, about 21.10 wt. % cobalt, about 13.48 wt. % chromium, about 3.94 wt. % molybdenum, about 0.93 wt. % niobium, about 2.48 wt. % tantalum, about 1.92 wt. % titanium, about 2.18 wt. % tungsten, about 1.00 wt. % boron, about 0.05 wt. % carbon, about 0.05 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

5. The nickel braze alloy of claim 1, wherein the alloy is a foil, tape, cloth, powder, or slurry.

6. The nickel braze alloy of claim 5, wherein the alloy is a foil.

7. The nickel braze alloy of claim 6, wherein the foil has a thickness of from about 1.0 mils (25.4 microns) to about 1.5 mils (38.1 microns).

8. A method of joining a first superalloy component with a first joining surface to a second superalloy component with a second joining surface along the matching joining surfaces comprises: forming an assembly wherein the first component and the second component are positioned such that the first and second joining surfaces are facing each other with a layer of transient liquid phase brazing alloy therebetween having the following composition: less than about 2.0 wt. % aluminum, about 18.0-23.0 wt. % cobalt, about 12.0-15.0 wt. % chromium, about 3.8-4.5 wt. % molybdenum, about 0.8-1.5 wt. % niobium, about 1.8-3.0 wt. % tantalum, less than about 2.0 wt. % titanium, about 2.0-3.5 wt. % tungsten, about 0.8-1.2 wt. % boron, about 0.02-0.10 wt. % carbon, about 0.03-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities on the first and/or second joining surfaces; heating the assembly to a predetermined temperature such that the transient liquid phase brazing alloy melts and the first and second superalloy joining surfaces do not melt; and holding the assembly at the predetermined temperature for a predetermined amount of time wherein the brazing alloy isothermally solidifies and forms a metallurgical bond between the first and second superalloy components.

9. The method of claim 8, wherein the transient liquid phase brazing alloy has the following composition: less than about 1.8 wt. % aluminum, about 20.0-22.0 wt. % cobalt, about 13.0-14.5 wt. % chromium, about 3.9-4.3 wt. % molybdenum, about 0.9-1.0 wt. % niobium, about 2.0-2.5 wt. % tantalum, less than about 1.95 wt. % titanium, about 2.1-3.0 wt. % tungsten, about 0.9-1.7 wt. % boron, about 0.04-0.06 wt. % carbon, about 0.04-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

10. The method of claim 8, wherein the transient liquid phase brazing alloy has the following composition: about 21.90 wt. % cobalt, about 14.00 wt. % chromium, about 4.10 wt. % molybdenum, about 0.97 wt. % niobium, about 2.58 wt. % tantalum, about 2.26 wt. % tungsten, about 1.00 wt. % boron, about 0.05 wt. % carbon, about 0.05 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

11. The method of claim 8, wherein the transient liquid phase brazing alloy has the following composition: about 1.73 wt. % aluminum, about 21.10 wt. % cobalt, about 13.48 wt. % chromium, about 3.94 wt. % molybdenum, about 0.93 wt. % niobium, about 2.48 wt. % tantalum, about 1.92 wt. % titanium, about 2.18 wt. % tungsten, about 1.00 wt. % boron, about 0.05 wt. % carbon, about 0.05 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

12. The method of claim 8, wherein the transient liquid phase brazing alloy is a foil, tape, cloth, powder, or slurry.

13. The method of claim 12, wherein the transient liquid phase brazing alloy is a foil.

14. The method of claim 13, wherein the foil has a thickness of from about 1.0 mils (25.4 microns) to about 1.5 mils (38.1 microns).

15. The method of claim 8, wherein the first component is made of an alloy with the following composition: about 2.6-4.8 wt. % aluminum, about 16.0-22.4 wt. % cobalt, about 6.6-14.3 wt. % chromium, about 1.9-3.9 wt. % molybdenum, about 0.9-3.0 wt. % niobium, about 1.4-3.5 wt. % tantalum, about 2.4-4.6 wt. % titanium, about 1.9-4.0 wt. % tungsten, about 0.02-0.10 wt. % boron, about 0.02-0.10 wt. % carbon, about 0.03-0.10 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

16. The method of claim 15, wherein the second component is made of an alloy with the following composition: about 3.10-3.75 wt. % aluminum, about 20.0-22.0 wt. % cobalt, about 9.5-11.25 wt. % chromium, about 2.8-4.2 wt. % molybdenum, about 1.6-2.4 wt. % niobium, about 4.2-6.1 wt. % tantalum, about 2.6-3.5 wt. % titanium, about 1.8-2.5 wt. % tungsten, about 0.02-0.09 wt. % boron, about 0.02-0.09 wt. % carbon, about 0.04-0.09 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

17. The method of claim 15, wherein the second component is made of an alloy with the following composition: about 3.2-4.1 wt. % aluminum, about 20.0-22.0 wt. % cobalt, about 8-10.5 wt. % chromium, about 2.8-3.1 wt. % molybdenum, about 1.6-2.4 wt. % niobium, about 2.5-7.3 wt. % tantalum, about 2.6-3.6 wt. % titanium, about 2.8-3.3 wt. % tungsten, about 0.02-0.09 wt. % boron, about 0.02-0.09 wt. % carbon, about 0.04-0.09 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0008] FIG. 1 is an exploded partial view of a gas turbine disc.

[0009] FIG. 2 is a flow diagram of an exemplary process of forming the gas turbine disc of FIG. 1.

[0010] FIG. 3 is an exploded partial view of a hybrid disc assembly according to an embodiment of the invention.

[0011] FIG. 4 is a flow diagram of a process for forming the hybrid disc assembly of FIG. 3 using a transient liquid phase brazing alloy according to an embodiment of the invention.

DETAILED DESCRIPTION

[0012] FIG. 1 is an exploded partial view of a gas turbine engine disc assembly 20 including a disc 22 and one of a plurality of blades 24. The disc 22 is generally annular, extending from an inboard bore or hub 26 at a central aperture to an outboard rim 28. A relatively thick web 30 extends radially between the bore 26 and rim 28. The periphery of the rim 28 has a circumferential array of engagement features 32 (e.g. dovetail slots) for engaging complementary features 34 of the blades 24. In other embodiments, the disc or blades may be a unitary structure (e.g. so called “integrally bladed” rotors or discs).

[0013] The disc 22 may be formed by a powder metallurgical forging process (e.g., as indicated in U.S. Pat. No. 6,521,175). FIG. 2 is a flow diagram of exemplary process 36. The elemental components of the alloy are mixed (e.g. as individual components of refined purity or alloys thereof) (step 36a). The mixture is melted sufficiently to eliminate component segregation (step 36b). The melted mixture is atomized to form droplets of molten metal cool and solidify into powder particles (step 36c). The powder may be screened to restrict the ranges of powder particle sizes allowed. The powder is consolidated in a multi-step process involving screening and containerizing (step 36d). In the next step the container is compacted to consolidate the powder and the hot material is extruded (step 36e). The resulting extruded powder then has reached near full theoretical density of the alloy without the chemical segregation typical of larger castings. The extruded billet is then machined and inspected (step 36f). A billet of the consolidated powder may then be forged at appropriate temperatures and deformation constraints to provide a forging with the basic disc profile (step 36g). The forging is then heat treated in a multi-step process involving high temperature heating followed by a rapid cooling process or quench (step 36h). Preferably the heat treatment optimizes the characteristic gamma (γ) grain size from an exemplary 10 micron or less to an exemplary 20-120 micron (with 30-60 micron being preferred). The final step is to machine the forging to produce a useful part (step 36i).

[0014] The quench for the heat treatment may also form strengthening precipitates of a desired distribution of sizes and desired volume percentages. Subsequent heat treatments are used to modify these distributions to produce the requisite mechanical properties of the manufactured forging. Increased grain size is associated with good high temperature creep resistance and decreased rate of crack growth during the service of the manufactured forging. The heat treated forging is then subject to machining of the final profile and the slots.

[0015] The alloy series described in the '175 alloy series patent forms a disc product with exceptional bore strength. Recent alloy series described in commonly owned U.S. Pat. App. Pubs. 2013/0209265 (the '265 alloy series) and 2013/02109266 (the '266 alloy series), which are incorporated herein by reference in their entirety, disclose alloys with improved high temperature creep and rupture lives over prior art alloys. Hybrid disc structures with '175 alloy series bores and '265 and/or '266 alloy series rim structures can provide improved performance over single-material disc structures.

[0016] The '175 alloy series bore composition comprises about 2.6-4.8 wt. % aluminum, about 16.0-22.4 wt. % cobalt, about 6.6-14.3 wt. % chromium, about 1.9-3.9 wt. % molybdenum, about 0.9-3.0 wt. % niobium, about 1.4-3.5 wt. % tantalum, about 2.4-4.6 wt. % titanium, about 1.9-4.0 wt. % tungsten, about 0.02-0.10 wt. % boron, about 0.02-0.10 wt. % carbon, about 0.03-0.10 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0017] The '265 alloy series rim composition comprises about 3.10-3.75 wt. % aluminum, about 20.0-22.0 wt. % cobalt, about 9.5-11.25 wt. % chromium, about 2.8-4.2 wt. % molybdenum, about 1.6-2.4 wt. % niobium, about 4.2-6.1 wt. % tantalum, about 2.6-3.5 wt. % titanium, about 1.8-2.5 wt. % tungsten, about 0.02-0.09 wt. % boron, about 0.02-0.09 wt. % carbon, about 0.04-0.09 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0018] The '266 alloy series rim composition comprises about 3.2-4.1 wt. % aluminum, about 20.0-22.0 wt. % cobalt, about 8-10.5 wt. % chromium, about 2.8-3.1 wt. % molybdenum, about 1.6-2.4 wt. % niobium, about 2.5-7.3 wt. % tantalum, about 2.6-3.6 wt. % titanium, about 2.8-3.3 wt. % tungsten, about 0.02-0.09 wt. % boron, about 0.02-0.09 wt. % carbon, about 0.04-0.09 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0019] FIG. 3 is an exploded view of a hybrid disc structure with separate bore and rim alloy components. Hybrid disc structure 40 includes inboard hub section 42, inboard web section 44 and hub joining surface 46. Hybrid disc structure 40 further comprises outboard rim section 48, outboard web section 50 and outboard rim joining surface 52. Hybrid disc structure 40 may be formed by joining outboard rim section 48 to inboard hub section 44 along joining surfaces 46 and 52 by joining methods well known in the art including welding, friction welding, inertia bonding, and other methods known in the art. A preferred joining method is brazing, in particular, transient liquid phase (TLP) brazing.

[0020] Advanced TLP braze alloys to join '175 hub alloys to '265 and/or '266 rim alloys to form hybrid disc structure 40 are the subject of the present disclosure. Prior art commercially available TLP braze alloys for superalloys are eutectic compositions of nickel, chromium, and boron, a melting point depressant. During brazing, the structure is heated to a fixed temperature exceeding the melting point of the braze alloy but not above the melting points of the two structures being joined. Maintaining the brazing temperature at a fixed temperature allows boron to defuse away from the joint and into the surrounding structure. As the braze alloy loses boron, the melting temperature increases until the braze alloy isothermally solidifies and forms a metallurgical bond.

[0021] Prior art brazing alloys could result in a weak bond as a result of the limited diffusion of solid solution strengtheners such as niobium, titanium and tungsten and the limited formation of gamma prime as a result of limited mean free path of diffusion of large atoms such as aluminum, titanium, tantalum, and niobium.

[0022] In an embodiment of the invention, a preferred brazing alloy composition for brazing superalloy disc structures includes less than about 2.0 wt. % aluminum, about 18.0-23.0 wt. % cobalt, about 12.0-15.0 wt. % chromium, about 3.8-4.5 wt. % molybdenum, about 0.8-1.5 wt. % niobium, about 1.8-3.0 wt. % tantalum, less than about 2.0 wt. % titanium, about 2.0-3.5 wt. % tungsten, about 0.8-1.2 wt. % boron, about 0.02-0.10 wt. % carbon, about 0.03-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0023] A preferred brazing alloy within this range has a composition that includes less than 1.8 wt. % aluminum, about 20.0-22.0 wt. % cobalt, about 13.0-14.5 wt. % chromium, about 3.9-4.3 wt. % molybdenum, about 0.9-1.0 wt. % niobium, about 2.0-2.5 wt. % tantalum, less than about 1.95 wt. % titanium, about 2.1-3.0 wt. % tungsten, about 0.9-1.1 wt. % boron, about 0.04-0.06 wt. % carbon, about 0.04-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0024] A particularly preferred braze alloy within this range has a composition that includes about 21.90 wt. % cobalt, about 14.00 wt. % chromium, about 4.10 wt. % molybdenum, about 0.97 wt. % niobium, about 2.58 wt. % tantalum, about 2.26 wt. % tungsten, about 1.00 wt. % boron, about 0.05 wt. % carbon, about 0.05 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0025] Another particularly preferred braze alloy within this range has a composition that includes about 1.73 wt. % aluminum, about 21.10 wt. % cobalt, about 13.48 wt. % chromium, about 3.94 wt. % molybdenum, about 0.93 wt. % niobium, about 2.45 wt. % tantalum, about 1.92 wt. % titanium, about 2.18 wt. % tungsten, about 1.00 wt. % boron, about 0.05 wt. % carbon, about 0.05 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0026] FIG. 4 is a flow diagram illustrating process 60 for forming hybrid disc structure 40 (FIG. 3) by transient liquid phase brazing the invention is outlined in FIG. 4. In the first step, the braze alloy is prepared (step 62). The braze alloy may be prepared by a number of processes known in the art. A preferred process is that described in the '175 patent where the braze alloy may be formed into a powder by gas or vacuum atomization. The powder may then be formed into a paste or slurry or may be consolidated into a billet for further deformation processing into foils. In preparation for joining, matching joining surfaces 46 and 52 may be cleaned by procedures known to those in the art (step 64). The braze alloy in paste, slurry, foil form or other forms known to those in the art may be applied to one or both joining surfaces. In an exemplary embodiment, braze alloy in foil form is used (step 66). Outboard rim section 48 and inboard hub section 42 may then be assembled in a mounting fixture with joining surfaces 46 and 52 separated by braze alloy (step 68). Mechanical force may be applied to ensure joint integrity during brazing. The fixture may then be heated to a temperature greater than the melting temperature of the braze alloy but less than the melting temperature of the outboard rim section and inboard hub section under a protective atmosphere or vacuum to melt braze alloy (step 70). The brazing temperature may be maintained until the brazing alloy isothermally solidifies and forms a metallurgical bond.

Discussion of Possible Embodiments

[0027] The following are non-exclusive descriptions of possible embodiments of the present invention.

[0028] A nickel braze alloy may include in combination less than about 2.0 wt. % aluminum, about 18.0-23.0 wt. % cobalt, about 12.0-15.0 wt. % chromium, about 3.8-4.5 wt. % molybdenum, about 0.8-1.5 wt. % niobium, about 1.8-3.0 wt. % tantalum, less than about 2.0 wt. % titanium, about 2.0-3.5 wt. % tungsten, about 0.8-1.2 wt. % boron, about 0.02-0.10 wt. % carbon, about 0.03-0.06 wt. % zirconium and a balance of nickel and minor amounts of impurities.

[0029] The alloy of the preceding paragraph can optionally included, additionally and/or alternatively any, one or more of the following features, configurations and/or additional components:

[0030] The composition may include less than about 1.8 wt. % aluminum, about 20.0-22.0 wt. % cobalt, about 13.0-14.5 wt. % chromium, about 3.9-4.3 wt. % molybdenum, about 0.9-1.0 wt. % niobium, about 2.0-2.5 wt. % tantalum, less than about 1.95 wt. % titanium, about 2.1-3.0 wt. % tungsten, about 0.9-1.1 wt. % boron, about 0.04-0.06 wt. % carbon, about 0.04-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0031] The composition may include about 21.90 wt. % cobalt, about 14.00 wt. % chromium, about 4.10 wt. % molybdenum, about 0.97 wt. % niobium, about 2.58 wt. % tantalum, about 2.26 wt. % tungsten about 1.00 wt. % boron, about 0.05 wt. % carbon, about 0.05 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0032] The composition may include about 1.73 wt. % aluminum, about 21.10 wt. % cobalt, about 13.48 wt. % chromium, about 3.94 wt. % molybdenum, about 0.93 wt. % niobium, about 2.48 wt. % tantalum, about 1.92 wt. % titanium, about 2.18 wt. % tungsten, about 1.00 wt. % boron, about 0.05 wt. % carbon, about 0.05 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0033] The alloy may be a foil, tape, cloth, powder, or slurry.

[0034] The alloy may be a foil.

[0035] The foil may have a thickness of from about 1.0 mils (2.54 microns) to about 1.5 mils (38.1 microns).

[0036] A method of joining a first superalloy component with a first joining surface to a second superalloy component with a second joining surface along the matching joining surfaces may include: forming an assembly wherein the first component and the second component are positioned such that the first and second joining surfaces are facing each other with a layer of transient liquid phase brazing alloy therebetween having the following composition: less than about 2.0 wt. % aluminum, about 18.0-23.0 wt. % cobalt, about 12.0-15.0 wt. % chromium, about 3.8-4.5 wt. % molybdenum, about 0.8-1.5 wt. % niobium, about 1.8-3.0 wt. % tantalum, less than about 2.0 wt. % titanium, about 2.0-3.5 wt. % tungsten, about 0.8-1.2 wt. % boron, about 0.02-0.10 wt. % carbon, about 0.03-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities on the first and/or second joining surfaces; heating the assembly to a predetermined temperature such that the transient liquid phase brazing alloy melts and the first and second superalloy joining surfaces do not melt; and holding the assembly at the predetermined temperature for a predetermined amount of time wherein the brazing alloy isothermally solidifies and forms a metallurgical bond between the first and second superalloy components.

[0037] The method of the preceding paragraph can optionally include, additionally and/or alternatively any, one or more of the following features, configurations and/or additional components:

[0038] The transient liquid phase brazing alloy may have the following composition: less than about 1.8 wt. % aluminum, about 20.-22.0 wt. % cobalt, about 13.0-14.5 wt. % chromium, about 3.9-4.3 wt. % molybdenum, about 0.9-1.0 wt. % niobium, about 2.0-2.5 wt. % tantalum, less than about 1.95 wt. % titanium, about 2.1-3.0 wt. % tungsten, about 0.9-1.7 wt. % boron, about 0.04-0.06 wt. % carbon, about 0.04-0.06 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0039] The transient liquid phase brazing alloy may have the following composition: about 21.90 wt. % cobalt, about 14.00 wt. % chromium, about 4.10 wt. % molybdenum, about 0.97 wt. % niobium, about 2.58 wt. % tantalum, about 2.26 wt. % tungsten, about 1.00 wt. % boron, about 0.05 wt. % carbon, about 0.05 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0040] The transient liquid phase brazing alloy may have the following composition: about 1.73 wt. % aluminum, about 21.10 wt. % cobalt, about 13.48 wt. % chromium, about 3.94 wt. % molybdenum, about 0.93 wt. % niobium, about 2.48 wt. % tantalum, about 1.92 wt. % titanium, about 2.18 wt. % tungsten, about 1.00 wt. % boron, about 0.05 wt. % carbon, about 0.05 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0041] The transient liquid phase brazing alloy may be a foil, tape, cloth, powder, or slurry.

[0042] The transient liquid phase brazing alloy may be a foil.

[0043] The foil may have a thickness of from about 1.0 mils (25.4 microns) to about 1.5 mils (38.1 microns).

[0044] The first component may be an alloy with the following composition: about 2.6-4.8 wt. % aluminum, about 16.0-22.4 wt. % cobalt, about 6.6-14-3 wt. % chromium, about 1.9-3.9 wt. % molybdenum, about 0.9-3.0 wt. % niobium, about 1.4-3.5 wt. % tantalum, about 2.4-4.6 wt. % titanium, about 1.9-4.0 wt. % tungsten, about 0.02-0.10 wt. % boron, about 0.02-0.10 wt. % carbon, about 0.03-0.10 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0045] The second component may be an alloy with the following composition: about 3.10-3.75 wt. % aluminum, about 20.0-22.0 wt. % cobalt, about 9.5-11.25 wt. % chromium, 2.8-4.2 wt. % molybdenum, about 1.6-2.4 wt. % niobium, about 4.2-6.1 wt. % tantalum, about 2.6-3.5 wt. % titanium, about 1.8-2.5 wt. % tungsten, about 0.02-0.09 wt. % boron, about 0.02-0.09 wt. % carbon, about 0.04-0.09 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0046] The second compound may be an alloy with the following composition: about 3.2-4.1 wt. % aluminum, about 20.0-22.0 wt. % cobalt, about 8-10.5 wt. % chromium, about 2.8-3.1 wt. % molybdenum, about 1.6-2.4 wt. % niobium, about 2.5-7.3 wt. % tantalum, about 2.6-3.6 wt. % titanium, about 2.8-3.3 wt. % tungsten, about 0.02-0.09 wt. % boron, about 0.02-0.09 wt. % carbon, about 0.04-0.09 wt. % zirconium, and a balance of nickel and minor amounts of impurities.

[0047] While the invention has been described with reference to an exemplary embodiment(s), it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiment(s) disclosed, but that the invention will include all embodiments falling within the scope of the appended claims.