Systems and methods for implementing bulk metallic glass-based macroscale compliant mechanisms
09783877 · 2017-10-10
Assignee
Inventors
Cpc classification
B26D2001/002
PERFORMING OPERATIONS; TRANSPORTING
International classification
C22C45/10
CHEMISTRY; METALLURGY
B21J1/00
PERFORMING OPERATIONS; TRANSPORTING
Abstract
Systems and methods in accordance with embodiments of the invention implement bulk metallic glass-based macroscale compliant mechanisms. In one embodiment, a bulk metallic glass-based macroscale compliant mechanism includes: a flexible member that is strained during the normal operation of the compliant mechanism; where the flexible member has a thickness of 0.5 mm; where the flexible member comprises a bulk metallic glass-based material; and where the bulk metallic glass-based material can survive a fatigue test that includes 1000 cycles under a bending loading mode at an applied stress to ultimate strength ratio of 0.25.
Claims
1. A macroscale compliant mechanism comprising: a flexible member that is strained during the operation of the compliant mechanism; wherein the flexible member has a thickness of at least approximately 0.5 mm; wherein the flexible member comprises a bulk metallic glass-based material; and wherein the bulk metallic glass-based material can survive a fatigue test that includes 1000 cycles under a bending loading mode at an applied stress to ultimate strength ratio of 0.25; and wherein the flexible member is configured such that its displacement-response to an applied force is nonlinear; wherein the bulk metallic glass-based material is a bulk metallic glass matrix composite; wherein the compliant mechanism is selected from the group consisting of a cutting device, a grasping device, a bistable mechanism, and a rotational hexfoil flexure; and wherein the cutting device comprises: a bladed section with a first and second blade; and a handled section with a first and second handle; wherein the cutting device is configured such that the rotation of the handles towards one another causes the rotation of the blades towards one another; wherein the grasping device comprises: a grasping section with a first and second grasping element; and a handled section with a first and second handle; wherein the grasping device is configured such that the rotation of the handles towards one another causes the rotation of the grasping elements towards one another; wherein the bistable mechanism is configured to be stable in two configurations; and wherein the rotational hexfoil flexure comprises: a base cylindrical portion; an overlaid cylindrical portion; and three beams; wherein one end of each beam is adjoined to the base cylindrical portion, and the opposite end of each beam is adjoined to the overlaid cylindrical portion; wherein the rotational hexfoil flexure is configured such that the base cylindrical portion and the overlaid cylindrical portion can be rotated relative to one another.
2. The bulk metallic glass-based macroscale compliant mechanism of claim 1, wherein the volume fraction of crystals within the bulk metallic glass matrix composite is between approximately 20% and 80%.
3. The bulk metallic glass-based macroscale compliant mechanism of claim 1, wherein the bulk metallic glass-based material has a yield strain greater than approximately 1.5%.
4. The bulk metallic glass-based macroscale compliant mechanism of claim 2, wherein the bulk metallic glass-based material has a strength to stiffness ratio greater than approximately 2.
5. The bulk metallic glass-based macroscale compliant mechanism of claim 1, wherein the bulk metallic glass-based material is one of: Ti.sub.44.3Zr.sub.20V.sub.12Cu.sub.5Be.sub.15, Zr.sub.39.6Ti.sub.33.9Nb.sub.7.6Cu.sub.6.4Be.sub.12.5, Zr.sub.56.2Ti.sub.13.8Nb.sub.5.0Cu.sub.6.9Be.sub.12.5, Ti.sub.31.4Zr.sub.36.6Nb.sub.7Cu.sub.5.9Be.sub.19.1, Ti.sub.43Zr.sub.25Nb.sub.7Cu.sub.6Be.sub.19, and Ti.sub.25Zr.sub.43Nb.sub.7Cu.sub.6Be.sub.19.
6. The bulk metallic glass-based macroscale compliant mechanism of claim 1, wherein the bulk metallic glass-based macroscale compliant mechanism is a TiZrBeXY alloy, wherein X is an additive that enhances glass forming ability and Y is an additive that enhances toughness.
7. The bulk metallic glass-based macroscale compliant mechanism of claim 6, wherein the bulk metallic glass-based material comprises: Ti in an amount between approximately 10 and 60 atomic %; Zr in an amount between approximately 18 and 60 atomic %; and Be in an amount between approximately 7 and 30 atomic %.
8. The bulk metallic glass-based macroscale compliant mechanism of claim 7, wherein X is one of Fe, Cr, Co, Ni, Cu, Al, B, C, Ag, Si, and mixtures thereof.
9. The bulk metallic glass-based macroscale compliant mechanism of claim 7, wherein: X is one of: C, Si, and B; and X is present in an amount less than approximately 2 atomic %.
10. The bulk metallic glass-based macroscale compliant mechanism of claim 7, wherein: X is one of: Cr, Co, and Fe; and X is present in an amount less than approximately 7 atomic %.
11. The bulk metallic glass-based macroscale compliant mechanism of claim 7, wherein X is Al and is present in an amount less than approximately 7 atomic %.
12. The bulk metallic glass-based macroscale compliant mechanism of claim 7, wherein X is a combination of Cu and Ni, and is present in an amount less than approximately 20 atomic %.
13. The bulk metallic glass-based macroscale compliant mechanism of claim 7, wherein the combination of X and Be is present in an amount less than approximately 30 atomic %.
14. The bulk metallic glass-based macroscale compliant mechanism of claim 13, wherein Y is one of: V, Nb, Ta, Mo, Sn, W, and mixtures thereof.
15. The bulk metallic glass-based macroscale compliant mechanism of claim 14, wherein Y is V and is present in amount less than approximately 15 atomic %.
16. The bulk metallic glass-based macroscale compliant mechanism of claim 14, wherein Y is Nb and is present in an amount between approximately 5 and 15 atomic %.
17. The bulk metallic glass-based macroscale compliant mechanism of claim 14, wherein Y is Ta and is present in an amount less than approximately 10 atomic %.
18. The bulk metallic glass-based macroscale compliant mechanism of claim 14, wherein Y is Mo and is present in an amount less than approximately 5 atomic %.
19. The bulk metallic glass-based macroscale compliant mechanism of claim 14, wherein Y is Sn and is present in an amount less than approximately 2 atomic %.
20. The bulk metallic glass-based macroscale compliant mechanism of claim 1, wherein the bulk metallic glass-based material can survive a fatigue test that includes 1000 cycles under a bending loading mode at an applied stress to ultimate strength ratio of 0.4.
21. A bulk metallic glass-based macroscale compliant mechanism comprising: a flexible member that is strained during the normal operation of the compliant mechanism; wherein the flexible member has a thickness of 0.5 mm; wherein the flexible member comprises a bulk metallic glass-based material; and wherein the bulk metallic glass-based material can survive a fatigue test that includes 1000 cycles under a bending loading mode at an applied stress to ultimate strength ratio of 0.25; wherein the compliant mechanism is a cutting device comprising: a bladed section with a first and second blade; and a handled section with a first and second handle; wherein the cutting device is configured such that the rotation of the handles towards one another causes the rotation of the blades towards one another.
22. A bulk metallic glass-based macroscale compliant mechanism comprising: a flexible member that is strained during the normal operation of the compliant mechanism; wherein the flexible member has a thickness of 0.5 mm; wherein the flexible member comprises a bulk metallic glass-based material; and wherein the bulk metallic glass-based material can survive a fatigue test that includes 1000 cycles under a bending loading mode at an applied stress to ultimate strength ratio of 0.25; wherein the compliant mechanism is a grasping device comprising: a grasping section with a first and second grasping element; and a handled section with a first and second handle; wherein the grasping device is configured such that the rotation of the handles towards one another causes the rotation of the grasping elements towards one another.
23. A bulk metallic glass-based macroscale compliant mechanism comprising: a flexible member that is strained during the normal operation of the compliant mechanism; wherein the flexible member has a thickness of 0.5 mm; wherein the flexible member comprises a bulk metallic glass-based material; and wherein the bulk metallic glass-based material can survive a fatigue test that includes 1000 cycles under a bending loading mode at an applied stress to ultimate strength ratio of 0.25; wherein the compliant mechanism is a rotational hexfoil flexure comprising: a base cylindrical portion; an overlaid cylindrical portion; and three beams; wherein one end of each beam is adjoined to the base cylindrical portion, and the opposite end of each beam is adjoined to the overlaid cylindrical portion; wherein the rotational hexfoil flexure is configured such that the base cylindrical portion and the overlaid cylindrical portion can be rotated relative to one another.
Description
BRIEF DESCRIPTION OF THE DRAWINGS
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8)
(9)
(10)
(11)
(12)
(13)
(14)
(15)
(16)
(17)
(18)
(19)
(20)
(21)
DETAILED DESCRIPTION
(22) Turning now to the drawings, systems and methods for implementing bulk metallic glass-based macroscale compliant mechanisms are illustrated. Compliant mechanisms can be understood to be mechanisms that transfer or transform motion, force, or energy via the elastic bending of their flexible members. They can be contrasted with mechanisms that achieve the transfer or transformation of motion, force, or energy via rigid body kinematics. In other words, whereas conventional mechanisms may rely on rigid body kinematics to achieve their operation, compliant mechanisms generally rely on strain energy to do so. Indeed, in many cases, compliant mechanisms are designed to replace multi-part elements such as rigid body pin joints.
(23) Note that the term ‘compliant mechanism’ often refers to mechanisms that are more intricate than simple torsional or linear springs, although compliant mechanisms can include simple torsional or linear springs. In many cases, compliant mechanisms redirect a motion, force, or energy, in a direction other than that which directly opposes the direction under which the initial actuating motion, force, or energy was input. Additionally, compliant mechanisms are often designed to survive many cycles of operation. For example, they may be designed to survive a thousand cycles of operation.
(24) Compliant mechanisms generally utilize materials that can be characterized by an elastic region for which an experienced stress (e.g. tension or compression) is linearly correlated with the applied strain. In other words, many materials have an elastic region, for which:
σ=Eε
where:
σ is the stress experienced by the materials
E is the Young's Modulus of the material, or its ‘stiffness’; and
ε is the extent to which the material is strained.
(25) As an example,
(26) Generally, when these materials are strained (to an extent not exceeding their respective elastic limits), energy is stored within them (‘strain energy’). The energy per unit volume generally correlates with the area under the material's stress-strain curve through the point at which the material is strained, and it is this energy that may be available for work. Generally, compliant mechanisms utilize these principles to achieve their functionality. More specifically, compliant mechanisms typically include at least one flexible member which is relied upon during the normal operation of the compliant mechanism for its ability to strain and utilize strain energy.
(27) For example,
(28) By contrast, the equivalent compliant mechanism depicted in
(29) Similarly, grasping compliant mechanisms can also be constructed using a similar design, e.g. replacing the bladed section with a grasping section that includes a first grasping element and a second grasping element.
(30) Compliant mechanisms can be advantageous in a number of respects. For example, as can be inferred from above, mechanisms that rely on rigid body kinematics often employ multiple discrete elements, including pins, bearings, screws, and other such linking components. These multiple components usually have to be distinctly manufactured and then assembled. Thus, the manufacture of such mechanisms can be considered to be inefficient in these respects. Moreover, during their operation, such mechanisms often rely on component-to-component interaction—which can result in friction that can impede the performance of the mechanism and/or result in wear. Any resulting such friction can require that the mechanism be sufficiently lubricated, which increases the sophistication of the system; and of course, any wear can compromise the lifespan of the mechanism. Compliant mechanisms can mitigate these deficiencies. For example, the operative/stressed portions of compliant mechanisms can be made to be monolithic, and thus the manufacturing complexities can be reduced, i.e. whereas mechanisms that rely on rigid body kinematics typically require the manufacture and subsequent assembly of multiple discrete elements, compliant mechanisms do not have to be as intricate. Similarly, because of the reduction of components, compliant mechanisms may also be produced more economically. Moreover, as compliant mechanisms primarily do not rely on rigid body kinematics, any deficiencies that arise from part to part interaction (e.g. friction and wear) can be eliminated.
(31) Although compliant mechanisms can provide numerous benefits, their design and manufacture can be challenging. In particular, it has traditionally been challenging to model the input and transfer of forces, motion, and energy through a compliant mechanism; in many instances, this modeling directly informs the design of the compliant mechanism. Additionally, as they are usually intricate and monolithic, compliant mechanisms are typically not fabricated from metallic materials. For example, the fabrication of a compliant mechanism from robust metallic materials entails either: EDM or computer controlled machining, which can be overly costly; casting, which is typically limited to low melting temperature metals; or additive manufacturing, which can be time consuming. Thus, compliant mechanisms are typically fabricated from polymers, which can be easily cast into the intricate shapes (as alluded to above, many compliant mechanism designs call for intricate structures). Unfortunately, these polymers usually do not possess desirable mechanical properties.
(32) Bulk metallic glasses (BMGs) and bulk metallic glass composites (BMGMCs) have a number of useful properties that would suggest that they would be well-suited for the fabrication of compliant mechanisms. Note that throughout this application, the term ‘BMG-based material’, along with any equivalent term, is meant to reference both BMGs and BMGMCs. For example, BMG-based materials can be easily cast like polymers, but at the same time can be developed to possess desirable mechanical properties. For instance, in many cases, it is desirable for compliant mechanisms to be fabricated from materials that have relatively high elastic strain limits, and it may also be desirable for compliant mechanisms to be constituted from materials that have relatively high strength to stiffness ratios. Table 1 below illustrates the material properties of some typical BMG-based materials relative to other typical engineering materials, and conveys their superior yield strains and strength to stiffness ratios.
(33) TABLE-US-00001 TABLE 1 Mechanical Properties of Typical BMGs vs. Traditional Engineering Materials Density Stiffness Yield Strength Yield Strain Processing Strength/ Material (g/cc) (GPa) (MPa) (%) T (° C.) Stiffness Stainless Steel 304 8.0 193-200 215 0.1 1400 0.1 Invar 36 8.1 141 276 0.3 1427 0.2 Ti-6Al-4V 4.4 114 965 1.0 1604 0.8 Pure Titanium 4.5 116 140 0.1 1650 0.1 Al-6061 2.7 69 276 0.4 582 0.4 Al-7075 2.8 72 462 0.6 477 0.6 Zr & Ti BMGs 4.4-6.0 70-115 1500-2500 2.0 350-600 2.7 Ti-BMG Composites 4.9-6.4 70-115 1000-1500 1.5-2.0 350-682 2
(34) Note also that the stiffness of the BMG-based materials is relatively low compared to the other listed engineering materials. In many instances, it is desirable to fabricate compliant mechanisms from materials that have a relatively low stiffness. This can allow a flexible member of a compliant mechanism to deflect more easily. For example, the deflection of a beam can be determined using the relationship:
δ=(FL.sup.3)/(3EI)
where
F is the force applied to the end of the beam;
L is the length of the beam;
E is the stiffness; and
I is the moment of inertia, which in the case of a rectangular beam is (bh.sup.3/12).
(35) Accordingly, with a lower stiffness, greater deflection can be achieved with less force.
(36) Moreover, in addition to these advantageous mechanical properties, BMG-based materials can also have additional characteristics that can further boost their utility, e.g. biocompatibility, corrosion resistance, and density.
(37) Nonetheless, in spite of their vast potential as engineering materials, the practical implementation of BMG-based materials has been largely limited to microscale structures. Specifically, various publications have concluded, and it is largely established, that the viability of BMG-based materials is limited to microscale structures. (See e.g., G. Kumar et al., Adv. Mater. 2011, 23, 461-476, and M. Ashby et al., Scripta Materialia 54 (2006) 321-326, the disclosures of which are hereby incorporated by reference.) For example, others have fabricated geometries that are akin to compliant mechanisms on the microscale—selected illustrations of produced structures are reproduced in
(38) In particular
(39) The Inventors of the instant application fabricated a compliant flexure that included 1 mm struts out of Vitreloy. Although the compliant mechanism was successfully fabricated, the inventors observed that the compliant mechanism failed via fatigue failure after merely 10 cycles. The failed strut is illustrated in
(40) The inventors thereby observed that, contrary to the suggestions of the scientific literature, BMG-based materials may be successfully employed within macroscale compliant mechanisms if they can be developed to withstand fatigue failure. In other words, the presumed lack of plasticity of BMG-based materials on a macroscale is not the only consideration when attempting to form a compliant mechanism from a BMG-based material. Indeed, as will be discussed further below, the inventors have developed BMG-based materials that possess requisite mechanical properties including a requisite resistance to fatigue failure, and are thereby suitable for the fabrication of compliant mechanisms. Thus, in many embodiments of the invention, a BMG-based macroscale compliant mechanism includes: a flexible member that is strained during the normal operation of the compliant mechanism; where the flexible member has a thickness of 0.5 mm; where the flexible member comprises a BMG-based material; and where the BMG-based material can survive a fatigue test that includes 1000 cycles under a bending loading mode at an applied stress to ultimate strength ratio of 0.25.
(41) Additionally, advantageous manufacturing methods for fabricating compliant mechanisms from BMGMCs are discussed. In particular, as BMGMCs may exhibit high viscosity, they may be advantageously manipulated using squeeze-casting techniques.
(42) The BMG-based material selection and design methodology for macroscale compliant mechanisms is now discussed below.
(43) BMG-Based Material Selection and Design Methodology for Compliant Mechanisms
(44) Whereas, existing scientific literature has generally counseled against employing BMG-based materials in macroscale structures that may experience strain for reasons including BMG-based materials' tendencies to fail under brittle modes on a macroscale, the inventors of the instant application have determined that BMG-based materials can indeed be implemented in structures that are strained—they can in fact be implemented in macroscale structures that rely on a material's ability to store and utilize strain energy. However, the inventors have observed that in selecting/developing a BMG-based material to be implemented in a BMG-based material, the fatigue characteristics of the material must be considered. Thus, in many embodiments of the invention, a method of fabricating a BMG-based macroscale compliant mechanism includes accounting for the fatigue characteristics of the BMG-based material. A method of fabricating a BMG-based macroscale compliant mechanism that includes selecting a BMG-based material that conforms to the compliant mechanism's design parameters and that also has a sufficient resistance to fatigue failure, and fabricating the compliant mechanism from the selected BMG-based material, is illustrated in
(45) Accordingly, a BMG-based material is selected (510) that conforms to the design parameters and that possesses a sufficient resistance to fatigue failure. Of course, any manner of assessing whether a BMG-based material has a sufficient resistance to fatigue failure can be employed. For example, in many instances, the selected BMG-based material must be able to withstand a fatigue test of 1000 cycles, where the loading mode is in bending, at an applied stress to ultimate tensile strength ratio of 0.25. In a number of embodiments, a material that can withstand 1000 cycles of an applied stress to ultimate tensile strength of 0.4 is selected. In many embodiments, a material that can withstand 100 cycles of an applied stress to ultimate tensile strength of 0.5 is selected. Of course, any number of cycles to failure can be required at any applied stress in accordance with embodiments of the invention. Generally, as compliant mechanisms are typically strained in tension, in rotation, or in bending, it is preferred that where fatigue testing is used to gauge the resistance to fatigue failure of the BMG, the fatigue test employ tension loading, bending loading, or rotational loading. Of course, any loading mode can be employed in assessing the resistance to fatigue of a candidate BMG-based material.
(46) The compliant mechanism can then be fabricated (520) from the selected material. The compliant mechanism can be fabricated in any suitable way in accordance with embodiments of the invention. Moreover, the type of material selected can inform the specific fabrication methodology. For example, where a BMG is selected, the fabrication technique can be one of: die casting, thermoplastic forming, capacitive discharge, powder metallurgy, injection casting, sheet forming, wire EDM from larger parts, machining, suction casting, spray coating, and investment casting. Where a BMGMC is selected, the fabrication technique can be selected from one of: die casting, injection casting, semisolid processing, squeeze casting, and from sheet forming.
(47) Moreover, in many embodiments, the design of the compliant mechanism may be tweaked to accommodate the fabrication method. For example, where standard die casting or injection molding is employed, blind features may be removed, or the thickness of the structural members may be increased.
(48) The above-described method of fabrication informs how to select a BMG-based material for the fabrication of a compliant mechanism. Below, it is discussed how to develop a BMG-based material so that it possesses the requisite materials properties for implementation within a compliant mechanism.
(49) Developing a BMG-Based Material for Use in a Compliant Mechanism
(50) In many embodiments, a BMG-based material is particularly developed so that it is well suited for implementation within a compliant mechanism. Generally, the development of BMG-based materials so that they possess desired mechanical properties involves alloying. For example, in many instances it is desirable to implement a stiffer BMG material. Accordingly, in many embodiments, the stiffness of a BMG is increased by alloying the BMG material with B, Si, Al, Cr, Co, and/or Fe. These alloying elements are usually added in concentrations of less than 5%. Of course, any alloying elements can be implemented that enhance the stiffness of a BMG material.
(51) The mechanical properties of BMGMC materials can also be developed via alloying. For example, in many embodiments, the stiffness of a BMGMC is decreased by increasing the volume fraction of soft, ductile dendrites or increasing the amount of beta stabilizing elements, e.g. V, Nb, Ta, Mo, Sn. Similarly, in a number of embodiments, the stiffness of a BMGMC is increased by decreasing the volume fraction of soft, ductile inclusions, increasing the hardness of the inclusions by either removing beta stabilizing elements, or adding elements that harden them, e.g. Al, W, Cr, Co, Mo, Si, B, etc. Generally, in BMGMCs, the stiffness of the material changes in accordance with the rule of mixtures, e.g., where there are relatively more dendrites, the stiffness decreases, and where there are relatively less dendrites, the stiffness increases.
(52) Note that, generally, when modifying the stiffness of BMG-based materials, the stiffness is modified largely without overly influencing other properties, such as elastic strain limit or processability. This ability to tune the stiffness independent of the other material properties or influencing processability is greatly advantageous in designing compliant mechanisms, as it greatly facilitates the material development process.
(53) Tables 2, 3, and 4 depict how the stiffness of a BMG-based material can vary based on composition, and how the elastic strain limit is largely independent of the composition variation. Note that the low processing temperatures are beneficial as they allow for net-shaped casting—which is useful for manufacturing purposes.
(54) TABLE-US-00002 TABLE 2 Material Properties of Select BMGMCs as a function of Composition BMG bcc ρ σ.sub.y σ.sub.max ε.sub.y E T.sub.s name atomic % weight % (%) (%) (g/cm.sup.3) (MPa) (MPa) (%) (GPa) (K) DV2 Ti.sub.44Zr.sub.20V.sub.12Cu.sub.5Be.sub.19 Ti.sub.41.9Zr.sub.36.3V.sub.12.1Cu.sub.6.3Be.sub.3.4 70 30 5.13 1597 1614 2.1 94.5 956 DV1 Ti.sub.48Zr.sub.20V.sub.12Cu.sub.5Be.sub.15 Ti.sub.44.3Zr.sub.35.2V.sub.11.8Cu.sub.6.1Be.sub.2.6 53 47 5.15 1362 1429 2.3 94.2 955 DV3 Ti.sub.56Zr.sub.18V.sub.10Cu.sub.4Be.sub.12 Ti.sub.51.6Zr.sub.31.6V.sub.9.8Cu.sub.4.9Be.sub.2.1 46 54 5.08 1308 1309 2.2 84.0 951 DV4 Ti.sub.62Zr.sub.15V.sub.10Cu.sub.4Be.sub.9 Ti.sub.57.3Zr.sub.26.4V.sub.9.8Cu.sub.4.9Be.sub.1.6 40 60 5.03 1086 1089 2.1 83.7 940 DVAI1 Ti.sub.60Zr.sub.16V.sub.9Cu.sub.3Al.sub.3Be.sub.9 Ti.sub.55.8Zr.sub.28.4V.sub.8.9Cu.sub.3.7Al.sub.1.6Be.sub.1.6 31 69 4.97 1166 1189 2.0 84.2 901 DVAI2 Ti.sub.67Zr.sub.11V.sub.10Cu.sub.5Al.sub.2Be.sub.5 Ti.sub.62.4Zr.sub.19.5V.sub.9.9Cu.sub.6.2Al.sub.1Be.sub.0.9 20 80 4.97 990 1000 2.0 78.7 998 Ti-6-4a Ti.sub.86.1Al.sub.10.3V.sub.3.6 Ti.sub.90Al.sub.6V.sub.4 (Grade 5 Annealed) na na 4.43 754 882 1.0 113.8 1877 Ti-6-4s Ti.sub.86.1Al.sub.10.3V.sub.3.6 [Ref] Ti.sub.90Al.sub.6V.sub.4 (Grade 5 STA) na na 4.43 1100 1170 ~1 114.0 1877 CP-Ti Ti.sub.100 Ti.sub.100 (Grade 2) na na 4.51 380 409 0.7 105.0 ~1930
(55) TABLE-US-00003 TABLE 3 Material Properties as a Function of Composition σ.sub.max ε.sub.tot σ.sub.y ε.sub.y E ρ G CIT RoA Alloy (MPa) (%) (MPa) (%) (GPa) (g/cm.sup.3) (GPa) (J) (%) υ Zr.sub.36.6Ti.sub.31.4Nb.sub.7Cu.sub.5.9Be.sub.19.1 (DH1) 1512 9.58 1474 1.98 84.3 5.6 30.7 26 44 0.371 Zr.sub.38.3Ti.sub.32.9Nb.sub.7.3Cu.sub.6.2Be.sub.15.3 (DH2) 1411 10.8 1367 1.92 79.2 5.7 28.8 40 50 0.373 Zr.sub.39.6Ti.sub.33.9Nb.sub.7.6Cu.sub.6.4Be.sub.12.5 (DH3) 1210 13.10 1096 1.62 75.3 5.8 27.3 45 46 0.376 Zr.sub.41.2Ti.sub.13.8Cu.sub.12.5Ni.sub.10Be.sub.22.5 (Vitreloy 1) 1737 1.98 — — 97.2 6.1 35.9 8 0 0.355 Zr.sub.56.2Ti.sub.13.8Nb.sub.5.0Cu.sub.6.9Ni.sub.5.6Be.sub.12.5 (LM 2) 1302 5.49 1046 1.48 78.8 6.2 28.6 24 22 0.375
(56) TABLE-US-00004 TABLE 4 Material Properties as a Function of Composition and Structure, where A is Amorphous, X, is Crystalline, and C is Composite A/X/C 2.0 Hv E (GPa) (CuZr42Al7Be10)Nb3 A 626.5 108.5 (CuZr46Al5Y2)Nb3 A 407.4 76.9 (CuZrAl7Be5)Nb3 A 544.4 97.8 (CuZrAl7Be7)Nb3 A 523.9 102.0 Cu40Zr40Al10Be10 A 604.3 114.2 Cu41Zr40Al7Be7Co5 C 589.9 103.5 Cu42Zr41Al7Be7Co3 A 532.4 101.3 Cu47.5Zr48Al4Co0.5 X 381.9 79.6 Cu47Zr46Al5Y2 A 409.8 75.3 Cu50Zr50 X 325.9 81.3 CuZr41Al7Be7Cr3 A 575.1 106.5 CuZrAl5Be5Y2 A 511.1 88.5 CuZrAl5Ni3Be4 A 504.3 95.5 CuZrAl7 X 510.5 101.4 CuZrAl7Ag7 C 496.1 90.6 CuZrAl7Ni5 X 570.0 99.2 Ni40Zr28.5Ti16.5Be15 C 715.2 128.4 Ni40Zr28.5Ti16.5Cu5Al10 X 627.2 99.3 Ni40Zr28.5Ti16.5Cu5Be10 C 668.2 112.0 Ni56Zr17Ti13Si2Sn3Be9 X 562.5 141.1 Ni57Zr18Ti14Si2Sn3Be6 X 637.3 139.4 Ti33.18Zr30.51Ni5.33Be22.88Cu8.1 A 486.1 96.9 Ti40Zr25Be30Cr5 A 465.4 97.5 Ti40Zr25Ni8Cu9Be18 A 544.4 101.1 Ti45Zr16Ni9Cu10Be20 A 523.1 104.2 Vit 1 A 530.4 95.2 Vit 105 (Zr52.5Ti5Cu17.9Ni14.6Al10) A 474.4 88.5 Vit 106 A 439.7 83.3 Zr55Cu30Al10Ni5 A 520.8 87.2 Zr65Cu17.5Al7.5Ni10 A 463.3 116.9 DH1 C 391.1 84.7 GHDT (Ti30Zr35Cu8.2Be26.8) A 461.8 90.5
(57) Moreover, just as the stiffness of the BMG-based materials can be tuned, the resistance to fatigue failure can also be tuned in accordance with embodiments of the invention. The alloying elements used to improve resistance to fatigue failure is largely experimentally determined. However, the inventors have observed that the same processing techniques that are used to enhance fracture toughness tend to also beneficially influence resistance to fatigue failure.
(58) Tables 5 and 6 below list reported data as to how fatigue characteristics with BMG-based materials vary as a function of composition.
(59) TABLE-US-00005 TABLE 5 Fatigue Characteristics as a Function of Composition Fracture strength Geometry Frequency Fatigue limit Fatigue Material (MPa) (mm) Loading mode.sup.a (Hz) R-ratio (MPa) ratio.sup.b Zr.sub.56.2Cu.sub.6.9Ni.sub.5.6Ti.sub.13.8Nb.sub.5.0Be.sub.12.5 Composites [62] 1480 3 × 3 × 30 4PB 25 0.1 ~296 0.200 Zr.sub.41.2Cu.sub.12.5Ni.sub.10Ti.sub.13.8Be.sub.22.5 [49] 1900 3 × 3 × 50 4PB 25 0.1 ~152 0.080 Zr.sub.41.2Cu.sub.12.5Ni.sub.10Ti.sub.13.8Be.sub.22.5 [74] 1900 2 × 2 × 60 3PB 10 0.1 768 0.404 Zr.sub.41.2Cu.sub.12.5Ni.sub.10Ti.sub.13.8Be.sub.22.5[74] 1900 2 × 2 × 60 3PB 10 0.1 359 0.189 Zr.sub.44Ti.sub.11Ni.sub.10Cu.sub.10Be.sub.25 [75] 1900 2.3 × 2.0 × 85 4PB 5-20 0.3 550 0.289 Zr.sub.44Ti.sub.11Ni.sub.10Cu.sub.10Be.sub.25 [75] 1900 2.3 × 2.0 × 85 4PB 5-20 0.3 390 0.205 Zr.sub.52.5Cu.sub.17.9Al.sub.10Ni.sub.14.6Ti.sub.5 [77] 1700 3.5 × 3.5 × 30 4PB 10 0.1 850 0.500 (Zr.sub.58N.sub.i13.6Cu.sub.18Al.sub.10.4).sub.99Nb.sub.1 [76] 1700 2 × 2 × 25 4PB 10 0.1 559 0.329 Zr.sub.55Cu.sub.30Ni.sub.5Al.sub.10 [78] 1560 2 × 20 × 50 Plate bend 40 0.1 410 0.263
(60) TABLE-US-00006 TABLE 6 Fatigue Characteristics as a Function of Composition Fracture strength Geometry Frequency Fatigue limit Fatigue Material (MPa) (mm) Loading mode.sup.a (Hz) R-ratio (MPa) ratio Zr.sub.56.2Cu.sub.6.9Ni.sub.5.6Ti.sub.13.8Nb.sub.5.0Be.sub.12.5 Composites [56] 1480 φ2.98 TT 10 0.1 239 0.161 Zr.sub.55Cu.sub.30Al.sub.10Ni.sub.5Nano [85] 1700 2 × 4 × 70 TT 10 0.1 ~340 0.200 Zr.sub.41.2Cu.sub.12.5Nb.sub.10Ti.sub.13.8Be.sub.22.5 [55] 1850 φ2.98 TT 10 0.1 703 0.380 Zr.sub.41.2Cu.sub.12.5Nb.sub.10Ti.sub.13.8Be.sub.22.5 [55] 1850 φ2.98 TT 10 0.1 615 0.332 Zr.sub.41.2Cu.sub.12.5Nb.sub.10Ti.sub.13.8Be.sub.22.5 [56] 1850 φ2.98 TT 10 0.1 567 0.306 Zr.sub.41.2Cu.sub.12.5Nb.sub.10Ti.sub.13.8Be.sub.22.5 [80] 1900 — CC 5 0.1 ~1050 0.553 Zr.sub.41.2Cu.sub.12.5Nb.sub.10Ti.sub.13.8Be.sub.22.5 [80] 1900 — TC 5 -1 ~150 0.079 Zr.sub.50Cu.sub.40Al.sub.10 [53] 1821 φ2.98 TT 10 0.1 752 0.413 Zr.sub.50Cu.sub.30Al.sub.10Ni.sub.10 [53] 1900 φ2.98 TT 10 0.1 865 0.455 Zr.sub.50Cu.sub.37Al.sub.10Pd.sub.3 [57] 1899 φ2.98 TT 10 0.1 983 0.518 Zr.sub.50Cu.sub.37Al.sub.10Pd.sub.3 [81] 1899 φ5.33 TT 10 0.1 ~900 0.474 Zr.sub.52.5Cu.sub.17.9Al.sub.10Ni.sub.14.6Ti.sub.5 [82] 1660 6 × 3 × 1.5 TT 1 0.1 — — Zr.sub.52.5Cu.sub.17.9Al.sub.10Ni.sub.14.6Ti.sub.5 [51] 1700 φ2.98 TT 10 0.1 907 0.534 Zr.sub.59Cu.sub.20Al.sub.10Ni.sub.8Ti.sub.3 [82] 1580 6 × 3 × 1.5 TT 1 0.1 — — Zr.sub.65Cu.sub.15Al.sub.10Ni.sub.10 [84] 1300 3 × 4 × 16 TT 20 0.1 ~280 0.215 Zr.sub.55Cu.sub.30Al.sub.10Ni.sub.5 [83] 1560 1 × 2 × 5 TT .13 0.5 — —
(61) Although this data has been reported, the Inventors note that this data is in conflict with their own results. Indeed through their own testing, the Inventors have identified particular compositions and families of compositions that are particularly suitable for the design, manufacture, and implementation of compliant mechanisms. This is now discussed below.
(62) Compositions that are Particularly Suitable for Compliant Mechanisms
(63) The Inventors conducted their own fatigue tests (under ASTM stress-life [S-N] testing parameters), and the results of the test are depicted in
(64) In particular,
(65) Similarly,
(66) The inventors also provide
(67) TABLE-US-00007 TABLE 7 Fatigue Crack Growth Parameters and Densities Material ΔK.sub.0 (MPa .Math. m.sup.1/2) m C(MPa .Math. m.sup.1/2) Density (g/cm.sup.3) DH1 5.0 3.5 1.5 × 10.sup.−11 5.58 composite DH1A 5.4 2.4 5.9 × 10.sup.−11 5.43 composite DH1B 5.7 3.5 1.5 × 10.sup.−11 5.85 composite Vitreloy 1.sup.2 1-3 2.7-4.9 1.5 × 10.sup.−11 − 6.05 1.6 × 10.sup.−11 Vitreloy 1.sup.25 1.5 1.5 . . . 6.05 Vitreloy 1 1.2 1.8 . . . . . . composite (LM2).sup.18 300-M Steel.sup.2 3 2-4 . . . 7.9 2090-T81 2.1 2-4 . . . 2.7 Al alloys.sup.2 ΔK.sub.0, threshold stress intensity factor range for fatigue crack initiation; m, Paris exponent.
(68) Accordingly, in view of this information, the Inventors have observed that DH composites would also serve as suitable materials from which to form compliant mechanisms. Note that
(69) Accordingly, in many embodiments of the invention, a compliant mechanism is fabricated from one of: Composite DV1 (Ag boat), Composite DV1 (Indus.), Composite DH3, Composite LM2, Composite DH1, Composite DH1A, Composite DH1 B, and Vitreloy.
(70) Additionally, the Inventors have further observed that, generally, ZrTiBe based BMG Composites with additives to improve glass forming ability and ductility, are well suited for compliant mechanism applications. In many embodiments, a compliant mechanism may be formed from a TiZrBeXY BMGMC where X is an additive that is used to enhance glass forming ability, and Y is an additive added for toughness.
(71) In many embodiments, Ti is between approximately 10 and 60 atomic %; Zr is between 18 and 60 atomic %; and Be is between approximately 7 and 30 atomic %.
(72) In a number of embodiments, X is one of: Fe, Cr, Co, Ni, Cu, Al, B, C, Al, Ag, Si, and mixtures thereof. The inventors have observed that: where C, Si, or B is the additive, it is generally preferable that the additive be added in an amount less than 2 atomic %; where Cr, Co, or Fe is the additive, it is generally preferable that the additive be added in an amount less than 7 atomic %; where Al is the additive, it is generally preferable to have it added in an amount less than 10 atomic %; and where Cu and Ni are the additives, it is generally preferable that one or both be added in an amount less than 20 atomic % (in combination). Additionally, it may be preferred that the combination of the atomic percentages of Be and X should be less than 30%, otherwise a BMG is formed and not a BMGMC—BMGMCs are preferable in many instances. For example, in many cases BMGMCs will plastically yield before they rupture; conversely, many BMG materials tend to rupture prior to noticeable yielding. Generally, the crystals that are present within BMGMCs increase their ductility. In many embodiments where BMGMC materials are used, the volume fraction of crystals ranges from 20-80%. Of course, the crystals can be present in any amount in accordance with embodiments of the invention, for example between approximately 5 and 95%. Indeed, any suitable BMGMCs can be used. On the whole, the Inventors have observed that BMGMCs are very well-suited for compliant mechanism applications, as they exhibit noteworthy resistance to fatigue. Of course, in many embodiments, compliant mechanisms are formed from monolithic BMG materials.
(73) In many embodiments, Y is one of: V, Nb, Ta, Mo, Sn, W and mixtures thereof. Generally, these elements can be considered as ‘beta stabilizers’ and they make the dendrites softer and the alloy tougher. The inventors have generally observed that: where V is the additive, it is generally preferable that it be added in an amount less than 15 atomic %; where Nb is the additive, it is generally preferable that it be added in an amount between approximately 5 and 15 atomic %; where Ta is the additive, it is generally preferable that it be added in an amount less than 10 atomic %; where Mo is the additive, it is generally preferable that it be added in an amount less than 5 atomic %; and where Sn is the additive, it is generally preferable that it be added in an amount less than 2 atomic %.
(74) Thus, in many embodiments, a compliant mechanism is fabricated from a BMGMC in accordance with the above-described compositions. The Inventors note that any of a variety of compliant mechanism designs can benefit from being formed from BMG-based materials, and some examples are discussed below.
(75) Examples of Compliant Mechanisms that can be Formed from BMG-Based Materials
(76) Of course any number of compliant mechanisms can be formed from BMG-based materials in accordance with embodiments of the invention. Some illustrative examples are discussed below.
(77) In some embodiments, a bistable mechanism is formed from a BMG-based material. A bistable mechanism is a type of compliant mechanism that uses elastic deformation to allow the mechanism to be stable in at least two configurations. Bistable mechanisms may be extremely useful for the storage of elastic strain energy that can later be released through actuation. This may include devices like switches or devices that can be used to deploy another component. Generally, in many instances, bistable mechanisms implement flexible members that, when strained, exert counteracting forces, and thereby allow the bistable mechanism to adopt multiple stable configurations.
(78) Bistable mechanisms fabricated from BMG-based materials can be particularly advantageous as BMG-based materials can store relatively more strain energy than many other materials that are commonly used to form compliant mechanisms.
(79) There exists many designs for bistable mechanisms, and any of them can of course be formed form a BMG-based material in accordance with embodiments of the invention. One example of a bistable mechanism is illustrated in
(80) Of course any bistable mechanism can be formed from a BMG-based material in accordance with embodiments of the invention, not just the ones illustrated. Indeed, any of a variety of compliant mechanisms can be formed from BMG-based materials in accordance with embodiments of the invention.
(81) For example, in some embodiments, compliant mechanisms for precision pointing applications (e.g. for use in optics) are fabricated from BMG-based materials. Generally, precision pointing applications require an actuation force that causes the elastic deformation of the flexural components. Forming such compliant mechanisms from BMG-based materials can be advantageous as BMG-based materials have relatively higher strength to stiffness ratios than many other metals; thus, BMG-based materials can result in designs that have relatively larger ranges of flexing for a fixed geometry, or alternatively a smaller size for a fixed force.
(82)
(83)
(84) Note that BMG-based materials are sufficiently amenable to the above-listed adjoining processes. More generally, in accordance with embodiments of the invention, BMG-based materials can be formed into sheets of material, which can easily be manipulated to fabricated structures. For example, BMG-based materials can be made into sheet-like forms, and can be cut, bent, stacked, welded, pinned, or otherwise assembled into a mechanism. In particular, sheets of BMG-based materials are easy to weld together and can be cut easily using waterjet cutting, EDM, laser cutting, etc.
(85) The compliant scissors depicted in
(86) As should evident from the above discussion, compliant mechanisms can be formed from any number of BMG-based materials in accordance with embodiments of the invention. As further discussed above, the particular BMG-based material that is selected for fabrication can be based on the desired design parameters. For example, the design requirements for a particular rotational hexfoil flexure may require that it be able to survive at least 100 cycles of an applied bending load at 50% of the total elastic strain limit. Accordingly, an appropriate BMG-based material that meets this criterion may be selected from which to fabricate the compliant mechanism.
(87) The Inventors have further observed that it many instances it may be beneficial to manufacture compliant mechanisms from BMGMCs using particular manufacturing techniques, and this is now discussed below.
(88) Methods for Fabricating BMGMC-Based Compliant Mechanisms
(89) In many cases, the relatively higher viscosities of BMGMCs impacts their ability to be serve as materials from which compliant mechanisms can be fabricated. Accordingly, the manufacture of compliant mechanisms from BMGMCs can benefit from tailored manufacturing methodologies. In particular, in many embodiments, compliant mechanisms are formed from BMGMCs using squeeze-casting techniques. Squeeze-casting is often utilized in the formation of plastic parts; however, many BMGMCs have a similarly viscous texture and are thereby amenable to such manufacturing techniques.
(90) A method of fabricating a BMGMC-based macroscale compliant mechanism that includes forging a BMGMC material into a mold at high pressure, ejecting the BMGMC material from the mold upon cooling, and excising any remnant flashing or remnant material is illustrated in
(91)
(92) Similarly,
(93) Note that to complete the cross-blade flexure, two z-shaped BMGMC-based compliant mechanisms must be adjoined. They can be adjoined in any suitable way in accordance with embodiments of the invention. For example, they can be adjoined using one of: welding, capacitive discharge, bolts, screws, pins, and mixtures thereof.
(94)
(95) The inventors also provide
(96) Note also that, in many instances, prior to fabricating a BMG-based macroscale compliant mechanism, a model of the compliant mechanism is manufactured from polymers using 3d-printing techniques. In this way, the efficacy of the design may be assessed before committing resources to fabricating the BMG-based part. This assessment can be particularly useful as polymers have similar strain characteristics of many BMGMCs—accordingly a 3d-printed polymer-based compliant mechanism can in many ways simulate the operation of the related BMG-based compliant mechanism. Moreover 3d-printing is generally more cost efficient as relative to the manufacturing techniques used in fabricating BMG-based compliant mechanisms.
(97) Any of the above-mentioned manufacturing techniques can be implemented in accordance with embodiments of the invention. More generally, as can be inferred from the above discussion, the above-mentioned concepts can be implemented in a variety of arrangements in accordance with embodiments of the invention. Accordingly, although the present invention has been described in certain specific aspects, many additional modifications and variations would be apparent to those skilled in the art. It is therefore to be understood that the present invention may be practiced otherwise than specifically described. Thus, embodiments of the present invention should be considered in all respects as illustrative and not restrictive.