PRINTING METHODS

Abstract

A method for determining coat weight of a printed transparent electrophotographic composition is described, in which a calibration composition is added to a transparent liquid electrophotographic composition to produce a test composition, the calibration composition comprising a carrier liquid, a polymer resin, and at least 5 wt. % of an optical brightening agent based on the total solids content of the calibration composition. The test composition is electrophotographically printed onto a test substrate to produce the printed transparent electrophotographic ink composition; the fluorescence of the printed transparent electrophotographic composition is measured; and the coat weight of the printed transparent electrophotographic composition is determine based on the fluorescence of the printed transparent electrophotographic composition.

Claims

1. A method for determining coat weight of a printed transparent electrophotographic composition, comprising: (i) adding to a transparent liquid electrophotographic composition a calibration composition, the calibration composition comprising a carrier liquid, a polymer resin, and at least 5 wt. % of an optical brightening agent based on the total solids content of the calibration composition to produce a test composition; (ii) electrophotographically printing the test composition onto a test substrate to produce the printed transparent electrophotographic ink composition; (iii) measuring the fluorescence of the printed transparent electrophotographic composition; and (iv) determining the coat weight of the printed transparent electrophotographic composition based on the fluorescence of the printed transparent electrophotographic composition.

2. The method of claim 1, wherein the calibration composition is a transparent or non-pigmented liquid electrophotographic composition.

3. The method of claim 1, wherein the optical brightening agent is a colourless optical brightening agent.

4. The liquid electrophotographic composition of claim 1, wherein the optical brightening agent is a fluorophore.

5. The liquid electrophotographic composition of claim 1, wherein the optical brightening agent comprises one or more of a triazine stilbene and derivatives thereof, a biphenyl stilbene and derivatives thereof, a coumarin and derivatives thereof, a benzoxazoline and derivatives thereof, a diazole and derivatives thereof, an imidazoline and derivatives thereof, or mixtures thereof.

6. The method of claim 1, wherein the polymer resin comprises a copolymer of an alkylene monomer and a monomer selected from acrylic acid and methacrylic acid.

7. The liquid electrophotographic composition of claim 1, wherein the composition further comprises a fluorescence adjuvant.

8. The liquid electrophotographic composition of claim 1, wherein the composition further comprises a charge director.

9. The method of claim 1, wherein the transparent liquid electrophotographic composition is non-pigmented liquid electrophotographic composition.

10. The method of claim 1, wherein the coat weight of the printed transparent electrophotographic composition is directly proportional to the fluorescence of the printed transparent electrophotographic composition.

11. A method of printing a transparent electrophotographic composition, comprising: performing the method of claim 1; adjusting a printing parameter based on the determined coat weight of the printed transparent electrophotographic composition; and printing the transparent liquid electrophotographic composition onto a print substrate.

12. The method of claim 11, wherein adjusting a printing parameter comprises adjusting the amount of the transparent liquid electrophotographic composition printed onto the print substrate.

13. The method of claim 11, wherein adjusting a printing parameter comprises adjusting a dosing parameter, a printing temperature, a printing pressure, or any combination thereof.

14. The method of claim 11, wherein the steps of determining the coat weight and adjusting a printing parameter are repeated before printing the transparent liquid electrophotographic composition onto the print substrate.

Description

BRIEF DESCRIPTION OF THE FIGURES

[0027] FIG. 1 shows the correlation between the coat weight of a printed transparent or colourless electrophotographic composition according to Example 1 and measured fluorescence;

[0028] FIG. 2 shows the correlation between the coat weight of a printed transparent or colourless electrophotographic composition according to Example 2 and measured fluorescence; and

[0029] FIG. 3 shows the correlation between the coat weight of a printed transparent or colourless electrophotographic composition according to Example 3 and measured fluorescence.

[0030] Described herein are methods of determining coat weight of a printed transparent electrophotographic composition, and methods of printing, for example by first calibrating a printing apparatus on the basis of the determined coat weight using fluorescence measurements. The printing apparatus may be any printing apparatus suited for electrophotographic printing, for example the HP Indigo series of printers.

[0031] The methods described herein use a calibration composition, which may be referred to as a liquid electrophotographic composition and which comprises a carrier liquid, a polymer resin and an optical brightening agent.

[0032] The methods described herein comprise adding the calibration composition to a transparent liquid electrophotographic composition to be printed. As previously described, such a liquid electrophotographic composition also comprises a carrier liquid and a polymer resin. The carrier liquid and polymer resin present in the calibration composition and in the transparent liquid electrophotographic composition to be printed will now be described.

[0033] Generally, the carrier liquid comprises substituted or unsubstituted, linear or branched, aliphatic compounds. The carrier liquid may include aryl substituents. In one example, the carrier liquid can be substantially nonaqueous, i.e. containing less than 0.5% water. In another example, the carrier liquid can be nonaqueous. The carrier liquid can comprise a member selected from the group of paraffins, isoparaffins, oils, alkanes having from about 6 to about 100 carbon atoms, and mixtures thereof.

[0034] As such, the carrier liquid can comprise, or substantially comprise, or even consist essentially of isoparaffins, such as or equivalent to the ISOPAR(R) high-purity isoparaffinic solvents with narrow boiling ranges marketed by Exxon Mobil Corporation (Fairfax, Va., USA).

[0035] The liquid electrophotographic compositions described herein include a polymer resin. The resin may comprise a copolymer of ethylene acrylic acid, ethylene methacrylic acid, ethylene acrylic ester maleic anhydride, ethylene acrylic ester glycidyl methacrylate, maleic anhydride, styrene maleic anhydride, and mixtures thereof.

[0036] The polymer resin can be selected from resins such as ethylene-vinyl acetate(EVA) copolymers; copolymers of ethylene and an ethylenically unsaturated acid of either acrylic acid and methacrylic acid; copolymers of ethylene, acrylic or methacrylic acid/alkyl ester of methacrylic or acrylic acid; polyethylene; polystyrene; crystalline polypropylene; ethylene ethyl acrylate; ethylene methacrylic acid copolymers which are partially neutralized with metal ions (e.g. Zn, Na, Li) such as SURLYN (R) ionomers; acid modified ethylene vinyl acetate terpolymer or blends thereof; polyesters; polyvinyl toluene; polyamides; styrene/butadiene copolymers; combinations thereof; and blends thereof. The polymer resin may be a copolymer of ethylene and an ethylenically unsaturated acid of either acrylic or methacrylic acid; an ionomer of ethylene methacrylic acid copolymer; an ester of ethylene methacrylic acid copolymer and an acid modified ethylene vinyl acetate terpolymer; combinations thereof; and/ or blends thereof. The polymer resin may be a NUCREL(R) polymer, such as NUCREL(R) 925, NUCREL(R) 2906, NUCREL(R) 2806, NUCREL(R) 960, NUCREL(R) 699 or NUCREL(R) 599.

[0037] The polymer resin may include polymers such as polyamines and polyamides. The resin may be a homopolymer or a copolymer of polyvinyl pyrrolidone. The resin may be a copolymer of polyvinyl pyrrolidone. Examples of monomers polymerized with vinyl pyrrolidone in order to form polyvinyl pyrrolidone copolymers include, but are not limited to, alkylmethacrylates-acrylates such as butylmethacrylates, methylmethacrylates and the like. Illustrative examples of polyvinyl pyrrolidones polymers include, for example, styrene/butylmethacrylate/vinyl pyrrolidone terpolymers, vinyl pyrrolidone/vinyl acetate copolymers, vinyl pyrrolidone homopolymers, and the like. The resin may be a vinyl pyrrolidone/triacontene copolymer (a copolymer of vinylpyrrolidone grafted with triacontene). The resin may be 2-pyrrolidinone 1-ethenyl triacontene polymer.

[0038] The resin may be a polyvinyl pyridine polymer or copolymer such as polyvinyl pyridine co-styrene or polyvinyl pyridine co-butyl methacrylate. The resin may be an amino terminated polyacrylate such as poly(t-butyl amino ethyl methacrylate) or poly(dimethyl amino ethyl methacrylate). The resin may be a polymer or copolymer selected from the group consisting of polyethylene imine; polyethylene oxide diamine terminated; polypropylene oxide, monoamine or di-amine terminated; polyamide; polydimethyl siloxane diamino propyl terminated; ethylene/butylene copolymer mono and dihydroxy terminated; hydroxyl ethyl cellulose.

[0039] Exemplary embodiments of the resin of the present disclosure include Antaron® WP-660 wax resin, a copolymer available from International Specialty Products and Alcyn® 575 wax resin, a copolymer available from Honeywell Inc.

[0040] The resin can encapsulate the optical brightening agent during grinding or mixing to create a fluorescent particle. The fluorescent particle can have a final particle size from about 1 micron to about 10 microns.

[0041] In some examples, the resin may represent from about 1 to about 99 weight percent (wt %) of the total amount of solids present in the composition, i.e. wt % of total weight of non volatile substances (NVS). In some other examples, resin may represent from about 25 to about 80 wt % of the total amount of solids present in the ink composition. In yet some other examples, resin may represent from about 35 to about 70 wt % of the total amount of solids present in the ink composition.

[0042] The liquid electrophotographic calibration composition includes an optical brightening agent (OBA). Optical brightening agents are typically used to improve whiteness and/or brightness of a media. An OBA absorbs ultraviolet light and re-emits blue light and so is a fluorescent compound. The blue light is added to the reflected light of the media. The media appears less green and/or yellow because more blue light is reflected.

[0043] An OBA is also commonly referred to as a fluorescence whitening agent (FWA). It has been recognised that inclusion of a calibration composition comprising an optical brightening agent into a liquid electrophotographic composition allows an inline determination of the coat weight or thickness of the printed composition based on the fluorescence profile of the optical brightening agent. References in this disclosure to the fluorescence profile of the optical brightening agent are to the difference between the fluorescence emission of the unprinted substrate and the fluorescence of a liquid electrophotographic composition as described herein printed on the substrate.

[0044] Basic classes of OBA that can be used in the calibration composition include triazine-stilbenes, coumarins, imidazolines, diazoles, triazoles, benzoxazolines, and biphenyl-stilbenes. Different OBAs are commercially available from a number of sources, including BASF Corporation Clariant Corporation, and the like. Tinopal® SFP is the trade name of an OBA commercially available from BASF Corporation. Leucophor® NS is the trade name of an anionic OBA commercially available from Clariant Corporation. Other examples of OBAs include Megawhite DT, Megawhite 2B, Megawhite WHN, Megawhite DMX (from Meghmani Dyes and Intermediates Ltd, India), Uvitex OB.

[0045] In one example, the liquid electrophotographic calibration composition described herein is used to determine coat weight by adding the calibration composition to a transparent LEP composition to be printed. The OBA is present in the liquid electrophotographic calibration composition in an amount sufficient to allow determination of a fluorescence profile once the composition has been mixed with the transparent LEP composition and printed.

[0046] The optical brightening agent may be substantially insoluble in the carrier liquid. The optical brightening agent may be completely insoluble in the carrier liquid.

[0047] The OBA can be present in the calibration composition in an amount of at least 5.0 wt % based on the total solids of the composition. In another example, the OBA can be present in the calibration composition in an amount of at least 10 wt % based on the total solids of the composition. In another example, the OBA can be present in the calibration composition in an amount of at least 15 wt % based on the total solids of the composition. In another example, the OBA can be present in the calibration composition in an amount of at least 20 wt % based on the total solids of the composition. In another example, the OBA can be present in the calibration composition in an amount of at least 30 wt % based on the total solids of the composition. In another example, the OBA can be present in the calibration composition in an amount of at about 40 wt % based on the total solids of the composition.

[0048] In another example, the OBA can be present in the calibration composition in an amount less than 40 wt % based on the total solids of the composition. In another example, the OBA can be present in the calibration composition in an amount less than 30 wt % based on the total solids of the composition. In another example, the OBA can be present in the calibration composition in an amount less than 20 wt % based on the total solids of the composition. In another example, the OBA can be present in the calibration composition in an amount less than 15 wt % based on the total solids of the composition. In another example, the OBA can be present in the calibration composition in an amount less than 10 wt % based on the total solids of the composition. In another example, the OBA can be present in the calibration composition in an amount of about 5 wt % based on the total solids of the composition.

[0049] The calibration composition comprising the OBA may be used in an amount such that, when mixed with a transparent LEP composition to be printed, the OBA may be present in the resulting test composition in an amount from 0.1% wt. to 2.0% wt based on the total solids content of the test composition. In another example, the calibration composition may be used in an amount such that the OBA is present in the test composition from 0.1% wt. to 1.5% wt based on the total solids content of the composition. Further, the composition described herein may be used in an amount such that the OBA is present in the test composition from 0.3% wt. to 1.0% wt based on the total solids content of the composition.

[0050] In another example, the calibration composition described herein may be used in an amount such that the OBA is present in the test composition in an amount less than 5.0 wt % based on the total solids of the composition. In another example, the composition described herein may be used in an amount such that the OBA is present in the test composition in an amount less than 2.0 wt % based on the total solids of the composition. In another example, the composition described herein may be used in an amount such that the OBA is present in the test composition in an amount less than 1.8 wt % based on the total solids of the composition. In another example, the composition described herein may be used in an amount such that the OBA is present in the test composition in an amount less than 1.7 wt % based on the total solids of the composition. In another example, the composition described herein may be used in an amount such that the OBA is present in the test composition in an amount less than 1.6 wt % based on the total solids of the composition. In another example, the composition described herein may be used in an amount such that the OBA is present in the test composition in an amount less than 1.5 wt % based on the total solids of the composition.

[0051] The calibration composition may also contain a fluorescence adjuvant. The fluorescence adjuvant increases the visible blue light emissions significantly and so enhances the fluorescence profile of the optical brightening agent in the printed composition. The fluorescence adjuvant may be an organic polyol. Examples of suitable polyols include high molecular weight polyethylene glycol or polyvinyl alcohol. Other examples of organic polyols which can be used as a fluorescence adjuvant include maltose monohydrate, sucrose, dextrin and sorbitol.

[0052] The calibration composition may contain a fluorescence adjuvant in an amount of at least 20 wt % of the total amount of solids present in the composition. The calibration composition may contain a fluorescence adjuvant in an amount of at least 25 wt % of the total amount of solids present in the composition. The calibration composition may contain a fluorescence adjuvant in an amount of at least 30 wt % of the total amount of solids present in the composition. The calibration composition may contain a fluorescence adjuvant in an amount of at least 40 wt % of the total amount of solids present in the composition. The calibration composition may contain a fluorescence adjuvant in an amount of about 50 wt % of the total amount of solids present in the composition.

[0053] The calibration composition may contain a fluorescence adjuvant in an amount of less than 50 wt % of the total amount of solids present in the composition. The calibration composition may contain a fluorescence adjuvant in an amount of less than 40 wt % of the total amount of solids present in the composition. The calibration composition may contain a fluorescence adjuvant in an amount of less than 30 wt % of the total amount of solids present in the composition. The calibration composition may contain a fluorescence adjuvant in an amount of less than 25 wt % of the total amount of solids present in the composition. The calibration composition may contain a fluorescence adjuvant in an amount of about 20 wt % of the total amount of solids present in the composition.

[0054] The liquid electrophotographic composition, which may be the calibration composition or the liquid electrophotographic composition the coat weight of which is to be determined, may comprise a cosolvent, such as one or more alkanes having from about 6 to about 14 carbon atoms, for example solvents sold under the NORPAR(R) (NORPAR(R) 12, 13 and 15) tradename available from Exxon Mobil Corporation (Fairfax, Va., USA). Other hydrocarbons for use as a carrier liquid, or cosolvent, are sold under the AMSCO(R) (AMSCO(R) 460 and OMS) tradename available from American Mineral Spirits Company (New York, N.Y., USA), under the SOLTROL(R) tradename available from Chevron Phillips Chemical Company LLC (The Woodlands, Tex., USA) and under the SHELLSOL(R) tradename available from Shell Chemicals Limited (London, UK). Such a carrier liquid, or cosolvent, can have desirable properties such as low odor, lack of color, selective solvency, good oxidation stability, low electrical conductivity, low skin irritation, low surface tension, superior spreadability, narrow boiling point range, non-corrosive to metals, low freeze point, high electrical resistivity, low surface tension, low latent heat of vaporization and low photochemical reactivity.

[0055] The liquid electrophotographic composition, which may be the calibration composition or the liquid electrophotographic composition to be printed, may contain a charge director. The charge director can be added to the carrier liquid in order to maintain sufficient electrostatic charge on the optical brightening agent particles. For example, the charge components can be nanoparticles of a simple salt and a sulfosuccinate salt of the general formula MA.sub.n, wherein M is a metal, n is the valence of M, and A is an ion of the general formula [R.sub.1—O—C(O)CH.sub.2CH(SO.sub.3OC(O)—O—R.sub.2] where each of R.sub.1 and R.sub.2 is an alkyl group, or other charge component as found in WO 2007/130069. Additionally, charge director compounds include ionic compounds, particularly metal salts of fatty acids, metal salts of sulfo-succinates, metal salts of oxyphosphates, metal salts of alkyl-benzenesulfonic acid, metal salts of aromatic carboxylic acids or sulfonic acids, as well as zwitterionic and non-ionic compounds, such as polyoxyethylated alkylamines, lecithin, polyvinylpyrrolidone, organic acid esters of polyvalent alcohols, etc. The charge director used herein can be any as known in the art such as described in U.S. Pat. No. 5,346,796.

[0056] The charge director may be present in an amount representing from about 0.001 to about 5 weight percent (wt %) of the total amount of solids present in the composition, i.e. wt % of total weight of non volatile substances (NVS). The charge director may be present in an amount representing from about 0.01 to about 0.5 wt % of the total amount of solids present in the composition.

[0057] The liquid electrophotographic composition, which may be the calibration composition or the liquid electrophotographic composition to be printed, may include a charge adjuvant. The charge adjuvant may include, but is not limited to, barium petronate, calcium petronate, Co salts of naphthenic acid, Ca salts of naphthenic acid, Cu salts of naphthenic acid, Mn salts of naphthenic acid, Ni salts of naphthenic acid, Zn salts of naphthenic acid, Fe salts of naphthenic acid, Ba salts of stearic acid, Co salts of stearic acid, Pb salts of stearic acid, Zn salts of stearic acid, Al salts of stearic acid, Zn salts of stearic acid, Cu salts of stearic acid, Pb salts of stearic acid, Fe salts of stearic acid, metal carboxylates (e.g., Al tristearate, Al octanoate, Li heptanoate, Fe stearate, Fe distearate, Ba stearate, Cr stearate, Mg octanoate, Ca stearate, Fe naphthenate, Zn naphthenate, Mn heptanoate, Zn heptanoate, Ba octanoate, Al octanoate, Co octanoate, Mn octanoate, and Zn octanoate), Co lineolates, Mn lineolates, Pb lineolates, Zn lineolates, Ca oleates, Co oleates, Zn palmirate, Ca resinates, Co resinates, Mn resinates, Pb resinates, Zn resinates, AB diblock copolymers of 2-ethylhexyl methacrylate-co-methacrylic acid calcium and ammonium salts, copolymers of an alkyl acrylamidoglycolate alkyl ether (e.g., methyl acrylamidoglycolate methyl ether-co-vinyl acetate), and hydroxy bis(3,5-di-tert-butyl salicylic) aluminate monohydrate. The charge adjuvant may be aluminum stearate or aluminum tristearate. The charge adjuvant may be present in an amount of about 0.1 to 5, about 0.5 to 4, and about 1 to 3% weight of the liquid electrophotographic composition.

[0058] The liquid electrophotographic compositions may also contain others additives such as a surface modifier, compatibility additives, a viscosity control agent, media additives, fixing additives and other additives. A viscosity control agent assists in maintaining viscosity of starting materials combined in a resin grinding and optical brightening agent dispersion process to adequately reduce particle size. During the processing, depending on physical properties of the resin and optical brightening agent and the operating conditions for grinding, optical brightening agent may become encapsulated by resin when loading it on the resin, though encapsulation is not required. A viscosity control agent may be selected that, after grinding, also functions as a charge adjuvant.

[0059] The liquid electrophotographic compositions of the present disclosure can also be suitable for use on many types of substrates of recording media, including but not limited to vinyl media, cellulose-based paper media, various cloth materials, polymeric materials (non-limitative examples of which include polyester white film or polyester transparent film), photopaper (non-limiting examples of which include polyethylene or polypropylene extruded on one or both sides of paper), metals, and/or mixtures or composites thereof.

[0060] The present disclosure relates to electrophotographic printing techniques and methods. Electrophotographic printing techniques involve the formation of a latent image on a photoconductor surface mounted on a photo imaging plate (PIP). The photoconductor is first sensitized to light, usually by charging with a corona discharge, and then exposed to light projected through a positive film of the document to be reproduced, resulting in dissipation of the charge in the areas exposed to light. The latent image is subsequently developed into a full image by the attraction of oppositely charged toner particles to the charge remaining on the unexposed areas. The developed image is transferred from the photoconductor to a rubber offset blanket (also referred to as an intermediate transfer medium), from which it is transferred to a substrate, such as paper, plastic or other suitable material, by heat or pressure or a combination of both to produce the printed final image.

[0061] The method of determining coat weight of a printed transparent electrophotographic composition comprises a step of adding to a transparent liquid electrophotographic composition a calibration composition, the calibration composition comprising a carrier liquid, a polymer resin, and at least 5 wt. % of an optical brightening agent based on the total solids content of the calibration composition to produce a test composition. The transparent liquid electrophotographic composition may be any non-pigmented or colourless liquid electrophotographic composition as described previously.

[0062] In one example, at least 5 wt % of the calibration composition is added to the transparent liquid electrophotographic composition to form the test composition. In one example, at least 10 wt % of the calibration composition is added to the transparent liquid electrophotographic composition to form the test composition. In one example, about 15 wt % of the calibration composition is added to the transparent liquid electrophotographic composition to form the test composition.

[0063] In one example, less than about 15 wt % of the calibration composition is added to the transparent liquid electrophotographic composition to form the test composition. In one example, less than about 10 wt % of the calibration composition is added to the transparent liquid electrophotographic composition to form the test composition. In one example, about 5 wt % of the calibration composition is added to the transparent liquid electrophotographic composition to form the test composition.

[0064] The calibration composition may be added to the transparent liquid electrophotographic print composition in press. The calibration composition may be added to the tank of the press containing the transparent print composition through the use of a metering pump, to accurately transfer the calibration composition from a reservoir to the tank containing the transparent print composition. Thus, the method comprises forming the test composition in situ in the tank which feeds a binary ink developer (BID) of the electrophotographic printing press.

[0065] The method of determining coat weight also comprises printing the test composition onto a test substrate. The step of printing the test composition onto the test substrate may in the first instance comprise operating the printing apparatus under normal operating parameters according to the manufacturer's operating manual.

[0066] The test substrate may be any substrate which is suitable for an electrophotographic printing process. Many types of printing paper include optical brightening agents, the presence of which may have an effect on the fluorescence profile of the printed composition. To circumvent this, the test substrate may comprise four layers of printed cyan ink which negates any effect of any optical brightening agents present in the test substrate.

[0067] The method of determining coat weight also comprises measuring the fluorescence of the printed composition. The fluorescent radiation can be quantified using any fluorometer. A suitable fluorometer is the PerkinElmer LS45 luminescence spectrometer. To avoid any experimental variation, the fluorescent intensity may be normalised against a photochemically fluorescent stable standard. One example of such a standard is USFS-205-020 from Labsphere (NH, USA).

[0068] In one example, the fluorescence measurement of the printed transparent electrophotographic composition and/or the test substrate may be carried out in-line with the printing step. In this context, “in-line” will be understood as meaning that the printed article is received by the fluorometer directly after leaving the intermediate transfer member and impression drum of the electrophotographic printing step or apparatus.

[0069] Measurement of the fluorescence of the printed composition and the test substrate allows the determination of the coat weight based on the fluorescence profiles so obtained. In one example, this determination may be carried out by reference to a previously generated calibration curve of coat weight versus normalised fluorescence intensity. The calibration curve may be generated by printing different numbers of layers of the transparent test composition onto a test substrate at various test patches (for example 10, 15, 20 and 25), measuring the fluorescence as described previously at each point, determining coat weight gravimetrically after removal of the printed compositions from the substrate and correlating this with the measured fluorescence.

[0070] The present disclosure also relates to a method of printing a transparent electrophotographic composition, comprising performing the method of determining coat weight described previously, and adjusting a printing parameter based the determined coat weight. For example, if the method of determining coat weight reveals that the printing apparatus has printed too much composition and the coat weight is greater than desired or intended, a printing parameter of the printing apparatus can be adjusted to ensure that less transparent composition is transferred to the print substrate.

[0071] In one example, adjusting a printing parameter comprises adjusting the amount of the transparent liquid electrophotographic composition printed onto the print substrate. In one example, adjusting a printing parameter comprises adjusting a dosing parameter, a printing temperature, a printing pressure, or any combination thereof. In one example, adjusting a printing parameter comprises adjusting the amount of charge adjuvant present in the transparent liquid electrophotographic composition.

[0072] In one example, a dosing parameter is adjusted to transfer less or more of the transparent liquid electrophotographic composition from the reservoir to the developer associated with the reservoir, or from the developer to the imaging plate. In one example, a dosing parameter is adjusted by increasing or decreasing the developer voltage to transfer more or less of the transparent liquid electrophotographic composition from the developer unit to the imaging plate. Transferring more or less of the transparent liquid electrophotographic composition from the reservoir and/or the developer to the imaging plate will result in more ore less of the composition being printed onto the print substrate. For example, if it was identified that a printed coat weight was 5% above target weight determined according to the methods described herein, a dosing parameter can be adjusted to deliver 5% less composition to the developer and imaging plate.

[0073] In one example, a printing temperature, for example the intermediate transfer member or blanket temperature is adjusted to transfer more or less of the transparent liquid composition to the print substrate from the intermediate transfer medium. In one example, a printing pressure, for example the pressure exerted by the blanket and impression drum onto the paper, is adjusted to transfer more or less of the transparent liquid composition to the print substrate from the intermediate transfer medium.

[0074] In one example, the steps of determining a coat weight and adjusting a printing parameter may be repeated until a desired coat weight is reproducibly achieved before the step of printing the transparent liquid electrophotographic composition onto the print substrate. The step of printing the transparent liquid electrophotographic composition onto the print substrate comprises operating the printing apparatus according to the last set of operating parameters applied during the calibration steps, but applying the transparent liquid electrophotographic composition in place of the calibration composition (comprising the liquid electrophotographic composition and the optical brightening agent).

EXAMPLES

[0075] The following examples are to be understood as being only exemplary or illustrative of the application of the principles of the present disclosure. Numerous modifications and alternative compositions and methods may be devised by those skilled in the art without departing from the spirit and scope of the present disclosure. Thus, these examples should not be considered as limitations of the present disclosure, but are merely in place to teach how to make and use compositions of the present disclosure.

[0076] Many printing papers contain brightening agents. In order to minimise fluorescence from the tested substrate and to demonstrate the correlation between fluorescence of the printed film (comprising the optical brightening agent) and the coat weight or thickness of the film, the liquid electrophotographic compositions of the present disclosure were printed onto a substrate which had been pre-printed with four layers of a cyan liquid electrophotographic ink (HP Indigo ElectroInk Cyan®).

[0077] Fluorescence was determined using a PerkinElmer® LS45 luminescence spectrometer. Excitation wavelength was 350 nm where fluorescence was measured at 450 nm. As mentioned above, fluorescent intensity is measured in RFU (relative fluorescent units). In order to exclude the effect of the fluorometer, a photochemically fluorescent stable standard was used as a reference. All the fluorescence values reported are relative to the fluorescence values of the standard measured before each experiment. The standard used was USFS-205-020 from Labsphere (NH, USA).

[0078] Coat weight of printed compositions was evaluated gravimetrically. 10, 15 and 20 layers of the tested transparent composition were printed. The ink layers were peeled from the substrate after printing and their mass and area were determined after drying overnight in a vacuum oven at room temperature. For complete removal of the printed composition the test composition was printed on a special substrate, DIGIPRINT-IG/WOSK from Folex. In addition, two layers of HP Indigo Yellow ElectroInk® were printed prior to the transparent test composition. The coat weight of the yellow ink was determined separately and was subtracted from the coat weight of the tested transparent composition. Coat weight of a single printed layer of the printed composition was calculated by dividing the coat weight by the number of layers printed. Coat weights of a single layer calculated from the 10, 15 and 20 layers were identical.

Example 1

[0079] 58.5 g of polymer resin (DuPont's Nucrel® 699 and Honeywell's A-C 5120 resins in a ratio of 4:1; swollen with Isopar™ L, from ExxonMobil; 40% solids), 12 g. fluorescent adjuvant (maltose monohydrate, from Sigma Aldrich) 1.8 g charge adjuvant (aluminum stearate, from Sigma Aldrich), and 4 g of optical brightening agent (Megawhite DT, from Meghmani Dyes and Intermediates Ltd. India) and 124.9 g of Isopar™ L were grinded for 24 h at 25° C. using a laboratory 01HD attritor from Union Process (USA). After grinding, the fluorescent concentrate was diluted with the carrier liquid (Isopar™ L) to level of 5% solids to give fluorescent concentrate 1. 62 g of the concentrate 1 and 93 g of carrier liquid (Isopar™ L) were added to an ink tank of an HP Indigo 7000 press, containing 1400 g of a 2% solid dispersion of HP Indigo Electroink Transparent®. After 5 min. of mixing, the ink was printed at a print speed of 2 m/sec and a blanket temperature of 100° C. As mentioned above the transparent composition containing the optical brightening agent was printed on top of 4 layers of cyan ElectroInk® to eliminate fluorescence from the paper substrate.

[0080] The fluorescence was calculated according to equation 1, in which “ink” refers to the printed composition and “background” refers to the test substrate:

[00001]$\begin{array}{cc}\mathrm{Reported}.Math..Math.\mathrm{fluorescence}.Math..Math..Math.\mathrm{Intensity}.Math.\left[\%\right]=\frac{\left(\mathrm{Fluorescence}.Math..Math.\mathrm{ink}-\mathrm{Fluorescence}.Math..Math.\mathrm{background}\right)}{\mathrm{Fluorescence}.Math..Math.\mathrm{Labsphere}.Math..Math.\mathrm{reference}}*100& \mathrm{Equation}.Math..Math.1\end{array}$

[0081] For coat weight determination, 10, 15 and 20 layers of the tested ink were printed and peeled of the substrate. The mass and the area were determined and the coat weight of a single layer was calculated as described above. The resultant calibration curve is presented in FIG. 1.

[0082] Validation of the calibration curve was performed by preparation of a different batch of HP Indigo Transparent ElectroInk® containing concentrate 1 as described in this example. The tested ink was printed and the coat weight of 1 layer of ink was compared to the coat weight obtained from the fluorescence measurements using the calibration curve. Coat weight determined gravimetrically was 0.68 gsm, while the coat weight calculated from fluorescence measurements was 0.70 gsm

Example 2

[0083] Concentrate 2 was prepared using a 1-S attritor. 672.75 grams of Nucrel® 699 paste from DuPont (40% solids), 138 g fluorescent adjuvant (sucrose, from Sigma Aldrich), 6.9 g charge adjuvant (aluminum stearate, from Sigma Aldrich), 46 g of optical brightening agent (Megawhite DT, from Meghmani Dyes and Intermediates Ltd. India) and 127.9 g of Isopar™ L (ExxonMobil) were grinded for 24 h at 25° C. The ink was diluted to 5% by the carrier liquid.

[0084] A test ink was prepared, by grinding 1076 grams of polymer resin (Nucrel® 699 from DuPont and A-C 5120 from Honeywell in a ratio of 4:1; swollen with Isopar™ L; 25% solids), 184 g maltose monohydrate (from Sigma Aldrich) 6.9 g aluminum stearate (from Sigma Aldrich) and 1032 g of Isopar™ L for 24 h at 25° C. using an 1-S attritor from Union Process (USA). The ink was diluted to 2% solids by the carrier liquid. 62 g of concentrate 2 (5% solids) and 93 g of Isopar™ L were added to 1400 g of 2% solids dispersion of the ink.

[0085] The ink was printed on an HP Indigo 7000 press after 5 min. of mixing, at a print speed of 2 m/sec and a blanket temperature of 100° C. As mentioned above the transparent composition containing the optical brightening agents was printed on top of 4 layers of HP Indigo ElectroInk Cyan® to eliminate fluorescence from the paper substrate. The fluorescence was calculated according to equation 1. For coat weight determination, 10, 15 and 20 layers of the tested ink were printed and peeled of the substrate. The mass and the area were determined and the coat weight of a single layer was calculated as described above. The resultant calibration curve is found in FIG. 2.

[0086] Validation of the calibration curve was performed by preparation of a different R&D transparent LEP ink containing concentrate 2 as described in this example. The tested ink was printed and the coat weight of 1 layer of ink was compared to the coat weight obtained from the fluorescence measurements using the calibration curve. Coat weight determined gravimetrically was 0.91 gsm, while the coat weight calculated from fluorescence measurement was 0.92 gsm.

Example 3

[0087] 53.5 g of Nucrel® 699 (40% solids, from DuPont), 12 g of maltose monohydrate (from Sigma Aldrich), 6 gr of Megawhite DT (from Meghmani Dyes and Intermediates Ltd. India), 0.6 g of aluminum stearate (Sigma Aldrich) and 127.9 gr of Isopar™ L (ExxonMobil) were grinded for 24 h at 25° C. using a laboratory 01HD attritor from Union Process (USA). After grinding, the mixture was diluted with the carrier liquid (Isopar™ L) to a level of 5% solids to give fluorescent concentrate 3. 40 g of the concentrate 3 and 60 g of carrier liquid were added to an HP Indigo 7000 Press ink tank containing 1400 g of a 2% solid dispersion of HP Indigo ElectroInk Transparent® After 5 min. of mixing, the composition was printed at a print speed of 2 m/sec and a blanket temperature of 100° C. As mentioned above, the transparent composition containing the optical brightening agent was printed on top of 4 layers of cyan ElectroInk® to eliminate fluorescence from the paper substrate. The fluorescence was calculated according to equation 1. For coat weight measurement, 10, 15 and 20 layers of the tested composition were printed and peeled from the substrate. The mass and the area were determined and the coat weight of a single layer was calculated as described above. The resultant calibration curve is found in FIG. 3.

[0088] Validation of the calibration curve was performed by preparation of a different batch of HP Indigo ElectroInk® containing concentrate 3 as described in this example. The tested composition was printed and the coat weight of 3 layers was compared to the coat weight obtained from the fluorescence measurements using the calibration curve. Coat weight determined gravimetrically was 1.05 gsm, while the coat weight calculated from fluorescence measurement was 1.10 gsm.

[0089] While the present disclosure has been described with reference to certain embodiments, those skilled in the art will appreciate that various modifications, changes, omissions, and substitutions can be made without departing from the spirit of the disclosure. It is intended, therefore, that the disclosure be limited only by the scope of the following claims. The features of any dependent claim can be combined with the features of any of the other dependent claims, and any independent claim.