FUEL CELL MATRIX COMPOSITION AND METHOD OF MANUFACTURING SAME

Abstract

A composition for use in forming a fuel cell matrix includes a support material, an electrolyte material, and an additive material that includes a plurality of flakes having an average length in a range of 5 to 40 micrometers and an average thickness of less than 1 micrometer.

Claims

1. A composition for use in forming a fuel cell matrix, the composition comprising: a support material, an electrolyte material, and an additive material comprising a plurality of flakes having an average length in a range of 5 μm to 40 μm and an average thickness of less than 1 μm.

2. The composition in accordance with claim 1, wherein the flakes of the additive material have an average Brunauer-Emmett-Teller (BET) surface area from 1 m.sup.2/g to 6 m.sup.2/g.

3. The composition in accordance with claim 1, wherein the flakes of the additive material are made of a metal.

4. The composition in accordance with claim 3, wherein the flakes of the additive material are made of aluminum.

5. The composition in accordance with claim 4, wherein an amount of the additive material in the composition is between 3 volume percent and 35 volume percent.

6. The composition in accordance with claim 1, wherein: the support material comprises lithium aluminum oxide; the flakes of the additive material are made of aluminum; and the electrolyte material comprises one or more of carbonate electrolyte and carbonate electrolyte precursor.

7. The composition in accordance with claim 1, wherein the flakes of the additive material have a leafing value of 70 to 100%.

8. The composition in accordance with claim 1, wherein the plurality of flakes have an average length in a range of 12 μm to 20 μm.

9. The composition in accordance with claim 1, wherein the plurality of flakes have an average length in a range of 15 μm to 18 μm.

10. The composition in accordance with claim 1, wherein the plurality of flakes have an average thickness of less than 0.5 μm.

11. The composition in accordance with claim 1, wherein the plurality of flakes have an average thickness in a range of 0.1 μm to 0.3 μm.

12. The composition in accordance with claim 1, wherein the flakes are coated with an acidic compound adapted to prevent re-agglomeration.

13. The composition in accordance with claim 12, wherein the acidic compound is stearic acid.

14. The composition in accordance with claim 1, further comprising a binder and a plasticizer.

15. A green tape cast element formed by tape casting the composition of claim 1.

16. A conditioned fuel cell matrix formed by conditioning the green tape cast element of claim 15 such that the additive material reacts with the electrolyte material.

17. The conditioned fuel cell matrix of claim 16, wherein the conditioning is performed by heating the green tape cast element at a temperature of at least 500° C. for at least two hours.

18. The conditioned fuel cell matrix of claim 16, wherein the conditioning is performed by heating the green tape cast element at a temperature in range of 500 to 650° C. for a time in a range of 2 to 150 hours.

19. The conditioned fuel cell matrix of claim 16, wherein the conditioned fuel cell matrix has a snap strength of at least 657 PSI.

20. A fuel cell system comprising one or more fuel cells, each of the fuel cells including an anode electrode, a cathode electrode and a conditioned fuel cell matrix in accordance with claim 16.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0012] The above and other features and aspects of the present invention will become more apparent upon reading the following detailed description in conjunction with the accompanying drawings in which:

[0013] FIGS. 1-2 show Scanning Electron Microscope (SEM) images of examples of large pores and large core shell structures from a conventional electrolyte matrix;

[0014] FIG. 3 shows a schematic structure of a molten carbonate fuel cell including an electrolyte matrix;

[0015] FIG. 4 shows a flow diagram of a method for making a fuel cell matrix for use in manufacturing the molten carbonate fuel cell;

[0016] FIG. 5 shows a flow diagram of another method for making a fuel cell matrix for use in manufacturing of the molten carbonate fuel cell;

[0017] FIG. 6 shows an SEM image of aluminum particles used to manufacture a conventional fuel cell matrix;

[0018] FIG. 7 shows an SEM image of aluminum flakes used to manufacture a fuel cell matrix according to the methods described herein;

[0019] FIGS. 8-9 show SEM images of burnout fuel cell matrix samples made using conventional aluminum particles;

[0020] FIGS. 10-11 show SEM images of burnout fuel cell matrix samples made using aluminum flakes;

[0021] FIG. 12 shows a graph comparing average snap strengths of two aluminum flake fuel cell matrix samples made according to the methods described herein to a fuel cell matrix made using conventional aluminum particles;

[0022] FIG. 13 shows a graph comparing a ratio of conventional matrix resistance to aluminum flake matrix resistance versus relative service life of the fuel cell matrix made according to the methods described herein and of the conventional fuel cell matrix made of conventional aluminum particles; and

[0023] FIG. 14 shows a graph comparing pore diameter versus log differential intrusion of a fuel cell matrix made according to methods described herein and of a conventional fuel cell matrix.

DETAILED DESCRIPTION

[0024] FIG. 3 schematically shows a Molten Carbonate Fuel Cell (“MCFC”) 1 including an electrolyte matrix 2 (hereinafter, “fuel cell matrix” or “matrix”) of the present invention. The fuel cell 1 also includes an anode 3 and a cathode 4 which are separated from one another by the matrix 2. Fuel gas is fed to the anode 3 and oxidant gas is fed to the cathode 4. In the fuel cell 1, fuel gas and oxidant gas undergo an electrochemical reaction in the presence of a carbonate electrolyte present in the pores of the electrolyte matrix 2. In typical fuel cell assemblies, individual fuel cells 1 are stacked to form a stack and are connected in series so as to produce sufficient amount of power.

[0025] In accord with the present invention, the matrix 2 comprises, and is formed from, a support material, such as lithium aluminum oxide (LiAlO.sub.2), electrolyte material such as a carbonate electrolyte or a carbonate electrolyte precursor, and a metal additive material such as aluminum. The metal additive material has flake form such that an average particle size or length of the additive material flakes ranges from 5 μm and 40 μm, and is preferably 12-20 μm, and the an average thickness of the flakes is less than 1 μm, and preferably less than 0.5 μm in order to avoid formation of large voids or pores when the aluminum reacts with the electrolyte. The thickness of the additive material flakes is a key parameter in order to prevent or eliminate large pores formed after the additive material reacts with the electrolyte material during conditioning or operation of the fuel cell. Thinner additive material flakes with a thickness of 0.1 μm to 0.3 μm are desired to effectively eliminate the formation of undesired large pores. The amount of the metal additive material in the matrix is between 3 vol % and 35 vol %. For optimal pore structure, the average BET surface area of the additive material is between 1 m.sup.2/g and 6 m.sup.2/g. When forming the matrix from the support material, electrolyte material and additive material, the additive material flakes may have a coating thereon, such as a stearic acid coating, in order to prevent re-agglomeration of the flakes and to eliminate any handling concerns.

[0026] Although LiAlO.sub.2 can be used as the support material in the matrix, other stable support materials in the molten carbonate electrolyte may be used in the support material. The electrolyte material comprises carbonate electrolyte, including one or more of Li.sub.2CO.sub.3, Na.sub.2CO.sub.3 and K.sub.2CO.sub.3. Alkaline precursors that form carbonate materials during conditioning and/or operation of the fuel cell may also be used as the electrolyte materials in the matrix. The metal additive material can be an aluminum flake material. It is understood that other materials may be suitable for use in the fuel cell matrix 2 of the fuel cell 1.

[0027] FIG. 4 shows a flow diagram of a method for making a fuel cell matrix for use in the molten carbonate fuel cell 1. As shown in FIG. 4, in a first step S401, a first predetermined amount of a support material is provided and in a second step S402, a second predetermined amount of an electrolyte material is provided. As mentioned herein, LiAlO.sub.2, including γ-LiAlO.sub.2, and α-LiAlO.sub.2, is suitable for use as the support material. Suitable electrolyte materials in this illustrative embodiment include lithium carbonate, potassium carbonate and sodium carbonate, and more specifically, eutectic or off-eutectic mixtures of these carbonate materials. As mentioned herein above, precursor materials that form carbonate electrolyte may be used as the electrolyte material. The second predetermined amount of the electrolyte material is relative to the first predetermined amount of the support material. In particular, the second predetermined amount of the electrolyte material, provided in step S402, is between 5 and 100 volume percent of the first predetermined volume amount of the support material. The support material and/or the electrolyte material may be pre-milled to achieve a desired particle size. Suitable particle size of the support material is from 0.005 μm to 0.5 μm and suitable particle size of the electrolyte material is from 0.01 μm to 0.5 μm.

[0028] In a third step S403, the support material provided in step S401 and the electrolyte material provided in step S402 are processed to form a first mixture by milling or mixing these materials in an appropriate solvent. The solvent may comprise a predetermined percentage of fish oil or other oil to prevent re-agglomeration of particles. Processing continues for a predetermined amount of time until a desired size is achieved. Conventional methods, such as dry blending in a blender, may be employed in the third step S403.

[0029] In a fourth step S404, a third predetermined amount of the metal additive material is added to the processed first mixture to form a second mixture. In particular, the third predetermined amount of the metal additive material comprises from about 3 volume percent to 35 volume percent of the fuel cell matrix, and according to some embodiments, from 10 volume percent to 25 volume percent (or 6-12 wt %). As discussed above, the metal additive is in a flake form with an average length of from 5 μm to 40 μm, and in some illustrative embodiments having an average length of 12 μm to 20 μm, and in further illustrative embodiments, having an average length from 15 μm to 18 μm. As discussed above, the metal additive material flakes have an average thickness of less than 1 μm, and in some embodiments, less than 0.5 μm, and in further embodiments from 0.1 μm to 0.3 μm. The metal additive material may comprise an average Brunauer-Emmett-Teller (BET) surface area of from 1 m.sup.2/g to 6 m.sup.2/g. Further, the metal additive may comprise a leafing value of from 70 to 100%.

[0030] Using the metal additive material flakes with the above described characteristics mitigates formation of large pores and large core shell structures in the fuel cell matrix after the additive material reacts with the electrolyte precursor material, and provides an optimal pore structure, enhancing strength of the fuel cell matrix and improving life resistance stability by over 40 percent.

[0031] According to an illustrative embodiment, the metal additive comprises a coating of an acidic compound that prevents re-agglomeration. In particular, the acidic compound comprises stearic acid or another acid suitable for such use.

[0032] In a fifth step S405, a fourth predetermined amount of at least one of a binder and a plasticizer are added to the second mixture to form a third mixture. The binder may be an acryloid binder and the plasticizer may be a Santicizer® 160 plasticizer. Other suitable materials may be used in the third mixture to form the desired consistency of the mixture.

[0033] In a sixth step S406, the third mixture is tape casted to form the fuel cell matrix. The tape casted fuel cell matrix is dried at a predetermined temperature for a predetermined amount of time, after which sheets of the fuel cell matrix are ready for use. Although tape casting is used to form the fuel cell matrix, other suitable methods may be used instead of tape casting.

[0034] In some illustrative embodiments, the metal additive material is processed ex-situ in step S407, which occurs prior to the fourth step S404, i.e., prior to adding the additive material to the first mixture. The metal additive material is processed, i.e., milled, for a predetermined amount of time to achieve desired flake dimensions using grinding media of a predetermined size at a predetermined speed. In some embodiments, the metal additive material is milled using YTZ® grinding media or other suitable grinding media having a ball size of 0.3 mm to 0.6 mm at the predetermined speed is from 2,000 Revolutions Per Minute (RPM) to 3,000 RPM, for the predetermined amount of time of 120 minutes to 300 minutes. The processed metal additive material flake has an average length from 5 μm to 40 μm with an average thickness from 0.1 μm to 1.0 μm.

[0035] FIG. 5 shows a flow diagram of another method for making a fuel cell matrix for use in the molten carbonate fuel cell 1. As shown in FIG. 5, in a first step S501, a first predetermined amount of a support material is provided and in a second step S502, a second predetermined amount of an electrolyte material is provided. Suitable support materials and electrolyte materials are described herein above. As in the method of FIG. 4, the second predetermined amount of the electrolyte material is relative to the first predetermined amount of the support material. In particular, the second predetermined amount of the electrolyte material, provided in step S502, is between 5 and 100 volume percent of the first predetermined volume amount of the support material. The support material and the electrolyte material may be pre-milled to achieve a desired particle size.

[0036] In a third step S503, the support material provided in step S501 and the electrolyte material provided in step S502 are processed to form a first mixture by milling or mixing in an appropriate solvent. The solvent may comprise a predetermined amount of fish oil or other oil to prevent re-agglomeration of particles. Processing continues for a predetermined amount of time until a desired size is achieved. The processing in step S503 is similar to the processing performed in step S403 in the method of FIG. 4 described above. Moreover, other mixing or milling methods, such as dry blending in a blender, may be employed in the third step S503.

[0037] In a fourth step S504, a third predetermined amount of a metal additive particulate material is added to the processed first mixture to form a second mixture. In particular, the third predetermined amount of the metal additive particulate material is from about 5 volume percent to 35 volume percent of the fuel cell matrix. The metal additive particulate material is in the form of rounded particles and has an average particle size of 5 to 7 μm.

[0038] In a fifth step S505, the second mixture is in-situ processed until the metal additive particles exhibit properties of a flake, i.e., the metal additive particulate material is physically converted to the metal additive material having the above-described flake form. In particular, the second mixture is processed by milling or blending to flatten the metal additive particles into flakes. The second mixture is processed, i.e., milled, for a predetermined amount of time to achieve desired flake dimensions of the metal additive material using grinding media of a predetermined size at a predetermined speed. In some illustrative embodiments, the predetermined amount of time is 120 minutes to 300 minutes, the predetermined size of the grinding media, e.g. YTZ® grinding media, is from 0.3 mm to 0.6 mm and the predetermined speed is from 2,000 RPM to 3,000 RPM. The processed metal additive material has a flake size with an average length of from 5 μm to 40 μm and an average thickness from 0.1 μm to 1.0 μm.

[0039] In a sixth step S506, a fourth predetermined amount of at least one of a binder and a plasticizer is added to the second mixture to form a third mixture. The binder and/or plasticizer are the same or similar to those used in the method of FIG. 4. Moreover, other suitable materials may be used to achieve a desired consistency of the mixture.

[0040] In a seventh step S507, the third mixture is tape cast to form the fuel cell matrix. The tape casted fuel cell matrix is dried at a predetermined temperature for a predetermined amount of time, after which sheets of the fuel cell matrix are ready for use. As mentioned above, other suitable methods may be used for forming the fuel cell matrix from the third mixture.

[0041] The optimal components and amounts of those components used to manufacture the fuel cell matrix using the above-described methods are dependent on the particular application and requirements of the molten carbonate fuel cell. Illustrative examples of methods of making the fuel cell matrix and compositions made from the methods are described herein below.

Example 1

[0042] In this illustrative example, the method shown in FIG. 4, and described above, is used to prepare the fuel cell matrix.

[0043] In the first step S401, a first predetermined amount of the support material is provided and in the second step S402, a second predetermined amount of the electrolyte material is provided. In this illustrative example, the support material comprises LiAlO.sub.2 and the electrolyte material comprises Li.sub.2CO.sub.3. The first predetermined amount of LiAlO.sub.2 is 150 grams (g), and the second predetermined amount of Li.sub.2CO.sub.3 is 69.3 g.

[0044] In the third step S403, the support material and the electrolyte precursor material are combined with a solvent, such as Methyl-Ethyl-Ketone (MEK), to form a first mixture. In particular, the solvent includes from 1 volume percent to 6 volume percent fish oil, which prevents re-agglomeration of particles in the mixture. In this illustrative example, the first mixture is processed according an attrition milling technique using Yttria-stabilized Zirconia (YTZ) grinding media having a ball size of from 0.3 mm to 3 mm. Grinding media loading is from 60 percent to 80 percent and grinding speed is from 2,000 RPM to 3,000 RPM.

[0045] After processing the first mixture to an appropriate size, in the fourth step S404, a third predetermined amount of a metal additive material having a flake form is added to the processed first mixture to form a second mixture. In particular, the metal additive material comprises an aluminum additive, such as Compound (A) or Compound (B), and the third predetermined amount is approximately from about 3 volume percent to 35 volume percent. In this illustrative example, the third predetermined amount is between about 3 volume percent and 5 volume percent (5 weight percent to 8 weight percent), of total mixture including the support material, the electrolyte material and the metal additive material. In this example, the aluminum additive material comprises aluminum flakes having the form described above.

[0046] In this illustrative example, the aluminum additive material is formed from one of Compounds (A) and (B) indicated in Tables 1 and 2, respectively:

TABLE-US-00001 TABLE 1 Compound (A) PROPERTIES VALUE UNIT Particle Size Distribution D 50 (approx.) 16 μm Passing 45 μm 99 % Non-Volatile Content 75.8 % Volatile Content 24.2 % Spatula Leafing (Leafing Value) 65-100 %

TABLE-US-00002 TABLE 2 Compound (B) PROPERTIES VALUE UNIT Particle Size Distribution D 50 (approx.) 17.5 μm Passing 45 μm 98.5-100 % Leafing Value   70-100 %

[0047] In the fifth step S405, a fourth predetermined amount of at least one of a binder and a plasticizer are added to the second mixture to form a third mixture. In particular, the binder and the plasticizer may comprise an acryloid binder and a polar polymer plasticizer, such as Sancticizer® 160, respectively. In this illustrative example, the fourth predetermined amount comprises about 19 to 20 weight percent of the total weight of the fuel cell matrix.

[0048] In the sixth step S406, forming the fuel cell matrix comprises tape casting the third mixture and drying the cast third mixture at a predetermined temperature, such as 60° C., for a predetermined amount of time, such as from 20 to 40 minutes. After drying, the fuel cell matrix, in the form of a green tape element, is ready for use and testing.

[0049] FIG. 6 shows an SEM image of aluminum particles used to manufacture a conventional fuel cell matrix. In particular, FIG. 6 shows that the aluminum particles form large pores and large core shell structures.

[0050] FIG. 7 shows an SEM image of aluminum flakes used to manufacture a fuel cell matrix according to the methods described herein. In particular, the aluminum flakes in FIG. 7 have an average length of 5 μm to 40 μm, and in some embodiments an average length of 12 μm to 20 μm, and in further embodiments, an average length of 15 μm to 18 μm; and an average thickness of the flakes is less than 1 μm, and in some embodiments, less than 0.5 μm, and in further embodiments between 0.1 μm and 0.3 μm. Additional properties of the aluminum flakes comprise an average BET surface area from 1 m.sup.2/g to 6 m.sup.2/g; and a leafing value of from 70 percent to 100 percent (%).

[0051] FIGS. 8-9 show SEM images of burnout fuel cell matrix samples made using conventional aluminum particles. FIGS. 10-11 illustrate SEM images of burnout fuel cell matrix samples made using aluminum flakes. Extended burnout tests were performed on the fuel cell matrix samples at 650° C. for 150 hours to compare a conventional fuel cell matrix made using conventional aluminum particles and the fuel cell matrix made according to the methods described herein. FIGS. 8-9 show that the fuel cell matrix samples made with conventional aluminum particles exhibit large pores and large core shell structures. FIGS. 10-11 show that the fuel cell matrix samples made with aluminum flakes exhibit a reduction of the length and a reduction or elimination of large pores and large core shell structures.

[0052] FIG. 12 shows a graph comparing average snap strength of two aluminum flake fuel cell matrix samples made according to the methods described herein to the average snap strength of a fuel cell matrix made using conventional aluminum particles. Samples were prepared for snap strength testing by heating the fuel cell matrix samples at approximately 500° C. for 2 hours. Average snap strength data presented in FIG. 12 were determined using three-point bending testing. As shown in FIG. 12, fuel cell matrix samples made with aluminum flakes using the methods of the present invention exhibited a snap strength of 667 Pounds per Square Inch (PSI) and 657 PSI, while a conventional fuel cell matrix made with conventional aluminum particles exhibited a snap strength of 470 PSI. This improvement in snap strength is due to the reduction and/or elimination of large pores and large core shell structures in the fuel cell matrix.

Molten Carbonate Fuel Cell Test:

[0053] A bench-scale MCFC was prepared as described above and tested to determine performance and stability of the fuel cell matrix made according to the methods described herein compared to a conventional fuel cell matrix. The MCFC assembly tested comprised an anode, such as a nickel-aluminum anode, a nickel-chromium anode and/or a nickel-aluminum chromium anode, and a cathode, such as a porous in-situ oxidized and lithiated nickel-oxide cathode. The anode and the cathode were separated by a porous ceramic fuel cell matrix, which, in separate tests, was a conventional fuel cell matrix and a fuel cell matrix made according to the methods described herein. The cathode was filled with an appropriate amount of Li.sub.2CO.sub.3/K.sub.2CO.sub.3 or Li.sub.2CO.sub.3/Na.sub.2CO.sub.3 electrolyte and an appropriate amount of Li.sub.2CO.sub.3/K.sub.2CO.sub.3 or Li.sub.2CO.sub.3/Na.sub.2CO.sub.3 electrolyte was also stored in a cathode current collector to ensure electrolyte balance.

[0054] During testing, anode gas comprised a composition of 72.8 percent H.sub.2, 18.2 percent CO.sub.2, and 9 percent H.sub.2O, and cathode gas comprised a composition of 18.5 percent CO.sub.2, 12.1 percent O.sub.2, 66.4 percent N.sub.2, and 3 percent H.sub.2O. Tests were performed under accelerated conditions with operating temperatures of 665° C., fuel utilization of 80 percent and steam content of 20 percent. Tests were performed at 160 mA/cm.sup.2 and 80 percent utilization in the anode and cathode. Cell resistance, voltage and gas cross-over stability were monitored to evaluate performance and stability of each fuel cell matrix.

[0055] FIG. 13 shows a graph comparing resistance stability of a conventional matrix (line (A)) to resistance stability of the fuel cell matrix with aluminum flake additive material in accordance with the present invention (line (B)). In FIG. 13, the X-axis represents the relative service life (in relative units of time of the fuel cell matrix while the Y-axis represents the resistance stability (in relative units) of the matrix. As can be seen in FIG. 13, the fuel cell matrix made with aluminum flakes in accord with the invention demonstrates greater than 40 percent improved resistance stability when compared with the resistance stability of the conventional fuel cell matrix. The improvement is due to fewer large pores in the fuel cell matrix of the present invention and its more stable pore structure. Aluminum flakes utilized as the additive material in the methods described herein reduce formation of large pores and large core shell structures in the resulting fuel cell matrices, maintaining stable capillary force and electrolyte retention.

[0056] FIG. 14 shows a graph comparing pore diameter (μm) versus log differential intrusion (mL/g) of a fuel cell matrix made according to methods described herein (line (A)) and a conventional fuel cell matrix (line (B)) at the end of life. The testing of the matrix samples was conducted under conditions of 160 mA/cm.sup.2 current density and 75 percent fuel utilization. FIG. 14 shows that the fuel matrix made according to methods described herein demonstrates fewer large pores and fewer large core shell structures than the conventional fuel cell matrix, providing a greater than 40 percent reduction in large pores, confirming the improvement of the fuel cell matrix made according to the methods described herein using aluminum flakes over the conventional fuel cell matrix.

Example 2

[0057] In this illustrative example, the method shown in FIG. 5, and described above, is used to prepare the fuel cell matrix.

[0058] In the first step S501, a first predetermined amount of the support material is provided and in the second step S502, a second predetermined amount of the electrolyte material is provided. In this illustrative example, the support material comprises LiAlO.sub.2 and the electrolyte material comprises Li.sub.2CO.sub.3. The first predetermined amount of the support material is 150 g, and the second predetermined amount of electrolyte material is 69.3 g. In the third step S503, the support material and the electrolyte material are combined with a solvent, such as MEK, to form a first mixture. In particular, the solvent includes from 1 volume percent to 6 percent by volume of fish oil, which prevents re-agglomeration of particles. In this illustrative example, the first mixture is processed using an attrition milling technique using Yttria-stabilized Zirconia (YTZ) grinding media having a ball size of from 0.3 mm to 3 mm. Grinding media loading is from 60 percent to 80 percent and grinding speed is from 2,000 RPM to 3,000 RPM.

[0059] After processing the first mixture to an appropriate size, in the fourth step S504, a third predetermined amount of a metal additive particulate material is added to the processed first mixture to form a second mixture. In particular, the metal additive particulate material comprises an aluminum particulate material, such as Al-100 rounded aluminum powder (Compound (C)), having generally rounded aluminum particles, and the third predetermined amount is approximately from about 3 volume percent to 35 volume percent of the total second mixture, and in some embodiments the third predetermined amount is 10 volume percent to 25 volume percent (6 weight percent to 12 weight percent) of the second mixture that includes the support material, the electrolyte material and the metal additive particulate material.

[0060] In this illustrative example, the aluminum particulate additive comprises Compound (C) having properties shown in Table 3:

TABLE-US-00003 TABLE 3 Compound (C) Properties Value Unit Particle size 1-5 μm Purity 99.9 %

[0061] In the fifth step S505, the second mixture is in-situ processed until the metal additive particulate material is converted to the metal additive material comprising aluminum flakes. The second mixture is processed by milling or blending to flatten the metal additive particles in the metal additive particulate material into flakes. The metal additive is processed, i.e., milled, for a predetermined amount of time to achieve the desired flake dimensions using grinding media of a predetermined size at a predetermined speed. In this illustrative example, the predetermined amount of time comprises 120 minutes to 300 minutes. The predetermined size of the grinding media comprises from 0.3 mm to 0.6 mm and the predetermined speed is from 2,000 RPM to 3,000 RPM. The processed metal additive comprises flakes having an average length from 5 μm to 40 μm with an average thickness from 0.1 μm to 1.0 μm.

[0062] In the sixth step S506, a fourth predetermined amount of at least one of a binder and a plasticizer are added to the second mixture to form a third mixture. In particular, the binder and the plasticizer may comprise an acryloid binder and a polar polymer plasticizer, such as Sancticizer® 160 respectively. In this illustrative example, the fourth predetermined amount is about 19 to 20 weight percent of the total weight of the fuel cell matrix.

[0063] In the seventh step S507, forming the fuel cell matrix comprises tape casting the third mixture and drying the cast third mixture at a predetermined temperature, such as 60° C., for a predetermined amount of time, such as from 20 to 40 minutes. After drying, the fuel cell matrix, in the form of a green tape element, is ready for use and testing.

[0064] In all cases it is understood that the above-described arrangements are merely illustrative of the many possible specific embodiments which represent applications of the present invention. Numerous and varied other arrangements can be readily devised in accordance with the principles of the present invention without departing from the spirit and the scope of the invention.