FAST CURING UV INKJET INKS BASED ON HYPER-BRANCHED POLYESTER ACRYLATES

Abstract

A fast-curing UV inkjet ink is based on hyperbranched polyester acrylates. The ink contains the following components: 1 wt % to 20 wt % of at least one hyperbranched polyester acrylate having a functionality in the range from 6 to 30, 1 wt % to 30 wt % of at least one reactive diluent, 1 wt % to 20 wt % of at least one free-radical photoinitiator of the Norrish I type, 30 wt % to 70 wt % of at least one multifunctional (meth)acrylate monomer, and 0 wt % to 30 wt % of at least one monofunctional (meth)acrylate monomer. The ink is particularly suited for inkjet printing and it is used in an inkjet printing process.

Claims

1. A UV curable ink, comprising: 1-20 wt % of at least one hyperbranched polyester acrylate having a functionality in a range from 6 to 30; 1-30 wt % of at least one reactive diluent selected from the group consisting of ethylene glycol divinyl ether, diethylene glycol divinyl ether, triethylene glycol divinyl ether, propylene glycol divinyl ether, n-butanediol divinyl ether, 1,4-cyclohexanedimethanol divinyl ether, 1,4-cyclohexanedimethanol divinyl ether and mixtures thereof; 1-20 wt % of at least one free-radical photoinitiator of the Norrish I type; 30-70 wt % of at least one multifunctional (meth)acrylate monomer; and 0 wt % to 30 wt % of at least one monofunctional (meth)acrylate monomer.

2. The ink according to claim 1, wherein the ink contains at least one hyper-branched polyester acrylate having a functionality in a range from 12 to 20.

3. The ink according to claim 1, wherein the reactive diluent is selected from the group consisting of N-vinylpyrrolidone, N-vinylcaprolactam, N-vinylformamide and vinyl ethers, such as ethyl vinyl ether, propyl vinyl ether, isopropyl vinyl ether, butyl vinyl ether, isobutyl vinyl ether, tert-butyl vinyl ether, amyl vinyl ether, 2-ethylhexyl vinyl ether, dodecyl vinyl ether, octadecyl vinyl ether, cyclohexyl vinyl ether, ethylene glycol monovinyl ether, ethylene glycol divinyl ether, diethylene glycol monovinyl ether, triethylene glycol monovinyl ether, tetraethylene glycol monovinyl ether, diethylene glycol divinyl ether, triethylene glycol divinyl ether, tetraethylene glycol divinyl ether, propylene glycol divinyl ether, polyethylene glycol divinyl ether, ethylene glycol butyl vinyl ether, triethylene glycol methyl vinyl ether, polyethylene glycol methyl vinyl ether, butanediol monovinyl ether, butanediol divinyl ether, hexanediol monovinyl ether, hexanediol divinyl ether, cyclohexanedimethanol monovinyl ether, cyclohexanedimethanol divinyl ether, trimethylolpropane trivinyl ether, aminopropyl vinyl ether, diethylaminoethyl vinyl ether and polytetrahydrofuran divinyl ether, vinyl esters, and vinylaromatics, 1,4-cyclohexanedimethanol divinyl ether and mixtures thereof.

4. The ink according to claim 3, wherein the vinyl esters are selected from the group consisting of vinyl acetate, vinyl propionate, vinyl stearate and vinyl laurate, and the vinylaromatics are selected from the group consisting of vinyltoluene, styrene, 2-butylstyrene, 4-butylstyrene and 4-decylstyrene.

5. The ink according to claim 1, wherein the multifunctional (meth)acrylate monomer is selected from the group consisting of pentaerythritol triacrylate, pentaerythritol tetraacrylate, pentaerythritol tetramethacrylate, dipentaerythritol hexaacrylate, 1,2-ethylene glycol diacrylate, 1,2-ethylene glycol dimethacrylate, diethylene glycol dimethacrylate, 1,4-butanediol dimethacrylate, triethylene glycol dimethacrylate, 1,6-hexanediol diacrylate, 1,6-hexanediol dimethacrylate, 1,12-dodecanol diacrylate, 1,12-dodecanol dimethacrylate, tris(2-hydroxyethyl) isocyanurate triacrylate, polyethylene glycol diacrylates and the acrylic esters of ethoxylated or propoxylated glycols and polyols, and mixtures thereof.

6. The ink according to claim 5, wherein the polyethylene glycol diacrylates are selected from the group consisting of tetraethylene glycol diacrylate, dipropylene glycol diacrylate, tripropylene glycol diacrylate, tripropylene glycol triacrylate, trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, glycerol propoxylate triacrylate, dipentaerythritol pentaacrylate, ethoxylated pentaerythritol tetraacrylate, propoxylated neopentylglycol diacrylate, neopentylglycol diacrylate, and bis(pentaerythritol) hexaacrylate, and the acrylic esters of ethoxylated or propoxylated glycols and polyols are selected from the group consisting of propoxylated neopentylglycol diacrylate, ethoxylated or propoxylated trimethylolpropane triacrylate and mixtures thereof.

7. The ink according to claim 1, wherein the at least one monofunctional (meth)acrylate monomer is selected from the group consisting of lauryl acrylate, lauryl methacrylate, isodecyl acrylate, isodecyl methacrylate, myristyl acrylate, octadecyl acrylate, behenyl acrylate, cyclohexanedimethanol diacrylate, isobornyl acrylate, isobornyl methacrylate, caprolactone acrylate, 2-phenoxyethyl acrylate, isooctyl acrylate, isooctyl methacrylate, butyl acrylate and mixtures thereof.

8. The ink according to claim 1, comprising the at least one hyperbranched polyester acrylate having a functionality in the range from 6 to 30 in an amount of 5 wt % to 10 wt %, the at least one reactive diluent in an amount of 5 wt % to 20 wt % and the at least one multifunctional (meth)acrylate monomer in an amount of 35 wt % to 60 wt %.

9. The ink according to claim 1, wherein the at least one monofunctional (meth)acrylate monomer is present in an amount of 5 wt % to 15 wt %.

10. The ink according to claim 1, wherein the photoinitiator is selected from the group consisting of 2-benzyl-2-dimethylamino-1-(4-morpholino-phenyl)butan-1-one, 2,4,6-trimethylbenzoyldiphenylphosphine oxide, 2-hydroxy-1-{4-[4-(2-hydroxy-2-methylpropionyl)benzyl]phenyl}-2-methylpropan-1-one, 1-hydroxycyclohexyl phenyl ketone, phenylbis-2,4,6-trimethylbenzoylphosphine oxide, 2-dimethylamino-2-(4-methylbenzyl)-1-(4-morpholin-4-ylphenyl)butan-1-one, 2-hydroxy-2-methyl-1-phenylpropan-1-one, 2-hydroxy-2-methylpropriophenone, 2,2-dimethoxy-2-phenylacetophenone, 2-methyl-1-[4-(methylothio)phenyl]-2-morpholinopropan-1-one, 2,2-dimethoxy-1,2-diphenylethan-1-one, methyl benzoylformate, 2-hydroxy-4′-hydroxyethoxy-2-methylpropiophenone, 2-hydroxy-4′-methoxy-2-(4-methoxyphenyl)acetophenone, 2,2-diethoxyacetophenone and 2,4,6-ethyl trimethylbenzoylphenylphosphinate or a mixture of two or more.

11. The ink according to claim 1, wherein the photoinitiator is present in an amount of 7 wt % to 17 wt %.

12. The ink according to claim 1, which further comprises at least one colorant.

13. The ink according to claim 12, wherein the colorant is present in an amount of 0.5 wt % to 15 wt %.

14. The ink according to claim 1, wherein the ink has a viscosity at 45° C. in a range from 5 mPas to 25 mPas.

15. The ink according to claim 14, wherein the viscosity at 45° C. lies in a range from 5 mPas to 15 mPas.

16. The ink according to claim 1, wherein the ink has a surface tension of between 15 mN/m an 40 mN/m at 25° C.

17. A process for inkjet printing, which comprises providing the ink according to claim 1 and printing with the ink.

Description

DETAILED DESCRIPTION OF AN EXEMPLARY EMBODIMENT

[0051] An embodiment of the invention will now be more particularly described by way of example:

[0052] An ink composition was prepared from the following constituents: [0053] 6 wt % of Irgacure® TPO (BASF SE) [0054] 6 wt % of Irgacure® 369 (BASF SE) [0055] 9 wt % of hyperbranched polyester acrylate (Sartomer CN2305) [0056] 10 wt % of lauryl acrylate (BASF LA1214) [0057] 10 wt % of triethylene glycol divinyl ether (BASF DVE-3) [0058] 42 wt % of DPGDA (Sartomer SR508®) [0059] 2 wt % of TMP(EO)3TA (Sartomer SR454®) [0060] 0.75 wt % of stabilizer (BASF Irgastab® UV25) [0061] 0.25 wt % of surface active substance (BYK UV-3505) [0062] 14 wt % of pigment dispersion (25% Pigment in PONPGDA; RJA Dispersions D3420-064)

[0063] The product was an ink having a viscosity of 10.6 m Pas at 45° C. The ink was printed onto plastics film/sheeting and paper labels and irradiated under light from an ultraviolet lamp of power 120 W/cm. The ink gave a print with good cure, adhesion and chemical resistance.