Disclosed herein is an in-situ process for the preparation of Metallic Organic Framework's (MOF's)polymer composites at room temperature, without requirement of pre-seeding o MOF's or substrate modification. Further, the invention provides MOF-polymer composites membranes, wherein MOF forms a layer substantially covering the porosity of the membrane.

According to example embodiments, a separation membrane includes a graphene on at least one surface of a polymer support. The graphene may include a plurality of grains defined by grain boundaries.

Embodiments include a method of making a metal organic framework membrane comprising contacting a substrate with a solution including a metal ion and contacting the substrate with a solution including an organic ligand, sufficient to form one or more layers of a metal organic framework on a substrate. Embodiments further include a defect-free metal organic framework membrane comprising MSiF.sub.6(pyz).sub.2, wherein M is a metal, wherein the thickness of the membrane is less than 1,000 m, and wherein the metal organic has a growth orientation along the [110] plane relative to a substrate.

Embodiments include a method of making a metal organic framework membrane comprising contacting a substrate with a solution including a metal ion and contacting the substrate with a solution including an organic ligand, sufficient to form one or more layers of a metal organic framework on a substrate. Embodiments further include a defect-free metal organic framework membrane comprising MSiF.sub.6(pyz).sub.2, wherein M is a metal, wherein the thickness of the membrane is less than 1,000 m, and wherein the metal organic has a growth orientation along the [110] plane relative to a substrate.

A separation apparatus 10 includes a pretreatment section 20 that subjects a target fluid containing an olefin compound to at least one or more of a treatment for reducing an acetylene-based compound, a treatment for reducing a sulfur compound, and a treatment for reducing a fine particle component. In the pretreatment section 20, one or more treatments selected from a hydrotreating and an adsorption treatment with an adsorbent may be performed as the treatment for reducing the acetylene-based compound, one or more treatments selected from a washing and absorption treatment, an adsorption treatment with an adsorbent, and a hydrodesulfurization treatment may be performed as the treatment for reducing the sulfur compound, and one or more treatments selected from a liquid absorption treatment, a collection treatment, or a filtration treatment with a filter may be performed as the treatment for reducing the fine particle component.

The invention relates to a composite or a composite membrane consisting of an ionomer and of an inorganic optionally functionalized phyllosilicate. The isomer can be: (a) a cation exchange polymer; (b) an anion exchange polymer; (c) a polymer containing both anion exchanger groupings as well as cation exchanger groupings on the polymer chain; or (d) a blend consisting of (a) and (b), whereby the mixture ratio can range from 100% (a) to 100% (b). The blend can be ionically and even covalently cross-linked. The inorganic constituents can be selected from the group consisting of phyllosilicates or tectosilicates.

The invention relates to a composite or a composite membrane consisting of an ionomer and of an inorganic optionally functionalized phyllosilicate. The isomer can be: (a) a cation exchange polymer; (b) an anion exchange polymer; (c) a polymer containing both anion exchanger groupings as well as cation exchanger groupings on the polymer chain; or (d) a blend consisting of (a) and (b), whereby the mixture ratio can range from 100% (a) to 100% (b). The blend can be ionically and even covalently cross-linked. The inorganic constituents can be selected from the group consisting of phyllosilicates or tectosilicates.

Described herein are facile, one-step initiated plasma enhanced chemical vapor deposition (iPECVD) methods of synthesizing hyper-thin (e.g., sub-100 nm) and flexible metal organic covalent network (MOCN) layers. As an example, the MOCN may be made from zinc tetraphenylporphyrin (ZnTPP) building units. When deposited on a membrane support, the MOCN layers demonstrate gas separation exceeding the upper bounds for multiple gas pairs while reducing the flux as compared to the support alone.

A hydrogen-selective membrane including a metal leaf applied to a substrate. A system and method for fabricating a hydrogen-selective membrane, including applying a metal leaf to a substrate, annealing the metal leaf, applying a hydrogen-permeable metal to the annealed metal leaf on the substrate, and annealing the hydrogen-permeable metal and the annealed metal leaf to give an alloy of the hydrogen-permeable metal and the metal leaf. A system and method for repairing a hydrogen-selective membrane having defects including applying a metal leaf to an external surface of membrane material of the hydrogen-selective membrane, annealing the metal leaf and metal of the membrane material to form an alloy of the metal leaf and the metal to repair the defects.

The invention relates to a method for producing a device for material exchange between two mediums, in which at least one mat of semipermeable hollow fibres (3) is wound onto a winding core (2), which has at least one core opening (2a) in its outer surface for a first in- or out-flowing medium, and the winding core (2) is arranged in an axially extending housing (1) having at least one housing opening (1a) for the first in- or out-flowing medium, and the axial end regions of the housing (1) are sealed by an adhesive (4) arranged around the hollow fibres (3), wherein at least one chamber region (5) surrounding the hollow fibres (3) is formed via the adhesion between the axial end regions (1b, 1c) of the housing (1) and between the winding core (2) and the housing (1), through which chamber region the first medium can flow via the core opening (2a) and the housing opening (1a), wherein the axial distance between the core opening (2a) and the housing opening (1a) is adjusted to a desired value of multiple possible values via the axial shifting of the winding core (2) relative to the hollow fibre winding (3) arranged around the winding core (2) and relative to the housing (1), and the hollow fibres (3) are adhered to the side of the housing (1) near to the housing opening (1a) in a region between the axial end surface of the housing and the housing opening (1a), and the hollow fibres (3) are adhered to the side of the housing (1) near to the core opening (2a) in a region between the axial end surface of the housing and the core opening (2a). The invention also relates to a number of multiple devices for material exchange between two mediums, wherein all devices comprise at least identical housings (1) and winding cores (2) that are identical at least in regions.