The present invention relates to a process for the production of a transition metal containing zeolite comprising expanding a layered silicate with a swelling agent and introducing the transition metal into the interlayer expanded silicate prior to calcination thereof for obtaining the transition metal containing zeolite. The present invention further relates to a zeolite containing transition metal nanoparticles as obtainable or obtained according to the inventive process, as well as to a zeolite containing nanoparticles per se. Finally the present invention relates to the use of a zeolite containing transition metal nanoparticles as obtainable or obtained according to the inventive process, as well as to the use of a zeolite containing nanoparticles per se.

There is provided an exhaust gas purification system that allows efficient purification of NOx present in exhaust gas emitted from an internal combustion engine. The exhaust gas purification system of the disclosure comprises a first exhaust gas purification device that purifies exhaust gas emitted from an internal combustion engine, wherein the atmosphere alternately switches between a reducing agent-excess atmosphere and an oxidizing agent-excess atmosphere with respect to the stoichiometric atmosphere, and a second exhaust gas purification device that further purifies the exhaust gas that has been purified by the first exhaust gas purification device, wherein the first exhaust gas purification device has a three-way catalyst, and the second exhaust gas purification device has an exhaust gas purifying catalyst that comprises an AMn.sub.2O.sub.4 spinel-type oxide support (A=Mg, Zn or Li) on which a precious metal is supported.

Disclosed is a preparation method of a nanometer metal oxide supported carrier based on anodic oxidation, comprising: Step 1: adding electrolyte to a reaction pool, and fixing the cathode and the anode oppositely, wherein the cathode is a metal plate that is identical to the nano-metal oxide, and the anode is a carrier metal material; Step 2: stirring the electrolyte at a constant speed, wherein the revolution speed is not lower than 500 rpm; Step 3: switching power on; setting the output voltage between 10 v and 50 v; and subjecting the metal plate of the anode to anodic oxidation reaction, wherein metal oxide nanotubes/nano particles are generated on the surface; under the action of stirring, the metal oxide nanotubes/nano particles on the anode surface are dissolved and shed off into the electrolyte; under the action of the electric field force, the dissolved and shed-off nano fragments migrate towards the cathode and are adhered to the surface of the cathode material, thereby forming a nano-metal oxide film. The film preparation method according to the disclosure offers advantages such as mild condition, simple instrumentation, easy operation, and low cost; the prepared film has a good load effect such that the metal oxide can hardly be shed off.

A catalytic system is provided which comprises a tubular reactor and at least one catalyst particle located within the tubular reactor. The catalyst particles have a particular geometric form which promotes heat transfer with the tubular reactor. Certain specific catalyst particles are also provided.

An absorbent composition having a bismuth material on a support containing at least one of a metal oxide, a metalloid oxide or an activated carbon and methods of making and using the same. The adsorbent composition is usful for adsorbing arsine from a fluid stream.

Catalyst for oxygen storage capacity applications that include a zinc doped manganese-iron spinel mixed oxide material. The zinc doped manganese-iron spinel mixed oxide material may be synthesized by a co-precipitation method using a precipitation agent such as sodium carbonate and exhibits a high oxygen storage capacity.

A method for producing a three-dimensional porous catalyst monolith of stacked catalyst fibers, comprising the following steps: a) Preparing a suspension paste in a liquid diluent of a reforming catalyst, and which suspension can furthermore comprise a binder material, all particles in the suspension having an average particle size in the range of from 0.5 to 500 μm, b) extruding the paste of step a) through one or more nozzles to form fibers, and depositing the extruded fibers to form a three-dimensional porous catalyst monolith precursor, c) drying the porous catalyst monolith precursor to remove the liquid diluent, d) calcining the porous catalyst monolith precursor to form the porous catalyst monolith.

A catalyst for production of carboxylic acid ester, containing: catalyst particles containing at least one element selected from the group consisting of nickel, cobalt, palladium, lead, platinum, ruthenium, gold, silver, and copper; and a support supporting the catalyst particles, wherein the catalyst for production of carboxylic acid ester has half-width Wa of pore distribution of 10 nm or less, the half-width Wa being calculated using BJH method from an adsorption isotherm obtained by nitrogen adsorption.

The present invention is generally directed to the production of low-carbon syngas from captured CO.sub.2 and renewable H.sub.2. The H.sub.2 is generated from water using an electrolyzer powered by renewable electricity, or from any other method of low-carbon H.sub.2 production. The improved catalysts use low-cost metals, they can be produced economically in commercial quantities, and they are chemically and physically stable up to 2,100° F. CO.sub.2 conversion is between 80% and 100% with CO selectivity of greater than 99%. The catalysts don't sinter or form coke when converting H.sub.2:CO.sub.2 mixtures to syngas in the operating ranges of 1,300-1,800° F., pressures of 75-450 psi, and space velocities of 2,000-100,000 hr.sup.−1. The catalysts are stable, exhibiting between 0 and 1% CO.sub.2 conversion decline per 1,000 hrs. The syngas can be used for the synthesis of low-carbon fuels and chemicals, or for the production of purified H.sub.2. The H.sub.2 can be used at the production site for the synthesis of low-carbon chemical products or compressed for transportation use.

A method for ammonia decomposition is disclosed. The method may comprise providing a catalyst comprising an zirconia support and a layer adjacent to the support. The layer comprises a tetragonal phase comprising zirconium, cerium, and oxygen, an oxide of at least one of an alkali metal and a rare earth metal, and an active metal. The method may comprise bringing the catalyst in contact with ammonia at a temperature of from about 400° C. to 700° C. to generate a reformate stream comprising hydrogen and nitrogen at an ammonia conversion efficiency of at least about 70%. The method may comprise directing the hydrogen to generate electricity. The method may comprise generating heat for a reformer comprising the catalyst by combustion of gases or by electricity generated from hydrogen.