The present invention relates to methods and catalysts for producing methylbenzyl alcohol from ethanol by catalytic conversion, and belongs to the field of chemical engineering and technology. The present invention develops a route of producing methylbenzyl alcohol starting from green and sustainable ethanol and provide corresponding catalysts used for the catalytic conversion route. This innovative reaction route has several advantages, such as, simple process, eco-friendly property, and easy separation of products, as compared with a traditional petroleum-based route. This present route has a reaction temperature of 150-450° C. and total selectivity of 72% for methylbenzyl alcohol, and has good industrial application prospect. The innovation of this patent comprises the catalysts synthesis and the reaction route.

The present subject matter relates to a composition for in-situ remediation of soil and aquifer comprising of a water miscible oil; a solvent (for dissolving the vegetable oil to form a solution); and a catalyst (selected from enzymes biocatalysts, particularly lipases, alkaline compounds, heat or combinations thereof). The present subject matter provides a process for the preparation of the composition and application of the same for surface remediation. Further, the present subject matter provides an in-situ alcoholysis remediation method to reduce contaminant concentrations in aquifer and soil by enabling the generation of both soluble and slowly fermenting electron donors required for the anaerobic remediation of organohalide compounds contaminating soils and groundwater. The method of remediation includes mixing an engineered water-soluble oil or water miscible oil with a solvent and adding a catalyst to groundwater to promote the formation of fatty acid alkyl esters, carboxylic acid salts and glycerol.

The invention discloses a phosphorus-doped tubular carbon nitride micro-nano material and application thereof in waste gas treatment. Melamine is partially hydrolyzed into cyanuric acid through a phosphorous acid-assisted hydrothermal method to form a melamine-cyanuric acid super molecular precursor; the center of the precursor starts to be pyrolyzed under heating calcination, and thus phosphorus-doped tubular carbon nitride is obtained; the phosphorus-doped tubular carbon nitride and sodium borohydride are mixed and subjected to low-temperature calcination in an inert gas atmosphere, and defect-modified phosphorus-doped tubular carbon nitride is obtained. The defect-modified phosphorus-doped tubular carbon nitride micro-nano material has a good photocatalytic effect on catalytic degradation of waste gas; besides, the production raw materials are abundant and easy to obtain, and the phosphorus-doped tubular carbon nitride micro-nano material is good in stability and recyclable and has application prospects in waste gas treatment.

The present invention provides a metal carbonitride comprising: i) a first metal, M.sup.1; and ii) a second metal, M.sup.2; wherein M.sup.1 is titanium, zirconium or hafnium; and M.sup.2 is vanadium, niobium, tantalum, chromium, molybdenum, tungsten, iron, ruthenium or osmium.

The present application relates to a cerium-tin-based composite oxide catalyst for catalyzing purification of a nitrogen oxide, a preparation method and an application thereof. The catalyst has the following chemical composition: a cerium-tin oxide and an M oxide, wherein the M is selected from any one of or a combination of at least two of P, Ti, Zr, V, Mn, Fe, Cu, Al, Si, Ni, Hf, Nb, Ta, Cr, Mo, W, or Re. According to the present application, a cerium-tin-based composite oxide catalyst having the characteristics such as high catalytic activity, high hydrothermal stability, excellent N.sub.2 generation selectivity, a wide operation temperature window, and adaptation to high space velocity reaction conditions is prepared by means of a non-toxic and harmless raw material and a simple method, and the present application is applicable to a device for catalyzing purification of a mobile source nitrogen oxide represented by diesel vehicle exhaust gas and a fixed source nitrogen oxide represented by flue gas from a coal-fired power plant.

A method of preparing catalyst particles (the “preparation method”) is disclosed. The preparation method comprises combining a Ru(0) complex and a carrier fluid to form a mixture and heating the mixture at an elevated temperature to nucleate the Ru(0) complex and give the catalyst particles in the carrier fluid. The preparation method optionally comprises isolating the catalyst particles from the carrier fluid. A method of preparing an organosilicon compound via dehydrogenative silylation with the catalyst particles (the “synthesis method”) is also disclosed. The synthesis method comprises reacting (A) an organohydridochlorosilane compound and (B) an alkene compound in the presence of (C) a catalyst, thereby preparing the organosilicon compound. The catalyst (C) of the synthesis method comprises the catalyst particles prepared by the preparation method.

The present invention relates to a catalyst comprising two layers on an inert catalyst carrier, a layer A containing at least palladium as a platinum group metal, in addition to a cerium/zirconium/lanthanum/yttrium mixed oxide, and a layer B, which is applied to layer A, containing at least rhodium as the platinum group metal, in addition to a cerium/zirconium/lanthanum/yttrium mixed oxide.

The present invention relates to a molding catalyst and a method for producing the same, wherein the molding catalyst is used in the Deacon process for commercial production of chlorine using hydrogen chloride oxidation reaction, exhibits only a small reduction in catalytic activity even when exposed to harsh reaction conditions to thus be durable, and has superb mechanical strength to be suitable for use in a fixed bed catalytic reactor.

Disclosed is high conversion and high carbon yielding CARGEN catalyst and a method of preparing the same. The catalyst comprises transition metals that may be supported or unsupported. The preparation method involves mixing a metal material with or without a support in a standard ball milling apparatus to produce a fine and homogenous solid mixture of the transition metal oxide and support. The catalyst is used in the CARGEN system.

A photocatalytic device includes: a metal layer; and a photocatalytic layer provided on the metal layer and containing a photocatalytic material. In the photocatalytic layer, a slit or an opening is formed to expose a portion of the metal layer.