Provided are a photocurable resin composition that can be suitably used for an optical three-dimensional shaping method, and a cured product obtained by photocuring the composition and a three-dimensional shaped object including the cured product. The photocurable resin composition contains a compound represented by the formula (1) and a compound containing two or more epoxy groups. ##STR00001##

Provided are a photocurable resin composition that can be suitably used for an optical three-dimensional shaping method, and a cured product obtained by photocuring the composition and a three-dimensional shaped object including the cured product. The photocurable resin composition contains a compound represented by the formula (1) and a compound containing two or more epoxy groups. ##STR00001##

A method and apparatus for the additive manufacturing of three-dimensional objects are disclosed. Two or more materials are extruded simultaneously as a composite, with at least one material in liquid form and at least one material in a solid continuous strand completely encased within the liquid material. A means of curing the liquid material after extrusion hardens the composite. A part is constructed using a series of extruded composite paths. The strand material within the composite contains specific chemical, mechanical, or electrical characteristics that instill the object with enhanced capabilities not possible with only one material.

Described herein are compositions, methods, and systems for printing metal three-dimensional objects. In an example, described is a method of printing a three-dimensional object comprising: (i) depositing a metal powder build material, wherein the metal powder build material has an average particle size of from about 10 μm to about 250 μm; (ii) selectively applying a binder fluid on at least a portion of the metal powder build material, wherein the binder fluid comprises an aqueous liquid vehicle and latex polymer particles dispersed in the aqueous liquid vehicle; (iii) heating the selectively applied binder fluid on the metal powder build material to a temperature of from about 40° C. to about 180° C.; and (iv) repeating (i), (ii), and (iii) at least one time to form the three-dimensional object.

Described herein are compositions, methods, and systems for printing metal three-dimensional objects. In an example, described is a method of printing a three-dimensional object comprising: (i) depositing a metal powder build material, wherein the metal powder build material has an average particle size of from about 10 μm to about 250 μm; (ii) selectively applying a binder fluid on at least a portion of the metal powder build material, wherein the binder fluid comprises an aqueous liquid vehicle and latex polymer particles dispersed in the aqueous liquid vehicle; (iii) heating the selectively applied binder fluid on the metal powder build material to a temperature of from about 40° C. to about 180° C.; and (iv) repeating (i), (ii), and (iii) at least one time to form the three-dimensional object.

The use of a water-soluble thermoset binder for binder jetting of a cemented carbide or cermet green body is provided. The water-soluble thermoset binder includes a compound A, being at least one organic, non-aromatic substance, including at least two hydroxyl groups and a compound B, being at least one organic, non-aromatic substance, including at least two carboxyl groups, wherein the compound A and compound B are monomers or oligomers. The binder will lead to an increased strength of the printed green body.

The invention relates to an ink based on near-infrared light polymerization. The method and technology of direct writing three-dimensional printing belong to the field of material processing technology area. The method is: direct writing nozzles move in three-dimensional space or stationery, the ink is squeezed out of the direct writing nozzle, receiving the near-infrared light irradiation, after curing, complete the three-dimensional object forming and curing. The solidifying time t does not exceed the ratio of near-infrared light diameter d.sub.1 and the ink extrusion speed vi, that is, t≤d.sub.1/v.sub.i. Since near-infrared light has a better medium mass penetration, can penetrate the structure during molding to promote both internal and external to a higher degree of curing, so as to achieve cross-scale structure 3D printing, and the method provided by the present invention accurately controls solidifying process of the ink and therefore achieve the DIW array 3D structure real-time curing.

The present invention relates to a biodegradable PLA filament composition for molding a porous structure. The biodegradable PLA filament composition for molding a porous structure according to one embodiment of the present invention includes polylactic acid (PLA) in 50% by weight to 60% by weight; polybutylene succinate (PBS) in 20% by weight to 30% by weight; polybutylene adipate terephthalate (PBAT) in 7% by weight to 9% by weight; an additive in 0.1% by weight to 1% by weight; a crystallization nucleating agent in 0.1% by weight to 1% by weight; a natural grapefruit seed powder (Jamongci_genu pectin type) in 0.1% by weight to 2% by weight; an inorganic filler in 1% by weight to 10% by weight; and a crosslinking agent in 0.001% by weight to 10% by weight.

A three-dimensional printing kit can include a wetting agent, a binding agent, and a particulate build material. The wetting agent an include water, from about 5 wt % to about 60 wt % organic co-solvent, and from about 0.1 wt % to about 10 wt% surfactant. The binding agent can include from about 2 wt % to about 25 wt % polymer binder and a liquid vehicle. The particulate build material can include from about 80 wt % to 100 wt % metal particles that can have a D50 particle size ranging from about 2 gm to about 150 μm.

Provided herein are manufacturing methods, e.g., comprising: (1a) forming a layer, including: depositing a starting material including a mixture of a metal and a sacrificial material; and applying a laser beam to the deposited starting material to consolidate the deposited starting material and form the layer; (1b) optionally repeating (1a) one or more times; and (1c) at least partially removing the sacrificial material to form a porous metal part.