A phosphorus production method can include reducing feed containing phosphate ore and providing a silica ratio from 0.3 to 0.7 in a reaction chamber from 1250 to 1380 C. Less than 20% of the phosphate remains in the residue. Another phosphorus production method includes continuously moving a reducing bed through the reaction chamber with the feed agglomerates substantially stable while in the reducing bed. Reaction chamber temperature can be from 1250 to 1380 C. A phosphorus production system includes a barrier wall segmenting the reaction chamber into a reduction zone differentiated from a preheat zone. The bed floor is configured to move continuously from the preheat zone to the reduction zone during operation. A method for producing a reduction product includes exothermically oxidizing reduction/oxidation products in the reaction chamber, thereby adding heat to the reducing bed from the freeboard as a second heat source.

Provided is an all-solid state secondary battery comprising a laminate in which a positive electrode layer, a solid electrolyte layer, and a negative electrode layer are laminated in this order, in which respective areas of the positive electrode layer, the solid electrolyte layer, and the negative electrode layer satisfy [the area of the positive electrode layer]<[the area of the negative electrode layer][the area of the solid electrolyte layer], a buffer layer having an area more than the area of the solid electrolyte layer and having a Young's modulus lower than that of each of, the positive electrode layer, the solid electrolyte layer, and the negative electrode layer is provided on either or both of a side of the positive electrode layer opposite to the solid electrolyte layer side and a side of the negative electrode layer opposite to the solid electrolyte layer side, and the laminate is in a pressurized state through the buffer layer.

A composition includes a few-layer phosphorene nanomaterial comprising at least one of mono-, bi-, and n-layer phosphorene nanosheets, where n is an integer selected from 3 to 6; deoxygenated water; and at least one amphiphilic surface active component.

Producing nanostructure materials in a thin film reactor (TFR) from starting material of inorganic or organic material of layered or two dimensional (2D) structure or inorganic material transformed in situ into 2D inorganic material, or single walled carbon nanotubes (SWCNTs), and a solvent or liquid phase. The TFR can be a vortex fluidic device (VFD) or a device with spaced first and second fluid contact surfaces, which can be conical, for relative rotation to generate shear stress in the thin film therebetween. A liquid supply means delivers a liquid between the first and second fluid contact surfaces. The composition can be exposed to laser energy. The thin film reactor can form graphene, graphene oxide, scrolls, tubes, spheres or rings of the layered or 2D material.

A reagent system for treating heavy metal-contaminated materials is provided and includes an oxidizer, a soluble phosphate, and an alkaline hydroxide source, such as a caustic soda or lime. A method of treating mine waste bearing one or more heavy metals is also provided and includes the step of admixing a reagent system with heavy metal-containing material to preferentially reduce the leachability of heavy metals and form precipitates and complexes of low metal solubility that remain stable within the host solid matrix for long durations in acidic and abrasive conditions.

A positive electrode active material for lithium ion rechargeable battery is disclosed. The positive electrode active material is represented by composition formula: Li.sub.2-XMg.sub.XCoP.sub.2O.sub.7, wherein X is equal to or greater than 0.01 and equal to or smaller than 0.2.

A single-step, in situ bipolar exfoliation system, and methods for exfoliations of multi-layer bulk black phosphorous into single-layer (two-dimensional), few-layer, or even nano-platelets phosphorene are provided. The bipolar exfoliation system can include: a first driving electrode; a second driving electrode electrically connected to the first driving electrode through an external power supply; at least one bipolar electrode comprising multi-layer bulk black phosphorous; and a solvent in physical contact with the first driving electrode, the second driving electrode, and the at least one bipolar electrode. The system can be configured such that the electric conditions between the first and second driving electrodes can be used to turn one end of the at least one bipolar electrode into an anodic pole and the other end of the at least one bipolar electrode into a cathodic pole such that the multi-layer black phosphorous is exfoliated into the single-layer, few-layer, or nano-platelets phosphorene.

A scalable approach for the synthesis of black phosphorus (BP) material thin films over large areas is described. A red phosphorus (RP) material thin film may be deposited on a substrate followed by conversion to a BP material thin film using high-pressure alone or high pressure and high temperature. A thin-film of dielectric material such as hexagonal boron nitride (hBN) can be formed on a RP material film before the conversion is performed to improve the crystalline quality and stability of the converted BP material. Surprisingly, an atomically sharp and defect-free interface can be formed between the converted BP material and hBN. The BP material has high crystalline uniformity and can be used to fabricate thin-film transistors and optoelectronic devices such as infrared photodetectors.

Described are methods of removing phosphorous from aqueous solutions using copper-substituted aluminosilicate materials. The copper-substituted aluminosilicate materials are copper-substituted zeolites that are recyclable and have desirable recovery efficiencies. Also described are methods of making copper-substituted aluminosilicate materials, using copper-substituted aluminosilicate materials, systems using copper-substituted aluminosilicate materials, and methods of using these systems.

A composition of matter having the following chemical structure:

[00001]$\left[\frac{H_x.Math.O_{\left(x-1\right)}}{2}\right].Math.Z_y$ wherein x is and odd integer3; y is an integer between 1 and 20; and Z is one of a monoatomic ion from Groups 14 through 17 having a charge value between 1 and 3 or a polyatomic ion having a charge between 1 and 3.