Patent classifications
C01B32/00
Powder, Electrode and Battery Comprising Such a Powder
Powder comprising particles comprising a matrix material and silicon-based domains dispersed in this matrix material, whereby the matrix material is carbon or a material that can be thermally decomposed to carbon, whereby either part of the silicon-based domains are present in the form of agglomerates of silicon-based domains whereby at least 98% of these agglomerates have a maximum size of 3 μm or less, or the silicon-based domains are not at all agglomerated into agglomerates.
Powder, Electrode and Battery Comprising Such a Powder
Powder comprising particles comprising a matrix material and silicon-based domains dispersed in this matrix material, whereby the matrix material is carbon or a material that can be thermally decomposed to carbon, whereby either part of the silicon-based domains are present in the form of agglomerates of silicon-based domains whereby at least 98% of these agglomerates have a maximum size of 3 μm or less, or the silicon-based domains are not at all agglomerated into agglomerates.
CARBON STRUCTURE INCLUDING AN ELECTRICALLY CONDUCTIVE MATERIAL
A composition of matter suitable for usage as a formative material for a lithium-sulfur battery cathode is provided. The composition of matter may include a carbon structure formed by multiple carbon particles interconnected to one another. Each carbon particle may include pores and exposed surfaces. In this way, an electrically conductive material (ECM) (e.g., silver and/or antimony) may be deposited in the pores and coated (e.g., conformally coated) on the exposed surfaces of respective carbon particles. In addition, at least some carbon particles may disintegrate and provide exposed surfaces prior to deposition of the ECM. For example, disintegrated carbon particles may have a greater surface-area-to-volume ratio than whole carbon particles, thereby providing an increased amount of surface area available for subsequent ECM deposition. In addition, in some aspects, an active material may be infiltrated in one or more carbon particles and pores.
Rare Earth Metal Instantiation
The invention includes apparatus and methods for instantiating rare earth metals in a nanoporous carbon powder.
Porous carbon, and positive electrode and lithium secondary battery comprising same
Porous carbon particles, and a positive electrode active material and a lithium secondary battery including the same. This may improve the energy density of the lithium secondary battery by applying a porous electrode containing micropores and mesopores and having a uniform size distribution and shape as a positive electrode material.
PROCESS FOR PREPARING AND USE OF HARD-CARBON CONTAINING MATERIALS
The invention relates to a process for preparing hard carbon-containing material with a specific surface area of 100 m.sup.2/g or less, comprising the utilisation of one or more animal-derived materials.
AQUEOUS POLYIMIDE PROCESSES
The present disclosure is directed to methods of forming polyamic acid and polyimide gels in water. The resulting polyamic acid and polyimide gels may be converted to aerogels, which may further be converted to carbon aerogels. Such carbon aerogels have the same physical properties as carbon aerogels prepared from polyimide aerogels obtained according to conventional methods, i.e., organic solvent-based. The disclosed methods are advantageous in reducing or avoiding costs associated with use and disposal of potentially toxic solvents and byproducts. Gel materials prepared according to the disclosed methods are suitable for use in environments involving electrochemical reactions, for example as an electrode material within a lithium-ion battery.
WATER CO-CATALYST FOR POLYIMIDE PROCESSES
The present disclosure is directed to methods of forming polyimide gels. The methods generally include forming a polyamic acid and dehydrating the polyamic acid with a dehydrating agent in the presence of water. The resulting polyimide gels may be converted to polyimide or carbon xerogels or aerogels. The methods are advantageous in providing rapid or even instantaneous gelation, which may be particularly useful in formation of beads comprising the polyimide gels. Polyimide or carbon gel materials prepared according to the disclosed method are suitable for use in environments containing electrochemical reactions, for example as an electrode material within a lithium-ion battery.
System and method for using ultramicroporous carbon for the selective removal of nitrate with capacitive deionization
The present disclosure relates to a flow through electrode, capacitive deionization (FTE-CDI) system which is able to adsorb nitrates from water being treated using the system. The system makes use of a pair of electrodes arranged generally parallel to one another, with a water permeable dielectric sandwiched between the electrodes. The electrodes receive a direct current voltage from an electrical circuit. At least one of the electrodes is formed from a carbon material having a hierarchical pore size distribution which includes a first plurality of pores having a width of no more than about 1 nm, and a second plurality of micro-sized pores. The micron-sized pores enable a flow of water to be pushed through the electrodes while the first plurality of pores form adsorption sites for nitrate molecules carried in the water flowing through the electrodes.
PROCESS FOR THE PREPARATION OF A POROUS CARBONACEOUS MATERIAL, POROUS CARBONACEOUS MATERIAL, AND A CATALYST MADE OF THE MATERIAL
Known processes for preparing a porous carbonaceous material require lengthy polymerization and washing steps involving solvents or neutralizing agents. The use of high quantities of pore formers leads to a lower carbon yield and higher costs, and use of sulphuric acid leads to sulphur contamination of the final material, but also to corrosion and corrosive by-products and a more complicated handling of the process. In order allows the manufacturing of a porous carbonaceous material with a high pore volume and avoiding the disadvantages of the known methods, a process is provide that comprise the steps of a) providing at least one carbon source and at least one amphiphilic species, b) combining at least the carbon source and the amphiphilic species to obtain a precursor material, c) heating the precursor material to a temperature in the range between 300° C. and 600° C. for at least 15 min so as to obtain a porous carbonaceous material, which is then cooled so as to form the porous carbonaceous material having a modal pore size and a pore volume and a skeleton density.