Disclosed are embodiments of high Q modified materials. In some embodiments, complex tungsten oxides and/or hexagonal perovskite crystal structures can be added to provide for advantageous properties. In some embodiments, no tin is used in the formation of the material.

An electronic device comprises a first blocking electrode; a second blocking electrode; and a dielectric material disposed between the first electrode and the second electrode, the dielectric material comprising a compound of Formula 1

Li.sub.24-b*y-c*z-a*xM.sup.1.sub.yM.sup.2.sub.zM.sup.3.sub.xO.sub.12-δ  (1)

wherein M.sup.1 is a cationic element having an oxidation state of b, wherein b is +1, +2, +3, +4, +5, +6, or a combination thereof; M.sup.2 is a cationic element having an oxidation state of c, wherein c is +1, +2, +3, +4, +5, +6, or a combination thereof; M.sup.3 is a cationic element having an oxidation state of a, wherein a is +1, +3, +4, or a combination thereof; 0≤y≤3; 0≤z≤3; 0≤x≤5; and 0≤δ≤2. Methods for the manufacture of the electronic device are also disclosed.

A precursor composition for a solid electrolyte is provided that is capable of achieving a high lithium ion conductivity even if the precursor composition is sintered at a temperature of 1000° C. or lower. The precursor composition for the solid electrolyte is a precursor composition for a garnet-type or garnet-like solid electrolyte containing Li, La, Zr, and M, wherein the M is one or more types of elements selected from Nb, Ta, and Sb, the compositional ratio of Li:La:Zr:M in the solid electrolyte is 7-x:3:2-x:x, a relationship of 0<x<2.0 is satisfied, and the precursor composition exhibits X-ray diffraction intensity peaks at diffraction angles 2θ of 28.4°, 32.88°, 47.2°, 56.01°, and 58.73° in an X-ray diffraction pattern.

A piezoelectric ceramic composition is represented by a composition formula A.sub.xBO.sub.3 and includes potassium sodium niobate containing K and Na that account for 80% or more of an amount of A-site elements and containing Nb that accounts for 70% or more of an amount of B-site elements. The piezoelectric ceramic composition contains Ta and Fe at a B-site.

A metal oxide nanoparticle comprises a metal oxide core of formula M.sub.2O.sub.5, wherein M is tantalum (V) or niobium (V) and alkylsiloxane ligands bonded to the metal oxide core.

A metal oxide nanoparticle comprises a metal oxide core of formula M.sub.2O.sub.5, wherein M is tantalum (V) or niobium (V) and alkylsiloxane ligands bonded to the metal oxide core.

According to one embodiment, provided is an active material including monoclinic niobium titanium composite oxide particles, and carbon fibers with which at least a part of surfaces of the monoclinic niobium titanium composite oxide particles is covered. The monoclinic niobium titanium composite oxide particles satisfy 1.5≤(α/β)≤2.5. The monoclinic niobium titanium composite oxide particles have an average primary particle size of 0.05 μm to 2 μm. The carbon fibers contain one or more metal elements selected from the group consisting of Fe, Co and Ni, and satisfy 1/10000≤(γ/σ)≤ 1/100. The carbon fibers have an average fiber diameter in the range of 5 nm to 100 nm.

A solid electrolyte material of the present disclosure includes: Li; M; O; and X. The M is at least one selected from the group consisting of Nb and Ta. The X is at least one selected from the group consisting of F, Cl, Br, and I. The solid electrolyte material of the present disclosure has, in an X-ray diffraction pattern obtained by X-ray diffraction measurement using a Cu-Kα ray, a first peak positioned within a range of a diffraction angle 2θ from 13.49° to 13.59° and a second peak positioned within a range of the diffraction angle 2θ from 14.82° to 14.92°. An intensity ratio of the first peak to the second peak is 0.50 or more and 4.50 or less.

A nanoparticle that includes a metal oxide core having the formula M.sub.2O.sub.5 wherein M is either tantalum (V) or niobium (V) and alkylsiloxane ligands surrounding the metal oxide core.

A nanoparticle that includes a metal oxide core having the formula M.sub.2O.sub.5 wherein M is either tantalum (V) or niobium (V) and alkylsiloxane ligands surrounding the metal oxide core.