In a process for manufacturing glass, a mixture of solid glass-forming materials may be melted by application of heat from one or more submerged combustion burners to produce a volume of unrefined molten glass comprising, by volume, 20% to 40% gas bubbles. A refining agent may be introduced into the unrefined molten glass to promote gas bubble removal from the molten glass. The unrefined molten glass including the refining agent may be heated at a temperature in the range of 1200° C. to 1500° C. to produce a volume of refined molten glass. The refined molten glass may comprise, by volume, fewer gas bubbles than the unrefined molten glass. A colorant material may be introduced into the refined molten glass to produce a volume of molten glass having a final desired color.

A method of fining low-density submerged combustion glass is disclosed. The method involves introducing unfined molten glass produced in a submerged combustion melter into a fining chamber of a downstream fining tank. Additionally, additive particles are also introduced into the fining chamber to release one or more fining agents into the molten glass bath contained in the fining chamber to accelerate the removal of bubbles from the molten glass bath. The fining of the molten glass bath as assisted by the one or more fining agents allows for fined glass to be discharged from the fining tank that has fewer bubbles and a greater density than that of the unfined molten glass introduced into the fining tank. Additive particles that include a physical mixture of a glass reactant material and the fining agent(s) are also disclosed.

A method of fining glass is disclosed that includes flowing a molten glass bath through a fining chamber. The molten glass bath has an undercurrent that flows beneath a skimmer that is partially submerged in the molten glass bath. One or more fining agents are introduced into the undercurrent of the molten glass bath directly beneath the skimmer from a dissolvable fining material component. In this way, the fining agent(s) may selectively target the gas bubbles drawn under the skimmer within the undercurrent of the molten glass for removal. The method may be employed to fine molten gas produced in a submerged combustion melter. A fining vessel for fining molten glass is also disclosed.

A method of producing and fining glass includes monitoring a temperature of a molten glass bath contained within a fining chamber of a fining vessel and, based on the monitored temperature, controlling an amount of a sulfate chemical fining agent added into a glass melt contained within an interior reaction chamber of an upstream submerged combustion melter that feeds the fining vessel. The temperature of the molten glass bath may be determined within a temperature indication zone that encompasses a subsurface portion of the molten glass bath that lies adjacent to a floor of a housing of the fining vessel. By monitoring the temperature of the molten glass bath and controlling the amount of the sulfate chemical fining agent added to the glass melt of the submerged combustion melter, the wasteful use of the sulfate chemical fining agent can be minimized and the fining process rendered more efficient.

A method of fining glass is disclosed that includes flowing a molten glass bath through a fining chamber. The molten glass bath has an undercurrent that flows beneath a skimmer that is partially submerged in the molten glass bath. One or more fining agents are introduced into the undercurrent of the molten glass bath directly beneath the skimmer from a carrier gas. In this way, the fining agent(s) may selectively target the gas bubbles drawn under the skimmer within the undercurrent of the molten glass for removal. The method may be employed to fine molten gas produced in a submerged combustion melter. A fining vessel for fining molten glass is also disclosed.

A method for making high optical quality multicomponent chalcogenide glasses without refractive index perturbations due to striae, phase separation or crystal formation using a sealed ampoule with chemical components enclosed inside, a two-zone furnace, a convection heating/mixing step, and multiple fining steps. Initially, the sealed ampoule is oriented vertically within the two-zone furnace and heated to melt the chemical components contained within, and a temperature gradient is created between the top zone and the bottom zone such that the bottom zone has a higher temperature. This temperature gradient causes convection currents within the viscous liquid until it is sufficiently mixed due to the convective flow. Then the temperature gradient is reversed such that the top zone now has a higher temperature and the convective flow ceases. The furnace temperatures are then reduced over a period of time, with holds at multiple temperatures for fining and cooling to form a solid glass.

A method for making high optical quality multicomponent chalcogenide glasses without refractive index perturbations due to striae, phase separation or crystal formation using a sealed ampoule with chemical components enclosed inside, a two-zone furnace, a convection heating/mixing step, and multiple fining steps. Initially, the sealed ampoule is oriented vertically within the two-zone furnace and heated to melt the chemical components contained within, and a temperature gradient is created between the top zone and the bottom zone such that the bottom zone has a higher temperature. This temperature gradient causes convection currents within the viscous liquid until it is sufficiently mixed due to the convective flow. Then the temperature gradient is reversed such that the top zone now has a higher temperature and the convective flow ceases. The furnace temperatures are then reduced over a period of time, with holds at multiple temperatures for fining and cooling to form a solid glass.

A glass ceramic and a preparation method thereof include a step of melting calcined electrolytic manganese slag to obtain molten glass. The molten glass is sequentially molded, nucleated, and crystallized to obtain the glass ceramic. The calcined electrolytic manganese slag is taken as a raw material, so that harmful gases are not generated in the raw material melting process, and secondary pollution is not caused. The preparation method provided by the present invention has the advantages of simple operation, high utilization rate of electrolytic manganese slag and low cost. Moreover, the prepared glass ceramic has good mechanical properties and corrosion resistance.

A method of fining glass is disclosed that includes flowing a molten glass bath through a fining chamber. The molten glass bath has an undercurrent that flows beneath a skimmer that is partially submerged in the molten glass bath. One or more fining agents are introduced into the undercurrent of the molten glass bath directly beneath the skimmer from a dissolvable fining material component. In this way, the fining agent(s) may selectively target the gas bubbles drawn under the skimmer within the undercurrent of the molten glass for removal. The method may be employed to fine molten gas produced in a submerged combustion melter. A fining vessel for fining molten glass is also disclosed that includes a housing, a skimmer, and a dissolvable fining material component disposed directly beneath the skimmer.

An enamel composition, a method for preparing an enamel composition, and a cooking appliance are provided. The enamel composition may include 15 to 50 wt % of phosphorus pentoxide (P.sub.2O.sub.5); 5 to 20 wt % of one or more of lithium oxide (Li.sub.2O), sodium oxide (Na.sub.2O), or potassium oxide (K.sub.2O); 1 to 5 wt % of one or more of sodium fluoride (NaF), calcium fluoride (CaF.sub.2), or aluminum fluoride (AlF.sub.3); 1 to 35 wt % of one or more of magnesium oxide (MgO), barium oxide (BaO), or calcium oxide (CaO); and 5 to 30 wt % of one or more of manganese dioxide (MnO.sub.2), molybdenum trioxide (MoO.sub.3), bismuth oxide (Bi.sub.2O.sub.3), or nickel oxide (NiO). The enamel composition may be cleaned without being putting it into water.