Architectural structures including an inorganic material carrier including cement and particles or fibers of a glass including a plurality of Cu.sup.1+ ions. In aspects, the glass may have a glass phase and a cuprite phase. In aspects, the glasses may include a plurality of Cu.sup.1+ ions, a degradable phase including B.sub.2O.sub.3, P.sub.2O.sub.5 and K.sub.2O and a durable phase including SiO.sub.2. In other aspects, the glass can have a plurality of Cu.sup.1+ ions disposed on the surface of the glass and in the glass network and/or the glass matrix. The glasses and articles disclosed herein can exhibit a 2 log reduction or greater in a concentration of at least one of Staphylococcus aureus, Enterobacter aerogenes, Pseudomonas aeruginosa bacteria, Methicillin Resistant Staphylococcus aureus, and E. coli, under the EPA Test Method for Efficacy of Copper Alloy as a Sanitizer testing condition and under Modified JIS Z 2801 for Bacteria testing conditions.

A product having a transparent volume-coloured glass-ceramic is provided. The glass-ceramic includes, based on oxide, 58-72% by weight SiO.sub.2, 16-26% by weight Al.sub.2O.sub.3, 1.0-5.5% by weight Li.sub.2O, 2.0-<4.0% by weight TiO.sub.2, 0-<2.0 by weight ZnO, and 0.005-0.12% by weight MoO.sub.3, and where the glass-ceramic, based on a thickness of 4 mm, has a luminous transmittance τ.sub.vis of 0.5%-3.5%, and where the glass-ceramic has the property that after passage through the glass-ceramic, based on a thickness of 4 mm, light of the standard illuminant D65 has a colour locus in the white region A1 that in the CIExyY-2° chromaticity diagram is defined by the following coordinates:

TABLE-US-00001 A1 0.3 0.27 0.28 0.315 0.35 0.38 0.342 0.31 0.3 0.27.

The invention relates to glass articles suitable for use as electronic device housing/cover glass which comprise a glass ceramic material. Particularly, a cover glass comprising an ion-exchanged glass ceramic exhibiting the following attributes (1) optical transparency, as defined by greater than 90% transmission at 400-750 nm; (2) a fracture toughness of greater than 0.6 MPa.Math.m.sup.1/2; (3) a 4-point bend strength of greater than 350 MPa; (4) a Vickers hardness of at least 450 kgf/mm.sup.2 and a Vickers median/radial crack initiation threshold of at least 5 kgf; (5) a Young's Modulus ranging between about 50 to 100 GPa; (6) a thermal conductivity of less than 2.0 W/m° C., and (7) and at least one of the following attributes: (i) a compressive surface layer having a depth of layer (DOL) greater and a compressive stress greater than 400 MPa, or, (ii) a central tension of more than 20 MPa.

A method is provided for calculating gaseous diffusion and oxidation evolution of a ceramic matrix composite (CMC) structure, which includes determining temperature and load distribution in a structural member; determining matrix crack distribution in the structure; establishing an equivalent diffusion coefficient model of a fiber bundle scale to predict a gas flow channel in a fiber bundle: averaging a total amount of gaseous diffusion in the channel to establish the equivalent diffusion coefficient model of the fiber bundle composite scale related to the matrix crack distribution; establishing a representative volume element (RVE) model; establishing an equivalent diffusion coefficient model of a RVE scale; calculating the distribution of the gas concentration and oxidation products in the structure; calculating a growth thickness of an oxide at cracks and pores in each element; and updating sealing conditions of the gas channel, and calculating a new equivalent diffusion coefficient field and the distribution of the oxidation products again.

The present invention relates generally to silicate-based coatings and to methods to make and apply same. In one embodiment, the silicate-coatings of the present invention are formed from a two part mixture of phosphate-based component and a glass-based component. In another embodiment, the silicate-based coatings of the present invention are free from any organic materials.

Provided in the present invention is a rare earth-doped reinforced glass-ceramic, and a preparation method and a use therefor. Raw materials rare earth-doped reinforced glass-ceramic comprise at least one of the following rare earth oxides: Ta.sub.2O.sub.5, La.sub.2O.sub.3, Y.sub.2O.sub.3, Tm.sub.2O.sub.3, or Nb.sub.2O.sub.5. In the present invention, a glass article doped with at least one rare earth oxide from among Ta.sub.2O.sub.5, La.sub.2O.sub.3, Y.sub.2O.sub.3, Tm.sub.2O.sub.3, or Nb.sub.2O.sub.5 is subjected to thermal treatment and ion exchange to produce the rare-earth doped reinforced glass-ceramic. In the rare earth-doped reinforced glass-ceramic, due to the high field strength and high accumulation effects of the rear earth element, the crystal size of the glass-ceramic is caused to low, and the crystal ratio thereof to be high, thus being able to effectively improve the mechanical performance and visible light transmittance of the glass-ceramic, and effectively controlling uniform devitrification of the glass. The invention is suitable for use in cover panels of electronic devices.

A glass includes from 42 mol % to 47 mol % P.sub.2O.sub.5, from 42 mol % to 48 mol % CuO, and from greater than 0 mol % to 15 mol % Fe.sub.2O.sub.3. The glass is an amorphous, single-phase glass. Methods of making a glass article include heating batch materials to a melting temperature from 900° C. to 1350° C. In aspects, methods include pouring the molten glass in an inert gaseous environment, and cooling the molten glass in the inter gaseous environment. In aspects, methods include cooling the molten glass to form the glass article and annealing the glass article without growing crystals in or on the glass article during the cooling or the annealing.

A glass includes from 42 mol % to 47 mol % P.sub.2O.sub.5, from 42 mol % to 48 mol % CuO, and from greater than 0 mol % to 15 mol % Fe.sub.2O.sub.3. The glass is an amorphous, single-phase glass. Methods of making a glass article include heating batch materials to a melting temperature from 900° C. to 1350° C. In aspects, methods include pouring the molten glass in an inert gaseous environment, and cooling the molten glass in the inter gaseous environment. In aspects, methods include cooling the molten glass to form the glass article and annealing the glass article without growing crystals in or on the glass article during the cooling or the annealing.

A preparation method includes the following steps: Step (1): pressing and then drying body powder to form a green brick; Step (2): applying a ground coat on the surface of the green brick; Step (3): inkjet-printing a pattern on the surface of the green brick having the ground coat, and applying an isolation glaze; Step (4): applying a fully polished glaze on the surface of the green brick having the isolation glaze; and Step (5): drying, firing, and polishing the green brick having the fully polished glaze to obtain a hard wear-resistant polished glazed ceramic tile. The phase composition of the fired fully polished glaze is as follows: 10 to 20 percent by weight of corundum, 20 to 30 percent by weight of hyalophane, 0.5 to 1.0 percent by weight of hematite, and 50 to 68 percent by weight of amorphous phase.

A method for producing a composite particle, the method containing: (a) mixing a raw material particle and at least one type of fine particles selected from SiO.sub.2 fine particles and Al.sub.2O.sub.3 fine particles, the fine paricles having a diameter smaller than that of the raw material particle; and (b) heating the mixture of the raw material particles and the fine particles, wherein the raw material particle contains three components of ZnO, Al.sub.2O.sub.3, and SiO.sub.2, and a content of the ZnO is 17 to 43% by mole, a content of the Al.sub.2O.sub.3 is 9 to 20% by mole, and a content of the SiO.sub.2 is 48 to 63% by mole, based on the total content of the three components.