The present disclosure provides a novel glass filler that has a low permittivity and is suitable for mass production. A glass filler provided includes a glass composition that includes, in wt %, for example, 40≤SiO.sub.2≤60, 25≤B.sub.2O.sub.3≤45, 0<Al.sub.2O.sub.3≤18, 0<R.sub.2O≤5, and 0≤RO≤12, and satisfies at least one of: i) SiO.sub.2+B.sub.2O.sub.3≥80 and SiO.sub.2+B.sub.2O.sub.3+Al.sub.2O.sub.3≤99.9; and ii) SiO.sub.2+B.sub.2O.sub.3≥78, SiO.sub.2+B.sub.2O.sub.3+Al.sub.2O.sub.3≤99.9, and 0<RO<10. Another glass filler provided includes a glass composition that includes SiO.sub.2, B.sub.2O.sub.3, Al.sub.2O.sub.3, R.sub.2O, and 3<RO<8 at the same contents as the above, and satisfies SiO.sub.2+B.sub.2O.sub.3≥75 and SiO.sub.2+B.sub.2O.sub.3+Al.sub.2O.sub.3<97, where R.sub.2O=Li.sub.2O+Na.sub.2O+K.sub.2O and RO=MgO+CaO+SrO.

An electronic-grade glass fiber composition includes the following components with corresponding amounts by weight percentages: 54.2-60% SiO.sub.2, 11-17.5% Al.sub.2O.sub.3, 0.7-4.5% B.sub.2O.sub.3, 18-23.8% CaO, 1-5.5% MgO, less than or equal to 24.8% CaO+MgO, less than 1% Na.sub.2O+K.sub.2O+Li.sub.2O, 0.05-0.8% TiO.sub.2, 0.05-0.7% Fe.sub.2O.sub.3, and 0.01-1.2% F.sub.2. The weight percentage ratio C1=SiO.sub.2/(RO+R.sub.2O) is greater than or equal to 2.20, and the total weight percentage of the above components is greater than or equal to 98.5%.

An electronic-grade glass fiber composition includes the following components with corresponding amounts by weight percentages: 54.2-60% SiO.sub.2, 11-17.5% Al.sub.2O.sub.3, 0.7-4.5% B.sub.2O.sub.3, 18-23.8% CaO, 1-5.5% MgO, less than or equal to 24.8% CaO+MgO, less than 1% Na.sub.2O+K.sub.2O+Li.sub.2O, 0.05-0.8% TiO.sub.2, 0.05-0.7% Fe.sub.2O.sub.3, and 0.01-1.2% F.sub.2. The weight percentage ratio C1=SiO.sub.2/(RO+R.sub.2O) is greater than or equal to 2.20, and the total weight percentage of the above components is greater than or equal to 98.5%.

Methods of making fiber reinforced composite articles are described. The methods may include treating fibers with a sizing composition that includes a polymerization compound, and introducing the treated fibers to a pre-polymerized composition. The combination of the treated fibers and pre-polymerized composition may then undergo a temperature adjustment to a polymerization temperature at which the pre-polymerized composition polymerizes into a plastic around the fibers to form the fiber-reinforced composite article. Techniques for introducing the treated fibers to the pre-polymerized composition may include pultrusion, filament winding, reactive injection molding (RIM), structural reactive injection molding (SRIM), resin transfer molding (RTM), vacuum-assisted resin transfer molding (VARTM), long fiber injection (LFI), sheet molding compound (SMC) molding, bulk molding compound (BMC) molding, a spray-up application, and/or a hand lay-up application, among other techniques.

Methods of making fiber reinforced composite articles are described. The methods may include treating fibers with a sizing composition that includes a polymerization compound, and introducing the treated fibers to a pre-polymerized composition. The combination of the treated fibers and pre-polymerized composition may then undergo a temperature adjustment to a polymerization temperature at which the pre-polymerized composition polymerizes into a plastic around the fibers to form the fiber-reinforced composite article. Techniques for introducing the treated fibers to the pre-polymerized composition may include pultrusion, filament winding, reactive injection molding (RIM), structural reactive injection molding (SRIM), resin transfer molding (RTM), vacuum-assisted resin transfer molding (VARTM), long fiber injection (LFI), sheet molding compound (SMC) molding, bulk molding compound (BMC) molding, a spray-up application, and/or a hand lay-up application, among other techniques.

An environmentally friendly, aqueous binder composition that includes a metal salt and a polyol is provided. The metal salt may be a water soluble salt, including salts of boron, aluminum, gallium, indium, tin, zirconium, thallium, lead, and bismuth. The polyol may include water miscible or water soluble polymeric alcohols including polyvinyl alcohol. The binder composition may be used in the formation of insulation materials and non-woven mats, among other products.

An environmentally friendly, aqueous binder composition that includes a metal salt and a polyol is provided. The metal salt may be a water soluble salt, including salts of boron, aluminum, gallium, indium, tin, zirconium, thallium, lead, and bismuth. The polyol may include water miscible or water soluble polymeric alcohols including polyvinyl alcohol. The binder composition may be used in the formation of insulation materials and non-woven mats, among other products.

The present disclosure provides a novel glass composition that has a low permittivity and is suitable for mass production. A glass composition provided satisfies, in wt %, for example, 40≤SiO.sub.2≤60, 25≤B.sub.2O.sub.3≤45, 0<Al.sub.2O.sub.3≤18, 0<R.sub.2O≤5, and 0≤RO≤12, and satisfies at least one of: i) SiO.sub.2+B.sub.2O.sub.3≥80 and SiO.sub.2+B.sub.2O.sub.3+Al.sub.2O.sub.3≤99.9; and ii) SiO.sub.2+B.sub.2O.sub.3≥78, SiO.sub.2+B.sub.2O.sub.3+Al.sub.2O.sub.3≤99.9, and 0<RO<10. Another glass composition provided includes SiO.sub.2, B.sub.2O.sub.3, Al.sub.2O.sub.3, R.sub.2O, and 3<RO<8 at the same contents as the above, and satisfies SiO.sub.2+B.sub.2O.sub.3≥75 and SiO.sub.2+B.sub.2O.sub.3+Al.sub.2O.sub.3<97, where R.sub.2O=Li.sub.2O+Na.sub.2O+K.sub.2O and RO=MgO+CaO+SrO.

The present disclosure provides a novel glass composition that has a low permittivity and is suitable for mass production. A glass composition provided satisfies, in wt %, for example, 40≤SiO.sub.2≤60, 25≤B.sub.2O.sub.3≤45, 0<Al.sub.2O.sub.3≤18, 0<R.sub.2O≤5, and 0≤RO≤12, and satisfies at least one of: i) SiO.sub.2+B.sub.2O.sub.3≥80 and SiO.sub.2+B.sub.2O.sub.3+Al.sub.2O.sub.3≤99.9; and ii) SiO.sub.2+B.sub.2O.sub.3≥78, SiO.sub.2+B.sub.2O.sub.3+Al.sub.2O.sub.3≤99.9, and 0<RO<10. Another glass composition provided includes SiO.sub.2, B.sub.2O.sub.3, Al.sub.2O.sub.3, R.sub.2O, and 3<RO<8 at the same contents as the above, and satisfies SiO.sub.2+B.sub.2O.sub.3≥75 and SiO.sub.2+B.sub.2O.sub.3+Al.sub.2O.sub.3<97, where R.sub.2O=Li.sub.2O+Na.sub.2O+K.sub.2O and RO=MgO+CaO+SrO.

New glass compositions and applications thereof are disclosed. Embodiments of the present invention relate to glass compositions, to fiber glass strands, to chopped fiber glass strands, to nonwoven mats of glass fibers, and to other products and methods. A fiber glass strand comprises a plurality of glass fibers comprising the glass composition of the present invention.