Disclosed is a method for preparing a material of plant origin rich in phenolic acids, including at least one metal, including: preparing a material of plant origin chosen from: aquatic plants; materials rich in tannins; materials rich in lignin; and obtaining a material of plant origin, rich in phenolic acids, in which the ratio of the intensity of the vibration band of the CO bond of the COOH group and the intensity of each of the vibration bands the aromatic ring determined in FT-IR is between 0.5 and 4. The material of plant origin is brought into contact with an effluent including from 0.1 to 1000 mg/l of at least one metal, thus obtaining a material of plant origin rich in phenolic acids including from 1 to 30% by weight of at least one metal relative to the total weight of the material.

Disclosed is a method for preparing a solid material including manganese, the method including the following steps: a. bringing into contact an aqueous effluent including manganese, for example at least 5 mg/L, typically at least 5 to 50 mg/L, and preferably 7 to 25 mg/L of manganese, with an oxidizing agent, manganese, preferably at a temperature between 10 C. and 50 C., and obtaining an oxidized aqueous solution; b. adding a base to the oxidized aqueous solution obtained at the end of step a) until a pH of between 8 and 12, preferably greater than 9, and preferably from 9 to 10.5, and obtaining a solution including a precipitate; c. filtration of the solution obtained at the end of step b); and d. obtaining a solid material including manganese, and especially manganese (IV) and/or Mn (III).

Provided is a production system for producing a hydrocarbon compound, which is a hydrocarbon compound production system capable of managing an environmental load reducing effect derived from a raw material. The hydrocarbon compound production system includes a hydrogen production device that generates hydrogen, a carbon dioxide supply device that supplies a carbon dioxide, and a hydrocarbon compound production device that generates a hydrocarbon compound from each of the hydrogen generated by the hydrogen production device and the carbon dioxide supplied from the carbon dioxide supply device, wherein, on the basis of at least either one of respective environmental indicators of the hydrogen generated by the hydrogen production device and the carbon dioxide supplied from the carbon dioxide supply device, an environmental load level of the hydrocarbon compound generated by the hydrocarbon compound production device is categorized.

Systems and methods for providing redundant access control systems are disclosed. According to some embodiments of the invention, the systems and methods include a smart lock that provides redundant access control. The smart lock includes a button that has a plurality of redundant access channels for receiving authentication information. The redundant access channels may include a biometric scanner for receiving biometric information, a passcode keypad for entering a token, or a wireless transceiver for receiving a token from a mobile device and transmitting a response to the mobile device. When the user cannot open the lock through the first redundant access channel, the smart lock is configured to allow access through a second access channel. In some embodiments, the button is a freely rotating button that translates the rotational energy into electrical energy using, for example piezo elements, to energize a rechargeable power source, such as a capacitor bank.

This present disclosure relates to processes for removing contaminants from hydrocarbon streams, e.g. removing chlorides, CO.sub.2, COS, H.sub.2S, AsH.sub.3, methanol, mercaptans and other S- or O-containing organic compounds from olefins, paraffins, aromatics, naphthenes and other hydrocarbon streams. The process involves contacting the stream with an adsorbent which comprises a zeolite, an alumina component and a metal component e.g. sodium, in an amount at least 30% of the zeolite's ion exchange capacity.

This present disclosure relates to processes for removing contaminants from hydrocarbon streams, e.g. removing chlorides, CO.sub.2, COS, H.sub.2S, AsH.sub.3, methanol, mercaptans and other S- or O-containing organic compounds from olefins, paraffins, aromatics, naphthenes and other hydrocarbon streams. The process involves contacting the stream with an adsorbent which comprises a zeolite, an alumina component and a metal component e.g. sodium, in an amount at least 30% of the zeolite's ion exchange capacity.

The present invention provides a modified composite molecular sieve, and a preparation method and an application of the modified composite molecular sieve. The modified composite molecular sieve comprises SiO.sub.2 and a composite molecular sieve that comprises molecular sieve MCM-22 and crystalline molecular sieve selected from at least one of ZSM-22, ZSM-23 and ZSM-48, wherein, the molecular sieve MCM-22 covers around the crystalline molecular sieve. The present invention further provides a catalyst and an application of the catalyst. The catalyst comprises a carrier and a noble metal loaded on the carrier, wherein, the carrier comprises a modified composite molecular sieve that is the modified composite molecular sieve provided in the present invention or the modified composite molecular sieve obtained with the method provided in the present invention. The catalyst that utilizes the composite molecular sieve as a carrier not only can decrease the solidifying point of waxy raw oil, but also can improve the yield of liquid product, is especially applicable to the isomerization dewaxing process of lube distillate, and has an advantage of remarkably improving the viscosity index of lube base oil.

The present invention provides a modified composite molecular sieve, and a preparation method and an application of the modified composite molecular sieve. The modified composite molecular sieve comprises SiO.sub.2 and a composite molecular sieve that comprises molecular sieve MCM-22 and crystalline molecular sieve selected from at least one of ZSM-22, ZSM-23 and ZSM-48, wherein, the molecular sieve MCM-22 covers around the crystalline molecular sieve. The present invention further provides a catalyst and an application of the catalyst. The catalyst comprises a carrier and a noble metal loaded on the carrier, wherein, the carrier comprises a modified composite molecular sieve that is the modified composite molecular sieve provided in the present invention or the modified composite molecular sieve obtained with the method provided in the present invention. The catalyst that utilizes the composite molecular sieve as a carrier not only can decrease the solidifying point of waxy raw oil, but also can improve the yield of liquid product, is especially applicable to the isomerization dewaxing process of lube distillate, and has an advantage of remarkably improving the viscosity index of lube base oil.

The invention relates to isomerization catalysts and can be used in the petroleum processing and petrochemical industry. The catalyst contains sulfated zirconium oxide and a binderaluminum oxide in a ratio of ZrO2/SO4 to Al2O3 from 70 to 30 to 90 to 10, as well as promoter, a group II metal, Ca, in a quantity ranging from 0.01 to 1 wt % of the weight of the catalyst. The catalyst also contains platinum and/or palladium in a quantity ranging from 0.1 to 0.45 wt % of the metal. Isomerization of C4-C7 paraffinic hydrocarbons in the presence of hydrogen at a temperature of 110-200 C., a pressure of 1-5 MPa, a hydrogen:hydrocarbon ratio of 0.5-4, and a feedstock space velocity of 0.5-4 h.sup.1 is carried out on a catalyst having the claimed composition. The proposed catalyst offers an enhanced degree of isomerization, improved selectivity of the process, and increased strength of the granules.

The invention relates to isomerization catalysts and can be used in the petroleum processing and petrochemical industry. The catalyst contains sulfated zirconium oxide and a binderaluminum oxide in a ratio of ZrO2/SO4 to Al2O3 from 70 to 30 to 90 to 10, as well as promoter, a group II metal, Ca, in a quantity ranging from 0.01 to 1 wt % of the weight of the catalyst. The catalyst also contains platinum and/or palladium in a quantity ranging from 0.1 to 0.45 wt % of the metal. Isomerization of C4-C7 paraffinic hydrocarbons in the presence of hydrogen at a temperature of 110-200 C., a pressure of 1-5 MPa, a hydrogen:hydrocarbon ratio of 0.5-4, and a feedstock space velocity of 0.5-4 h.sup.1 is carried out on a catalyst having the claimed composition. The proposed catalyst offers an enhanced degree of isomerization, improved selectivity of the process, and increased strength of the granules.