The invention relates to a polymer composition comprising polyolefin (a), which is other than low density polyethylene (LDPE), and polyolefin (b), which is an LDPE polymer and obtainable by a high pressure process which process comprises the steps: (i) compressing one or more monomer(s) under pressure in a compressor, using a compressor lubricant for lubrication, (ii) polymerising a monomer optionally together with one or more comonomer(s) in a polymerisation zone, (iii) separating the obtained polyolefin (b) from the unreacted products and recovering the separated polyolefin in a recovery zone, wherein in step (i) the compressor lubricant comprises a non-mineral oil; a power cable, e.g. of a direct current (DC) power cable, use of a polymer composition and a process for producing a DC power cable.

A process for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution, where the monomer solution comprises at least two initiators, one of the initiators is a peroxide with the exception of persulfate, and the molar ratio of peroxide to further initiator is at least 1:8, the water-absorbing polymer particles themselves, and hygiene articles comprising these water-absorbing polymer particles.

A process for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution, where the monomer solution comprises at least two initiators, one of the initiators is a peroxide with the exception of persulfate, and the molar ratio of peroxide to further initiator is at least 1:8, the water-absorbing polymer particles themselves, and hygiene articles comprising these water-absorbing polymer particles.

Disclosed in the invention is a fluorine-containing polymer microsphere. A polymerization monomer, a photoinitiator and a stable dispersant are added into a reaction kettle, carbon dioxide gas is introduced for emptying air therein, then liquid carbon dioxide is injected, an initiating light source is used for irradiating in the reaction kettle after the temperature and pressure of the reaction kettle are constant, the reaction is performed under the conditions of −20-30° C. and 20-70 bar, wherein the concentration of the polymerization monomer accounting for the total volume of the reactants is 0.02-2 g/ml, and the weight ratio of the photoinitiator, stable dispersant and polymerization monomer is (0.3-10):(2-20):100; after the reaction is finished, the temperature returns to room temperature, and the precipitate is washed with liquid carbon dioxide, so as to obtain the polymer microspheres. The fluorine-containing polymer which covers the surface of the microspheres in the present invention can reduce the surface energy thereof, and can benefit the timely migration of the microspheres to the coating surface; a tertiary amine group is introduced into the fluorine-containing polymer to firmly bond the microspheres into a cross-linked network, and thus benefits the tight integration of the microspheres and the coating; a RAFT active group is introduced to firmly anchor the microspheres onto the coating film; thus ensuring the stability of the cured coating.

The present invention provides aqueous caulk or sealant compositions that are substantially free of any plasticizer comprising an aqueous emulsion copolymer having a broad measured glass transition temperature by differential scanning calorimetry (DSC), soft phases and hard phases, and two separate Tan Delta transition temperatures as measured by dimensional mechanical analysis (DMA), (ii) one or more filler in a filler to binder ratio of up to 4:1, and (iii) from 0.2 to 5 wt. % as solids, based on the total weight of the composition, of one or more thickener or rheology modifier. In addition, the invention provides methods of making the composition comprising polymerizing by gradually adding from a flask into a polymerization vessel a soft monomer composition, and, after feeding at least 20 wt. % of such composition in the vessel, gradually adding into the flask a hard comonomer composition, feeding all flask contents into the vessel and polymerizing.

This invention relates to poly(acrylonitrile) homo- or co-polymer having a number average molecular weight (M.sub.n) of at least 200,000 g/mol and a dispersity () of less than 1.3.

The present invention relates to an additive composition for controlling and inhibiting polymerization of monomers, wherein the composition comprises a combination of (a) a phenol compound comprising catechol compound with (b1) an aliphatic tertiary amine, (b2) oxide treated derivative of the aliphatic tertiary amine, or (b2) a mixture thereof, wherein the aliphatic tertiary amine contains one or more hydroxyl groups in the alkyl chain of the aliphatic tertiary amine. In one embodiment, the present invention also relates to a method for controlling and inhibiting polymerization of monomers by employing the additive composition of the present invention. In another embodiment, the present invention also relates to a method of using the additive composition of the present invention for controlling and inhibiting polymerization of monomers. In another embodiment, the present invention also relates to methods for controlling and inhibiting polymerization of monomers in a primary fractionator (or an ethylene plant), and for operating a primary fractionator, and for reducing fouling and polymer deposits in a primary fractionator, and to extend a run-length of a primary fractionator or of an ethylene plant.

The invention relates to a process for producing a polypropylene composition by sequential polymerization said polypropylene composition having low sealing initiation temperature (SIT) and high melting point (Tm), presenting thus a broad sealing window.

Described herein is a process for producing a propylene copolymer in at least a pre-polymerization stage, a first and a second reaction stage connected in series with improved monomer recovery, wherein a product stream, comprising a propylene polymer mixture, unreacted propylene, unreacted ethylene and hydrogen, if present, is separated in a separation unit into a first overhead stream and a first bottom product stream, wherein the desired propylene polymer mixture is recovered from the first bottom product stream. The first overhead stream is at least partially condensed, passed to a distillation column and separated into a second overhead stream and a second bottom product stream. The second overhead stream is at least partially condensed and split into three distinct streams, wherein a distillation reflux stream is returned into the distillation column, a first recycle stream is passed to the second reaction stage and a second recycle stream is passed to a stripping column from where a third bottom product stream is withdrawn and at least a part of it is passed to a propylene feed vessel, to the pre-polymerisation stage, to the first reaction stage, or to a combination thereof. Further disclosed is a polymerization unit, particularly suitable for carrying out the inventive process.

A process is useful for producing optical molding materials on the basis of methyl methacrylate (MMA), wherein this MMA has been produced by an optimized method and the molding materials feature in particular a very low yellowness index. This MMA has been produced by direct oxidative esterification of methacrolein. In particular, an optimized workup of the reactor output from the oxidative esterification of methacrolein is useful for removing particularly discoloring byproducts. This process moreover has the advantage that fewer demands than described in related art are placed on plant apparatus configuration.