C08F220/00

Transition Metal Catalysts For Olefin Polymerization
20190338058 · 2019-11-07 ·

In one aspect, a chelating phosphine-phosphonic diamide (PPDA) ligand is described herein for constructing transition metal complexes operable for catalysis of olefin polymerization, including copolymerization of ethylene with polar monomer.

Transition Metal Catalysts For Olefin Polymerization
20190338058 · 2019-11-07 ·

In one aspect, a chelating phosphine-phosphonic diamide (PPDA) ligand is described herein for constructing transition metal complexes operable for catalysis of olefin polymerization, including copolymerization of ethylene with polar monomer.

Poly (meth) acrylic acid (salt)-based particulate water-absorbing agent and production method therefor

To provide a disposable diaper enabling reduction in re-wet amount and having an excellent speed of incorporating liquid regardless of concentration and configuration of a water-absorbing agent in an absorbent material. A water-absorbing agent having excellent Gel Capillary Absorption (GCA) and Free Gel Bed Permeability (FGBP) is obtained by crushing a crosslinked hydrogel polymer obtained in a polymerization step to have a specific weight average particle diameter while fluid retention capacity and a surface tension of a water-absorbing agent are adjusted in a specific range, drying the crushed crosslinked hydrogel polymer, and then adding a liquid permeability enhancer thereto during surface crosslinking or after surface crosslinking.

Poly (meth) acrylic acid (salt)-based particulate water-absorbing agent and production method therefor

To provide a disposable diaper enabling reduction in re-wet amount and having an excellent speed of incorporating liquid regardless of concentration and configuration of a water-absorbing agent in an absorbent material. A water-absorbing agent having excellent Gel Capillary Absorption (GCA) and Free Gel Bed Permeability (FGBP) is obtained by crushing a crosslinked hydrogel polymer obtained in a polymerization step to have a specific weight average particle diameter while fluid retention capacity and a surface tension of a water-absorbing agent are adjusted in a specific range, drying the crushed crosslinked hydrogel polymer, and then adding a liquid permeability enhancer thereto during surface crosslinking or after surface crosslinking.

Three dimensional manufacturing apparatus and method for manufacturing three dimensional manufactured product

A three dimensional manufactured product is manufactured A speed of filing an uncured light curing resin in a space for a next layer is enhanced, to improve a manufacturing speed. One surface of a container housing a light curing resin is configured by a gas-permeable sheet that faces the light curing resin, and transmits irradiation light of a light irradiating apparatus, and a light transmitting plate disposed at an outer side of the container from the gas permeable member. A pressurizing chamber controllable in pressure by a pressure controlling apparatus is defined between the gas-permeable sheet and the light transmitting plate. At moving a manufacturing stage, an inside of the pressurizing chamber is de-pressurized to cause the gas-permeable sheet to perform concave surface deformation, and at a time of performing light irradiation, gas in the pressurizing chamber is caused to permeate into the light curing resin by pressurizing.

Three dimensional manufacturing apparatus and method for manufacturing three dimensional manufactured product

A three dimensional manufactured product is manufactured A speed of filing an uncured light curing resin in a space for a next layer is enhanced, to improve a manufacturing speed. One surface of a container housing a light curing resin is configured by a gas-permeable sheet that faces the light curing resin, and transmits irradiation light of a light irradiating apparatus, and a light transmitting plate disposed at an outer side of the container from the gas permeable member. A pressurizing chamber controllable in pressure by a pressure controlling apparatus is defined between the gas-permeable sheet and the light transmitting plate. At moving a manufacturing stage, an inside of the pressurizing chamber is de-pressurized to cause the gas-permeable sheet to perform concave surface deformation, and at a time of performing light irradiation, gas in the pressurizing chamber is caused to permeate into the light curing resin by pressurizing.

Aqueous polymer emulsion

The present invention relates to an aqueous polymer emulsion comprising at least 30 wt. % of a vinyl copolymer (A), said vinyl copolymer comprising: (I) from 10 to 90 wt. % of 2-octyl acrylate monomer; (II) from 10 to 90 wt. % of at least one itaconate ester monomer according to formula (1) ##STR00001##
in which A and B may be different or the same and A and B are independently an alkyl group or an aryl group; and (III) from 0 to 80 wt. % of ethylenically unsaturated monomer other than (I) and (II); whereby the summed amount of (I), (II) and (III) is 100 wt. % and whereby the amount of vinyl copolymer (A) is given relative to the total weight amount of the polymers present in the emulsion.

Method for the production of absorbent polymer particles by polymerizing drops of a monomer solution

A process for preparing water-absorbing polymer beads by polymerizing droplets comprising at least one monomer in a gas phase surrounding the droplets, the droplets being obtained by enveloping a first monomer solution with a second monomer solution and polymerizing the second monomer solution and polymerizing to give a more highly crosslinked polymer than the first monomer solution.