The present disclosure discloses a high-performance rubber damping material and a method for preparing the same, relating to the technical field of damping materials. The method for preparing the high-performance rubber damping material includes: grafting hydroxyethyl methacrylate and lignin to a rubber molecular chain of natural rubber latex through graft copolymerization reaction, so as to obtain a high-performance rubber damping material. This method adopts natural rubber latex as a base material, the hydroxyethyl methacrylate and lignin are grafted to the rubber molecular chain of natural rubber latex through graft copolymerization reaction, to form a semi-interpenetrating network structure.

The present disclosure discloses a high-performance rubber damping material and a method for preparing the same, relating to the technical field of damping materials. The method for preparing the high-performance rubber damping material includes: grafting hydroxyethyl methacrylate and lignin to a rubber molecular chain of natural rubber latex through graft copolymerization reaction, so as to obtain a high-performance rubber damping material. This method adopts natural rubber latex as a base material, the hydroxyethyl methacrylate and lignin are grafted to the rubber molecular chain of natural rubber latex through graft copolymerization reaction, to form a semi-interpenetrating network structure.

An adhesive sheet in which the adhesive strength of an adhesive layer to other adherends is low, adhesive layers can be firmly bonded to each other, the adhesive layers will not be destroyed even if the adhesive layers are peeled after having once been bonded, and sufficient bonding strength is obtained even if the adhesive layers are re-bonded. An adhesive sheet in which an intermediate layer containing methyl methacrylate-grafted natural rubber is provided on a substrate containing a vinyl chloride resin and a plasticizer, and an adhesive layer including an adhesive containing the plasticizer and a rubber component containing natural rubber and methyl methacrylate-grafted natural rubber is provided on the intermediate layer, wherein a degree of swelling of the rubber component with respect to the plasticizer is by a factor of 1.5 to 4.5.

An adhesive sheet in which the adhesive strength of an adhesive layer to other adherends is low, adhesive layers can be firmly bonded to each other, the adhesive layers will not be destroyed even if the adhesive layers are peeled after having once been bonded, and sufficient bonding strength is obtained even if the adhesive layers are re-bonded. An adhesive sheet in which an intermediate layer containing methyl methacrylate-grafted natural rubber is provided on a substrate containing a vinyl chloride resin and a plasticizer, and an adhesive layer including an adhesive containing the plasticizer and a rubber component containing natural rubber and methyl methacrylate-grafted natural rubber is provided on the intermediate layer, wherein a degree of swelling of the rubber component with respect to the plasticizer is by a factor of 1.5 to 4.5.

Provided is a method of preparing a graft polymer, which includes: adding a diene-based rubber polymer, a first monomer mixture including a (meth)acrylate-based monomer and an aromatic vinyl-based monomer, and a reactive ultraviolet (UV) stabilizer to a reactor and carrying out polymerization to prepare a composite rubber polymer; and graft-polymerizing a second monomer mixture including a (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyanide-based monomer to the composite rubber polymer to prepare a graft polymer, wherein the reactive UV stabilizer is added in an amount of 0.1 to 2 parts by weight based on 100 parts by weight of the sum of the diene-based rubber polymer, the first monomer mixture, and the second monomer mixture.

Provided is a method of preparing a graft polymer, which includes: adding a diene-based rubber polymer, a first monomer mixture including a (meth)acrylate-based monomer and an aromatic vinyl-based monomer, and a reactive ultraviolet (UV) stabilizer to a reactor and carrying out polymerization to prepare a composite rubber polymer; and graft-polymerizing a second monomer mixture including a (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyanide-based monomer to the composite rubber polymer to prepare a graft polymer, wherein the reactive UV stabilizer is added in an amount of 0.1 to 2 parts by weight based on 100 parts by weight of the sum of the diene-based rubber polymer, the first monomer mixture, and the second monomer mixture.

A toner having a toner particle containing a binder resin and a styrene-acrylic resin, the toner being characterized in that the styrene-acrylic resin is a graft polymer having an aliphatic hydrocarbon compound segment and a styrene-acrylic segment, the styrene-acrylic segment has a specific monomer unit, the melting point of the styrene-acrylic segment is from 30° C. to 80° C., and when the toner is measured using a FT-IR ATR method, the intensity assigned to the styrene-acrylic resin and the intensity assigned to the binder resin satisfy a specific relationship.

A toner having a toner particle containing a binder resin and a styrene-acrylic resin, the toner being characterized in that the styrene-acrylic resin is a graft polymer having an aliphatic hydrocarbon compound segment and a styrene-acrylic segment, the styrene-acrylic segment has a specific monomer unit, the melting point of the styrene-acrylic segment is from 30° C. to 80° C., and when the toner is measured using a FT-IR ATR method, the intensity assigned to the styrene-acrylic resin and the intensity assigned to the binder resin satisfy a specific relationship.

The invention relates to an aqueous polymer dispersion which comprises: a) an aqueous polymer dispersion comprising grafted rubber polymeric particles from rubber polymer being selected from natural or synthetic rubber, b) an aqueous polymer dispersion with polymeric particles of a second polymer comprising monomeric units derived from a monomeric composition b) comprising: b1) a (meth)acrylate of a linear or branched alcohol in C.sub.4 to C.sub.10 or a mixture of such (meth)acrylates, said (meth)acrylate having Tg.sub.b1 lower than −30° C., b2) optionally, at least one comonomer having Tg.sub.b2 higher than −30° C.,

with said grafted rubber polymeric particles being grafted in an aqueous dispersion by a part of said monomeric composition b) as defined above. The invention covers also a specific process of preparation of said dispersion, an adhesive composition comprising said dispersion, the use of said dispersion in pressure sensitive adhesives and the resulting adhesive.

The invention relates to an aqueous polymer dispersion which comprises: a) an aqueous polymer dispersion comprising grafted rubber polymeric particles from rubber polymer being selected from natural or synthetic rubber, b) an aqueous polymer dispersion with polymeric particles of a second polymer comprising monomeric units derived from a monomeric composition b) comprising: b1) a (meth)acrylate of a linear or branched alcohol in C.sub.4 to C.sub.10 or a mixture of such (meth)acrylates, said (meth)acrylate having Tg.sub.b1 lower than −30° C., b2) optionally, at least one comonomer having Tg.sub.b2 higher than −30° C.,

with said grafted rubber polymeric particles being grafted in an aqueous dispersion by a part of said monomeric composition b) as defined above. The invention covers also a specific process of preparation of said dispersion, an adhesive composition comprising said dispersion, the use of said dispersion in pressure sensitive adhesives and the resulting adhesive.