The invention contemplates certain polyethers, polyether derivatives, and methods of making and using those same polymers. For example, the starting materials can, e.g., citronellol, prenol, isocitronellol and isoprenol.

The invention contemplates certain polyethers, polyether derivatives, and methods of making and using those same polymers. For example, the starting materials can, e.g., citronellol, prenol, isocitronellol and isoprenol.

A novel polyol compound represented by Formula (I) is provided. A polyurethane-based adhesive composition comprising the polyol compound can produce an adhesive layer exhibiting superior bond strength and heat seal strength which will not be substantially deteriorated by the change in the weight ratio between isocyanate component and polyol component. Methods for preparing the polyol compound and for preparing the adhesive composition, as well as a laminate article prepared with said adhesive composition are also provided.

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A novel polyol compound represented by Formula (I) is provided. A polyurethane-based adhesive composition comprising the polyol compound can produce an adhesive layer exhibiting superior bond strength and heat seal strength which will not be substantially deteriorated by the change in the weight ratio between isocyanate component and polyol component. Methods for preparing the polyol compound and for preparing the adhesive composition, as well as a laminate article prepared with said adhesive composition are also provided.

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Provided are a system and a method for preparing a polyether amine by catalytic amination of a polyether diol. The preparation method includes: filling a catalyst into the fixed bed reactor; pressurizing the internal pressure of the fixed bed reactor to 10˜13 MPa by a hydrogen gas, and raising the temperature of the fixed bed reactor to 150˜185° C.; adjusting the temperature of the multi-stage preheater so that the feeding temperature of a raw material reaches 125˜135° C.; and simultaneously feeding a polyether diol, liquid ammonia and the hydrogen gas into the multi-stage preheater, and after mixing and preheating, introducing into the fixed bed reactor from the feed inlet of the fixed bed reactor for a continuous catalytic amination reaction. The total amine value of the polyether amine finally obtained by the present invention reaches 28˜32 mgKOH/g, the color reaches 10˜20, and it is colorless transparent liquid.

Provided are a system and a method for preparing a polyether amine by catalytic amination of a polyether diol. The preparation method includes: filling a catalyst into the fixed bed reactor; pressurizing the internal pressure of the fixed bed reactor to 10˜13 MPa by a hydrogen gas, and raising the temperature of the fixed bed reactor to 150˜185° C.; adjusting the temperature of the multi-stage preheater so that the feeding temperature of a raw material reaches 125˜135° C.; and simultaneously feeding a polyether diol, liquid ammonia and the hydrogen gas into the multi-stage preheater, and after mixing and preheating, introducing into the fixed bed reactor from the feed inlet of the fixed bed reactor for a continuous catalytic amination reaction. The total amine value of the polyether amine finally obtained by the present invention reaches 28˜32 mgKOH/g, the color reaches 10˜20, and it is colorless transparent liquid.

A fluorine-containing ether compound represented by R.sup.1—R.sup.2—CH.sub.2—R.sup.3—CH.sub.2—R.sup.4—R.sup.5 is provided. (R.sup.3 is a perfluoropolyether chain; R.sup.1 and R.sup.5 are each independently any one of an alkyl group that may have a substituent, an organic group having at least one double bond or at least one triple bond, and a hydrogen atom; and —R.sup.2—CH.sub.2—R.sup.3 is represented by Formula (2), and R.sup.3—CH.sub.2—R.sup.4— is represented by Formula (3))
-[A]-[B]—O—CH.sub.2—R.sup.3  (2)
R.sup.3—CH.sub.2—O—[C]-[D]-  (3)
([A] is represented by Formula (4), [B] is represented by Formula (5), [C] is represented by Formula (6), [D] is represented by Formula (7), and in the formula, a and b are integers of 0 to 2, c is an integer of 2 to 5, d and f are integers of 0 to 2, and e is an integer of 2 to 5, and at least one of b and d in the formula is 1 or more) ##STR00001##

Disclosed are chemical products useful for crude oil conditioning, particularly to demulsifying basic compounds. Disclosed are PEO.sub.w-PPO.sub.y-PEO.sub.w triblock bipolymers, with amphoteric groups, β-amino acid derivatives, at the chain ends, which destabilize water-in-crude oil (W/O) emulsions, thereby removing emulsified water and salts dissolved salts in the aforementioned phase.

A fluoropolyether-containing polymer-modified silane having a hydroxyl group protected with a carbonyl, sulfonyl or phosphoryl group may be synthesized without forming by-products.

Disclosed are a multifunctionalized polyethylene glycol derivative and a preparation method therefor. The derivative has an H-shaped structure as represented by formula (1) and comprises one linear core LPEG and four PEG branch chains, where n.sub.1, n.sub.2, n.sub.3, and n.sub.4 respectively are the degrees of polymerization of the branch chains, U.sub.1 and U.sub.2 are trivalent branching groups connecting the core LPEG to two of the PEG branch chains, F.sub.1 and F.sub.2 contain a functional group or a protected form R.sub.01 thereof and may or may not contain a branched group G, correspondingly, the number of R.sub.01 is one or more, F.sub.1 and F.sub.2 are either identical or different, any one linking group in the molecule or any linking group formed with an adjacent heteroatom group can either remain stable or be degraded, and any one PEG segment in the molecule is discretely polydispersed or monodispersed. The multifunctional polyethylene glycol is flexible and diverse in terms of branch structures and the lengths of branching arms, has various parameters and performance indicators that are adjustable and easy to control, and has a broad applicability.