The invention relates to cross-linkable thermoplastics, processes of making such cross-linkable thermoplastics and products comprising such cross-linkable thermoplastics. Such cross-linkable thermoplastics provide articles made by the additive manufacturing (AM) process with increased strength, the desired in use temperature stability and the desired thermo-oxidative stability.

A process to prepare a (iv) cyclic polyester oligomer composition includes a cyclic polyester oligomer having furanic units and two to five repeat units. The process includes (a) reacting a monomer composition including: (i) a bifunctional furan-derivative and (ii) a diol in an linear oligomerization step to produce a (iii) linear oligomer composition including a linear oligomer species, (b) reacting the (iii) linear oligomer composition in a distillation-assisted cyclization (DA-C) step to form a (iv) cyclic polyester oligomer composition and a (v) diol byproduct. The (v) diol byproduct is removed by evaporation in the distillation-assisted cyclization (DA-C) step.

A method for making oligomers is described. The method includes reacting a polyol with a precursor having mixed functionality. The precursor includes a curable functional group and an isocyanate group capable of reacting with an alcohol group of the polyol. The precursor reacts with the alcohol group of the polyol to form a urethane linkage and to add a covalently bonded curable functional group to the polyol. The oligomers can be included in coating compositions for optical fiber and lead to coatings having improved tear strength.

A method of producing an oligomer or polymer with carbonate segment chemical structure, the method including the steps of (1) introducing into a reactor high-molecular-weight polyester and reactive oligomer; (2) introducing into the reactor a carbonate compound and a catalyst such that the poly(polyol) reacts with the carbonate monomers by one-pot in situ to produce a crude product; and (3) introducing the crude product into water to obtain an oligomer or polymer with carbonate segment chemical structure. The oligomer or polymer with carbonate segment chemical structure is applicable to automobile manufacturing, wires & cables, and medical equipment.

The invention relates to bis(aniline) compounds containing multiple arylethynyl, alkylethynyl, ethynyl groups or their combinations, processes of making such compounds and materials comprising such compounds. Such, bis(aniline) compounds preferably comprise multiple phenylethynyl (PE) groups, i.e. 2-4 PE moieties. Such compounds are useful monomers for the preparation of polyimides, polyamides and poly(amide-imides) whose post-fabrication crosslinking chemistry (i.e. reaction temperature) can be controlled by the number of PE per repeat unit as well as finding utility in thermosetting matrix resins, 3D printable resins, and as high-carbon-content precursors to carbon-carbon composites.

Provided is a polyorganosiloxane, wherein a value obtained by integrating dw/d log(M) from 2.5log(M)3.1 is 0 to 10% of a value obtained by integrating dw/d log(M) over the entire range of log (M) in a differential molecular weight distribution curve, wherein the differential molecular weight distribution curve is determined by gel permeation chromatography using the polystyrene calibration curve, has an x-axis showing a logarithmic value log(M) of a molecular weight M and has a y-axis showing dw/d log(M) obtained by differentiating a concentration fraction w with respect to the logarithmic value log(M) of the molecular weight.

The invention relates to poly(oligo(ethylene glycol) methacrylate) microgels, to the process for preparing same and the uses thereof in various fields of application such as optics, electronics, pharmacy and cosmetics.

These microgels have the advantage of being monodisperse, pH-responsive and temperature-responsive. They can carry magnetic nanoparticles or biologically active molecules. These microgels may also form transparent films, which have novel optical and electromechanical properties.

A method of producing an oligomer or polymer with carbonate segment chemical structure, the method including the steps of (1) introducing into a reactor high-molecular-weight polyester and reactive oligomer; (2) introducing into the reactor a carbonate compound and a catalyst such that the poly(polyol) reacts with the carbonate monomers by one-pot in situ to produce a crude product; and (3) introducing the crude product into water to obtain an oligomer or polymer with carbonate segment chemical structure. The oligomer or polymer with carbonate segment chemical structure is applicable to automobile manufacturing, wires & cables, and medical equipment.

The invention relates to poly(oligo(ethylene glycol) methacrylate) microgels, to the process for preparing same and the uses thereof in various fields of application such as optics, electronics, pharmacy and cosmetics. These microgels have the advantage of being monodisperse, pH-responsive and temperature-responsive. They can carry magnetic nanoparticles or biologically active molecules. These microgels may also form transparent films, which have novel optical and electromechanical properties.

A process for producing polycarbonate comprising: a) contacting a dialkyl carbonate with a dihydroxy compound in an oligomerization zone in the presence of an oligomerization catalyst under oligomerization conditions to form a first intermediate; and b) contacting the first intermediate with a diaryl carbonate in a polymerization zone in the presence of a polymerization catalyst under polymerization conditions to produce the polycarbonate wherein the molar ratio of dihydroxy compound to dialkyl carbonate in the oligomerization zone is at least 2:1.