Patent classifications
C08G2190/00
Liquid hydrocarbon-based copolymers bearing two cyclocarbonate ester end groups
1) Hydrocarbon-based copolymer comprising two end groups preceded by an ester function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, an exo-vinylene cyclocarbonate and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II) ##STR00001## in which R.sup.0 is notably a methyl radical; and the number-average molecular mass Mn of which is between 400 and 100 000 g/mol. 2) Process for preparing said copolymer, comprising: (i) a step of heating a statistical bipolymer A chosen from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and then (ii) a step of heating the product formed, in the presence of a chain-transfer agent. 3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.
Liquid copolymer formed by ring-opening copolymerization of cyclopentene, crosslinkable composition, and crosslinked rubber object
A liquid cyclopentene ring-opened copolymer includes a monomer unit derived from cyclopentene and a monomer unit derived from a norbornene compound, the monomer unit derived from cyclopentene being present in an amount of 60 to 95 wt %, the liquid cyclopentene ring-opened copolymer having a hydroxyl group-terminated copolymer chain and having a melt viscosity at 25° C. of less than 500 Pa.Math.s, which is measured using a B-type viscometer.
SILICONE-POLYETHER COPOLYMER COMPOSITION, METHOD OF PREPARING SAME, AND SEALANT
A silicone-polyether copolymer has the formula (X-D.sup.2).sub.g-Y, where each X is an independently selected silicone moiety having a particular structure, D.sup.2 is a divalent hydrocarbon group, subscript g is greater than 1, and Y is a linear or branched polyether moiety. A method of preparing the silicone-polyether copolymer comprising reacting a polyether compound and an organosilicon compound in the presence of a hydrosilylation-reaction catalyst. A sealant is also disclosed, the sealant comprising the silicone-polyether copolymer and a condensation-reaction catalyst.
Continuous Production Device and Method for Silane-Modified Sealing Material
A continuous production device and method for a silane-modified sealing material are provided. The device includes a twin screw extruder set, a cooling unit, and a static mixing unit; where the twin screw extruder set includes at least two twin screw extruders in series, each of which is provided with at least two inlets and at least one vacuum port, the cooling unit is disposed between last two stages of the twin screw extruders, and an outlet of a last-stage twin screw extruder is connected to the static mixing unit. Through the arrangement of various units of the device and their positional relations, components can be mixed in sequence or added in stages, so as to adapt to the characteristics of each component; a heat stabilizer and a polymer are added together as raw materials, which can increase the temperature for dehydration and avoid thermal decomposition of the polymer, and they cooperate with a dehydrant to make water in the system easier to remove; and the device has high operation flexibility and can adapt to the requirement of variability of a formulation of the silane-modified sealing material.
Liquid hydrocarbon copolymers having two cyclocarbonate ether end groups
1) Hydrocarbon-based copolymer comprising two end groups preceded by an ether function and chosen from a 2-oxo-1,3-dioxolan-4-yl (or cyclocarbonate), a dithiocyclocarbonate, and a 2-oxo-1,3-dioxolen-4-yl, the main chain of which comprises units (I) and (II) ##STR00001## in which R.sup.0 is notably a methyl radical; and the number-average molecular mass Mn of which is between 400 and 100 000 g/mol. 2) Process for preparing said copolymer, comprising: (i) a step of heating a statistical bipolymer A chosen from a poly(butadiene-isoprene), a poly(butadiene-myrcene) and a poly(butadiene-farnesene); and then (ii) a step of heating the product formed, in the presence of a chain-transfer agent. 3) Use as adhesive, as a mixture with an amine compound comprising at least two amine groups.
Polyurethane-based binder system
A binder system, containing a special polyol mixture as a resin component, said polyol mixture containing at least one polyester based on a fatty acid dimer, a fatty acid trimer or the alcohols derived therefrom, and at least one polyisocyanates as a resin component and/or a NCO-terminated polyurethane prepolymer. The binder system can be used as an adhesive/sealing material, in particular as an adhesive for gluing various substrates.
SILICONE-POLYCARBONATE COPOLYMER, SEALANTS COMPRISING SAME, AND RELATED METHODS
A silicone-polycarbonate copolymer has the formula X.sub.g[Z.sub.jY.sub.o].sub.c, where each X is an independently selected silicone moiety having a particular structure, each Y is an independently selected polycarbonate moiety, each Z is an independently selected siloxane moiety, subscript c is from 1 to 150, subscript g is >1, 0≤j<2, and 0<o<2, with the proviso that j+o=2 in each moiety indicated by subscript c. Methods of preparing the silicone-polycarbonate copolymer are also disclosed. Further, a sealant is disclosed, the sealant comprising the silicone-polycarbonate copolymer and a condensation-reaction catalyst.
Method for producing a biopolyether polyol, biopolyether polyol, and biopolyurethane resin
The present invention relates to a method for producing a biopolyether polyol, which is a copolymerization reaction of tetrahydrofuran and 2-methyltetrahydrofuran in a monomer ratio (by mass) of 85/15 to 50/50, and the resulting polyether polyol of 100% plant origin having a number-average molecular weight of 500-5000. In addition, a polyurethane resin, which is the product of a synthetic reaction having as the main reactants the above polyether polyol of 100% plant origin, a polyisocyanate compound, and a chain extender that reacts with isocyanate groups, has a change in storage modulus (E′) in the low temperature range (0° C.) with respect to normal temperature (20° C.) of within 0-15%.
ADHESIVE COMPOSITION
A two-component solventless polyurethane adhesive composition including (A) at least one isocyanate component and (B) at least one polyol component. The isocyanate component (A) comprises an isocyanate prepolymer that is the reaction product of (Ai) a polyisocyanate and (Aii) an isocyanate-reactive component; wherein the isocyanate-reactive component comprises (Aiia) at least one polyol having a functionality greater than two, (Aiib) at least one aromatic polyester polyol having a functionality of greater than two, and (Aiic) at least one hydrophobic polyol. The polyol component (B) comprises (Bi) at least one polyether polyol having a functionality greater than two, (Bii) at least one aromatic polyester polyol transesterified with a natural oil, and (Biii) at least one phosphate ester polyol. A method for forming a laminate is also disclosed, the method comprising the steps of: (I) mixing the above reactants (components (A) and (B)) to form a solventless adhesive composition, (II) applying a layer of the solventless adhesive composition to a surface of a first substrate, (III) bringing the layer of the solventless adhesive composition on the first substrate into contact with a surface of a second substrate to form a laminate, and (IV) curing the solventless adhesive composition. A laminate comprising the above solventless adhesive composition is also disclosed.
Compositions using polyuretdione resins
The present invention provides a reaction mixture comprising a hot blend of a first isocyanate-based uretdione resin and a second isocyanate-based uretdione resin, a neutralized polyol and a tertiary amine catalyst, and optionally, an additive package selected from the group consisting of flow control additives, pigments (colorants), wetting agents, and solvents, wherein the first isocyanate and the second isocyanate are different. The isocyanate-based uretdiones that have been hot blended together produce coatings, adhesives, castings, composites, and sealants, which exhibit better performance properties (such as microhardness) than those coatings, adhesives, castings, composites, and sealants produced from the constituent isocyanate-based uretdiones alone.