Patent classifications
C08G2340/00
Polypropylene backbone, and nanoporous polypropylene membrane
The invention relates to a film Film comprising a random graft copolymer having a polypropylene (PP) backbone and from 3 to 8 polyester segments covalently bonded to said backbone, wherein the number average molecular weight (Mn) of the polypropylene backbone ranges between 10.000 and 100.000 Dalton (as determined with HT-SEC in o-DCB at 150 C.), wherein the Mn of each polyester segment ranges between 5.000 and 25.000 Daltons, wherein the amount of PP ranges between 45 and 80 mol %, wherein the amount of polyester segments ranges between 55 and 20 mol %, wherein the film has a thickness in the range of 0.01-10 mm, wherein the polypropylene and polyester domains form independently continuous phases, and wherein the mol % is calculated relative to the total moles of monomer units present in the copolymer. The invention further relates to a nano porous PP membrane and its use.
SEPARATION FUNCTIONAL LAYER, SEPARATION MEMBRANE, AND METHOD FOR MANUFACTURING SEPARATION FUNCTIONAL LAYER
The present invention provides a new separation functional layer suitable for separating an acid gas from a gas mixture containing the acid gas. A separation functional layer of the present invention includes polyimide. The polyimide includes a structural unit A1 derived from a tetracarboxylic dianhydride having a six-membered ring acid anhydride structure, and a structural unit B1 derived from diamine. At least one of the structural unit A1 and the structural unit B1 has at least one functional group selected from the group consisting of a carboxyl group, a hydroxyl group, a thiol group, and metal salts of these groups.
BLENDED MEMBRANES FOR WATER VAPOR TRANSPORT AND METHODS FOR PREPARING SAME
Water vapor transport membranes for ERV and other water vapor transport applications are provided. The membranes include a substrate and an air impermeable selective layer coated on the substrate, the selective layer including a cellulose derivative and a sulfonated polyaryletherketone. In some embodiments the sulfonated polyaryletherketone is in a cation form and/or the selective layer includes s PEEK and CA in an s PEEK:CA (wt.:wt.) ratio in the range of about 7:3 to 2:3. Methods for making such membranes are provided. The methods include applying a coating solution/dispersion to a substrate and allowing the coating solution/dispersion to dry to form an air impermeable selective layer on the substrate, the coating solution/dispersion including a cellulose derivative and a sulfonated polyarylether ketone. In some embodiments the sulfonated polyaryletherketone is in a cation form and/or the coating solution/dispersion includes s PEEK and CA in an sPEEK:CA (wt.:wt.) ratio in the range of about 7:3 to 2:3.
FUNCTIONALIZED POLY(ARYL ETHER SULFONE) COPOLYMERS
The invention relates to a side-chain functionalized poly(aryl ether sulfone) (PAES) copolymer (P1), to the process for preparing the copolymer (P1), and to its use in the preparation of a membrane, a composite material or a coating. The copolymer (P1) comprises PAES recurring units (R.sub.P1) and PAES side-chain functionalized recurring units (R*.sub.P1).
Polymeric matrices formed from monomers comprising a protected amine group
The present disclosure relates to polymeric matrices composed of protected amine compound residues and membranes composed from such polymeric matrices. In particular, the present disclosure relates to a polymeric matrix comprising amine compound residues, acyl compound residues and protected amine compound residues.
Sulfur scavenging materials for filters and coatings
Materials which react with (scavenge) sulfur compounds, such as hydrogen sulfide and mercaptans, are used to limit sulfur-induced corrosion. Filters and protective coatings including these materials, described broadly as polyhexahydrotriazines (PHT) and polyhemiaminals (PHA), are disclosed. Methods of using these materials to prevent corrosion are described. PHT and PHA materials have excellent thermal and mechanical properties for many applications as coatings and filtration media. Specifically, PHT and PHA materials react with sulfur compounds in such a manner as to incorporate sulfur atoms into the polymeric matrix, thus sequestering the sulfur atoms and allowing removal from fluids such as crude oil, natural gas, hydrocarbon combustion exhaust gases, sulfur polluted air and water. A coating PHT or PHA material on a component to be protected similarly reacts with sulfur compounds prior to sulfur being able to penetrate to the component.
NEW COPOLYMERS SUITABLE FOR MAKING MEMBRANES
Copolymer comprising polyarylene ether blocks and hydrophilic-hydrophobic blocks, wherein said hydrophilic-hydrophobic blocks comprise polyisobutene blocks.
Sulfur scavenging materials for filters and coatings
Materials which react with (scavenge) sulfur compounds, such as hydrogen sulfide and mercaptans, are used to limit sulfur-induced corrosion. Filters and protective coatings including these materials, described broadly as polyhexahydrotriazines (PHT) and polyhemiaminals (PHA), are disclosed. Methods of using these materials to prevent corrosion are described. PHT and PHA materials have excellent thermal and mechanical properties for many applications as coatings and filtration media. Specifically, PHT and PHA materials react with sulfur compounds in such a manner as to incorporate sulfur atoms into the polymeric matrix, thus sequestering the sulfur atoms and allowing removal from fluids such as crude oil, natural gas, hydrocarbon combustion exhaust gases, sulfur polluted air and water. A coating PHT or PHA material on a component to be protected similarly reacts with sulfur compounds prior to sulfur being able to penetrate to the component.
METHOD OF MAKING SULFONATED POLYPHENYLENES
Described herein is a method for making sulfonated polyphenylene polymers and the uses thereof. Such sulfonated polyphenylene polymers, and membranes prepared therefrom, have applications in fuel cells, water electrolyzers, water purification, battery products, and other electrochemical devices.
Polyurethane resin-forming composition for membrane-sealing material, and membrane and membrane module using same
Provided is a polyurethane resin-forming composition for a membrane-sealing material, the polyurethane resin-forming composition contributing to formation of (1) a urethane resin that is excellent in moldability, has a suppressed elution amount of a low-molecular-weight reaction product, and has excellent appearance or (2) a urethane resin that has a low viscosity, is excellent in cast moldability, and has a reduced water elution amount of a low-molecular-weight reaction product and a reduced solvent elution amount of a molded product. The polyurethane resin-forming composition for a membrane-sealing material comprises: a polyisocyanate prepolymer (A) or an allophanate group-containing polyisocyanate prepolymer (A) comprising a reaction product of a diphenylmethane diisocyanate (a1-1) and/or a modified product of a diphenylmethane diisocyanate (a1-2), and an active hydrogen-containing compound (a2); and a castor oil polymerized polyol (b1) comprising a castor oil polymerization product.