Patent classifications
C08J3/00
Bimodal high-density polyethylene resins and compositions with improved properties and methods of making and using the same
Bimodal high-density polyethylene polymer compositions with increased high melt strength and good processability. The compositions comprise a base resin having a density of about 945 kg/m.sup.3 to about 955 kg/m.sup.3, and an ethylene polymer (A) having a density of at least about 968 kg/m.sup.3, in an amount ranging from 45% to 55% by weight and an ethylene polymer (B) having a density lower than the density of polymer (A). The composition has a complex viscosity at a shear rate of 0.01 rad/s ranging from about 200 to 450 kPa.Math.s and a complex viscosity at a shear rate of 100 rad/s ranging from about 1900 to 2500 Pa.Math.s. Articles made from these compositions, such as pipes and fittings achieve long-term oxidative resistance and have a low wall thickness variability while maintaining high production output.
Artificial timber
An artificial timber comprises the following components in parts by weight: 35-50 parts of cellulose, 20-35 parts of hemicellulose and 15-35 parts of lignin, wherein the artificial timber has a density of 0.01-0.05 g/cm.sup.3. The preparing method comprises: (1) dissolving 15-35 parts by weight of lignin, 35-50 parts by weight of cellulose and 20-35 parts by weight of hemicellulose with an ionic liquid; (2) cleaning and replacing it with water to obtain a lignocellulose hydrogel; and (3) drying the lignocellulose hydrogel to obtain an artificial timber. The artificial timber prepared by the present invention is large in specific area, low in density, low in material energy consumption, moderate in condition and easy for operation. The artificial timber obtained by the present invention is regular in shape and is shaped like a sandy beige cylinder without obvious damage and deformation, which indicates that such artificial timber with high specific area has well molding capacity.
Thermoplastic resin composition, method of producing thermoplastic resin composition, molded article of cellulose-reinforced resin, and method of producing molded article of cellulose-reinforced resin
A method of producing a thermoplastic resin composition containing a thermoplastic synthetic resin and a cellulose, in which at least one type of the thermoplastic synthetic resin is a resin having a group containing a partial structure of an acid anhydride in the polymer molecule; a molded article of a cellulose-reinforced resin; and a method of producing a molded article of a cellulose-reinforced resin.
Cellulose based composition
The present invention concerns a cellulose based composition for manufacturing a film or foil, which composition comprises at least one selected from the group consisting of cellulose acetate butyrate, cellulose acetate propionate and ethyl cellulose, together with tall oil fatty acid ester, as well as a manufacturing method thereof. The invention also concerns packaging film comprising the composition and use of the composition.
Ethylene-based polymer, method of producing ethylene-based polymer, and film
Provided are an ethylene-based polymer capable of obtaining a film in which thickness unevenness is reduced, a method of producing the ethylene-based polymer, and a film containing the ethylene-based polymer. In the ethylene-based polymer according to the present invention, the following Expressions (1) and (2) are satisfied:
0.362≤ηL.sup.1,256%/ηL.sup.10%≤0.466 (1)
0.0282≤I5.sup.2,506%/I1.sup.2,506%≤0.0328 (2).
Bio-based UV-curable 3D printed resin and preparation method thereof
A bio-based UV-curable 3D printed resin includes the following components by weight percentage: 19-78% of biodegradable starch resin polymer, 1-9% of radical initiator, 0.2-4% of adjuvant, 13-62% of reactive diluent and 2-8% hydroxyethyl starch. The preparation method thereof comprises the following steps of: mixing the above components by component proportion, ultrasonically washing the mixture for 10-20 min by an ultrasonic cleaner under a water temperature of 50° C., and then mixing the same in a homogenizer homogeneously to obtain the bio-based UV-curable 3D printed resin. The renewable resources are adopted and the environmental pollution and energy consumption are reduced, which is of bio-safety. Moreover, the hydroxyethyl starch has a high molecular compound generated by hydroxyethylation of glucose ring of amylose, resulting in various benefits. The 3D printed resin obtained has excellent performance and low skin irritation value.
CROSSLINKED OLEFIN-BASED THERMOPLASTIC ELASTOMER EXPANDED BEAD AND METHOD FOR PRODUCING SAME
A crosslinked olefin-based thermoplastic elastomer expanded bead including a base polymer having an olefin-based thermoplastic elastomer and a brominated bisphenol-based flame retardant having a chemical structure represented by formula (1). A difference Tm.sub.TPO-T.sub.FR is −5° C. to 40° C., where Tm.sub.TPO is a melting point of the olefin-based thermoplastic elastomer and T.sub.FR is the lower of a glass transition temperature T.sub.gFR and a melting point Tm.sub.FR of the brominated bisphenol-based flame retardant. A xylene insoluble content is 5 mass % to 80 mass %. R.sup.1 and R.sup.3 in the formula (1) are monovalent substituents, R.sup.2 is a divalent substituent, and n is an integer from 1 to 6:
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Polyolefin based compositions modified by silanes
A thermoplastic polyolefin composition which is capable of being shaped and repeatedly recycled, comprises propylene-based polymers, said composition being modified with 0.01-5 wt % of organic oligomeric silanes selected from partially hydrolyzed alkoxy substituted vinyl, allyl or methacryl silanes, and blends thereof, and 0.0005-0.5 wt % of a compound capable of generating free radicals.
LEAD-FREE THREE-COMPONENT PIEZOELECTRIC POLYMER COMPOSITE
A polymer composite exhibiting piezoelectric properties can be formed for flexible and/or thin film applications, in which the polymer composite includes a polymer matrix and a piezoelectric ceramic filler embedded in the polymer matrix. The polymer matrix may include at least two polymers: a first polymer and a second polymer. The first polymer may be a fluorinated polymer, and the second polymer may be compatible with the first polymer and have a dielectric constant of less than approximately 20. The piezoelectric ceramic filler may be a lead-free ceramic filler, such as barium titanate, and be approximately 40-70% by volume of the polymer composite. The remaining 30-60% by volume may be the polymer matrix, which may itself be approximately 5-20% by weight second polymer and 80-95% fluorinated polymer.
CHITOSAN-POLYACRYLAMIDE COMPOSITE POROUS HYDROGEL, PREPARATION AND USE THEREOF, AND METAL ION-DETECTING REAGENT AND METHOD
The present application relates to the technical field of wastewater treatment and rapid pollutant detection, in particular to a chitosan-polyacrylamide composite porous hydrogel, preparation and use thereof, and a metal ion-adsorbing and detecting reagent and method. The chitosan-polyacrylamide composite porous hydrogel of the present application is prepared by in situ polymerization of a chitosan sol, an acrylamide, a crosslinking agent and a surfactant into a mixed solution comprising liquid droplets, followed by steps of curing, washing, and freeze-drying. The present application further provides a metal ion-detecting reagent, which is obtained by adsorbing a color developing agent into the chitosan-polyacrylamide composite porous hydrogel as described above, wherein the color developing agent is a dye that changes color when encountering metal ions. The chitosan-polyacrylamide composite porous hydrogel of the present application has balanced mechanical properties and porosity.