A multi-stage flexible acrylic resin comprises a branched polymer which is a reaction product of reactants comprising one or more monoethylenically unsaturated ester monomers, a chain transfer agent in an amount of 0.1 to 10 wt. %, and a crosslinker in an amount of 0.1 to 10 wt. %, wherein wt. % is based on total amount of reactants, provided the amount of crosslinker in moles is less than the amount of chain transfer agent in moles. A process for producing the multi-stage flexible acrylic resin is also disclosed.

Provided are a method of preparing a graft copolymer, a graft copolymer, and a thermoplastic resin molded article including the graft copolymer, the method including: 1) preparing a seed by adding one or more selected from the group consisting of an alkyl (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a vinyl cyan-based monomer and performing polymerization; 2) in the presence of the seed, preparing a core by adding an alkyl (meth)acrylate-based monomer and performing polymerization; and 3) in the presence of the core, preparing a shell by adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer and performing polymerization, wherein the method further includes adding an alkyl acrylate-based polymer. When the alkyl acrylate-based polymer is included in a graft copolymer, a graft copolymer and a thermoplastic resin molded article excellent in weather resistance, fluidity, mechanical properties, and appearance quality can be provided.

A resin composition that contains: (A) a bio-polyethylene resin; (B) an ethylene-vinyl alcohol copolymer having an ethylene content of 20 to 60 mol %; and (C) at least one component selected from the group consisting of an ethylene-vinyl acetate copolymer, an acid-modified ethylene-α-olefin copolymer, an ethylene-unsaturated monocarboxylic acid copolymer, an ionomer of the ethylene-unsaturated monocarboxylic acid copolymer, an ethylene-vinyl alcohol copolymer having an ethylene content of 70 to 90 mol %, and a hydrotalcite compound. The resin composition employs a bio-polyethylene resin and yet can suppress gumming and provide a formed product having an excellent appearance.

A resin composition that contains: (A) a bio-polyethylene resin; (B) an ethylene-vinyl alcohol copolymer having an ethylene content of 20 to 60 mol %; and (C) at least one component selected from the group consisting of an ethylene-vinyl acetate copolymer, an acid-modified ethylene-α-olefin copolymer, an ethylene-unsaturated monocarboxylic acid copolymer, an ionomer of the ethylene-unsaturated monocarboxylic acid copolymer, an ethylene-vinyl alcohol copolymer having an ethylene content of 70 to 90 mol %, and a hydrotalcite compound. The resin composition employs a bio-polyethylene resin and yet can suppress gumming and provide a formed product having an excellent appearance.

The present invention relates to a method for producing a diene-based graft copolymer resin, and a diene-based graft copolymer resin produced therefrom, the method including: mixing an aromatic vinyl-based monomer, a diene-based rubber polymer, and a polymerization initiator to prepare a first reactant; mixing a vinyl cyan-based monomer and an antioxidant to prepare a second reactant; adding and polymerizing the first reactant and the second reactant into a polymerization reactor to prepare a polymer; and removing unreacted monomers in a devolatilization tank.

The present invention relates to a method for producing a diene-based graft copolymer resin, and a diene-based graft copolymer resin produced therefrom, the method including: mixing an aromatic vinyl-based monomer, a diene-based rubber polymer, and a polymerization initiator to prepare a first reactant; mixing a vinyl cyan-based monomer and an antioxidant to prepare a second reactant; adding and polymerizing the first reactant and the second reactant into a polymerization reactor to prepare a polymer; and removing unreacted monomers in a devolatilization tank.

Disclosed is a composition for non-aqueous secondary battery adhesive layer which comprises a particulate polymer and a binder, wherein the particulate polymer comprises 5% to 50% by mass of a (meth)acrylonitrile monomer unit and 0.1% to 3.5% by mass of a cross-linkable monomer unit. Also disclosed is a non-aqueous secondary battery adhesive layer prepared by using the composition for non-aqueous secondary battery adhesive layer. Also disclosed is a laminate which comprises a substrate and the non-aqueous secondary battery adhesive layer disposed on at least one side of the substrate either directly or indirectly through one or more other layers. Also disclosed is a non-aqueous secondary battery wherein at least one of a positive electrode, a negative electrode, and a separator comprises the non-aqueous secondary battery adhesive layer.

Thermoplastic moulding composition consisting of (A) 51 to 69.9 wt % of polyamide elastomer; (B) 15 to 38 wt % of ethylene-α-olefin copolymer; (C) 3 to 25 wt % of polyamide selected from the group consisting of: PA6, PA66, PA6/66, PA610, PA612, PA614, PA616, PA6/610, PA66/610 or mixtures thereof; (D) 0.1 to 2.0 wt % of heat stabilizers based on copper and/or iodide, organic stabilizers or a mixture thereof; (E) 0 to 5.0 wt % of additives, different from (A) to (D);
where the sum of (A) to (E) makes 100 wt % of the total moulding composition, and with the proviso that the sum of (B) and (C) is in the range from 30 to 48 wt % based on the total moulding composition.

A thermoplastic resin composition of the present invention includes 55 to 70% by weight of a non-grafted copolymer (A) containing 65 to 83% by weight of a (meth)acrylic acid alkyl ester compound, 2 to 12% by weight of an N-substituted maleimide compound, 1 to 6% by weight of a vinyl cyanide compound, and 7 to 17% by weight of an aromatic vinyl compound; 20 to 42% by weight of an acrylate-based rubber-aromatic vinyl compound-vinyl cyanide compound graft copolymer (B) containing acrylate-based rubber having an average particle diameter of 50 to 200 nm; and 1 to 15% by weight of an acrylate-based rubber-aromatic vinyl compound-vinyl cyanide compound graft copolymer (C) containing acrylate-based rubber having an average particle diameter of 300 to 600 nm. Within this range, a thermoplastic resin composition having excellent weather resistance, heat resistance, scratch resistance, and colorability.

The present invention relates to a polymeric composition comprising an impact modifier, a processing aid and a mineral filler and its process of preparation and its use. In particular the present invention relates to a polymeric composition comprising an impact modifier, a processing aid and a mineral filler and its use for thermoplastic polymers. More particularly the present invention relates to the process of preparation of polymeric composition comprising an impact modifier, a processing aid and a mineral filler and its use for the transformation and/or processing of thermoplastic polymers.