A resist underlayer film-forming composition including: (A) component: an isopoly or heteropoly acid, or a salt thereof, or a combination thereof; and (B) component: polysiloxan, poly hafnium oxide or zirconium oxide, or a combination thereof, wherein an amount of the (A) component is 0.1 to 85% by mass of a total amount of the (A) component and the (B) component; and polysiloxan is a hydrolysis-condensation product of hydrolyzable silane of Formula (1):
R.sup.1.sub.aR.sup.2.sub.bSi(R.sup.3).sub.4−(a+b)  Formula (1)
and a hydrolyzable silane whose (a+b) is 0 is contained in a proportion of 60 to 85 mol % of a total hydrolyzable silane in Formula (1); the poly hafnium oxide is a hydrolysis-condensation product of hydrolyzable hafnium of Formula (2):
Hf(R.sup.4).sub.4  Formula (2)
and the zirconium oxide is a hydrolysis-condensation product of hydrolyzable zirconium of Formula (3) or Formula (4):
Zr(R.sup.5).sub.4  Formula (3)
ZrO(R.sup.6).sub.2  Formula (4)
or a hydrolysis-condensation product of a combination thereof.

A polymetalloxane is described having a constituent unit represented by the following general formula (1):

##STR00001##

wherein R.sup.1, R.sup.2, R.sup.3, M a, b and m are as defined.

A polymetalloxane is described having a constituent unit represented by the following general formula (1):

##STR00001##

wherein R.sup.1, R.sup.2, R.sup.3, M a, b and m are as defined.

The present invention provides a hydrogel for comprising a biodegradable polyphosphazene polymer, a radiation-sensitive diselenide cross-linker; and one or more payloads releasably loaded within the hydrogel. The present invention further provides methods for radiosensitizing target tissues such as tumors and providing sustained delivery of therapeutics triggered by irradiation. In another aspect, the present invention provides a method that includes: introducing the hydrogel, as describes herein, adjacent to malignant or marginal tissue; and administering radiation to the hydrogel, thereby disrupting the selenocystamine cross-linkers and releasing the one or more payloads.

A composition providing a copper-carboxylic acid complex, the copper-carboxylic acid complex having a molar ratio of copper (Cu) to carboxylic acid that is between 1:0.1 and 1:1.5; and an asphalt composition. A method for scavenging hydrogen sulfide from asphalt, the method providing a composition comprising a copper-carboxylic acid complex having a molar ratio of copper (Cu) to carboxylic acid of the copper-carboxylic acid complex is between 1:0.1 and 1:1.5; and adding the composition to an asphalt composition.

A composition providing a copper-carboxylic acid complex, the copper-carboxylic acid complex having a molar ratio of copper (Cu) to carboxylic acid that is between 1:0.1 and 1:1.5; and an asphalt composition. A method for scavenging hydrogen sulfide from asphalt, the method providing a composition comprising a copper-carboxylic acid complex having a molar ratio of copper (Cu) to carboxylic acid of the copper-carboxylic acid complex is between 1:0.1 and 1:1.5; and adding the composition to an asphalt composition.

Disclosed is a polymetalloxane including a constituent unit represented by the following general formula (1), which stably exists in a transparent and uniform state in a solution and can form a homogeneous cured film: ##STR00001##
wherein R.sup.1 is an organic group and at least one of R.sup.1 is an (R.sup.3.sub.3SiO—) group, R.sup.3 is optionally selected from specific groups, R.sup.2 is optionally selected from specific groups, when plural R.sup.1, R.sup.2, and R.sup.3 exist, they may be the same or different, M represents a specific metal atom, m is an integer indicating a valence of a metal atom M, and a is an integer of 1 to (m−2).

Disclosed is a polymetalloxane including a constituent unit represented by the following general formula (1), which stably exists in a transparent and uniform state in a solution and can form a homogeneous cured film: ##STR00001##
wherein R.sup.1 is an organic group and at least one of R.sup.1 is an (R.sup.3.sub.3SiO—) group, R.sup.3 is optionally selected from specific groups, R.sup.2 is optionally selected from specific groups, when plural R.sup.1, R.sup.2, and R.sup.3 exist, they may be the same or different, M represents a specific metal atom, m is an integer indicating a valence of a metal atom M, and a is an integer of 1 to (m−2).

Provided is a manufacturing method of a graphene-based liquid crystal fiber including: polymerizing a first aromatic monomer on a graphene-based compound to prepare a graphene composite in which a first aromatic polymer is surface-polymerized on the graphene-based compound; wet-spinning the graphene composite to manufacture a hydrogel fiber; and polymerizing a second aromatic monomer on the hydrogel fiber to fill pores of the hydrogel fiber with a second aromatic polymer.

Provided is a manufacturing method of a graphene-based liquid crystal fiber including: polymerizing a first aromatic monomer on a graphene-based compound to prepare a graphene composite in which a first aromatic polymer is surface-polymerized on the graphene-based compound; wet-spinning the graphene composite to manufacture a hydrogel fiber; and polymerizing a second aromatic monomer on the hydrogel fiber to fill pores of the hydrogel fiber with a second aromatic polymer.