The purpose of the present invention is to provide: a composite pigment, and production method thereof, which can suppress luster of a coating film by modifying an inorganic coloring pigment, and which can be used in various applications such as low-gloss (luster reduction effect) pigments and matte pigments; a paint composition which can achieve both an excellent coating film texture and also the property of having low gloss and luster even when added to a coating film; and a coating film. In this composite pigment, the inorganic coloring pigment is fixed by an inorganic compound, and a plurality of particles of the inorganic coloring pigment are aggregated into granular form through the inorganic compound.

A surface-treated aggregated boron nitride powder is prepared by using the boron nitride powder as the raw material, adding an oxidizer to the boron nitride aggregated grains, wet-pulverizing or wet-crushing the grains for surface modification treatment of the particles and allowing reaction of the particles with a metal coupling agent. The surface-treated boron nitride aggregated grains are formed by aggregation of hexagonal h-BN primary particles; (B) have any one or more of Si, Ti, Zr, Ce, Al, Mg, Ge, Ga, and V in an amount of 0.1 atm % or more and 3.0 atm % or less in its composition on the surface of 10 nm; (C) have a crushing strength of 5 MPa or more; and (D) have an average particle diameter of 20 μm or more and 100 μm or less.

There is provided a modified zirconium phosphate tungstate which effectively suppresses the elution of phosphorus ions even when it contacts with water, can develop the performance excellent as a negative thermal expansion material, and can be dispersed in a polymer compound such as a resin, and use of which enables a low-thermal expansive material containing a negative thermal expansion filler to be well produced. The surface of a zirconium phosphate tungstate particle is coated with an inorganic compound containing one or two or more elements (M) selected from Zn, Si, Al, Ba, Ca, Mg, Ti, V, Sn, Co, Fe and Zr. The BET specific surface area of the zirconium phosphate tungstate particle is preferably 0.1 m.sup.2/g to 50 m.sup.2/g.

There is provided a modified zirconium phosphate tungstate which effectively suppresses the elution of phosphorus ions even when it contacts with water, can develop the performance excellent as a negative thermal expansion material, and can be dispersed in a polymer compound such as a resin, and use of which enables a low-thermal expansive material containing a negative thermal expansion filler to be well produced. The surface of a zirconium phosphate tungstate particle is coated with an inorganic compound containing one or two or more elements (M) selected from Zn, Si, Al, Ba, Ca, Mg, Ti, V, Sn, Co, Fe and Zr. The BET specific surface area of the zirconium phosphate tungstate particle is preferably 0.1 m.sup.2/g to 50 m.sup.2/g.

A surface-treated aggregated boron nitride powder is prepared by using the boron nitride powder as the raw material, adding an oxidizer to the boron nitride aggregated grains, wet-pulverizing or wet-crushing the grains for surface modification treatment of the particles and allowing reaction of the particles with a metal coupling agent. The surface-treated boron nitride aggregated grains are formed by aggregation of hexagonal h-BN primary particles; (B) have any one or more of Si, Ti, Zr, Ce, Al, Mg, Ge, Ga, and V in an amount of 0.1 atm % or more and 3.0 atm % or less in its composition on the surface of 10 nm; (C) have a crushing strength of 5 MPa or more; and (D) have an average particle diameter of 20 μm or more and 100 μm or less.

Disclosed in certain embodiments is a method of preparing structural colorants comprising photonic particles, the method comprising varying the calcination temperature in the process to enable the tuning of pore size to obtain a wide variety of possible colors.

Disclosed in certain embodiments is a composition comprising a structural colorant comprising photonic particles comprising a metal oxide and a transition metal, the molar ratio of transition metal to metal oxide being less than about 2:1.

An article includes a reflector having a first surface, a second surface opposite the first surface, and a third surface; and a first selective light modulator layer external to the first surface of the reflector; wherein the third surface of the reflector is open. A method of making an article is also disclosed.

The present invention concerns a process for the preparation of flocculated filler particles, wherein at least two aqueous suspensions of at least one filler material and at least one flocculating additive are combined.

The present invention concerns a process for the preparation of flocculated filler particles, wherein at least two aqueous suspensions of at least one filler material and at least one flocculating additive are combined.