A compound of formula (I) ##STR00001##
wherein R.sup.1 is hydrogen or an organic radical of 1 to 100 carbon atoms, R.sup.2, R.sup.3 are independently hydrogen or an organic radical of 1 to 100 carbons, Z is a single bond or a divalent organic group of 1 to 100 carbons, A is an (n+m)-valent organic group of 1 to 1 000 000 carbons, X is a single bond or a divalent organic group of 1 to 40 carbons, n is an integer from 1 to 1000, m is 0, 1, or 2, the sum of n+m being an integer from 2 to 1002. Such compounds are obtainable from specific 4-oxy-but-2-yn-1-ol derivatives, or used as intermediate(s), crosslinker(s), or monomer(s) in polymerization or oligomerization reactions, or for two-component compositions having such compound(s) and multifunctional hardener(s). Such compound(s) may be used to prepare polyunsaturated compounds, by reaction with an (oligo/poly)-functional nucleophile, or polymers.

A compound of formula (I) ##STR00001##
wherein R.sup.1 is hydrogen or an organic radical of 1 to 100 carbon atoms, R.sup.2, R.sup.3 are independently hydrogen or an organic radical of 1 to 100 carbons, Z is a single bond or a divalent organic group of 1 to 100 carbons, A is an (n+m)-valent organic group of 1 to 1 000 000 carbons, X is a single bond or a divalent organic group of 1 to 40 carbons, n is an integer from 1 to 1000, m is 0, 1, or 2, the sum of n+m being an integer from 2 to 1002. Such compounds are obtainable from specific 4-oxy-but-2-yn-1-ol derivatives, or used as intermediate(s), crosslinker(s), or monomer(s) in polymerization or oligomerization reactions, or for two-component compositions having such compound(s) and multifunctional hardener(s). Such compound(s) may be used to prepare polyunsaturated compounds, by reaction with an (oligo/poly)-functional nucleophile, or polymers.

A fluorine-containing copolymer composition includes repeating units derived from a fluorine-containing monomer represented by Formula (I) and from a monomer having at least two polymerizable groups, in which the latter is 3% by mass or more with respect to a total mass of the fluorine-containing copolymer, and the former is 15% by mass or more with respect to a total solid content in the composition, in the Formula (I), R.sup.1 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R.sup.2 represents a group having at least one fluorine atom; and L.sub.1 represents a divalent linking group including at least one selected from the group consisting of —O—, —(C═O)O—, —O(C═O)—, —(C═O)NH—, —NH(C═O)—, a divalent aromatic group which may have a substituent, a divalent aliphatic chain group which may have a substituent, and a divalent aliphatic cyclic group which may have a substituent.

A fluorine-containing copolymer composition includes repeating units derived from a fluorine-containing monomer represented by Formula (I) and from a monomer having at least two polymerizable groups, in which the latter is 3% by mass or more with respect to a total mass of the fluorine-containing copolymer, and the former is 15% by mass or more with respect to a total solid content in the composition, in the Formula (I), R.sup.1 represents a hydrogen atom or an alkyl group having 1 to 20 carbon atoms; R.sup.2 represents a group having at least one fluorine atom; and L.sub.1 represents a divalent linking group including at least one selected from the group consisting of —O—, —(C═O)O—, —O(C═O)—, —(C═O)NH—, —NH(C═O)—, a divalent aromatic group which may have a substituent, a divalent aliphatic chain group which may have a substituent, and a divalent aliphatic cyclic group which may have a substituent.

A water-based acrylic pressure-sensitive adhesive for clothing and a preparation method thereof are provided. Since a specific internal crosslinking agent is used in a predetermined range during polymerization of an acrylic emulsion resin, a glass transition temperature and an internal crosslinking degree may be controlled while maintaining physical properties of the resin equal to those of the existing adhesives, and thus a residual ratio of the pressure-sensitive adhesive may be greatly reduced at the time of removing the pressure-sensitive adhesive from a substrate such as a fabric for clothing, etc.

A water-based acrylic pressure-sensitive adhesive for clothing and a preparation method thereof are provided. Since a specific internal crosslinking agent is used in a predetermined range during polymerization of an acrylic emulsion resin, a glass transition temperature and an internal crosslinking degree may be controlled while maintaining physical properties of the resin equal to those of the existing adhesives, and thus a residual ratio of the pressure-sensitive adhesive may be greatly reduced at the time of removing the pressure-sensitive adhesive from a substrate such as a fabric for clothing, etc.

A water-based acrylic pressure-sensitive adhesive for clothing and a preparation method thereof are provided. Since a specific internal crosslinking agent is used in a predetermined range during polymerization of an acrylic emulsion resin, a glass transition temperature and an internal crosslinking degree may be controlled while maintaining physical properties of the resin equal to those of the existing adhesives, and thus a residual ratio of the pressure-sensitive adhesive may be greatly reduced at the time of removing the pressure-sensitive adhesive from a substrate such as a fabric for clothing, etc.

The invention relates to a composition that is liquid at room temperature, can be fixed by radiation and cured by heat, comprising the following components: (A) an at least bifunctional epoxy-containing compound; (B) an at least bifunctional thiol; (C) a radiation-curable compound; (D) a photoinitiator; (E) a stabilizer blend that contains at least one sulfonyl isocyanate and at least one acid; and (F) a nitrogen compound as an accelerator. The compositions are processable at room temperature over a period of at least 24 h and can be completely cured even at low temperatures.

The invention relates to a composition that is liquid at room temperature, can be fixed by radiation and cured by heat, comprising the following components: (A) an at least bifunctional epoxy-containing compound; (B) an at least bifunctional thiol; (C) a radiation-curable compound; (D) a photoinitiator; (E) a stabilizer blend that contains at least one sulfonyl isocyanate and at least one acid; and (F) a nitrogen compound as an accelerator. The compositions are processable at room temperature over a period of at least 24 h and can be completely cured even at low temperatures.

An object of the present invention is to provide an adhesive composition having excellent adhesiveness and crack resistance. The present invention relates to a conductive adhesive composition comprising (a) a (meth)acrylic acid ester monomer, (b) a tackifier, (c) bismaleimide, and (d) a radical initiator, wherein a homopolymer of the (meth)acrylic acid ester monomer (a) has a glass transition temperature (T.sub.g) of 50° C. or lower, and the tackifier (b) has a Hazen unit colour number of 300 or less.