C09J135/00

Material for printed circuit board, metal laminate, methods for producing them, and method for producing printed circuit board
10844153 · 2020-11-24 · ·

A material having a fluorinated resin layer is subjected to heat treatment. The fluorinated resin layer is composed of a composition containing a fluorinated copolymer (a) having at least one type of functional group selected from a carbonyl group-containing group, a hydroxy group, an epoxy group and an isocyanate group, having a melting point of from 280 to 320 C. and a melt flow rate of at least 2 g/10 min measured at 372 C. under a load of 49 N. The heat treatment is carried out at a temperature of at least 250 C. and lower by at least 5 C. than the melting point of the fluorinated copolymer (a) so that the ratio of the melt flow rate of the fluorinated resin layer after the heat treatment to that before the heat treatment, and the melt flow rate of the fluorinated resin layer after the heat treatment, are respectively within specific ranges.

ADHESIVE COMPOSITION, ADHESIVE LAYER AND ADHESIVE SHEET

The present invention relates to an adhesive composition containing a base polymer, a water-absorbing material, and a moisture-curable component, wherein the moisture-curable component is contained in an unreacted state, an adhesive layer made from the adhesive composition, and an adhesive sheet including the adhesive layer.

ADHESIVE COMPOSITION, ADHESIVE LAYER AND ADHESIVE SHEET

The present invention relates to an adhesive composition containing a base polymer, a water-absorbing material, and a moisture-curable component, wherein the moisture-curable component is contained in an unreacted state, an adhesive layer made from the adhesive composition, and an adhesive sheet including the adhesive layer.

SILSESQUIOXANE DERIVATIVE HAVING RADICAL POLYMERIZABLE FUNCTIONAL GROUP, COMPOSITION THEREOF, AND CURED FILM HAVING LOW CURE SHRINKAGE
20190375896 · 2019-12-12 ·

Provided is a new compound which can provide a cured film obtained from a resin composition with low cure shrinkage while suppressing reduction of hardness (scratch resistance) thereof. A silsesquioxane derivative having a radically polymerizable functional group, which is represented by formula (1), (2) or (3). In the formulas (1) to (3), R.sup.1 is a group independently selected from alkyl having 1 to 45 carbons, cycloalkyl having 4 to 8 carbons, aryl having 6 to 14 carbons and arylalkyl having 7 to 24 carbons, R.sup.2 and R.sup.3 are a group independently selected from alkyl having 1 to 10 carbons, cyclopentyl, cyclohexyl and phenyl, and X is independently hydrogen or a monovalent organic group, in which at least one of X is a radically polymerizable functional group represented by formula (4).

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ADHESIVE COMPOSITION, ADHESIVE LAYER AND ADHESIVE SHEET

The present invention relates to an adhesive composition containing a base polymer and a moisture-curable component, wherein the base polymer contains a polymer having no functional group which reacts with the moisture-curable component, and a water content of the base polymer after storage at 25 C. and 50% RH for 24 hours is 0.1% by weight or less, and wherein the moisture-curable component is contained in an unreacted state, an adhesive layer made from the adhesive composition, and an adhesive sheet including the adhesive layer.

Two-Component Composition Based on Compounds With At Least Two Exo-Vinylene Cyclic Carbonate Units

The present invention provides a composition having two separate, reactive components that when mixed together form a reactive mixture that undergoes curing or hardening, said two-component sealant and/or adhesive composition comprising: i) in a first component, at least one compound (VCC) having two or more exo-vinylene cyclic carbonate units, wherein said exo-vinylene cyclic carbonate units are bonded to one another by means of at least one organic, siloxane-free linking group, wherein said linking group is not directly bonded to the exo-vinylene double bonds and linking groups formed by polymerization of (meth)acrylic monomers are excluded; and, ii) in a second component, at least one multifunctional hardener that has at least two functional groups (F) selected from the group consisting of primary amino groups, secondary amino groups, hydroxy groups, phosphine groups, phosphonate groups, and mercaptan groups,
wherein the compound (VCC) of said first component is characterized in that it has at least one acetal group in the linking group in the case that the compound has exactly two exo-vinylene cyclic carbonate units,

Two-Component Composition Based on Compounds With At Least Two Exo-Vinylene Cyclic Carbonate Units

The present invention provides a composition having two separate, reactive components that when mixed together form a reactive mixture that undergoes curing or hardening, said two-component sealant and/or adhesive composition comprising: i) in a first component, at least one compound (VCC) having two or more exo-vinylene cyclic carbonate units, wherein said exo-vinylene cyclic carbonate units are bonded to one another by means of at least one organic, siloxane-free linking group, wherein said linking group is not directly bonded to the exo-vinylene double bonds and linking groups formed by polymerization of (meth)acrylic monomers are excluded; and, ii) in a second component, at least one multifunctional hardener that has at least two functional groups (F) selected from the group consisting of primary amino groups, secondary amino groups, hydroxy groups, phosphine groups, phosphonate groups, and mercaptan groups,
wherein the compound (VCC) of said first component is characterized in that it has at least one acetal group in the linking group in the case that the compound has exactly two exo-vinylene cyclic carbonate units,

Curable polymeric materials and methods of using same

Polymeric materials are disclosed herein that include a Polymer A, a Polymer B, and an oxalate ester or reaction product thereof. Polymer A contains electrophilic reactive groups, and Polymer B contains nucleophilic groups. In certain embodiments, the polymeric materials are free-flowing liquids at 100% solids that can be used, for example, as topical skin adhesives.

Curable compound

Provided is a curable compound having a low melting temperature, having excellent workability as a result of having good solvent solubility, and being capable of forming a cured product having excellent heat resistance. The curable compound according to an embodiment of the present invention includes the following characteristics (a) to (e). (a) Number average molecular weight (calibrated with polystyrene standard): 1000 to 15000. (b) Proportion of a structure derived from an aromatic ring in the total amount of the curable compound: 50 wt. % or greater. (c) Solvent solubility at 25? C.: 1 g/100 g or greater. (d) Glass transition temperature: 280? C. or lower. (e) 5% Weight loss temperature (T.sub.d5) measured at a rate of temperature increase of 10? C./min (in nitrogen), for a cured product of the curable compound: 300? C. or higher.

CURABLE POLYMERIC MATERIALS AND METHODS OF USING SAME

Polymeric materials are disclosed herein that include a Polymer A, a Polymer B, and an oxalate ester or reaction product thereof. Polymer A contains electrophilic reactive groups, and Polymer B contains nucleophilic groups. In certain embodiments, the polymeric materials are free-flowing liquids at 100% solids that can be used, for example, as topical skin adhesives.