Powdered adhesives for making lignocellulosic composite products and methods for making same. The powdered adhesive can include a powdered phenol-aldehyde resin and a powdered kraft lignin. The powdered kraft lignin can contain less than 3 wt % of ash, as measured according to ASTM D2584-11. The powdered adhesive can contain less than 10 wt % of water.

Lignin-containing mixtures and methods for making and using same. The lignin-containing mixture can include one or more lignin materials and one or more phenol-aldehyde resins. The mixture can include less than 10 wt % of water.

Methods for making composite products are provided. In at least one specific embodiment, the method can include combining a plurality of lignocellulose substrates, a free radical precursor, and a polyphenolic material to produce a mixture. The polyphenolic material can be in a liquid form, a solid form, or both when combined to produce the mixture. The method can also include maintaining the mixture at a temperature of less than 60 C. for at least 10 minutes while retaining at least 11 wt % of the free radical precursor charged to the mixture. The mixture can also include heating the mixture comprising at least 11 wt % of the free radical precursors charged to the mixture to a temperature of at least 60 C. to about 300 C. to produce a composite product.

A method for making a composite product can include combining a plurality of lignocellulose substrates and a binder to produce a resinated furnish. The binder can be or include a polyphenolic compound, a free radical precursor, and an unsaturated compound having two or more unsaturated carbon-carbon bonds. At least one of the unsaturated carbon-carbon bonds is a pi-bond that is not conjugated with an aromatic moiety and is capable of free radical addition. The method can also include pressing the resinated furnish between at least two surfaces in a press, where at least one of the at least two surfaces can be a porous surface, and at least partially curing the binder in the resinated furnish to produce a composite product.

A method for preparing a lignin adhesive and a product thereof are provided. The method includes: treating a wood fiber raw material with a mixed solution; after the treatment, adding an organic solvent to perform a solid-liquid separation while stirring, subjecting an obtained liquid to a rotary evaporation to remove the organic solvent, and washing and drying the product to obtain the lignin adhesive. The method can remove a large amount of lignin from wood fiber raw materials at a low temperature, and in the process of lignin removal, the lignin adhesive is formed by the cross-linking reaction with the solvent in the system, realizing the separation of lignin and the formation of lignin adhesive simultaneously. And the method is simple, has low cost and high yield, and can realize the large-scale preparation of lignin adhesive and the efficient removal of lignin.

A polymer blend material comprising the following components: (i) a lignin component; (ii) a nitrile butadiene rubber component; and (iii) a filler component comprising ceramic particles and/or carbon particles having an average primary particle size of 1-100 nm, wherein component (iii) is present in an amount of 0.1-10 wt % by weight of components (i) and (ii); wherein component (i) is present in an amount of about 5 wt % to about 95 wt % by weight of components (i) and (ii), and wherein the blend material may optionally include a PAN-containing homopolymer or copolymer as an additional component. Methods for producing the polymer blend, molded forms thereof, and articles thereof, are also described. Methods for bonding surfaces together by use of the polymer blend are also described.

The present invention relates to a process for preparing a bonding resin, lignin in solid form or in the form of a dispersion in water is mixed with a crosslinker; and optionally one or more additives followed by addition of a basic solution. The bonding resin is useful for example in the manufacture of laminates, mineral wool insulation and wood products such as plywood, oriented strandboard (OSB), laminated veneer lumber (LVL), medium density fiberboards (MDF), high density fiberboards (HDF), parquet flooring, curved plywood, veneered particleboards, veneered MDF or particle boards, laminates or mineral wool insulation.

An aqueous binder composition for mineral fibers comprising one or more oxidized lignins and one or more modifiers.

An aqueous adhesive composition for lignocellulosic materials which comprises a component (i) in the form of one or more oxidized lignins, a component (ii) in the form of one or more cross-linkers, and a component (iii) in the form of one or more plasticizers.

A method for preparing a lignin adhesive and a product thereof are provided. The method includes: treating a wood fiber raw material with a mixed solution; after the treatment, adding an organic solvent to perform a solid-liquid separation while stirring, subjecting an obtained liquid to a rotary evaporation to remove the organic solvent, and washing and drying the product to obtain the lignin adhesive. The method can remove a large amount of lignin from wood fiber raw materials at a low temperature, and in the process of lignin removal, the lignin adhesive is formed by the cross-linking reaction with the solvent in the system, realizing the separation of lignin and the formation of lignin adhesive simultaneously. And the method is simple, has low cost and high yield, and can realize the large-scale preparation of lignin adhesive and the efficient removal of lignin.