Provided is a conversion process for an inferior oil, relating to the field of biomass utilization, energy and chemical industry. The conversion process is carried out in presence of a catalyst selected from the group consisting of an iron oxide compound, a desulfurization waste agent resulting from use of an iron oxide compound as desulfurizer, and a regeneration product of the desulfurization waste agent, under a controlled molar ratio of iron element to sulfur element. It is found that free radical condensation polymerization of inferior oil during cracking process can be blocked effectively by using carbonylation, and hydrogenation is achieved with active hydrogen produced from the conversion of CO and water. In the conversion process, inferior oil can be, directly converted, thereby increasing liquefaction yield and calorific value of the obtained oils. No large amount of waste water is generated after completion of the conversion.

An integrated process for the production of a useful liquid hydrocarbon product comprises: feeding a gasification zone with an oxygen-containing feed and a first carbonaceous feedstock comprising waste materials and/or biomass, gasifying the first carbonaceous feedstock in the gasification zone to produce first synthesis gas, partially oxidising the first synthesis gas in a partial oxidation zone to generate partially oxidised synthesis gas, combining at least a portion of the first synthesis gas and/or the partially oxidised synthesis gas and at least a portion of electrolysis hydrogen obtained from an electrolyser in an amount to achieve the desired hydrogen to carbon monoxide molar ratio of from about 1.5:1 to about 2.5:1, and to generate a blended synthesis gas, wherein the electrolyser operates using green electricity; and subjecting at least a portion of the blended synthesis gas to a conversion process effective to produce the liquid hydrocarbon product.

A system and method for treating flue gas of a boiler based on solar energy are provided, wherein a heat pump is connected with a heat collector via first and second valves, a carbon dioxide electrolysis chamber is connected with a flue gas pretreatment chamber and a power distribution control module for electrolyzing and reducing carbon dioxide, a gas phase separation chamber is connected with a gas phase outlet to separate a mixture, and discharge the separated gas phase products; a Fischer-Tropsch reaction chamber is connected with the gas phase separation chamber to pass the separated carbon monoxide and hydrogen into a flowing reaction cell, a liquid phase product separation chamber is connected with a liquid phase outlet to separate the liquid phase hydrocarbon fuel products, and separate and supplement electrolyte; an electrolyte cooling circulation chamber is connected with the liquid phase product separation chamber.

An abrupt interface electroreduction catalyst includes a porous gas diffusion layer and a catalyst layer providing a sharp reaction interface. The electroreduction catalyst can be used for converting CO.sub.2 into a target product such as ethylene. The porous gas diffusion layer can be hydrophobic and configured for contacting gas-phase CO.sub.2 while the catalyst layer is disposed on and covers a reaction interface side of the porous gas diffusion layer. The catalyst layer has another side contacting an electrolyte and can be hydrophilic, composed a metal such as Cu and is sufficiently thin to prevent diffusion limitations of the reactant in the electrolyte and enhance selectivity for the target product. The electroreduction catalyst can be made by vapor deposition methods and can be used for electrochemical production of ethylene in reaction system.

Process control parameters for production of hydrogen and FT products by steam/CO2 reforming include controlling steam reformer temperature, addition of steam, CO and optionally, biogas. Optimization of parameters have resulted in increased production of H.sub.2, removal of sulfur and halogen contaminants, and control of the H.sub.2/CO ratio for efficient generation of Fischer-Tropsch products.

A syngas generator is disclosed as an exothermic gas generator that can accommodate high combustion temperatures of a natural gas/oxygen flame. The generator consists of four sections: a heavily insulated combustion chamber, a catalyst chamber, a spray chamber, and a heat exchanger. These four sections may be arranged in series and tightly bolted together to form a gas-tight system. Natural gas, oxygen and steam are supplied to a burner at the inlet end of the combustion chamber. This mixture is ignited and the resulting hot process gas is then fed into a catalyst bed where it reacts with the steam and is converted to carbon monoxide and hydrogen (syngas). The syngas is fed to a Fischer-Tropsch unit to create liquid fuel.

Ammonia, methanol, Fischer Tropsch products, and derivatives thereof are made by using hydrogen and oxygen supplied from an electrolyzer that is at least partially powered by renewable power, resulting in green process and systems that produce green products disclosed herein. A process using biomass and renewable energy includes producing an unshifted syngas from biomass and oxygen in a gasification unit, introducing water into an electrolyzer to produce an oxygen product and a hydrogen product, and introducing the oxygen product to the gasification unit. The electrolyzer is powered by renewable energy, and the oxygen product supplies at least a portion of the oxygen to the gasification unit.

The present invention relates to a process for preparing liquid hydrocarbons by the Fischer-Tropsch process integrated into refineries, in particular comprising recycling streams from the steam reforming hydrogen production process as the feedstock for the Fischer-Tropsch process.

The present invention relates to a process for preparing liquid hydrocarbons by the Fischer-Tropsch process integrated into refineries, in particular comprising recycling streams from the steam reforming hydrogen production process as the feedstock for the Fischer-Tropsch process.

The present invention is generally directed to processes and systems for the purification and conversion of CO.sub.2 into low-carbon or zero-carbon high quality fuels and chemicals using renewable energy. In one aspect, the present invention provides a process for producing a stream comprising at least 90 mol % CO.sub.2. In certain cases, the CO.sub.2 stream is processed to make low carbon fuels and chemicals. In this process at least a portion of the CO.sub.2 is reacted with a stream comprising H.sub.2 in a Reverse Water Gas Shift (RWGS) reactor to produce a product stream that comprises CO.