The present invention relates to a method of deoxygenating tall oil pitch, yielding aliphatic and aromatic hydrocarbons. The invention even comprises turning the aliphates into polymerizable olefins by steam cracking, and turning the aromates into polymerizable terephthalic acid by oxygenation and, as necessary, rearrangement. The monomers can be used for the production of polymers of partially or completely biologic origin. According to the invention, tall oil pitch is first heated to turn it into liquid, which is then fed into a catalyst bed and catalytically deoxygenated with hydrogen. The deoxygenation catalyst is preferably a Ni—Mo catalyst and, in addition, a cracking catalyst can be used, such as an acidic zeolite catalyst. The deoxygenated product stream is cooled down so as to obtain a liquid, which is distilled for separation of the aliphatic and aromatic hydrocarbons for use in the production of the respective monomers and finally polymers.

There is provided a process for producing hydrocarbon material from a hydrocarbon material precursor which includes free fatty acid material, comprising: supplying a hydrocarbon material precursor-comprising feed material to a conversion zone, with effect that the hydrocarbon material precursor-comprising feed material is converted to a gaseous hydrocarbon material-comprising product; condensing a portion of the gaseous hydrocarbon material-comprising product such that a condensed hydrocarbon material-comprising product is obtained; and recycling the condensed hydrocarbon material-comprising product to the conversion zone as a reflux; wherein the condensing is effected in response to emplacement of the gaseous hydrocarbon material-comprising product in heat transfer communication with a heat sink disposed externally of the conversion zone.

There is provided a process for producing hydrocarbon material from a hydrocarbon material precursor which includes free fatty acid material, comprising: supplying a hydrocarbon material precursor-comprising feed material to a conversion zone, with effect that the hydrocarbon material precursor-comprising feed material is converted to a gaseous hydrocarbon material-comprising product; condensing a portion of the gaseous hydrocarbon material-comprising product such that a condensed hydrocarbon material-comprising product is obtained; and recycling the condensed hydrocarbon material-comprising product to the conversion zone as a reflux; wherein the condensing is effected in response to emplacement of the gaseous hydrocarbon material-comprising product in heat transfer communication with a heat sink disposed externally of the conversion zone.

Processes and systems for making recycle content hydrocarbons, including olefins, from recycled waste material. Recycle waste material may be pyrolyzed to form recycle content pyrolysis oil composition (r-pyoil), at least a portion of which may then be cracked to form a recycle content olefin composition (r-olefin). In some cases, a heavy fraction from the cracker effluent may be used to form a recycle content pyrolysis gasoline composition (r-pyrolysis gasoline).

A composition having a recycle content value is obtained by reacting a recycle content feedstock to make a recycle content alpha olefin or by deducting from a recycle inventory a recycle content value applied to an alpha olefin composition. At least a portion of the recycle content value in the feedstock or in an allotment obtained by an alpha olefin manufacturer has its origin in recycled waste and/or pyrolysis of recycled waste and/or in thermal steam cracking of recycle content pyoil.

A mixed ester composition having a recycle content value is obtained by reacting a recycle content feedstock to make a recycle content mixed ester or by deducting from a recycle inventory a recycle content value applied to a mixed ester composition. At least a portion of the recycle content value in the feedstock or in an allotment obtained by a mixed ester manufacturer has its origin in recycled waste and/or pyrolysis of recycled waste and/or in thermal steam cracking of recycle content pyoil.

A process of producing a hydrocracking product in a slurry hydrocracking reactor. A pyrolysis oil, a hydrocarbon feedstock, and a hydrocracking catalyst is provided. The pyrolysis oil is combined with the hydrocarbon feedstock and the hydrocracking catalyst, the pyrolysis oil being maintained at a temperature of less than 100° C. until the pyrolysis oil contacts both the hydrocarbon feedstock and the hydrocracking catalyst. The hydrocarbon feedstock and the pyrolysis oil are hydrocracked in the slurry hydrocracking reactor in the presence of the hydrocracking catalyst and hydrogen gas. A fuel precursor obtainable by the process.

The present disclosure relates to a process for manufacturing organic chemicals and/or distillate hydrocarbon fuels from waste textiles comprising cellulosic fibers, wherein the process includes providing waste textiles comprising cellulosic fibers, processing the waste textiles into an aqueous slurry of comminuted waste textiles, saccharification of the comminuted waste textiles into monomer sugars in the presence of a catalyst; and processing the monomer sugars into organic chemicals and/or distillate hydrocarbon fuels.

The present disclosure is directed to methods of producing zincoaluminosilicate structures with AEI, CHA, and GME topologies using organic structure directing agents (OSDAs), and the compositions and structures resulting from these methods.

A process for combined renewable 1-decene and renewable carboxylic diacid production from a fatty acid ester containing feedstock, wherein the feedstock is first subjected to metathesis reaction conditions, recovery of 1-decene and then to microbial oxidation to yield diacids in a fermentation broth. Diacids of unusual carbon chains lengths are thereby obtainable.