This disclosure relates to the production of chemicals and plastics using pyrolysis oil from the pyrolysis of plastic waste as a co-feedstock along with a petroleum-based or fossil fuel co-feed, or as a feedstock in the absence of a petroleum-based or fossil fuel co-feed. A mass balance accounting approach is employed to attribute the pounds of pyrolyzed plastic products derived from pyrolysis oil to any output stream of a given unit, which permits assigning circular product credit to product streams. In an aspect, the polymers and chemicals produced according to this disclosure can be certified under International Sustainability and Carbon Certification (ISCC) provisions as circular polymers and chemicals at any point along complex chemical reaction pathways.

The present invention relates to a sequential thermo-chemical treatment along with adsorption-based pre-treatment process for residual oils having a very high naphthenic acid content. First stage of the process is a thermal pre-treatment step which results into generation of hydrocarbon stream with a reduced naphthenic acid content due to high temperature. In second stage of pre-treatment, generated hydrocarbon stream from stage-1 is subjected to esterification reaction with alcohol, such as methanol, to further reduce the TAN of hydrocarbon stream. After recovery of alcohol from the reaction mixture, depending on TAN reduction required reaction mixture may be subjected to an adsorption stage, third stage pre-treatment, where an adsorbent mixture comprising of FCC spent catalyst is used to adsorb the TAN of feed hydrocarbon stream. The treated hydrocarbon stream is then co-processed with DCU feed stock for producing lighter hydrocarbons.

Provided is a method for preparing synthesis gas, and more particularly, a method for preparing synthesis gas including: supplying a cracked gas stream discharged from a cracking furnace of a naphtha cracking center (NCC) process to a gasoline fractionator, separating a side discharge stream from the gasoline fractionator using a first stripper, and separating a lower discharge stream from the gasoline fractionator using a second stripper, wherein a mixed oil stream of a PGO stream and a PFO stream formed by controlling a flow rate of each stream are used.

Systems and methods of production for consistently sized and shaped optically anisotropic mesophase pitch from vacuum residue, one method including supplying processed vacuum residue to an extruder; heating the processed vacuum residue throughout a horizontal profile of the extruder from an inlet to an outlet of the extruder; venting hydrocarbon off-gases from the extruder along the horizontal profile of the extruder from the inlet to the outlet of the extruder; and physically shaping the consistently sized and shaped mesophase pitch at the outlet of the extruder for production of carbon fibers.

A method is disclosed of producing hydrocarbons from a recycled or renewable organic material, wherein the recycled or renewable organic material contains from 5 to 30 wt-% oxygen as organic oxy-gen compounds and from 1 to 1000 ppm phosphorous as phosphorous compounds. Exemplary methods include (a) providing the recycled or renewable organic material (c) thermally cracking the recycled or renewable organic material thereby reducing the oxygen and phosphorous content of the recycled or renewable organic material to obtain (i) a vapor fraction containing a major part of volatiles, and (ii) a thermally cracked recycled or renewable organic material fraction containing less oxygen and less phosphorous than the recycled or renewable organic material provided in step (a); and (f) hydrotreating the thermally cracked recycled or renewable organic material fraction in a presence of a hydrotreating catalyst; to obtain hydrocarbons containing less than 1 wt % oxygen and less phosphorous than the recycled or re-newable organic material provided in step (a).

A method is disclosed of producing hydrocarbons from a recycled or renewable organic material, wherein the recycled or renewable organic material contains from 5 to 30 wt-% oxygen as organic oxy-gen compounds and from 1 to 1000 ppm phosphorous as phosphorous compounds. Exemplary methods include (a) providing the recycled or renewable organic material (c) thermally cracking the recycled or renewable organic material thereby reducing the oxygen and phosphorous content of the recycled or renewable organic material to obtain (i) a vapor fraction containing a major part of volatiles, and (ii) a thermally cracked recycled or renewable organic material fraction containing less oxygen and less phosphorous than the recycled or renewable organic material provided in step (a); and (f) hydrotreating the thermally cracked recycled or renewable organic material fraction in a presence of a hydrotreating catalyst; to obtain hydrocarbons containing less than 1 wt % oxygen and less phosphorous than the recycled or re-newable organic material provided in step (a).

Systems and methods are provided for integrated pyrolysis and gasification of a biomass feed, either as a separate feed or under co-processing conditions. The integrated pyrolysis and gasification can be performed using any convenient reactor configuration, such as fluidized coking reactor configuration or a fluid catalytic cracking reactor configuration. The biomass feed can initially by pyrolyzed to form liquid products, gas phase products, and char. The char can then be used as the input feed to gasification. In aspects where the biomass feed is co-processed, the biomass can be co-processed with a co-feed that is suitable for processing under fluidized coking conditions or other pyrolysis conditions, such as a conventional fluidized coking feedstock.

Provided is a method for preparing synthesis gas, and more particularly, a method for preparing synthesis gas including: supplying a pyrolysis fuel oil (PFO) stream including a PFO and a pyrolysis gas oil (PGO) stream including a PGO discharged from a naphtha cracking center (NCC) process to a distillation tower as a feed stream (S10); and supplying a lower discharge stream from the distillation tower to a combustion chamber for a gasification process to obtain synthesis gas (S20), wherein the PGO stream is supplied to an upper end of the distillation tower and the PFO stream is supplied to a lower end of the distillation tower.

A method for vaporizing liquid propane to be supplied as a raw material to a naphtha cracking ractor. The method comprises: decompressing liquid propane to lower a vaporization point and vaporize at least a portion of the liquid propane; utilizing vaporization heat, generated during vaporization of the portion of liquid propane, as a refrigerant; compressing the vaporized propane gas to increase pressure of the propane gas and produce compressed propane gas; and preheating the compressed propane gas. By using this method, it is possible to reduce pressure of liquid propane to a significantly lower pressure than the related art method so that all the vaporization latent heat or vaporization heat included in liquid propane may be utilized as a refrigerant, while also reducing heat energy consumed in a preheat process before it is supplied to the naphtha cracking reactor.

A method for vaporizing liquid propane to be supplied as a raw material to a naphtha cracking ractor. The method comprises: decompressing liquid propane to lower a vaporization point and vaporize at least a portion of the liquid propane; utilizing vaporization heat, generated during vaporization of the portion of liquid propane, as a refrigerant; compressing the vaporized propane gas to increase pressure of the propane gas and produce compressed propane gas; and preheating the compressed propane gas. By using this method, it is possible to reduce pressure of liquid propane to a significantly lower pressure than the related art method so that all the vaporization latent heat or vaporization heat included in liquid propane may be utilized as a refrigerant, while also reducing heat energy consumed in a preheat process before it is supplied to the naphtha cracking reactor.