A system for processing a renewable bio-based material comprising: a reactor, a feedstock substantially renewable and comprising triglycerides and free fatty acids, with hydrogen in the presence of a catalyst in a reactor to form a treated oil; a heat exchanger for receiving the treated oil from the reactor and reducing its temperature to a predetermined temperature; a high-pressure separator followed by a low-pressure separator; and (i) a distillation unit for passing the treated oil through to form green diesel and an adsorption unit for passing the green diesel through; or (ii) at least one distillation column to separate the treated oil into at least one component and an adsorption column for passing the at least one component through; wherein the reactor comprises a cooling function for controlling the temperature of the reactor; wherein the cooling function is an internal cooling function comprising adding a cooling substance into the reactor.

The invention provides a process to purify a gas stream by using an adsorbent bed and a secondary device to remove heavy hydrocarbons with a recycle stream then sent first to a vessel containing an amine solvent to remove acid gases including carbon dioxide and hydrogen sulfide and then in most embodiments of the invention sending the treated gas stream to a dehydration unit such as an adsorbent bed or to a triethylene glycol absorbent to remove water. The invention further provides improved integration of the process streams to allow for smaller amine solvent and dehydration units as compared to the prior art.

A process and device for reducing the environmental contaminants in a ISO 8217 compliant Feedstock Heavy Marine Fuel Oil, the process involving: mixing a quantity of the Feedstock Heavy Marine Fuel Oil with a quantity of Activating Gas mixture to give a feedstock mixture; contacting the feedstock mixture with one or more catalysts to form a Process Mixture from the feedstock mixture; separating the Product Heavy Marine Fuel Oil liquid components of the Process Mixture from the gaseous components and by-product hydrocarbon components of the Process Mixture and, discharging the Product Heavy Marine Fuel Oil. The Product Heavy Marine Fuel Oil is compliant with ISO 821 7 for residual marine fuel oils and has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05% wt. to 0.5% wt. The Product Heavy Marine Fuel Oil can be used as or as a blending stock for an ISO 8217 compliant, IMO MARPOL Annex VI (revised) compliant low sulfur or ultralow sulfur heavy marine fuel oil.

The present invention provides a method which can efficiently adsorb and remove ionic mercury and/or organic mercury contained in a hydrocarbon oil for a long period of time. The method involves bringing the hydrocarbon oil into contact with an adsorbent containing a layered silicate mineral having an interlayer charge of 0 or an interlayer charge of greater than 0 to 0.6 or less.

A process for treating a petroleum fraction and for efficiently absorbing an organic halogen compound from a fluid mixture of the organic halogen compound and an inorganic halogen compound derived from crude oil. Also disclosed is an improvement in absorption performance of a halogen-compound-absorbing material, thereby reducing the frequency with which the absorbing material is exchanged. The absorbing agent includes attapulgite (palygorskite) having high absorption performance with respect to organic halogen compounds. Also disclosed is an absorption column in which the aforementioned absorbing agent and a halogen-compound-absorbing agent, that includes zinc oxide, are disposed in series, thereby making it possible to raise the treatment performance with respect to a fluid that contains, in high concentrations, the organic halogen compound in addition to the inorganic halogen compound.

The present subject matter relates generally to methods for selectively saturating the unsaturated C.sub.2-C.sub.4. More specifically, the present subject matter relates to methods for saturating butadiene and butenes from a hydrocarbon stream before it is combined with a fresh feed and enters a reaction zone. Removing the unsaturates from the hydrocarbon stream before the hydrocarbon stream enters the reaction zone prevents the reactor internals from coking.

The present subject matter relates generally to methods for selectively saturating the unsaturated C.sub.2-C.sub.4. More specifically, the present subject matter relates to methods for saturating butadiene and butenes from a hydrocarbon stream before it is combined with a fresh feed and enters a reaction zone. Removing the unsaturates from the hydrocarbon stream before the hydrocarbon stream enters the reaction zone prevents the reactor internals from coking.

The present invention relates to the use of adsorbents comprising zinc oxide nanowires decorated with catalytically active metal particles for the removal of sulfur from hydrocarbon feedstocks, including the desulfurization of diesel fuels and the deep desulfurization of natural gas, and to the use of decorated zinc oxide nanowire adsorbents for the hydrogenation of naphthalene selectively to tetralin in the presence of sulfur compounds. The adsorbent comprises nickel metal particles or nickel-zinc alloy particles deposited on zinc oxide nanowires.

Materials and methods for mitigating the effects of halide species contained in process streams are provided. A halide-containing process stream can be contacted with mitigation materials comprising active metal oxides and a non-acidic high surface area carrier combined with a solid, porous substrate. The halide species in the process stream can be reacted with the mitigation material to produce neutralized halide salts and a process stream that is essentially halide-free. The neutralized salts can be attracted and retained on the solid, porous substrate.

Systems and methods for separating hydrocarbons on an internal combustion powered vehicle via one or more metal organic frameworks are disclosed. Systems and methods can further include utilizing separated hydrocarbons and exhaust to generate hydrogen gas for use as fuel. In one aspect, a method for separating hydrocarbons can include contacting a first component containing a first metal organic framework with a flow of hydrocarbons and separating hydrocarbons by size. In certain embodiments, the hydrocarbons can include alkanes.