An object of the invention is to provide a heat-resistant hexavalent chromium removal agent, which is capable of remaining in a leather or leather article for a long period of time and stably detoxifying hexavalent chromium over the long term even when a leather or leather article contains hexavalent chromium, and a leather or leather article, in which the hexavalent chromium content is less than 3 ppm. The leather or leather article of the present invention contains at least: an organic compound (A) having a structure shown in chemical formula (1) and hydroxyphenyl but not aldehyde and carboxyl, which organic compound has a property to reduce hexavalent chromium to trivalent chromium; and trivalent chromium, and the hexavalent chromium content determined in accordance with ISO 17075: 2008-02 is less than 3 ppm.

An object of the invention is to provide a heat-resistant hexavalent chromium removal agent, which is capable of remaining in a leather or leather article for a long period of time and stably detoxifying hexavalent chromium over the long term even when a leather or leather article contains hexavalent chromium, and a leather or leather article, in which the hexavalent chromium content is less than 3 ppm. The leather or leather article of the present invention contains at least: an organic compound (A) having a structure shown in chemical formula (1) and hydroxyphenyl but not aldehyde and carboxyl, which organic compound has a property to reduce hexavalent chromium to trivalent chromium; and trivalent chromium, and the hexavalent chromium content determined in accordance with ISO 17075: 2008-02 is less than 3 ppm.

The invention relates to a method for coating textiles and/or leather, comprising applying at least one polyurethane urea dissolved in a solvent or solvent mixture, wherein the solvent consists of one or more monohydroxy-functional alcohols, or a solvent mixture consisting of organic solvents, containing >80 wt. % of at least one monohydroxy-functional alcohol in relation to the total mass of the solvent mixture is used, and wherein the polyurethane urea is formed by: a) at least one araliphatic, aliphatic and/or cycloaliphatic diisocyanate; b) at least one polyether polyol having a number average molecular weight M.sub.n≧400 and ≦6000 g/mol and an average hydroxyl functionality of ≧1.5 and ≦4; c) at least one amino-functional compound having at least two isocyanate reactive amino groups; and optionally other components. The invention also relates to a textile or leather coating produced using this method and a dissolved polyurethane urea, and to the use of the polyurethane urea for coating substrates and for producing free films.

The present invention is a stretchable film of a cured product of a resin including: a polymer compound having a urethane bond in the main chain, a repeating unit containing a fluorine atom, and a repeating unit containing a silicon atom. The present invention provides a stretchable film that has excellent stretchability and strength, with the film surface having excellent water repellency, and a method for forming the same.

Provided is an ink jet liquid composition including an organic solvent, a bifunctional urethane (meth)acrylate oligomer having a weight-average molecular weight of 2,000 to 15,000, a photopolymerization initiator, and a vinyl chloride-vinyl acetate copolymer, in which a content of the organic solvent is 40% by mass or more and 90% by mass or less with respect to a total mass of the liquid composition. Also provided is an ink jet recording method using the ink jet liquid composition.

A manufacturing process of three-dimensional leather objects, including the following steps: applying a hardener additive on the flesh side of a piece of leather, positioning the flesh side of the piece of leather on a shape, introducing the shape with the piece of leather in a vacuum sack, applying rough vacuum in the vacuum sack, heating the vacuum sack with the shape and the piece of leather, and progressively applying vacuum during the heating step, stopping the vacuum pressure and cooling the vacuum sack with the shape and the piece of leather, opening the sack and extracting the shape with the piece of leather from the vacuum sack and removing the piece of leather from the shape in such a way that the piece of leather has the shape of a three-dimensional object.

A manufacturing process of three-dimensional leather objects, including the following steps: applying a hardener additive on the flesh side of a piece of leather, positioning the flesh side of the piece of leather on a shape, introducing the shape with the piece of leather in a vacuum sack, applying rough vacuum in the vacuum sack, heating the vacuum sack with the shape and the piece of leather, and progressively applying vacuum during the heating step, stopping the vacuum pressure and cooling the vacuum sack with the shape and the piece of leather, opening the sack and extracting the shape with the piece of leather from the vacuum sack and removing the piece of leather from the shape in such a way that the piece of leather has the shape of a three-dimensional object.

A tanning agent-free leather making method is provided. A raw hide is subjected to controllable dehydration with a molecular sieve-polar organic solvent composite dehydration media to achieve a dehydrated hide, and then a tanning agent-free leather is prepared by increasing the surface roughness of the dehydrated hide and reducing the surface energy of the dehydrated hide. The present disclosure does not use any metal or non-metal tanning agent, which is eco-friendly. The present disclosure breaks the balance of water distribution between the raw hide and the polar organic solvent, which realizes a multi-medium self-driven directional controllable dehydration of the raw hide, effectively solving the problems during dehydration of the raw hide only using polar organic solvent. The molecular sieve-polar organic solvent dehydration system is easy to recover and can be recycled for the controllable dehydration of the raw hide multiple times. Therefore, a brand-new clean leather making technology is provided.

Disclosed are a leather odor removal composition, a method of manufacturing leather with reduced odor using the same, and leather manufactured through the method. The method of reducing leather odor may include using a composition including a filler and a softening mixture.

Disclosed are a leather odor removal composition, a method of manufacturing leather with reduced odor using the same, and leather manufactured through the method. The method of reducing leather odor may include using a composition including a filler and a softening mixture.