The present invention provides a sintered body containing W and WC, having excellent hardness, strength, compactness, and corrosion resistance, without containing W.sub.2C, and capable of being used for the purpose of a cutting tool or a glass molding die, or a seal ring. There is provided a sintered body containing 4 to 50 vol % of tungsten metal as binder phases, 50 to 95 vol % of tungsten carbide (WC), and 0.5 to 5.0 vol % of tungsten oxide (WO.sub.2), in which the tungsten oxide (WO.sub.2) has an average grain size of 5 nm to 150 nm and is present in a sintered body structure at an average density of 5 to 20 particles/μm.sup.2.

A preparation method of cemented carbide with FeCoCu medium-entropy alloy as binding phase is provided. The preparation method includes: 1) preparing FeCoCu precursor powders by solution combustion synthesis; 2) preparing FeCoCu medium-entropy alloy powders by mechanical alloying; 3) evenly mixing the FeCoCu medium-entropy alloy powders with ultra-fine WC powders and a binder to obtain mixed powders and pressing the mixed powders into a shaped green body; 4) preparing a WC-FeCoCu cemented carbide by microwave sintering after removing the binder from the shaped green body. The preparation method reduces sintering temperature and time and obtains a new-type cemented carbide with fine grains, high hardness and good toughness while reducing the cost.

A solid-state additive manufacturing additive manufacturing system applicable to building up 3D structures, coating and functionalizing surfaces, joining structures, adding customized features to objects, compounding proprietary compositions and repairing various structures is disclosed. The solid-state additive manufacturing system enables deposition of different fillers, viz. metals, metal alloys, MMCs, polymers, plastics, composites, hybrids and gradient compositions, as well as controls the resulting deposit structures, e.g. specific nano-/micro-, gradient- and porous-material structures. The system accommodates various feeding-, spindle- and tool-designs for depositing different forms of filler materials, viz. rods, wires, granules, powders, powder-filled-tubes, scrap pieces or their combination, and a working platform with multiple access points. One or multiple motors, driving and monitoring units control the movement of the workpiece, spindle and tool and move the filler through the feeding system, which passageway is in communication with the passageways of the spindle and the tool.

A coated tool of the present disclosure may include a base and a coating layer covering at least a part of the base. The base may include a hard phase of a carbonitride including Ti and a binder phase including at least one of Co and Ni and has a thermal expansion coefficient at 25 to 1000° C. of 9.0×10.sup.−6/° C. or more. The coating layer may include a TiCN layer and an Al.sub.2O.sub.3 layer positioned on the TiCN layer. The TiCN layer may have a compressive stress of 250 to 500 MPa. The Al.sub.2O.sub.3 layer may have a thickness of 2 μm or more and a compressive stress of 450 MPa or more, and the value of the compressive stress is greater than the compressive stress of the TiCN layer.

The invention relates to a decorative item made of a cermet material including by weight between 70 and 97% of a ceramic phase and between 3 and 30% of a metal binder phase, the metal binder comprising at least one element or its alloy selected from the list consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, gold and silver, the ceramic phase including a nitride phase and optionally an oxide and/or oxynitride phase, said nitride phase being present in relation to the total weight of the cermet material in a percentage between 70 and 97% and said oxide and/or oxynitride phase in a percentage between 0 and 15%.

The present invention also relates to the method implemented to produce this item.

A process line tool of a cemented carbide comprising in wt %; about 2.9-11 Ni; about 0.1-2.5 Cr.sub.3C.sub.2; and about 0.1-1 Mo; and a balance of WC, with an average WC grain size less than or equal to 0.5 μm.

Systems and methods for making ceramic powders configured with consistent, tailored characteristics and/or properties are provided herein. In some embodiments a system for making ceramic powders, includes: a reactor body having a reaction chamber and configured with a heat source to provide a hot zone along the reaction chamber; a sweep gas inlet configured to direct a sweep gas into the reaction chamber and a sweep gas outlet configured to direct an exhaust gas from the reaction chamber; a plurality of containers, within the reactor body, configured to retain at least one preform, wherein each container is configured to permit the sweep gas to flow therethrough, wherein the preform is configured to permit the sweep gas to flow there through, such that the precursor mixture is reacted in the hot zone to form a ceramic powder product having uniform properties.

Systems and methods for making ceramic powders configured with consistent, tailored characteristics and/or properties are provided herein. In some embodiments a system for making ceramic powders, includes: a reactor body having a reaction chamber and configured with a heat source to provide a hot zone along the reaction chamber; a sweep gas inlet configured to direct a sweep gas into the reaction chamber and a sweep gas outlet configured to direct an exhaust gas from the reaction chamber; a plurality of containers, within the reactor body, configured to retain at least one preform, wherein each container is configured to permit the sweep gas to flow therethrough, wherein the preform is configured to permit the sweep gas to flow there through, such that the precursor mixture is reacted in the hot zone to form a ceramic powder product having uniform properties.

A sintered friction material, in which a content of a copper component is 0.5 mass % or less, is provided. The sintered friction material includes a titanate and a metal material other than copper, as a matrix. A content of the metal material other than copper is 10.0 volume % to 34.0 volume %. A method for manufacturing a sintered friction material is provided. The method includes a mixing step of mixing raw materials containing a titanate and a metal material other than copper, a molding step of molding the raw materials mixed in the mixing step, and a sintering step of sintering, at 900° C. to 1300° C., a molded product molded in the molding step. In the sintered friction material, the titanate and the metal material other than copper form a matrix, and a content of the metal material other than copper is 10.0 volume % to 34.0 volume %.

A heterogeneous composite consisting of near-nano ceramic clusters dispersed within a ductile matrix. The composite is formed through the high temperature compaction of a starting powder consisting of a core of ceramic nanoparticles held together with metallic binder. This core is clad with a ductile metal such that when the final powder is consolidated, the ductile metal forms a tough, near-zero contiguity matrix. The material is consolidated using any means that will maintain its heterogeneous structure.