Methods and systems for preparing metallic alloys comprising volatile materials such as phosphorus suitable for bulk metallic glasses are described. The methods variously involve carrying out alloying at temperatures and pressures that minimize or counteract sublimation of the volatile species.

Methods and systems for preparing metallic alloys comprising volatile materials such as phosphorus suitable for bulk metallic glasses are described. The methods variously involve carrying out alloying at temperatures and pressures that minimize or counteract sublimation of the volatile species.

Metallic dental prostheses made of bulk-solidifying amorphous alloys wherein the dental prosthesis has an elastic strain limit of around 1.2% or more and methods of making such metallic dental prostheses are provided.

Metallic dental prostheses made of bulk-solidifying amorphous alloys wherein the dental prosthesis has an elastic strain limit of around 1.2% or more and methods of making such metallic dental prostheses are provided.

Systems and methods in accordance with embodiments of the invention implement bulk metallic glass-based macroscale compliant mechanisms. In one embodiment, a bulk metallic glass-based macroscale compliant mechanism includes: a flexible member that is strained during the normal operation of the compliant mechanism; where the flexible member has a thickness of 0.5 mm; where the flexible member comprises a bulk metallic glass-based material; and where the bulk metallic glass-based material can survive a fatigue test that includes 1000 cycles under a bending loading mode at an applied stress to ultimate strength ratio of 0.25.

Systems and methods in accordance with embodiments of the invention implement bulk metallic glass-based macroscale compliant mechanisms. In one embodiment, a bulk metallic glass-based macroscale compliant mechanism includes: a flexible member that is strained during the normal operation of the compliant mechanism; where the flexible member has a thickness of 0.5 mm; where the flexible member comprises a bulk metallic glass-based material; and where the bulk metallic glass-based material can survive a fatigue test that includes 1000 cycles under a bending loading mode at an applied stress to ultimate strength ratio of 0.25.

Disclosed is a method of brazing articles together to form at least one braze defined by complementarily curved faying surfaces on the articles, the faying surfaces each having at least one region of curvature comprising at least one point from which the surface curves in more than one direction, the method comprising the steps of: a) disposing between the complementarily curved faying surfaces at least one amorphous brazing alloy preform of complementary curvature at least in part to said at least one region of the complementarily curved faying surfaces to conform to the complementarily curved faying surfaces in said region; and b) heating the articles and at least one amorphous brazing alloy preform to a brazing temperature at which the amorphous brazing alloy flows and brazes. and brazing alloy preforms for use in such methods. Methods of forming an article comprising a curved surface from a sheet of an amorphous metal alloy are disclosed, by applying heat from a fluid to a sheet of the amorphous metal alloy to raise at least a portion of the sheet to a temperature above the glass transition temperature T.sub.g and below the crystallization temperature T.sub.x.

A metallic alloy, more particularly, a high-entropy alloy with a composite structure exhibits high strength and good ductility, and is used as a component material in electromagnetic, chemical, shipbuilding, machinery, and other applications, and in extreme environments, and the like.

An apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, and blow molding in a time frame of Less than 1 second.

An apparatus and method of uniformly heating, rheologically softening, and thermoplastically forming metallic glasses rapidly into a net shape using a rapid capacitor discharge forming (RCDF) tool are provided. The RCDF method utilizes the discharge of electrical energy stored in a capacitor to uniformly and rapidly heat a sample or charge of metallic glass alloy to a predetermined “process temperature” between the glass transition temperature of the amorphous material and the equilibrium melting point of the alloy in a time scale of several milliseconds or less. Once the sample is uniformly heated such that the entire sample block has a sufficiently low process viscosity it may be shaped into high quality amorphous bulk articles via any number of techniques including, for example, injection molding, dynamic forging, stamp forging, and blow molding in a time frame of Less than 1 second.