An aluminum alloy material comprising a composition containing no less than 1.2 at % and no more than 6.5 at % of Fe, no less than 0.15 at % and no more than 5 at % of at least one first element selected from the group consisting of Nd, W, and Sc, and no less than 0.005 at % and no more than 2 at % of at least one second element selected from the group consisting of C and B, the balance being Al and inevitable impurities.

A continuous casting and rolling line for casting, rolling, and otherwise preparing metal strip can produce distributable metal strip without requiring cold rolling or the use of a solution heat treatment line. A metal strip can be continuously cast from a continuous casting device and coiled into a metal coil, optionally after being subjected to post-casting quenching. This intermediate coil can be stored until ready for hot rolling. The as-cast metal strip can undergo reheating prior to hot rolling, either during coil storage or immediately prior to hot rolling. The heated metal strip can be cooled to a rolling temperature and hot rolled through one or more roll stands. The rolled metal strip can optionally be reheated and quenched prior to coiling for delivery. This final coiled metal strip can be of the desired gauge and have the desired physical characteristics for distribution to a manufacturing facility.

An aluminum alloy according to the present invention includes 1.2% by mass to 4.0% by mass of copper, 4.0% by mass to 14.0% by mass of zinc, 0.5% by mass to 4.0% by mass of magnesium, 0.01% or less of silicon, and 0.01% or less of iron, with the balance containing aluminum and inevitable impurities, and has an average equivalent circle crystal grain size of 500 nm or less.

A method for producing an aluminum alloy extrusion includes: conducting extrusion processing using a casted billet of an aluminum alloy containing 6.0 to 7.0% by mass of Zn, 1.5 to 2.0% by mass of Mg, 0.20 to 1.50% by mass of Cu, 0.10 to 0.25% by mass of Zr, 0.005 to 0.05% by mass of Ti, 0.15 to 0.35% by mass of Mn, 0.25% by mass or less of Sr, content of Mn and Zr and Sr being 0.10 to 0.50% by mass, with the balance being Al and inevitable impurities to obtain an aluminum alloy extrusion; cooling the extrusion to 100° C. or less at a cooling rate of 50 to 750° C./min immediately after the extrusion processing; and then conducting an aging treatment which is performed in one-stage or two-stage and a heat treatment which is performed at higher temperature for a shorter time than the aging treatment.

The present invention relates to a spiral spring for a balance wheel made of an alloy of niobium and titanium with an essentially single-phase structure, and the method of manufacture thereof which comprises: a step of producing a blank in a niobium-based alloy consisting of: niobium: balance to 100 wt %, titanium: between 40 and 49 wt %, traces of elements selected from the group consisting of O, H, C, Fe, Ta, N, Ni, Si, Cu, Al, between 0 and 1600 ppm by weight individually, and cumulatively less than 0.3 wt %, a step of type β hardening of said blank at a given diameter, in such a way that the titanium of the niobium-based alloy is essentially in the form of a solid solution with niobium in β phase, the content of titanium in α phase being less than or equal to 10 vol %, at least one deformation step of said alloy alternating with at least one step of heat treatment, the number of steps of heat treatment and of deformation being limited so that the niobium-based alloy obtained retains a structure in which the titanium of the niobium-based alloy is essentially in the form of a solid solution with niobium in β phase, the content of titanium in α phase being less than or equal to 10 vol % and it has an elastic limit greater than or equal to 600 MPa and an elastic modulus less than or equal to 100 GPa, a step of winding to form the spiral spring being carried out before the last heat treatment step.

The present invention relates to a spiral spring for a balance wheel made of an alloy of niobium and titanium with an essentially single-phase structure, and the method of manufacture thereof which comprises: a step of producing a blank in a niobium-based alloy consisting of: niobium: balance to 100 wt %, titanium: between 40 and 49 wt %, traces of elements selected from the group consisting of O, H, C, Fe, Ta, N, Ni, Si, Cu, Al, between 0 and 1600 ppm by weight individually, and cumulatively less than 0.3 wt %, a step of type β hardening of said blank at a given diameter, in such a way that the titanium of the niobium-based alloy is essentially in the form of a solid solution with niobium in β phase, the content of titanium in α phase being less than or equal to 10 vol %, at least one deformation step of said alloy alternating with at least one step of heat treatment, the number of steps of heat treatment and of deformation being limited so that the niobium-based alloy obtained retains a structure in which the titanium of the niobium-based alloy is essentially in the form of a solid solution with niobium in β phase, the content of titanium in α phase being less than or equal to 10 vol % and it has an elastic limit greater than or equal to 600 MPa and an elastic modulus less than or equal to 100 GPa, a step of winding to form the spiral spring being carried out before the last heat treatment step.

An object is to predict a microstructure of Al in an industrial process more accurately than conventional techniques. In an information processor (1), an inter-step information integration section supplies a PC(i) and an MS(i, 0) to each i-th step calculating section included in a step calculating section. Each i-th step calculating section supplies an MS(i, t) and a TMP(i, t) to a microstructure calculating section and thereby causes the microstructure calculating section to find an MS(i, tfi), and supplies the MS(i, tfi) to the inter-step information integration section (11). The inter-step information integration section (11) sets, as an MS(i+1, 0), the MS(i, tfi) received from the i-th step calculating section.

The present invention relates to a spiral spring for a balance wheel made of an alloy of niobium and titanium with an essentially single-phase structure, and the method of manufacture thereof which comprises: a step of producing a blank in a niobium-based alloy consisting of: niobium: balance to 100 wt %, titanium: between 40 and 49 wt %, traces of elements selected from the group consisting of O, H, C, Fe, Ta, N, Ni, Si, Cu, Al, between 0 and 1600 ppm by weight individually, and cumulatively less than 0.3 wt %, a step of type β hardening of said blank at a given diameter, in such a way that the titanium of the niobium-based alloy is essentially in the form of a solid solution with niobium in β phase, the content of titanium in α phase being less than or equal to 10 vol %, at least one deformation step of said alloy alternating with at least one step of heat treatment, the number of steps of heat treatment and of deformation being limited so that the niobium-based alloy obtained retains a structure in which the titanium of the niobium-based alloy is essentially in the form of a solid solution with niobium in β phase, the content of titanium in α phase being less than or equal to 10 vol % and it has an elastic limit greater than or equal to 600 MPa and an elastic modulus less than or equal to 100 GPa, a step of winding to form the spiral spring being carried out before the last heat treatment step.

The present invention relates to a spiral spring for a balance wheel made of an alloy of niobium and titanium with an essentially single-phase structure, and the method of manufacture thereof which comprises: a step of producing a blank in a niobium-based alloy consisting of: niobium: balance to 100 wt %, titanium: between 40 and 49 wt %, traces of elements selected from the group consisting of O, H, C, Fe, Ta, N, Ni, Si, Cu, Al, between 0 and 1600 ppm by weight individually, and cumulatively less than 0.3 wt %, a step of type β hardening of said blank at a given diameter, in such a way that the titanium of the niobium-based alloy is essentially in the form of a solid solution with niobium in β phase, the content of titanium in α phase being less than or equal to 10 vol %, at least one deformation step of said alloy alternating with at least one step of heat treatment, the number of steps of heat treatment and of deformation being limited so that the niobium-based alloy obtained retains a structure in which the titanium of the niobium-based alloy is essentially in the form of a solid solution with niobium in β phase, the content of titanium in α phase being less than or equal to 10 vol % and it has an elastic limit greater than or equal to 600 MPa and an elastic modulus less than or equal to 100 GPa, a step of winding to form the spiral spring being carried out before the last heat treatment step.

A nickel-titanium alloy with an average grain size of between 0.2 and 10 microns and a recoverable strain of greater than 9% is disclosed herein, in which the alloy is formed using a method which involves applying a shape set heat treatment to the nickel-titanium alloy. The heat treatment includes applying heat at a temperature between 225° C. and 350° C. for a period of time between 20 and 240 minutes.